Home About us Contact
|
Home About us Contact | ||
|
|
||
Main Units (main + unit)
Selected Abstracts1,1,-Dimethoxy-3,3,-dimethyl-3,3,-(hexane-1,6-diyl)bis(triazen-2-ium-2-olate): a nitric oxide donorACTA CRYSTALLOGRAPHICA SECTION C, Issue 1 2009Zhengrong Zhou The title compound, C10H24N6O4, is the most stable type of nitric oxide (NO) donor among the broad category of discrete N -diazeniumdiolates (NO adducts of nucleophilic small molecule amines). Sitting astride a crystallographic inversion center, the molecule contains a symmetric dimethylhexane-1,6-diamine structure bearing two planar O2 -methylated N -diazeniumdiolate functional groups [N(O)=NOMe]. These two groups are parallel to each other and have the potential to release four molecules of NO. The methylated diazeniumdiolate substituent removes the negative charge from the typical N(O)=NO, group, thereby increasing the stability of the diazeniumdiolate structure. The crystal was nonmerohedrally twinned by a 180° rotation about the real [101] axis. This is the first N -based bis-diazeniumdiolate compound with a flexible aliphatic main unit to have its structure analyzed and this work demonstrates the utility of stabilizing the N -diazeniumdiolate functional group by methylation. [source] Projecting climate change impacts on species distributions in megadiverse South African Cape and Southwest Australian Floristic Regions: Opportunities and challengesAUSTRAL ECOLOGY, Issue 4 2010COLIN J. YATES Abstract Increasing evidence shows that anthropogenic climate change is affecting biodiversity. Reducing or stabilizing greenhouse gas emissions may slow global warming, but past emissions will continue to contribute to further unavoidable warming for more than a century. With obvious signs of difficulties in achieving effective mitigation worldwide in the short term at least, sound scientific predictions of future impacts on biodiversity will be required to guide conservation planning and adaptation. This is especially true in Mediterranean type ecosystems that are projected to be among the most significantly affected by anthropogenic climate change, and show the highest levels of confidence in rainfall projections. Multiple methods are available for projecting the consequences of climate change on the main unit of interest , the species , with each method having strengths and weaknesses. Species distribution models (SDMs) are increasingly applied for forecasting climate change impacts on species geographic ranges. Aggregation of models for different species allows inferences of impacts on biodiversity, though excluding the effects of species interactions. The modelling approach is based on several further assumptions and projections and should be treated cautiously. In the absence of comparable approaches that address large numbers of species, SDMs remain valuable in estimating the vulnerability of species. In this review we discuss the application of SDMs in predicting the impacts of climate change on biodiversity with special reference to the species-rich South West Australian Floristic Region and South African Cape Floristic Region. We discuss the advantages and challenges in applying SDMs in biodiverse regions with high levels of endemicity, and how a similar biogeographical history in both regions may assist us in understanding their vulnerability to climate change. We suggest how the process of predicting the impacts of climate change on biodiversity with SDMs can be improved and emphasize the role of field monitoring and experiments in validating the predictions of SDMs. [source] Upper Pleistocene-Holocene geomorphic changes dictating sedimentation rates and historical land use in the valley system of the Chifeng region, Inner Mongolia, northern ChinaEARTH SURFACE PROCESSES AND LANDFORMS, Issue 11 2010Y. Avni Abstract This study focuses on the late Quaternary landscape evolution in the Chifeng region of Inner Mongolia, China, its relations to the history of the Pleistocene-Holocene loess accumulation, erosion and redeposition, and their impact on human occupation. Based on 57 optically stimulated luminescence (OSL) ages of loess sediments, fluvial sand and floodplain deposits accumulated on the hill slopes and floodplains, we conclude that during most of the Pleistocene period the region was blanketed by a thick layer of aeolian loess, as well as by alluvial and fluvial deposits. The loess section is divided into two main units that are separated by unconformity. The OSL ages at the top of the lower reddish loess unit yielded an approximate age of 193,ka, roughly corresponding to the transition from MIS 7 to 6, though they could be older. The upper gray loess unit accumulated during the upper Pleistocene glacial phase (MIS 4,3) at a mean accumulation rate of 0·22,m/ka. Parallel to the loess accumulation on top of the hilly topography, active fans were operating during MIS 4,2 at the outlet of large gullies surrounding the major valley at a mean accumulation rate of 0·24,m/ka. This co-accumulation indicates that gullies have been a long-term geomorphic feature at the margins of the Gobi Desert since at least the middle Pleistocene. During the Holocene, the erosion of the Pleistocene loess on the hills led to the burial of the valley floors by the redeposited sediments at a rate that decreases from 3·2,m/ka near the hills to 1,0·4,m/ka1 in the central part of the Chifeng Valley. This rapid accumulation and the frequent shifts of the courses of the river prevented the construction of permanent settlements in the valley floors, a situation which changed only with improved man-made control of the local rivers from the tenth century AD. Copyright © 2010 John Wiley & Sons, Ltd. [source] Energy,exergy analysis and modernization suggestions for a combined-cycle power plantINTERNATIONAL JOURNAL OF ENERGY RESEARCH, Issue 2 2006Ahmet Cihan Abstract Energy and exergy analysis were carried out for a combined-cycle power plant by using the data taken from its units in operation to analyse a complex energy system more thoroughly and to identify the potential for improving efficiency of the system. In this context, energy and exergy fluxes at the inlet and the exit of the devices in one of the power plant main units as well as the energy and exergy losses were determined. The results show that combustion chambers, gas turbines and heat recovery steam generators (HRSG) are the main sources of irreversibilities representing more than 85% of the overall exergy losses. Some constructive and thermal suggestions for these devices have been made to improve the efficiency of the system. Copyright © 2005 John Wiley & Sons, Ltd. [source] Structure and impact indicators of the Cretaceous sequence of the ICDP drill core Yaxcopoil-1, Chicxulub impact crater, MexicoMETEORITICS & PLANETARY SCIENCE, Issue 7 2004T. KENKMANN The Cretaceous rocks are investigated with respect to deformation features and shock metamorphism to better constrain the deformational overprint and the kinematics of the cratering process. The sequence displays variable degrees of impact-induced brittle damage and post-impact brittle deformation. The degree of tilting and faulting of the Cretaceous sequence was analyzed using 360°-core scans and dip-meter log data. In accordance with lithological information, these data suggest that the sedimentary sequence represents a number of structural units that are tilted and moved with respect to each other. Three main units and nine sub-units were discriminated. Brittle deformation is most intense at the top of the sequence and at 1300,1400 m. Within these zones, suevitic dikes, polymict clastic dikes, and impact melt rock dikes occur and may locally act as decoupling horizons. The degree of brittle deformation depends on lithology; massive dolomites are affected by penetrative faulting, while stratified calcarenites and bituminous limestones display localized faulting. The deformation pattern is consistent with a collapse scenario of the Chicxulub transient crater cavity. It is believed that the Cretaceous sequence was originally located outside the transient crater cavity and eventually moved downward and toward the center to its present position between the peak ring and the crater rim, thereby separating into blocks. Whether or not the stack of deformed Cretaceous blocks was already displaced during the excavation process remains an open question. The analysis of the deformation microstructure indicates that a shock metamorphic overprint is restricted to dike injections with an exception of the so called "paraconglomerate." Abundant organic matter in the Yax-1 core was present before the impact and was mobilized by impact-induced heating and suggests that >12 km3 of organic material was excavated during the cratering process. [source] Design and application of a membrane bioreactor unit to upgrade and enhance the required performance of an installed wastewater treatment plantASIA-PACIFIC JOURNAL OF CHEMICAL ENGINEERING, Issue 1 2010Teresa Castelo-Grande Abstract Wastewater treatment plants (WWTPs) are nowadays common solutions to improve the quality of streams and soils. However, there are still many issues required to be solved within these plants. We were commissioned to redesign a WWTP in Amarante, Portugal, which was not working properly. Among the several units we have designed, there is a membrane bioreactor representing one of the main units of this remodelled WWTP. The biological treatment stage at the upgraded WWTP will take place in the remodelled primary and secondary settlers and in the remodelled and improved biological reactor. Hence, the primary settler is readapted in such a way that it functions as the anoxic area of the biological treatment, while the aerobic treatment will be sequentially performed at the remodelled biological reactor and at the actual secondary settler. Membrane treatment will be performed by using ultrafiltration membranes. Copyright © 2009 Curtin University of Technology and John Wiley & Sons, Ltd. [source] | ||||||||||