Home About us Contact
|
Home About us Contact | ||
|
|
||
Master Curve (master + curve)
Selected AbstractsMaster curve and time,temperature,transformation cure diagram of lignin,phenolic and phenolic resol resinsJOURNAL OF APPLIED POLYMER SCIENCE, Issue 5 2007M. V. Alonso Abstract The aim of this work is to generate both a master curve of resol resins based on the time,temperature superposition principle and their TTT cure diagrams. The samples used for this purpose were lignin,phenolic and phenol,formaldehyde resol resins. A TMA technique was employed to study the gelation of resol resins. In addition, a DSC technique was employed to determine the kinetic parameters through the Ozawa method, which allowed us to obtain isoconversional curves from the data fit to the Arrhenius expression. Establishing the relationship between the glass-transition temperature and curing degree allowed the determination of the vitrification lines of the resol resins. Thus, using the experimental data obtained by TMA and DSC, we generated a TTT cure diagram for each of resins studied. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 103: 3362,3369, 2007 [source] Response of saturated porous media to cyclic thermal loadingINTERNATIONAL JOURNAL FOR NUMERICAL AND ANALYTICAL METHODS IN GEOMECHANICS, Issue 11 2003E. Blond Abstract The response of a semi-infinite saturated porous medium subjected to a harmonic thermal loading on its free face is studied herein. The pressure diffusion equation that governs the fluctuation of the interstitial pressure is established. It allows us to obtain prevalent parameters, i.e. the thermal and fluid mass diffusivities and the coefficient of relative bulk variation. Closed-form solutions of the maximum fluid pressure Pmax and its location xcr are derived. It is shown that the location xcr of Pmax is localized and depends on the diffusivity ratio and the frequency of the thermal loading while the magnitude of Pmax depends on the diffusivity ratio and the thermal amplitude. Master curves for xcr and Pmax versus diffusivity ratio are built. It follows that three regimes can be distinguished: namely, thin spalling, thick spalling or in-depth cracking and no cracking. Copyright © 2003 John Wiley & Sons, Ltd. [source] The eigenvalues of isolated bridges with transverse restraints at the end abutmentsEARTHQUAKE ENGINEERING AND STRUCTURAL DYNAMICS, Issue 8 2010Nicos Makris Abstract This paper examines the eigenvalues of multi-span seismically isolated bridges in which the transverse displacement of the deck at the end abutments is restricted. With this constraint the deck is fully isolated along the longitudinal direction, whereas along the transverse direction the deck is a simple-supported beam at the end abutments which enjoys concentrated restoring forces from the isolation bearings at the center piers. For moderate long bridges, the first natural period of the bridge is the first longitudinal period, while the first transverse period is the second period, given that the flexural rigidity of the deck along the transverse direction shortens the isolation period offered by the bearings in that direction. This paper shows that for isolated bridges longer than a certain critical length, the first transverse period becomes longer than the first longitudinal period despite the presence of the flexural rigidity of the deck. This critical length depends on whether the bridge is isolated on elastomeric bearings or on spherical sliding bearings. This result is also predicted with established commercially available numerical codes only when several additional nodes are added along the beam elements which are modeling the deck in-between the bridge piers. On the other hand, this result cannot be captured with the limiting idealization of a beam on continuous distributed springs (beam on Wrinkler foundation),a finding that has practical significance in design and system identification studies. Finally, the paper shows that the normalized transverse eigenperiods of any finite-span deck are self-similar solutions that can be represented by a single master curve and are independent of the longitudinal isolation period or on whether the deck is supported on elastomeric or spherical sliding bearings. Copyright © 2009 John Wiley & Sons, Ltd. [source] Dimensional analysis of the earthquake-induced pounding between adjacent structuresEARTHQUAKE ENGINEERING AND STRUCTURAL DYNAMICS, Issue 7 2009Elias Dimitrakopoulos Abstract In this paper the dynamic response of two and three pounding oscillators subjected to pulse-type excitations is revisited with dimensional analysis. Using Buckingham's ,-theorem the number of variables that govern the response of the system is reduced by three. When the response is presented in the dimensionless ,-terms remarkable order emerges. It is shown that regardless of the acceleration level and duration of the pulse all response spectra become self-similar and follow a single master curve. This is true despite the realization of finite duration contacts with increasing durations as the excitation level increases. All physically realizable contacts (impacts, continuous contacts, and detachments) are captured via a linear complementarity approach. The study confirms the existence of three spectral regions. The response of the most flexible among the two oscillators amplifies in the low range of the frequency spectrum (flexible structures); whereas, the response of the most stiff among the two oscillators amplifies at the upper range of the frequency spectrum (stiff structures). Most importantly, the study shows that pounding structures such as colliding buildings or interacting bridge segments may be most vulnerable for excitations with frequencies very different from their natural eigenfrequencies. Finally, by applying the concept of intermediate asymptotics, the study unveils that the dimensionless response of two pounding oscillators follows a scaling law with respect to the mass ratio, or in mathematical terms, that the response exhibits an incomplete self-similarity or self-similarity of the second kind with respect to the mass ratio. Copyright © 2008 John Wiley & Sons, Ltd. [source] Master curve and time,temperature,transformation cure diagram of lignin,phenolic and phenolic resol resinsJOURNAL OF APPLIED POLYMER SCIENCE, Issue 5 2007M. V. Alonso Abstract The aim of this work is to generate both a master curve of resol resins based on the time,temperature superposition principle and their TTT cure diagrams. The samples used for this purpose were lignin,phenolic and phenol,formaldehyde resol resins. A TMA technique was employed to study the gelation of resol resins. In addition, a DSC technique was employed to determine the kinetic parameters through the Ozawa method, which allowed us to obtain isoconversional curves from the data fit to the Arrhenius expression. Establishing the relationship between the glass-transition temperature and curing degree allowed the determination of the vitrification lines of the resol resins. Thus, using the experimental data obtained by TMA and DSC, we generated a TTT cure diagram for each of resins studied. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 103: 3362,3369, 2007 [source] Boson Peak, Elastic Properties, and Rigidification Induced by the Substitution of Nitrogen for Oxygen in Oxynitride GlassesJOURNAL OF THE AMERICAN CERAMIC SOCIETY, Issue 10 2010Nicolas F. Richet The effects of the substitution of nitrogen for oxygen on the heat capacity and vibrational entropy of three yttrium aluminosilicate glasses with 0, 3.4, and 7.4 mol% Si3N4 have been investigated from 10 to 300 K. The partial molar heat capacity and entropy of Si3N4 calculated from these and previous measurements indicate stronger average bonding than for SiO2 units, whereas the values derived for Y2O3 are consistent with the dual network modifying and Al3+ charge-compensating role of yttrium. The low-frequency part of the vibrational densities of states g(,) and the boson peaks g(,)/,2 derived from the inversion of the heat capacities indicate that nitrogen rigidifies the TO4 (T=Si, Al) tetrahedral network and that yttrium hampers the librational motion of the AlO4 tetrahedra, which contribute to the excitations associated with the boson peak. Along with data reported previously for borate and silicate glasses, these results for oxynitrides show a general monotonically increasing relation between transverse acoustic velocities and the temperature of the calorimetric boson peak. Illustrating the universal phenomenology of the boson peak, all these data collapse on the same master curve when plotted in a reduced form. [source] Effect of contact configuration on the durability and friction coefficient of pressure-sprayed MoS2 coatings under fretting conditions,LUBRICATION SCIENCE, Issue 5 2009D. B. Luo Abstract Fretting wear is often found at the contact surfaces of a tight assembly where small-amplitude oscillatory movement occurs, which can be the concealed origin of some enormous accidents. Employment of solid lubrication coatings, as one of effective measurements to palliate the fretting damage, has been widely acknowledged. The present work studied the fretting behaviour of a molybdenum disulphide coating on SUS 316 stainless steel substrate by a relatively cheap and easy-to-use process: pressure spraying. Two contact configurations (cylinder-on-flat and ball-on-flat) were used in the tests with different displacement amplitudes (from 5 to 75,µm) and normal loads (from 100 to 400,N for ball-on-flat and from 400 to 1000,N for cylinder-on-flat). The results showed that large displacement amplitude is adverse to friction coefficient and coating lifetime and that under a critical contact pressure, coating endurance is improved contact pressure increases. Contact configuration influences friction coefficient by changing contact area and distribution of contact pressure. One master curve of average dissipated energy per cycle in initial stable stage was obtained for two contact configurations, which can be employed to approximately predict coating lifetime. Copyright © 2009 John Wiley & Sons, Ltd. [source] Study of the Segmental Dynamics in Semi-Crystalline Poly(lactic acid) using Mechanical SpectroscopiesMACROMOLECULAR BIOSCIENCE, Issue 4 2005João F. Mano Abstract Summary: The glass transition of poly(L -lactic acid) (PLLA) occurs not far above typical service temperatures (room or body temperatures) which has consequences on the material properties during its use, such as damping or the occurrence of structural relaxation. This work aims at characterising the glass transition dynamics of a semi-crystalline PLLA using both dynamic mechanical analysis (DMA) and thermally stimulated recovery (TSR). The main viscoelastic parameters have been characterised at 1 Hz using DMA and the master curve obtained after isothermal experiments at different temperatures provided a full picture of the solid-state rheological behaviour throughout a wide frequency range. The activation energies calculated from the shift factors agree with the TSR ones, exhibiting a maximum near the Tg. Above the Tg, the results can be described with the WLF model. In the glassy state, the activation energy decreases with decreasing temperatures being always higher than the prediction of the Adam and Gibbs theory, at least down to temperatures 30,°C below the Tg. This suggests the existence of non-arrested degrees of freedom in the glassy state, being consistent with the existence of a significant degree of cooperativity in the TSR results. Temperature dependence of the apparent activation energy across the glass transition. [source] Humidity-Responsive Starch-Poly(methyl acrylate) FilmsMACROMOLECULAR CHEMISTRY AND PHYSICS, Issue 7 2008Julious L. Willett Abstract Blown films prepared from starch-poly(methyl acrylate) graft copolymers plasticized with urea and water display shrinkage at relative humidities greater than 50%. Shrinkage at relative humidities below approximately 75% is strongly correlated with the urea/starch weight ratio, which controls the equilibrium moisture content (MC) in the films. Above 75% relative humidity, film shrinkage is essentially independent of composition. At relative humidities below 90%, films plasticized with urea and water exhibited greater shrinkage than films plasticized with water only. A master curve can be constructed by shifting shrinkage data with respect to a reference relative humidity, indicating that relaxation processes in the starch phase control film shrinkage. This conclusion is confirmed by the fact that shrinkage data for a wide range of compositions and relative humidities fall on a single curve when plotted against MC. Polarized Fourier transform infrared spectroscopy indicated some loss of orientation in the starch phase during shrinkage. These results demonstrate that the hydrophilic nature of starch can be exploited to develop responsive polymers which display controllable shrinkages activated by increases in relative humidities. [source] Dynamic mechanical properties of extruded nylon,wood compositesPOLYMER COMPOSITES, Issue 4 2008Jianmin Chen Dynamic mechanical properties determine the potential end use of a newly developed extruded nylon,wood composite in under-the-hood automobile applications. In this article, the dynamic mechanical properties of extruded nylon,wood composites were characterized using a dynamic mechanical thermal analyzer (DMTA) to determine storage modulus, glass transition temperature (Tg), physical aging effects, long-term performance prediction, and comparisons to similar products. The storage modulus of the nylon,wood composite was found to be more temperature stable than pure nylon 66. The Tg range of the nylon,wood composite was found to be between 23 and 56°C, based on the decrease in storage modulus. A master curve was constructed based on the creep curves at various temperatures from 30 to 80°C. The results show that the relationship between shift factors and temperature follows Arrhenius behavior. Nylon,wood composites have good temperature-dependent properties. Wood fillers reduced the physical aging effects on nylon in the wood composites. The comparison of the nylon,wood composite with other similar products shows that nylon,wood composites are a promising low cost material for industrial applications. POLYM. COMPOS., 2008. © 2008 Society of Plastics Engineers [source] Creep behavior of biocomposites based on sisal fiber reinforced cellulose derivatives/starch blendsPOLYMER COMPOSITES, Issue 3 2004Vera A. Alvarez Biodegradable composites based on cellulose derivatives/starch blends reinforced with sisal short fibers were fabricated by injection molding. Results of short-term flexural creep tests are reported to investigate the time-dependence behavior of the composites. Fiber content and temperature effects are also considered, taking into account various methods and equations. At short times, a creep power law is employed. A master curve with the Arrhenius model is used to determine the creep resistance at longer times and different temperatures. Good fitting of the experimental results with the four-parameter model is reported, leading to a relationship between the observed creep behavior and the composite morphology. The addition of sisal fibers to the polymeric matrix promotes a significant improvement of the composite creep resistance. Polym. Compos. 25:280,288, 2004. © 2004 Society of Plastics Engineers. [source] The draw ratio,Deborah number diagram: A useful tool for coating applicationsPOLYMER ENGINEERING & SCIENCE, Issue 3 2006S. Bourrigaud The understanding of the basic physical effects of viscoelasticity on drawing performances in the coating process leads to a useful approach to link the rupture of the polymer melt to critical processing conditions. In particular, we show that when solving the drawing problem in the air gap with a simple constitutive equation,like the upper convected Maxwell model,a mathematical inconsistency appears for some drawing parameters. This mathematical instability may be experimentally correlated to the occurrence of melt-rupture, giving rise to a discussion on the effect of viscoelastic properties on drawing performances. Results are given in terms of a diagram representing the maximum drawing ratio Dr with respect to the Deborah number De. A master curve, obtained form experimental results, accounts for the temperature, melt-index, air-gap height, and extrusion output dependences. The limitations of the "universality" of the concept are discussed later. POLYM. ENG. SCI. 46:372,380, 2006. © 2006 Society of Plastics Engineers [source] Rheological behavior and mechanical properties of high-density polyethylene blends with different molecular weightsJOURNAL OF APPLIED POLYMER SCIENCE, Issue 3 2010Lu Bai Abstract The dynamic rheological and mechanical properties of the binary blends of two conventional high-density polyethylenes [HDPEs; low molecular weight (LMW) and high molecular weight (HMW)] with distinct different weight-average molecular weights were studied. The rheological results show that the rheological behavior of the blends departed from classical linear viscoelastic theory because of the polydispersity of the HDPEs that we used. Plots of the logarithm of the zero shear viscosity fitted by the Cross model versus the blend composition, Cole,Cole plots, Han curves, and master curves of the storage and loss moduli indicated the LMW/HMW blends of different compositions were miscible in the melt state. The tensile yield strength of the blends generally followed the linear additivity rule, whereas the elongation at break and impact strength were lower than those predicted by linear additivity; this suggested the incompatibility of the blends in solid state. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2010 [source] Compatibility and viscoelastic properties of brominated isobutylene- co - p -methylstyrene rubber/tackifier blendsJOURNAL OF APPLIED POLYMER SCIENCE, Issue 3 2008K. Dinesh Kumar Abstract Brominated isobutylene- co-p -methylstyrene (BIMS) rubber has been blended with hydrocarbon resin tackifier and alkyl phenol formaldehyde resin tackifier, and the compatibility between the blend components has been systematically evaluated. Dynamic mechanical analysis (DMA) and differential scanning calorimetry (DSC) studies show that BIMS rubber and hydrocarbon resin tackifier blends are compatible at all blend proportions studied. However, BIMS rubber and phenol formaldehyde resin blends exhibit very limited compatibility with each other and phase separation even at very low phenolic tackifier concentration. Morphological studies of the rubber,resin blends by scanning electron microscopy (SEM) corroborate well with the DMA and DSC results. From the DMA frequency sweep and temperature sweep studies, it is shown that the hydrocarbon resin tackifier acts as a diluent and causes a decrease in the storage modulus values (by reducing the entanglement and network density) in the rubbery plateau region. On the other hand, phenol formaldehyde resin behaves in the way similar to that of the reinforcing filler by increasing the storage modulus values (by increasing the entanglement and network density) in the rubbery plateau zone. The relaxation time estimated from the different zones of frequency sweep master curves provides information about the influence of the two tackifiers on the viscoelastic properties of the BIMS rubber in the respective zones. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 [source] Prediction of the relaxation behavior of amorphous pharmaceutical compounds.JOURNAL OF PHARMACEUTICAL SCIENCES, Issue 7 2003Abstract Variability in the time to crystallization is a major technical and economic hurdle in using amorphous solids in dosage forms. It is hypothesized that amorphous solids "age", and that the older they are, the more relaxed they are and the higher the probability of crystallization. At present, there is no method that allows the "effective age" of an amorphous raw material to be assessed relative to its unrelaxed initial condition. A method has been developed that may satisfy this unmet need and provide a first step in subsequent investigation of the crystallization "event". This method consists of using master curves to enable the determination of the effective age (,aging') of an amorphous compound given normal excursions in storage conditions. The present study shows that master curves can be prepared for different storage conditions and subsequently be used to predict the relaxation or aging behavior of amorphous compounds with expected variations in storage conditions. Given the constraint that the system remain within the area enclosed by the equilibrium supercooled liquid line and the glass on the enthalpy,temperature diagram, experimental results using indomethacin and salicin as model compounds show that master curves can be used to predict aging behavior under nonisothermal conditions, with temperature excursions as large as 10°C. The nonisothermal relaxation behavior can be modeled by combining the Kohlrausch,Williams,Watts (KWW) stretched exponential function, the relaxation function, and a shift factor. In addition, a model was developed that extends the range of applicability to time/temperature regions in which partial crystallization occurs. © 2003 Wiley-Liss, Inc. and the American Pharmacists Association J Pharm Sci 92:1464,1472, 2003 [source] Influence of Molecular Weight on Physical and Mechanical Properties of Linear Symmetric S-(S/B)-S Triblock CopolymersMACROMOLECULAR CHEMISTRY AND PHYSICS, Issue 2 2009Mahendra Thunga Abstract Symmetric linear S-(S/B)-S triblock copolymers with 80 wt.-% of PS having a block composition of 20-60-20 and a S/B ratio of 70:30 in the middle block are studied with varying molecular weights (). Increase in the leads to a change in the morphology from disordered to ordered microphase separated structure, as characterised by TEM and SAXS. Two distinct glass transitions for PS- and PB-rich phases are observed from DMA measurements, which are due to phase separation at high . Rheological studies (master curves) reveal an extended rubbery plateau and a delay in the terminal response with an increase in , whereas a terminal flow behaviour is observed for materials having a disordered nature at low . A brittle-to-tough transition is observed from tensile tests with the increase in . [source] Effect of mold temperature on the long-term viscoelastic behavior of polybutylene terepthalatePOLYMER ENGINEERING & SCIENCE, Issue 5 2008K. Banik The effect of mold temperature variation during injection molding on the long-term viscoelastic behavior of polybutylene terepthalate (PBT) was studied by dynamic mechanical thermal analysis (DMTA) and flexural creep tests. The time,temperature superposition (TTS) principle was applied to the experimental data and the master curves were created to predict their long-term behavior. The WLF and Arrhenius models were verified for the shift data in the investigating temperature range and the activation energies for the deformation process were calculated based on the Arrhenius equation. Further a four-element Burger model was applied to the creep results to represent the creep behavior of the PBT processed at two different mold temperatures and to better understand the deformation mechanism. Differential scanning calorimetry (DSC) and density measurements were accomplished to characterize the process-dependent microstructures. POLYM. ENG. SCI., 2008. © 2008 Society of Plastics Engineers [source] Rheological characterization of HDPE/sisal fiber compositesPOLYMER ENGINEERING & SCIENCE, Issue 10 2007Smita Mohanty The present paper summarizes an experimental study on the molten viscoelastic behavior of HDPE/sisal composites under steady and dynamic mode. Variations of the melt viscosity and die swell of the composites with an increase in shear rate, fiber loading, and coupling agent concentration have been investigated using capillary rheometer. The shear rate , at the wall was calculated using Rabinowitsch correction applied to the apparent shear rate values. It was observed that the melt viscosity of the composites increased with the addition of fibers and maleic anhydride-grafted PE (MAPE). Die swell of HDPE also decreased with the addition of sisal fibers and MAPE. Further, the dynamic viscoelastic behavior of the composites was measured employing parallel plate rheometer. Time,temperature superposition was applied to generate various viscoelastic master curves. Temperature sweeps were also carried out to study the flow activation energy determined from Arrhenius equation. The fiber,matrix morphology of the extrudates was also examined using scanning electron microscopy. POLYM. ENG. SCI., 47:1634,1642, 2007. © 2007 Society of Plastics Engineers [source] Rheology of polyurethane solutions with different solventsPOLYMER INTERNATIONAL, Issue 1 2002L de Vasconcelos Abstract Hard segment hydrogen bonding interactions in a particular polyurethane segmented copolymer have been analysed through a viscometric approach to determine the behaviour of polyurethane solutions with different solvent compositions. Analysis of log,,spversus log c[,] master curves (solely comprising dilute and semidilute regimes) showed that these systems could be differentiated by the slope of the first part of the curve (dilute regime), the characteristic reduced concentration c*[,], and the slope of the second part of the curve (semidilute regime), differences which were related to a possible occurrence of polymer aggregates. Experiments with solutions in the concentrated regime, at different temperatures, were used to relate non-Newtonian behaviour to hydrogen bonding. © 2001 Society of Chemical Industry [source] Viscoelastic properties of branched polyacrylate meltsPOLYMER INTERNATIONAL, Issue 6 2001Nasir M Ahmad Abstract The viscoelastic properties of poly(n-butyl acrylate), poly(ethyl acrylate) and poly(methyl acrylate) melts have been studied using samples that varied in both molar mass and the mol% branched repeat units, these properties having been previously determined by gel permeation chromatography and 13C NMR spectroscopy, respectively. Poly(n-butyl acrylate) was studied most extensively using seven samples; one sample of poly(n-butyl acrylate), two samples of poly(ethyl acrylate) and one sample of poly(methyl acrylate) were used to study the effect of side-group size. Storage and loss moduli were measured over a range of frequency (1,×,10,3 to 1,×,102,rad,s,1) at temperatures from Tg,+,20,°C to Tg,+,155,°C and then shifted to form master curves at Tg,+,74,°C through use of standard superposition procedures. The plateau regions were not distinct due to the broad molar mass distributions of the polyacrylates. Hence, the upper and lower limits of shear storage modulus from the nominal ,plateau' region of the curves for the seven poly(n-butyl acrylate) samples were used to calculate the chain molar mass between entanglements, Me, which gave the range 13.0,kg,mol,1,<,Me,<,65.0,kg,mol,1. The Graessley,Edwards dimensionless interaction density and dimensionless contour length concentration were calculated for poly(n-butyl acrylate) using the mean value of plateau modulus (1.2,×,105,Pa) and three different methods for estimation of the Kuhn length; the data fitted closely to the Graessley,Edwards universal plot. The Williams,Landel,Ferry C1 and C2 parameters were determined for each of the polyacrylates; the data for the poly(n-butyl acrylate) samples indicate an overall reduction in C1 and C2 as the degree of branching increases. Although the values of C1 and C2 were different for poly(n-butyl acrylate), poly(ethyl acrylate) and poly(methyl acrylate), there is no trend for variation with structure. Thus the viscoelastic properties of the polyacrylate melts are similar to those for other polymer melts and, for the samples investigated, the effect of molar mass appears to dominate the effect of branching. © 2001 Society of Chemical Industry [source] Scaling behaviour of pair correlation functions for randomly faulted hexagonal close-packed structuresACTA CRYSTALLOGRAPHICA SECTION A, Issue 4 2007Pratyush Tiwary Monte Carlo simulations and analytical results are used to demonstrate that the hexagonal close-packed (h.c.p.) pair correlation functions for different values of randomly distributed growth and deformation faults can be collapsed into master curves when plotted against a spatial variable, scaled with respect to a characteristic length (L). The functional dependences of L on different types of faults are found to be non-universal. A simple method for the determination of L from the measured intensity distributions is also outlined. [source] | ||||||||||||||||