Home About us Contact
|
Home About us Contact | ||
|
|
||
Mass Exchange (mass + exchange)
Selected AbstractsWDX Studies on Ceramic Diffusion Barrier Layers of Metal Supported SOECsFUEL CELLS, Issue 6 2009D. Wiedenmann Abstract Solid oxide electrolyser cells (SOECs) have great potential for efficient and economical production of hydrogen fuel. Element diffusion between the Ni-cermet electrode and the metal substrate of metal supported cells (MSC) is a known problem in fuel cell and electrolysis technology. In order to hinder this unintentional mass transport, different ceramic diffusion barrier layers (DBLs) are included in recent cell design concepts. This paper is based on wavelength dispersive X-ray fluorescence investigations of different SOEC and focuses on Fe, Cr and Ni diffusion between the metal grains of the cathode and the metal substrate. Due to the low detection limits and therefore high analytical sensitivity, wavelength dispersive electron probe microanalysis (EPMA) provides a precise method to determine element distribution, absolute element concentration and changes between the reference material and aged cells on a microstructural level by element mappings and concentration profiles. The results of this work show considerable concentration gradients in the metal grains caused by mass exchange during cell operation. Diffusion can be inhibited significantly by integrating different ceramic DBLs of doped LaCrO3 -type or doped LaMnO3 -type perovskite, either by vacuum plasma spraying (VPS) or physical vapour deposition technique (PVD). [source] Modeling fluid saturated porous media under frost attackGAMM - MITTEILUNGEN, Issue 1 2010Tim Ricken Abstract Freezing and thawing are important processes in civil engineering. On the one hand frost damage of porous building materials like road pavements and concrete in regions with periodical freezing is well known. On the other hand, artificial freezing techniques are widely used, e.g. for tunneling in non-cohesive soils and other underground constructions as well as for the protection of excavation and compartmentalization of contaminated tracts. Ice formation in porous media results from a coupled heat and mass transport and is accompanied by the ice expansion. The volume increase in space and time is assigned to the moving freezing front inside the porous solid. In this paper, a macroscopic ternary model is presented within the framework of the Theory of Porous Media (TPM) in view of the description of phase transition. For the mass exchange between ice and water an evolution equation based on the local balance of the heat flux vector is used. Examples illustrate the application of the model for saturated porous solids under thermal loading (© 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) [source] Interpretation of the enhancement of field-scale effective matrix diffusion coefficient in a single fracture using a semi-analytical power series solutionHYDROLOGICAL PROCESSES, Issue 6 2009Tai-Sheng Liou Abstract A power series solution for convergent radial transport in a single fracture (PCRTSF) is developed. Transport processes considered in PCRTSF include advection and hydrodynamic dispersion in the fracture, molecular diffusion in the matrix, diffusive mass exchange across the fracture-matrix interface, and mixing effects in the injection and the extraction boreholes. An analytical solution in terms of a power series in Laplace domain is developed first, which is then numerically inverted by de-Hoog et al.'s algorithm. Four dimensionless parameters determine the behaviour of a breakthrough curve (BTC) calculated by PCRTSF, which are, in the order of decreasing sensitivity, the matrix diffusion factor, two mixing factors, and the Peclet number. The first parameter is lumped from matrix porosity, effective matrix diffusion coefficient, fracture aperture, and retardation factors. Its value increases as the matrix diffusion effect becomes significant. A non-zero matrix diffusion factor results in a , 3/2 slope of the tail of a log,log BTC, a common property for tracer diffusion into an infinite matrix. Both mixing factors have equal effects on BTC characteristics. However, the Peclet number has virtually no effect on BTC tail. PCRTSF is applied to re-analyse two published test results that were obtained from convergent radial tracer tests in a discrete, horizontal fracture in Silurian dolomite. PCRTSF is able to fit the field BTCs better than the original channel model does if a large matrix diffusion coefficient is used. Noticeably, the ratio of field-scale to lab-scale matrix diffusion coefficients can be as large as 378. This enhancement of the field-scale matrix diffusion coefficient may be ascribed to the presence of a degraded zone at the fracture-matrix interface because of karstic effects, or to flow channeling as a result of aperture heterogeneity. Copyright © 2009 John Wiley & Sons, Ltd. [source] Creep of saturated materials as a chemically enhanced rate-dependent damage processINTERNATIONAL JOURNAL FOR NUMERICAL AND ANALYTICAL METHODS IN GEOMECHANICS, Issue 14 2007Liang Bo Hu Abstract Material behaviour that exhibits characteristics of creep induced by a spontaneous mineral dissolution enhanced by material damage is studied. It is believed that the characteristic rates of the chemical processes involved determine the time-rate dependence of the resulting strain. A basic model of a combined chemo-plastic softening and chemically enhanced deviatoric strain hardening for saturated geomaterials is presented. Chemical softening is postulated to occur as a consequence of the net mass removal resulting from dissolution and precipitation of specific minerals occurring at the damage-generated inter-phase interfaces. Closed and open systems are discussed. In the former case, deformation at constant stress results entirely from a local compensation mechanism between the chemical softening and strain hardening. The classical three stages of creep are interpreted in terms of mechanisms of dissolution and precipitation, as well as the variation in the reaction surface areas involved in the mass exchange. In an open system, the above local mechanism is enhanced by the removal of mass via diffusion of species affecting the mass balance. Such a system is addressed via a boundary value problem as shown in an example. Copyright © 2007 John Wiley & Sons, Ltd. [source] Explicit solutions for the instantaneous undrained contraction of hollow cylinders and spheres in porous elastoplastic mediumINTERNATIONAL JOURNAL FOR NUMERICAL AND ANALYTICAL METHODS IN GEOMECHANICS, Issue 3 2002A. Giraud Abstract In this article we present closed-form solutions for the undrained variations in stress, pore pressure, deformation and displacement inside hollow cylinders and hollow spheres subjected to uniform mechanical pressure instantaneously applied to their external and internal boundary surfaces. The material is assumed to be a saturated porous medium obeying a Mohr,Coulomb model failure criterion, exhibiting dilatant plastic deformation according to a non-associated flow rule which accounts for isotropically strain hardening or softening. The instantaneous response of a porous medium submitted to an instantaneous loading is undrained, i.e. without any fluid mass exchange. The short-term equilibrium problem to be solved is now formally identical to a problem of elastoplasticity where the constitutive equations involve the undrained elastic moduli and particular equivalent plastic parameters. The response of the model is presented (i) for extension and compression undrained triaxial tests, and (ii) for unloading problems of hollow cylinders and spheres through the use of appropriately developed closed-form solutions. Numerical results are presented for a plastic clay stone with strain hardening and an argilite with strain softening. The effects of plastic dilation, of the strain softening law and also of geometry of the cavity on the behaviour of the porous medium have been underlined. Analytical solutions provide valuable benchmarks enabling various numerical methods in undrained conditions with a finite boundary to be verified. Copyright © 2002 John Wiley & Sons, Ltd. [source] Investigation of the temperature oscillations in the cylinder walls of a diesel engine with special reference to the limited cooled caseINTERNATIONAL JOURNAL OF ENERGY RESEARCH, Issue 11 2004C. D. Rakopoulos Abstract This work investigates the interesting phenomenon of the temperature (cyclic) oscillations in the combustion chamber walls of a diesel engine. For this purpose, a comprehensive simulation code of the thermodynamic cycle of the engine is developed taking into account both the closed and the open parts of it. The energy and state equations are applied, with appropriate combustion, gas heat transfer, and mass exchange with the atmosphere sub-models, to yield cylinder pressure, local temperatures and heat release histories as well as various performance parameters of the engine. The model is appropriately coupled to a wall periodic conduction model, which uses the gas temperature variation as boundary condition throughout the engine cycle after being treated by Fourier analysis techniques. It is calibrated against measurements, at various load and speed conditions, from an experimental work carried out on a direct injection (DI), naturally aspirated, four-stroke, diesel engine located at the authors' laboratory, which has been reported in detail previously. After gaining confidence into the predictive capabilities of the model, it is used to investigate the phenomenon further, thus providing insight into many interesting aspects of transient engine heat transfer, as far as the influence that engine wall material properties have on the values of cyclic temperature swings. These swings can take prohibitive values causing high wall thermal fatigue, when materials of specific technological interest such as thermal insulators (ceramics) are used, and may lead to deterioration in engine performance. Copyright © 2004 John Wiley & Sons, Ltd. [source] A study of major mergers using a multi-phase ISM codeASTRONOMISCHE NACHRICHTEN, Issue 9-10 2009J. Weniger Abstract Galaxy interactions are a common phenomenon in clusters of galaxies. Especially major mergers are of particular importance, because they can change the morphological type of galaxies. They have an impact on the mass function of galaxies and they trigger star formation , the main driver of the Galactic Matter Cycle. Therefore, we conducted a study of major mergers by means of a multi-phase ISM code. This code is based on a TREE-SPH-code combined with a sticky particle method allowing for star formation controlled by the properties of a multi-phase ISM. This is in contrast to the usually implemented Schmidt law depending mainly on the gas density. Previously, this code was used on isolated galaxies. Since our star formation recipe is not restricted to a special type of galaxy, it is interesting to apply it to interacting galaxies, too. Our study on major mergers includes a research of global properties of the interacting system, namely the star formation rate and the star formation efficiency, the evaporation and condensation rates, as well as the mass exchange of distinct components, namely stars, diffuse ISM, and clouds. Investigating these properties provides insight to interrelations between various physical processes. The results indicate that the star formation efficiency as well as the evaporation and condensation rates are influenced by the interaction (© 2009 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) [source] Magnetic survey of emission line B-type stars with FORS 1 at the VLT,ASTRONOMISCHE NACHRICHTEN, Issue 7 2009S. Hubrig Abstract We report the results of our search for magnetic fields in a sample of 16 field Be stars, the binary emission-line B-type star , Sgr, and in a sample of fourteen members of the open young cluster NGC3766 in the Carina spiral arm. The sample of cluster members includes Be stars, normal B-type stars and He-strong/He-weak stars. Nine Be stars have been studied with magnetic field time series obtained over ,1 hour to get an insight into the temporal behaviour and the correlation of magnetic field properties with dynamical phenomena taking place in Be star atmospheres. The spectropolarimetric data were obtained at the European Southern Observatory with the multi-mode instrument FORS1 installed at the 8m Kueyen telescope. We detect weak photospheric magnetic fields in four field Be stars, HD 62367, , Cen, o Aqr, and , Tuc. The strongest longitudinal magnetic field, ,Bz, = 117 ± 38 G, was detected in the Be star HD 62367. Among the Be stars studied with time series, one Be star, , Eri, displays cyclic variability of the magnetic field with a period of 21.12 min. The binary star , Sgr, in the initial rapid phase of mass exchange between the two components with strong emission lines in the visible spectrum, is a magnetic variable star, probably on a timescale of a few months. The maximum longitudinal magnetic field ,Bz, = ,102 ± 10 G at MJD 54333.018 was measured using hydrogen lines. The cluster NGC3766 seems to be extremely interesting, where we find evidence for the presence of a magnetic field in seven early B-type stars out of the observed fourteen cluster members (© 2009 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) [source] Evidence for weak magnetic fields in early-type emission starsASTRONOMISCHE NACHRICHTEN, Issue 10 2007S. Hubrig Abstract We report the results of our study of magnetic fields in a sample of 15 Be stars using spectropolarimetric data obtained at the European Southern Observatory with the multi-mode instrument FORS 1 installed at the 8m Kueyen telescope. We detect weak photospheric magnetic fields in four stars, HD56014, HD148184, HD155806, and HD181615. We note that for HD181615 the evolutionary status is not obvious due to the fact that it is a binary system currently observed in the initial rapid phase of mass exchange between the two components. Further, we notify the possible presence of distinct circular polarisation features in the circumstellar components of Ca II H&K in three stars, HD58011, HD117357, and HD181615, hinting at a probable presence of magnetic fields in the circumstellar mass loss disks of these stars. We emphasize the need for future spectropolarimetric observations of Be stars with detected magnetic fields to study the temporal evolution of their magnetic fields and the correlation of magnetic field properties with dynamical phenomena taking place in the gaseous circumstellar disks of these stars. (© 2007 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) [source] | ||||||||||