Many Advantages (many + advantage)

Distribution by Scientific Domains
Distribution within Chemistry


Selected Abstracts


Purchasing Portfolio Models: A Critique and Update

JOURNAL OF SUPPLY CHAIN MANAGEMENT, Issue 3 2005
Cees J. Gelderman
Summary Purchasing portfolio models have spawned considerable discussion in the literature. Many advantages and disadvantages have been put forward, revealing considerable divergence in opinion on the merits of portfolio models. This study addresses the question of whether or not the use of purchasing portfolio models is considered as a sign of purchasing sophistication. Using data from a broad sample of industries, it was found that purchasing sophistication is a two-dimensional construct: purchasing's professionalism and purchasing's position within companies. Results revealed that the position and the professionalism of purchasing are both positively related to the greater use of purchasing portfolio models. Findings indicate that portfolio usage is definitely a sign of purchasing sophistication. [source]


Multiple path-based approach to image-based street walkthrough

COMPUTER ANIMATION AND VIRTUAL WORLDS (PREV: JNL OF VISUALISATION & COMPUTER ANIMATION), Issue 2 2005
Dong Hoon Lee
Abstract Image-based rendering for walkthrough in the virtual environment has many advantages should over the geometry-based approach, due to the fast construction of the environment and photo-realistic rendered results. In image-based rendering technique, rays from a set of input images are collected and a novel view image is rendered by the resampling of the stored rays. Current such techniques, however, are limited to a closed capture space. In this paper, we propose a multiple path-based capture configuration that can handle a large-scale scene and a disparity-based warping method for novel view generation. To acquire the disparity image, we segment the input image into vertical slit segments using a robust and inexpensive way of detecting vertical depth discontinuity. The depth slit segments, instead of depth pixels, reduce the processing time for novel view generation. We also discuss a dynamic cache strategy that supports real-time walkthroughs in large and complex street environments. The efficiency of the proposed method is demonstrated with several experiments. Copyright © 2005 John Wiley & Sons, Ltd. [source]


Some benefits of dichotomization in psychiatric and criminological research

CRIMINAL BEHAVIOUR AND MENTAL HEALTH, Issue 2 2000
Professor David P. Farrington PhD FBA
Background The product-moment correlation r is widely used in criminology and psychiatry to measure strength of association. However, most criminological and psychiatric variables contravene its underlying assumptions. Aim To compare statistical measures of association based on dichotomous variables with the use of r. Method Explanatory variables for delinquency are investigated in the Pittsburgh Youth Study using a sample of 506 boys aged 13,14. Results Dichotomization does not necessarily cause a decrease in measured strength of associations. Conclusions about the most important explanatory variables for delinquency were not greatly affected by using dichotomous as opposed to continuous variables, by different dichotomization splits, or by using logistic versus OLS multiple regression. Non-linear relationships, interaction effects and multiple risk factor individuals were easily studied using dichotomous data. Conclusions Dichotomization produces meaningful findings that are easily understandable to a wide audience. Measures of association for dichotomous variables, such as the odds ratio, have many advantages and are often more realistic and meaningful measures of strength of relationship than the product-moment correlation r. Copyright © 2000 Whurr Publishers Ltd. [source]


Influence of surgical repositioning of mature permanent dog teeth following experimental intrusion: a histologic assessment

DENTAL TRAUMATOLOGY, Issue 6 2002
R. F. Cunha
Abstract,,, The aim of this study was to evaluate, through histologic examination, the effect of surgical repositioning of intruded dog teeth upon the pulpal and surrounding tissues. Thirty teeth in 10 adult dogs, aged 2,3 years, were used. Fifteen teeth were intruded, surgically repositioned and fixed using orthodontics wire, composite resin, and enamel acid conditioning. All these teeth served as the experimental group. The remaining intruded teeth were not treated (control group). The animals were sacrificed to allow observations at 7, 15, and 30 post-operative days. The maxillary and mandibular archs were removed and processed for histologic exam. Based on the methodology and observed results, we concluded that: pulpal necrosis, external root resorption and ankylosis were common sequelae to severe traumatic intrusion; a careful immediate surgical repositioning of severed intruded permanent tooth with complete root formation has many advantages with few disadvantages. [source]


Granular cell tumor of the neurohypophysis: Report of a case with intraoperative cytologic diagnosis

DIAGNOSTIC CYTOPATHOLOGY, Issue 1 2008
Maria Luisa C. Policarpio-Nicolas M.D.
Abstract Cytological techniques including touch and smear preparations are very useful diagnostic modality in the evaluation of central nervous system (CNS) lesions and, in many instances, may be effectively used as the sole modality of tissue preparation for intraoperative consultation. Cytologic preparations offer many advantages over frozen sections for CNS specimens. These include selective examination of multiple areas from small biopsy specimens, superior preservation and details of cellular morphology, fewer artifacts, faster results, and improved cost-effectiveness. We describe the cytologic diagnosis of a granular cell tumor (GCT) of the neurohypophysis in a 33-year-old male who presented with headache and blurred vision. CT scan revealed an enlarged sella with a 2.15 × 2.0 cm pituitary lesion. Transsphenoidal resection of the mass was performed and submitted for intraoperative consultation. Smears and touch preparations were made on a portion of the mass that showed uniform polygonal cells with round to ovoid nuclei and abundant eosinophilic granular cytoplasm. An intraoperative cytological diagnosis of "favor GCT" was rendered. The histologic sections of the remaining material confirmed the diagnosis. Although GCT of the neurohypophysis is very rare, a specific intraoperative cytological diagnosis is possible. We report the clinical, cytological, and pathological findings of a GCT affecting the neurohypophysis. Diagn. Cytopathol. 2008;36:58,63. © 2007 Wiley,Liss, Inc. [source]


Development of a solvent-free, solid-phase in vitro bioassay using vertebrate cells

ENVIRONMENTAL TOXICOLOGY & CHEMISTRY, Issue 5 2006
Stephanie K. Bopp
Abstract Miniaturized bioassays offer many advantages in exploring the toxic potential of chemicals, including small sample volumes and compatibility with high-throughput screening. One problem common to miniaturized systems, however, is the loss of test chemicals because of sorption. The idea of the current study was to use the sorption phenomenon in a positive way. It was found that contaminants sorbed to the growth surface in wells of tissue-culture plates or to the surface of selected sorbent bead materials are available to vertebrate cells growing in direct contact with the contaminant-coated surface. The use of beads provided more flexibility with regard to surface area, materials, and assay format. Biosilon, a bead cell-culture carrier made of polystyrene, was found to be most suitable. It supported cell adherence and allowed the detection of reproducible dose-response curves of an increase in cytochrome CYP1A enzyme activity by sorbed polycyclic aromatic hydrocarbons in the rainbow trout (Oncorhynchus mykiss) liver cell line, RTL-W1. The resulting bead assay provides a miniaturized, solvent-free exposure system. Potential future applications include the coupling to environmental sampling, in which the bead material is used as solid receiving phase before serving as a surface for vertebrate cells to attach and respond. [source]


A Parimutuel Market Microstructure for Contingent Claims

EUROPEAN FINANCIAL MANAGEMENT, Issue 1 2005
Jeffrey Lange
G10; G13; G14 Abstract Parimutuel principles are widely used as an alternative to fixed odds gambling in which a bookmaker acts as a dealer by quoting fixed rates of return on specified wagers. A parimutuel game is conducted as a call auction in which odds are allowed to fluctuate during the betting period until the betting period is closed or the auction ,called'. The prices or odds of wagers are set based upon the relative amounts wagered on each risky outcome. In financial microstructure terms, trading under parimutuel principles is characterised by (1) call auction, non-continuous trading; (2) riskless funding of claim payouts using the amounts paid for all of the claims during the auction; (3) special equilibrium pricing conditions requiring the relative prices of contingent claims equal the relative aggregate amounts wagered on such claims; (4) endogenous determination of unique state prices; and (5) higher efficiency. Recently, a number of large investment banks have adopted a parimutuel mechanism for offering contingent claims on various economic indices, such as the US Nonfarm payroll report and Eurozone Harmonised inflation. Our paper shows how the market microstructure incorporating parimutuel principles for contingent claims which allows for notional transactions, limit orders, and bundling of claims across states is constructed. We prove the existence of a unique price equilibrium for such a market and suggest an algorithm for computing the equilibrium. We also suggest that for a broad class of contingent claims, that the parimutuel microstructure recently deployed offers many advantages over the dominant dealer and exchange continuous time mechanisms. [source]


Microwave-Assisted Hydrothermal Synthesis of Structurally and Morphologically Controlled Sodium Niobates by Using Niobic Acid as a Precursor

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, Issue 8 2008
Amauri J. Paula
Abstract There are many advantages to using a microwave as a source of heat in hydrothermal reactions. Because it is a quick and homogeneous way to crystallize ceramic powders, it was used in this work for the production of antiferroelectric sodium niobate (NaNbO3) in a cubic-like form and its intermediary phase, disodium diniobate hydrate (Na2Nb2O6.H2O), with a fiber morphology. The syntheses were carried out by treating niobic acid (Nb2O5·nH2O) with NaOH. By changing the reaction time and the concentration of the reactants, particles with different structures and different morphologies could be obtained. The structural evolution of the products of this reaction was elucidated on the basis of the arrangement of the NbO6 octahedral units. Conclusive results were obtained with morphological and structural characterizations through XRD, TEM, MEV, and NMR and Raman spectroscopy. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008) [source]


Mitigation of the produced voltages in AC overhead power-lines/pipelines parallelism during power frequency and lightning conditions

EUROPEAN TRANSACTIONS ON ELECTRICAL POWER, Issue 4 2005
I. A. Metwally
Abstract This paper presents a theoretical simulation for a pipeline running in parallel to AC overhead power lines using the ,CONCEPT II' package. This package is based on the method of moment combined with a transmission-line model. A 1,km long, 132,kV, three-phase, double-circuit transmission line, and a 2,km long, 40,cm diameter, 1,m high above-ground pipeline are modelled. Extra shielding wires (ESW) under the phase conductors are investigated. Produced voltages in the pipeline are computed under steady-state power frequency (50,Hz) as well as under direct and indirect lightning strikes to the power line. Different current waveforms are simulated to cover the whole range of those of the anticipated lightning. Under lightning strikes, the voltages across line insulators are computed, too. The results reveal that the ESW give many advantages; namely, (1) reducing the power-frequency electric and magnetic fields at the ground level to meet the regularity limits, (2) improving the shielding effectiveness during lightning strikes by reducing the insulator voltages, (3) mitigating the induced voltages in any metallic structure near the power lines, e.g., pipelines, and (4) using them as optical ground wires for telecommunication purposes, where the probability of lightning strikes to such ESW is much lower than that for the normally used grounding wire(s) at the tower top. Copyright © 2005 John Wiley & Sons, Ltd. [source]


Photonic Crystals in Bioassays

ADVANCED FUNCTIONAL MATERIALS, Issue 18 2010
Yuanjin Zhao
Abstract Photonic crystal (PC) based bioassay techniques have many advantages in sensitive biomolecular screening, label-free detection, real-time monitoring of enzyme activity, cell morphology research, and so on. This study provides an overall survey of the basic concepts and up-to-date research concerning the very promising use of PC materials for bioassays. It includes the design and application of PC films, PC microcarriers, PC fibers, and PC optofluidics for fluorescence enhancement or label-free bioassays. Emphasis is given to the description of the functional structures of different PC materials and their respective sensing mechanisms. Examples of detecting various types of analytes are presented. This article promotes communication among chemistry, biology, medicine, pharmacy, and material science. [source]


Functionalized Self-Assembled InAs/GaAs Quantum-Dot Structures Hybridized with Organic Molecules

ADVANCED FUNCTIONAL MATERIALS, Issue 3 2010
Miaoxiang Chen
Abstract Low-dimensional III,V semiconductors have many advantages over other semiconductors; however, they are not particularly stable under physiological conditions. Hybridizing biocompatible organic molecules with advanced optical and electronic semiconductor devices based on quantum dots (QDs) and quantum wires could provide an efficient solution to realize stress-free and nontoxic interfaces to attach larger functional biomolecules. Monitoring the modifications of the optical properties of the hybrid molecule,QD systems by grafting various types of air-stable diazonium salts onto the QD structures surfaces provides a direct approach to prove the above concepts. The InAs/GaAs QD structures used in this work consist of a layer of surface InAs QDs and a layer of buried InAs QDs embedded in a wider-bandgap GaAs matrix. An enhancement in photoluminescence intensity by a factor of 3.3 from the buried QDs is achieved owing to the efficient elimination of the dangling bonds on the surface of the structures and to the decrease in non-radiative recombination caused by their surface states. Furthermore, a narrow photoluminescence band peaking at 1620,nm with a linewidth of 49 meV corresponding to the eigenstates interband transition of the surface InAs QDs is for the first time clearly observed at room temperature, which is something that has rarely been achieved without the use of such engineered surfaces. The experimental results demonstrate that the hybrid molecule,QD systems possess a high stability, and both the surface and buried QDs are very sensitive to changes in their surficial conditions, indicating that they are excellent candidates as basic sensing elements for novel biosensor applications. [source]


Using an airgun array in a land reservoir as the seismic source for seismotectonic studies in northern China: experiments and preliminary results

GEOPHYSICAL PROSPECTING, Issue 4 2008
Yong Chen
ABSTRACT This paper reports the field setup and preliminary results of experiments utilizing an airgun array in a reservoir in north China for a seismotectonic study. Commonly used in offshore petroleum resource exploration, the airgun source was found to be more useful than a traditional explosive source for large-scale and long offset land seismic surveys. The airgun array, formed by four 1,500 in3 airguns (a total of 6,000 in3 in volume) was placed at a depth of 6,9 m into the reservoir to generate the pressure impulse. No direct evidence was found that the airgun source adversely affected the fish in the reservoir. The peak ground acceleration recorded on the top of the reservoir dam 100 m away was 17.8 gal in the horizontal direction; this is much less than the designed earthquake-resistance threshold of 125 gal for this dam. The energy for one shot of this airgun array is about 6.68 MJ, equivalent to firing a 1.7 kg explosive. The seismic waves generated by the airgun source were recorded by receivers of the regional seismic networks and a temporary wide-angle reflection and refraction profile formed by 100 short-period seismometers with the maximum source-receiver offset of 206 km. The seismic wave signature at these long-offset stations is equivalent to that generated by a traditional blast source in a borehole with a 1,000,2,000 kg explosive. Preliminary results showed clear seismic phases from refractions from the multi-layer crustal structures in the north China region. Forward modelling using numerical simulation confirms that the seismic arrivals are indeed from lower crustal interfaces. The airgun source is efficient, economical, environmentally friendly and suitable for being used in urbanized areas. It has many advantages over an explosive source for seismotectonic studies such as the high repeatability that is supreme for stacking to improve signal qualities. The disadvantage is that the source is limited to existing lakes or reservoirs, which may restrict experimental geometry. [source]


New school in liver development: Lessons from zebrafish,

HEPATOLOGY, Issue 5 2009
Jaime Chu
There is significant overlap in the genes and pathways that control liver development and those that regulate liver regeneration, hepatic progenitor cell expansion, response to injury, and cancer. Additionally, defects in liver development may underlie some congenital and perinatal liver diseases. Thus, studying hepatogenesis is important for understanding not only how the liver forms, but also how it functions. Elegant work in mice has uncovered a host of transcription factors and signaling molecules that govern the early steps of hepatic specification; however, the inherent difficulty of studying embryogenesis in utero has driven developmental biologists to seek new systems. The rapidly developing vertebrate zebrafish is a favorite model for embryology. The power of forward genetic screens combined with live real-time imaging of development in transparent zebrafish embryos has highlighted conserved processes essential for hepatogenesis and has uncovered some exciting new players. This review presents the advantages of zebrafish for studying liver development, underscoring how studies in zebrafish and mice complement each other. In addition to their value for studying development, zebrafish models of hepatic and biliary diseases are expanding, and using these small, inexpensive embryos for drug screening has become de rigueur. Zebrafish provide a shared platform for developmental biology and translational research, offering innovative methods for studying liver development and disease. The story of hepatogenesis has something for everyone. It involves transcriptional regulation, cell-cell interaction, signaling pathways, control of cell proliferation and apoptosis, plus morphogenic processes that sculpt vasculature, parenchymal cells, and mesenchyme to form the multifaceted liver. Decades of research on liver development in mice and other vertebrates offer valuable lessons in how the multipotent endoderm is programmed to form a functional liver. Of equal importance are insights that have illuminated the mechanisms by which hepatic progenitors are activated in a damaged liver, how the adult liver regenerates, and, possibly, the basis for engineering liver cells in vitro for cell transplantation to sustain patients with liver failure. Moreover, processes that are key to liver development are often co-opted during pathogenesis. Therefore, reviewing hepatogenesis is informative for both basic and translational researchers. In this review, we bring to light the many advantages offered by the tropical freshwater vertebrate zebrafish (Danio rerio) in studying hepatogenesis. By comparing zebrafish and mice, we highlight how work in each system complements the other and emphasize novel paradigms that have been uncovered using zebrafish. Finally, we highlight exciting efforts using zebrafish to model hepatobiliary diseases. (HEPATOLOGY 2009.) [source]


Preparation of Inorganic Materials Using Ionic Liquids

ADVANCED MATERIALS, Issue 2 2010
Zhen Ma
Abstract Conventional synthesis of inorganic materials relies heavily on water and organic solvents. Alternatively, the synthesis of inorganic materials using, or in the presence of, ionic liquids represents a burgeoning direction in materials chemistry. Use of ionic liquids in solvent extraction and organic catalysis has been extensively studied, but their use in inorganic synthesis has just begun. Ionic liquids are a family of non-conventional molten salts that can act as templates and precursors to inorganic materials, as well as solvents. They offer many advantages, such as negligible vapor pressures, wide liquidus ranges, good thermal stability, tunable solubility for both organic and inorganic molecules, and much synthetic flexibility. In this Review, the use of ionic liquids in the preparation of several categories of inorganic and hybrid materials (i.e., metal structures, non-metal elements, silicas, organosilicas, metal oxides, metal chalcogenides, metal salts, open-framework structures, ionic liquid-functionalized materials, and supported ionic liquids) is summarized. The status quo of the research field is assessed, and some future perspectives are furnished. [source]


Conjugated-Polymer Blends for Optoelectronics

ADVANCED MATERIALS, Issue 38-39 2009
Christopher R. McNeill
Abstract Solution-processed polymer optoelectronic devices such as light-emitting diodes and solar cells have many advantages for large-area manufacture, and show increasing levels of performance. Here, we review recent progress in using blends of two conjugated polymers for optoelectronic devices. The blending of two or more polymers allows tuning of device performance, and for photovoltaics presents an attractive way to combine donor and acceptor materials with a morphology controlled by polymer phase separation. We discuss recent advances in imaging the microstructure of conjugated polymer blends, and we demonstrate how the blend structure leads to performance advantages in both LEDs and photovoltaic devices. [source]


A BTOP model to extend TOPMODEL for distributed hydrological simulation of large basins

HYDROLOGICAL PROCESSES, Issue 17 2008
Kuniyoshi Takeuchi
Abstract Topography is a dominant factor in hillslope hydrology. TOPMODEL, which uses a topographical index derived from a simplified steady state assumption of mass balance and empirical equations of motion over a hillslope, has many advantages in this respect. Its use has been demonstrated in many small basins (catchment areas of the order of 2,500 km2) but not in large basins (catchment areas of the order of 10 000,100 000 km2). The objective of this paper is to introduce the Block-wise TOPMODEL (BTOP) as an extension of the TOPMODEL concept in a grid based framework for distributed hydrological simulation of large river basins. This extension was made by redefining the topographical index by using an effective contributing area af(a) (0,f(a),1) per unit grid cell area instead of the upstream catchment area per unit contour length and introducing a concept of mean groundwater travel distance. Further the transmissivity parameter T0 was replaced by a groundwater dischargeability D which can provide a link between hill slope hydrology and macro hydrology. The BTOP model uses all the original TOPMODEL equations in their basic form. The BTOP model has been used as the core hydrological module of an integrated distributed hydrological model YHyM with advanced modules of precipitation, evapotranspiration, flow routing etc. Although the model has been successfully applied to many catchments around the world since 1999, there has not been a comprehensive theoretical basis presented in such applications. In this paper, an attempt is made to address this issue highlighted with an example application using the Mekong basin. Copyright © 2007 John Wiley & Sons, Ltd. [source]


Hidden Markov model-based real-time transient identifications in nuclear power plants

INTERNATIONAL JOURNAL OF INTELLIGENT SYSTEMS, Issue 8 2002
Kee-Choon Kwon
In this article, a transient identification method based on a stochastic approach with the hidden Markov model (HMM) has been suggested and evaluated experimentally for the classification of nine types of transients in nuclear power plants (NPPs). A transient is defined as when a plant proceeds to an abnormal state from a normal state. Identification of the types of transients during an early accident stage in NPPs is crucial for proper action selection. The transient can be identified by its unique time-dependent patterns related to the principal variables. The HMM, a double-stochastic process, can be applied to transient identification that is a spatial and temporal classification problem under a statistical pattern-recognition framework. The trained HMM is created for each transient from a set of training data by the maximum-likelihood estimation method which uses a forward-backward algorithm and the Baum-Welch re-estimation algorithm. The transient identification is determined by calculating which model has the highest probability for given test data using the Viterbi algorithm. Several experimental tests have been performed with normalization methods, clustering algorithms, and a number of states in HMM. There are also a few experimental tests that have been performed, including superimposing random noise, adding systematic error, and adding untrained transients to verify its performance and robustness. The proposed real-time transient identification system has been proven to have many advantages, although there are still some problems that should be solved before applying it to an operating NPP. Further efforts are being made to improve the system performance and robustness in order to demonstrate reliability and accuracy to the required level. © 2002 Wiley Periodicals, Inc. [source]


Evidence-based practice: A framework for clinical practice and research design

INTERNATIONAL JOURNAL OF NURSING PRACTICE, Issue 5 2006
Matthew J Leach PhD BN(Hons) ND RN
The evidence-based practice (EBP) framework emerged in the early 1970s as a means of improving clinical practice. This shift towards EBP allowed health professionals to move from a culture of delivering care based on tradition, intuition and authority, to a situation where decisions were guided and justified by the best available evidence. Despite the many advantages of EBP, many practitioners remain cautious about embracing the model. Part of this opposition is due to a misunderstanding of EBP, which this paper aims to address. [source]


Nine Times Fluoride can be Good for your Syntheses.

ADVANCED SYNTHESIS & CATALYSIS (PREVIOUSLY: JOURNAL FUER PRAKTISCHE CHEMIE), Issue 17 2009
Not just Cheaper: Nonafluorobutanesulfonates as Intermediates for Transition Metal-Catalyzed Reactions
Abstract How much fluoride is good for a strong electron-withdrawing effect? In this review we summarize recent results on the use of perfluoroalkanesulfonates, in particular of the cost effective nonafluorobutanesulfonates (nonaflates), in transition metal-catalyzed reactions and a few other typical transformations. During the last decade many advantages over the commonly used triflates have been discovered. The generation of alkenyl and (het)aryl nonaflates and their applications in metal-catalyzed processes such as Heck, Suzuki, Sonogashira, Stille, and Negishi couplings or amination reactions are described. Although far from a systematic investigation, all the presented results clearly demonstrate the many advantages of nonaflates and of similar higher fluorinated sulfonates in laboratory and industrial scale organic synthesis. [source]


An effective iodide formulation for killing Bacillus and Geobacillus spores over a wide temperature range

JOURNAL OF APPLIED MICROBIOLOGY, Issue 2 2004
N. Kida
Abstract Aims:, To develop a sporicidal reagent which shows potent activity against bacterial spores not only at ambient temperatures but also at low temperatures. Methods and Results:, Suspension tests on spores of Bacillus and Geobacillus were conducted with the reagent based on a previously reported agent (N. Kida, Y. Mochizuki and F. Taguchi, Microbiology and Immunology 2003; 47: 279,283). The modified reagent (tentatively designated as the KMT reagent) was composed of 50 mmol l,1 EDTA-2Na, 50 mmol l,1 ferric chloride hexahydrate (FeCl3·6H2O), 50 mmol l,1 potassium iodide (KI) and 50% ethanol in 0·85% NaCl solution at pH 0·3. The KMT reagent showed significant sporicidal activity against three species of Bacillus and Geobacillus spores over a wide range of temperature. The KMT reagent had many practical advantages, i.e. activity was much less affected by organic substances than was sodium hypochlorite, it did not generate any harmful gas and it was stable for a long period at ambient temperatures. The mechanism(s) of sporicidal activity of the KMT reagent was considered to be based on active iodine species penetrating the spores with enhanced permeability of the spore cortex by a synergistic effect of acid, ethanol and generated active oxygen. Conclusions:, The data suggest that the KMT reagent shows potent sporicidal activity over a wide range temperatures and possesses many advantages for practical applications. Significance and Impact of the Study:, The results indicate development of a highly applicable sporicidal reagent against Bacillus and Geobacillus spores. [source]


Sterilization system for air purifier by combining ultraviolet light emitting diodes with TiO2

JOURNAL OF CHEMICAL TECHNOLOGY & BIOTECHNOLOGY, Issue 10 2009
Xiaohui Huang
Abstract BACKGROUND: Ultraviolet light emitting diodes (UV LEDs) were used as a light source in TiO2 photocatalysis because of their many advantages, such as, long life, safety, low pollution, etc. In this experiment, a light source panel was successfully fabricated with UV LEDs, the light intensities of which were relatively uniform. RESULTS: The sterilization process comprised two steps. First, an aerosol was blocked by high efficient particulate air (HEPA) filter paper coated with TiO2 photocatalyst. Second, Staphylococcus aureus in the aerosol decreased gradually in the photocatalysis process of UV LED/TiO2. After 52 h irradiation all the S. aureus were killed. CONCLUSION: The UV LED light source panel had a larger surface for irradiation than a mercury lamp. Thus, its sterilization efficiency was much better than that of traditional methods. The feasibility of UV LED/TiO2 for photocatalysis was proved. Copyright © 2009 Society of Chemical Industry [source]


Removing pharmaceuticals and endocrine-disrupting compounds from wastewater by photocatalysis

JOURNAL OF CHEMICAL TECHNOLOGY & BIOTECHNOLOGY, Issue 2 2007
Omatoyo K Dalrymple
Abstract Widespread concerns continue to be raised about the increasing presence of emerging contaminants in the environment. Such compounds include a wide range of persistent organic chemicals, including pharmaceuticals and endocrine-disrupting compounds whose effects are poorly known, often because they have only begun to enter the environment and are showing up in wastewater treatment plants. The occurrence and behavior of these compounds in wastewater are key issues with regard to water reclamation and reuse. Treatment plants are now faced with the challenge of removing the compounds from their effluent before they enter natural waterways. In this regard, photocatalysis is a promising technology for wastewater treatment that offers many advantages over conventional and some advanced treatment options. The application of photocatalysis for the removal of pharmaceuticals and endocrine-disrupting compounds for wastewater is comprehensively surveyed in this paper. This treatment technology is not intended to replace conventional systems but to supplement for higher-quality effluent. The assessment places emphasis on the process fundamentals, advantages, and disadvantages of the technology. It also focuses on the current limitations and future research needs. Copyright © 2007 Society of Chemical Industry [source]


Bioprocesses for the removal of nitrogen oxides from polluted air

JOURNAL OF CHEMICAL TECHNOLOGY & BIOTECHNOLOGY, Issue 5 2005
Yaomin Jin
Abstract Nitrogen oxides (NOx) of environmental concern are nitrogen monoxide (NO) and nitrogen dioxide (NO2). They are hazardous air pollutants that lead to the formation of acid rain and tropospheric ozone. Both pollutants are usually present simultaneously and are, therefore, called NOx. Another compound is N2O which is found in the stratosphere where it plays a role in the greenhouse effect. Concern for environmental and health issues coupled with stringent NOx emission standards generates a need for the development of efficient low-cost NOx abatement technologies. Under such circumstances, it becomes mandatory for each NOx-emitting industry or facility to opt for proper NOx control measures. Several techniques are available to control NOx emissions: selective catalytic reduction (SCR), selective non-catalytic reduction (SNCR), adsorption, scrubbing, and biological methods. Each process offers specific advantages and limitations. Since bioprocesses present many advantages over conventional technologies for flue gas cleaning, a lot of interest has recently been shown for these processes. This article reviews the major characteristics of conventional non-biological technologies and recent advances in the biological removal of NOx from flue gases based on the catalytic activity of either eucaryotes or procaryotes, ie nitrification, denitrification, the use of microalgae, and a combined physicochemical and biological process (BioDeNOx). Relatively uncomplicated design and simple operation and maintenance requirements make biological removal a good option for the control of NOx emissions in stationary sources. Copyright © 2005 Society of Chemical Industry [source]


Reflection, the way to professional development?

JOURNAL OF CLINICAL NURSING, Issue 3 2004
Christine Gustafsson MA
Background., Many studies have focused on reflection and the advantages that can be gained from the practice of reflection among Registered Nurses (RNs) but, what are the implications of the nurses' reflections, what do they reflect about, and how do they deal with their reflections? Aims and objectives., The aim of this study was to describe the RNs' experiences of reflection in relation to nursing care situations, and to understand how RNs use reflection in their daily work. What are the implications of the nursing care situations that the RNs' reflect upon? What consequences did the practice of reflection have in nursing care situations in relation to the RNs professional development? Design and method., The study was carried out with interviews and the phenomenographic method. Interviews were carried out with four RNs. The choice of informants was made with purposive sampling with the aim of finding informants who could bring the kind of knowledge that was necessary for the study. Results., The qualitative differences regarding the RNs' experiences of reflection were categorized as follows: to reflect (to think back , consider, mirroring, to reflect before and reflect after, to use experiences), nursing care situations (ethical considerations, to have courage, to use one's imagination, empathy) and consequences (to meet the unique, empathy, development). Finally, the findings were implicated in the model of professional development. Conclusion., By using reflection as a tool, many advantages can be gained in the development of nursing care. Encouraging RNs to reflect upon nursing situations, in order to promote the nurse's professional development, will imply better nursing care for the patients. The model for professional development implies a simplified representation of the thoughts pertaining to professional nursing development. Relevance to clinical practice., The relevance for clinical practice will be to understand the contents of the RNs reflections, to recognize the advantages of reflective practice and how and when to use such measures. Furthermore, to show how the model for professional development can be used in order to create a framework for evaluating these observations and consequently, for expressing tacit knowledge. [source]


Flexible system for simulating and tele-operating robots through the internet

JOURNAL OF FIELD ROBOTICS (FORMERLY JOURNAL OF ROBOTIC SYSTEMS), Issue 3 2005
F. A. Candelas
Simulation and teleoperation tools offer many advantages for the training or learning of technological subjects, such as flexibility in time-tables and student access to expensive and limited equipment. In this paper, we present a new system for simulating and tele-operating robot arms through the Internet, which allows many users to simulate and test positioning commands for a robot by means of a virtual environment, as well as execute the validated commands in a real remote robot of the same characteristics. The main feature of the system is its flexibility in managing different robots or including new robot models and equipment. © 2005 Wiley Periodicals, Inc. [source]


Facial Soft Tissue Depths in Craniofacial Identification (Part II): An Analytical Review of the Published Sub-Adult Data,

JOURNAL OF FORENSIC SCIENCES, Issue 6 2008
Carl N. Stephan Ph.D.
Abstract:, Prior research indicates that while statistically significant differences exist between subcategories of the adult soft tissue depth data, magnitudes of difference are small and possess little practical meaning when measurement errors and variations between measurement methods are considered. These findings raise questions as to what variables may or may not hold meaning for the sub-adult data. Of primary interest is the effect of age, as these differences have the potential to surpass the magnitude of measurement error. Data from the five studies in the literature on sub-adults which describe values for single integer age groups were pooled and differences across the ages examined. From 1 to 18 years, most soft tissue depth measurements increased by less than 3 mm. These results suggest that dividing the data for children into more than two age groups is unlikely to hold many advantages. Data were therefore split into two groups with the division point corresponding to the mid-point of the observed trends and main data density (0,11 and 12,18 years; division point = 11.5 years). Published sub-adult data for seven further studies which reported broader age groups were pooled with the data above to produce the final tallied soft tissue depth tables. These tables hold the advantages of increased sample sizes (pogonion has greater than 1770 individuals for either age group) and increased levels of certainty (as random and opposing systematic errors specific to each independent study should average out when the data are combined). [source]


Preparation of polymer-supported polyethylene glycol and phase-transfer catalytic activity in benzoate synthesis

AICHE JOURNAL, Issue 3 2010
Baojiao Gao
Abstract The crosslinked polymeric microspheres (GMA/MMA) of glycyl methacrylate (GMA) and methyl methacrylate (MMA) were prepared by suspension polymerization. Polyethylene glycol (PEG) was grafted on GMA/MMA microsphers via the ring-opening reaction of the epoxy groups on the surfaces of GMA/MMA microspheres, forming a polymer-supported triphase catalyst, PEG-GMA/MMA. The Phase-transfer catalytic activity of PEG-GMA/MMA microspheres was evaluated using the esterification reaction of n -chlorobutane in organic phase and benzoic acid in water phase as a model system. The effects of various factors on the phase transfer catalysis reaction of liquid,solid,liquid were investigated. The experimental results show that the PEG-GMA/MMA microspheres are an effective and stable triphase catalyst for the esterification reaction carried out between oil phase and water phase. The polarity of the organic solvent, the ratio of oil phase volume to water phase volume and the density of the grafted PEG on PEG-GMA/MMA microspheres affect the reaction rate greatly. For this investigated system, the solvent with high polarity is appropriate, an adequate volume ratio of oil phase to water phase is 2:1, and the optimal PEG density on the polymeric microspheres is 15 g/100 g. Triphase catalysts offer many advantages associated with heterogeneous catalysts such as easy separation from the reaction mixture and reusability. The activity of PEG-GMA/MMA microspheres is not nearly decreased after reusing of 10 recycles. © 2009 American Institute of Chemical Engineers AIChE J, 2010 [source]


Design of mixed conducting ceramic membranes/reactors for the partial oxidation of methane to syngas

AICHE JOURNAL, Issue 10 2009
Xiaoyao Tan
Abstract The performance of mixed conducting ceramic membrane reactors for the partial oxidation of methane (POM) to syngas has been analyzed through a two-dimensional mathematical model, in which the material balance, the heat balance and the momentum balance for both the shell and the tube phase are taken into account. The modeling results indicate that the membrane reactors have many advantages over the conventional fixed bed reactors such as the higher CO selectivity and yield, the lower heating point and the lower pressure drop as well. When the methane feed is converted completely into product in the membrane reactors, temperature flying can take place, which may be restrained by increasing the feed flow rate or by lowering the operation temperature. The reaction capacity of the membrane reactor is mainly determined by the oxygen permeation rate rather than by the POM reaction rate on the catalyst. In order to improve the membrane reactor performance, reduction of mass transfer resistance in the catalyst bed is necessary. Using the smaller membrane tubes is an effective way to achieve a higher reaction capacity, but the pressure drop is a severe problem to be faced. The methane feed velocity for the operation of mixed conducting membrane reactors should be carefully regulated so as to obtain the maximum syngas yield, which can be estimated from their oxygen permeability. The mathematical model and the kinetic parameters have been validated by comparing modeling results with the experimental data for the La0.6Sr0.4Co0.2Fe0.8O3-, (LSCF) membrane reactor. © 2009 American Institute of Chemical Engineers AIChE J, 2009 [source]


A ceramic microfiltration tube membrane dispersion extractor

AICHE JOURNAL, Issue 2 2004
G. G. Chen
Abstract Although the phase-free membrane extraction process has shown many advantages over the traditional extraction, the process is still at the experimental stage. On the other hand, in a new extractor a microfiltration membrane is used as a dispersion medium. The mass-transfer performance of the new extractor was tested with 30% TBP (in kerosene),nitric acid,H2O as an experimental system. The overall mass-transfer coefficient and the equipment efficiency were calculated with the concentrations of the inlet and outlet. The extractor was designed and constructed with two special inner elements for improving the performance further. The effects of the transmembrane pressure, the continuous-phase flow rate, and the geometric parameters of the inner elements on the mass-transfer performance, as well as on the flux of the dispersion phase, are discussed. The experimental results showed that very higher efficiency was reached. The inner elements could improve the mass-transfer performance greatly by changing the two-phase contact status. The results suggested that the mass-transfer process could be completed quickly while the drop size was in the range of micrometers. In addition, the flux of the dispersed phase was mainly influenced by the transmembrane pressure, not by the equipment structures, inner elements, and the continuous-phase flow rate. The new extractor can be operated with very higher efficiency and higher flux, and the efficiency can be predicted with a cubic polynomial. © 2004 American Institute of Chemical Engineers AIChE J, 50: 382,387, 2004 [source]


Failure of xenoimplantation using porcine synovium-derived stem cell-based cartilage tissue constructs for the repair of rabbit osteochondral defects

JOURNAL OF ORTHOPAEDIC RESEARCH, Issue 8 2010
Ming Pei
Abstract The use of xenogeneic tissues offers many advantages with respect to availability, quality control, and timing of tissue harvest. Our previous study indicated that implantation of premature tissue constructs from allogeneic synovium-derived stem cells (SDSCs) facilitated cartilage tissue regeneration. The present study investigated the feasibility of xenoimplantation of SDSC-based premature tissue constructs for the repair of osteochondral defects. Porcine SDSCs were mixed with fibrin gel, seeded in polyglycolic acid (PGA) scaffolds, and cultured in a rotating bioreactor system supplemented for 1 month with growth factor cocktails. The engineered porcine premature tissues were implanted to repair surgically induced osteochondral defects in the medial femoral condyles of 12 rabbits. Three weeks after surgery, the xenoimplantation group exhibited a smooth, whitish surface while the untreated control remained empty. Surprisingly, 6 months after surgery, the xenoimplantation group displayed some tissue loss while the untreated control group was overgrown with fibrocartilage tissue. In the xenoimplantation group, chronic inflammation was observed in synovial tissue where porcine major histocompatibility complex (MHC) class II antigen positively stained in the engulfed foreign bodies. In addition, porcine source cells also migrated from the implantation site and may have been responsible for the observed loss of glycosaminoglycans (GAGs) underneath surrounding articular cartilage. The histological score was much worse in the xenoimplanted group than in the untreated control. Our study suggested that SDSC-based xenogeneic tissue constructs might cause delayed immune rejection. Xenotransplantation may not be an appropriate approach to repair osteochondral defects. © 2010 Orthopaedic Research Society. Published by Wiley Periodicals, Inc. J Orthop Res 28:1064,1070, 2010 [source]