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Macropores

Distribution by Scientific Domains

Engineering	25%
Polymers and Materials Science	20%
Physics and Astronomy	19%
Earth and Environmental Science	17%
Chemistry	11%
Life Sciences	3%

Selected Abstracts

Topographic controls upon soil macropore flow

EARTH SURFACE PROCESSES AND LANDFORMS, Issue 3 2009
Joseph Holden
Abstract Macropores are important components of soil hydrology. The spatial distribution of macropore flow as a proportion of saturated hydraulic conductivity was tested on six humid,temperate slopes using transects of tension infiltrometer measurements. Automated water table and overland flow monitoring allowed the timing of, and differentiation between, saturation-excess overland flow and infiltration-excess overland flow occurrence on the slopes to be determined and related to tension-infiltrometer measurements. Two slopes were covered with blanket peat, two with stagnohumic gleys and two with brown earth soils. None of the slopes had been disturbed by agricultural activity within the last 20 years. This controlled the potential for tillage impacts on macropores. The proportion of near-surface macropore flow to saturated hydraulic conductivity was found to vary according to slope position. The spatial patterns were not the same for all hillslopes. On the four non-peat slopes there was a relationship between locations of overland flow occurrence and reduced macroporosity. This relationship did not exist for the peat slopes investigated because they experienced overland flow across their whole slope surfaces. Nevertheless, they still had a distinctive spatial pattern of macropore flow according to slope position. For the other soils tested, parts of slopes that were susceptible to saturation-excess overland flow (e.g. hilltoes or flat hilltops) tended to have least macropore flow. To a lesser extent, for the parts of slopes susceptible to infiltration-excess overland flow, the proportion of macropore flow as a component of infiltration was also smaller compared with the rest of the slope. The roles of macropore creation and macropore infilling by sheet wash are discussed, and it is noted that the combination of these may result in distinctive topographically controlled spatial patterns of macropore flow. Copyright © 2008 John Wiley & Sons, Ltd. [source]

A classification of drainage and macropore flow in an agricultural catchment

HYDROLOGICAL PROCESSES, Issue 1 2002
Dr C. M. Heppell
Abstract This paper uses a variety of multivariate statistical techniques in order to improve current understanding of the antecedent and rainfall controls on drainage characteristics for an agricultural underdrained clay site. Using the dataset obtained from a two-year hillslope study at Wytham (Oxfordshire, UK) a number of patterns in the nature and style of drainage events were explored. First, using principal components analysis, a distinction was drawn between drainflow controlled by antecedent conditions and drainflow controlled by rainfall characteristics. Dimensional analysis then distinguished between two further types of drainflow event: antecedent limited events (ALE) and non-antecedent limited events (NALE). These were drainflow events requiring a minimum antecedent hydraulic head to occur (ALE) and events that occurred in response to rainfall irrespective of the antecedent conditions, because the rainfall was either of high enough intensity or duration to prompt a response in drainflow (NALE). 2. The dataset also made possible a preliminary investigation into the controls on and types of macropore flow at the site. Principal components analysis identified that rainfall characteristics were more important than antecedent conditions in generating high proportions of macropore flow in drainflow. Of the rainfall characteristics studied, rainfall amount and intensity were the dominant controls on the amount of macropore flow, with duration as a secondary control. Two styles of macropore flow were identified: intensity-driven and duration-driven. Intensity-driven events are characterized by rainfall of high intensity and short duration. During such events the amount of macropore flow is proportional to the rainfall intensity and the interaction between macropore and matrix flow is kinetically limited. The second style of macropore flow is characterized by long-duration events. For these events the amount of macropore flow approaches a maximum value whatever the rainfall duration. This suggests that these events are characterized by an equilibrium interaction between macropores and matrix flow. Copyright © 2002 John Wiley & Sons, Ltd. [source]

Theoretical analysis and experimental study on SO2 adsorption onto pistachio-nut-shell activated carbon

AICHE JOURNAL, Issue 2 2009
Aik Chong Lua
Abstract The adsorption study of SO2 onto the activated carbon prepared from pistachio-nut shell was studied theoretically and experimentally. A single-particle sorption model known as concentration-dependent surface diffusivity micropore, surface and macropore diffusion control model incorporating micropore, macropore and surface diffusions, together with a nonlinear isotherm at the micropore mouth, has been derived and solved by a finite difference method. The effects of different types of nonlinear isotherms and concentration dependent surface diffusivities have been thoroughly studied. The effects of adsorbate concentration and temperature on adsorption were studied experimentally. Good agreement was found between the model predictions and the experimental results. The value of the tortuosity factor and the extracted diffusion coefficients obtained are consistent with their corresponding values reported. © 2008 American Institute of Chemical Engineers AIChE J 2009 [source]

Analysis of multicomponent adsorption kinetics on activated carbon

AICHE JOURNAL, Issue 4 2003
L. P. Ding
An integrated mathematical model for the kinetics of multicomponent adsorption on microporous carbon was developed. Transport in this bidisperse solid is represented by balance equations in the macropore and micropore phases, in which gas-phase diffusion dominates the mass transfer in the macropores, with the phenomenological diffusivities represented by the generalized Maxwell,Stefan (GMS) formulation. Viscous flow also contributes to the macropore fluxes and is included in the MS expressions. Diffusion of the adsorbed phase controls the mass transfer in the micropore phase, which is also described in a similar way by the MS method. The adsorption isotherms are represented by a new heterogeneous modified vacancy solution theory formulation of adsorption, which has proved to be a robust method for adsorption on activated carbons. The model is applied to the coadsorption and codesorption of C2H6 and C3H8 on Ajax and Norit carbon, as well as the displacement on Ajax carbon. The effect of the viscous flow in the macropore phase is not significant for the cases studied. The model accurately predicts the overshoot behavior and rollup of C2H6 during coadsorption. The prediction for the heavier compound C3H8 is always satisfactory, though at higher C3H8 mole fraction, the overshoot extent of C2H6 is overpredicted, possibly due to neglect of heat effects. [source]

Pharmaceutical antibiotic compounds in soils , a review

JOURNAL OF PLANT NUTRITION AND SOIL SCIENCE, Issue 2 2003
Sören Thiele-Bruhn
Antibiotics are highly effective, bioactive substances. As a result of their consumption, excretion, and persistence, they are disseminated mostly via excrements and enter the soils and other environmental compartments. Resulting residual concentrations in soils range from a few ,g upto g kg,1 and correspond to those found for pesticides. Numerous antibiotic molecules comprise of a non-polar core combined with polar functional moieties. Many antibiotics are amphiphilic or amphoteric and ionize. However, physicochemical properties vary widely among compounds from the various structural classes. Existing analytical methods for environmental samples often combine an extraction with acidic buffered solvents and the use of LC-MS for determination. In soils, adsorption of antibiotics to the organic and mineral exchange sites is mostly due to charge transfer and ion interactions and not to hydrophobic partitioning. Sorption is strongly influenced by the pH of the medium and governs the mobility and transport of the antibiotics. In particular for the strongly adsorbed antibiotics, fast leaching through soils by macropore or preferential transport facilitated by dissolved soil colloids seems to be the major transport process. Antibiotics of numerous classes are photodegraded. However, on soil surfaces this process if of minor influence. Compared to this, biotransformation yields a more effective degradation and inactivation of antibiotics. However, some metabolites still comprise of an antibiotic potency. Degradation of antibiotics is hampered by fixation to the soil matrix; persisting antibiotics were already determined in soils. Effects on soil organisms are very diverse, although all antibiotics are highly bioactive. The absence of effects might in parts be due to a lack of suitable test methods. However, dose and persistence time related effects especially on soil microorganisms are often observed that might cause shifts of the microbial community. Significant effects on soil fauna were only determined for anthelmintics. Due to the antibiotic effect, resistance in soil microorganisms can be provoked by antibiotics. Additionally, the administration of antibiotics mostly causes the formation of resistant microorganisms within the treated body. Hence, resistant microorganisms reach directly the soils with contaminated excrements. When pathogens are resistant or acquire resistance from commensal microorganisms via gene transfer, humans and animals are endangered to suffer from infections that cannot be treated with pharmacotherapy. The uptake into plants even of mobile antibiotics is small. However, effects on plant growth were determined for some species and antibiotics. Pharmazeutische Antibiotika in Böden , ein Überblick Antibiotika sind hochgradig wirksame, bioaktive Substanzen. Infolge ihrer Anwendung, Ausscheidung und Persistenz werden sie meist über die Exkremente in Böden und andere Umweltkompartimente eingetragen. Die resultierenden Rückstandskonzentrationen in Böden im Bereich von wenigen ,g bis zu g kg,1 entsprechen in etwa denen von Pflanzenschutzmitteln. Die Molekülstruktur von Antibiotika besteht häufig aus einem unpolaren Kern und polaren Randgruppen. Viele Antibiotika sind amphiphil oder amphoter und bilden Ionen, jedoch weisen die zahlreichen Antibiotika unterschiedlicher Strukturklassen stark divergierende physikochemische Eigenschaften auf. In den vorliegenden Nachweis"methoden für Umweltproben werden häufig sauer gepufferte Lösungsmittel zur Extraktion und eine Bestimmung mittels LC-MS kombiniert. Die Adsorption der Antibiotika an den organischen als auch an den mineralischen Bodenaustauschern erfolgt zumeist durch Ladungs- und Ionenwechselwirkungen und weniger durch hydrophobe Bindungen. Das Verteilungsverhalten hängt dabei entscheidend vom pH-Wert des Mediums ab und beeinflusst die Mobilität und Verlagerung der Antibiotika. Bei vielen, insbesondere stark adsorbierten Antibiotika sind v.,a. schnelle Fließvorgänge wie durch präferenziellen und Makroporenfluss sowie der Cotransport mit gelösten Bodenkolloiden von besonderer Bedeutung. Antibiotika vieler Strukturklassen können durch Licht abgebaut werden. Dieser Abbaupfad spielt auf Bodenoberflächen jedoch nur eine untergeordnete Rolle. Hingegen kommt es insbesondere durch biologische Transformationsprozesse zu einer intensiven Degradation und Inaktivierung der Antibiotika. Verschiedene Metaboliten weisen jedoch ebenfalls ein antibiotisches Potential auf. Der Abbau der Antibiotika wird durch die Festlegung in Böden gehemmt; dementsprechend wurde eine Persistenz verschiedener Antibiotika nachgewiesen. Trotz der starken bioaktiven Wirkung aller Antibiotika sind die festgestellten Effekte auf Bodenorganismen sehr unterschiedlich. Dies liegt nicht zuletzt an einem Mangel an geeigneten Testmethoden. In der Regel sind jedoch von Dosis und Wirkungsdauer abhängige Effekte insbesondere auf Mikroorganismen festzustellen, die zu Veränderungen der Mikroorganismenpopulation führen können. Lediglich durch Anthelmintika wurden deutliche Wirkungen auf Vertreter der Bodenfauna hervorgerufen. Infolge der antibiotischen Wirkung der Pharmazeutika kann eine Resistenzbildung bei Bodenorganismen ausgelöst werden. Zudem hat die Medikation von Antibiotika die Bildung resistenter Mikroorganismen bereits im behandelten Organismus zur Folge. Durch deren anschließende Ausscheidung gelangen resistente Keime auch direkt in die Böden. Handelt es sich um resistente Pathogene oder kommt es zur Übertragung der Resistenzgene zwischen kommensalen und pathogenen Mikroorganismen, so besteht das erhebliche Risiko einer nicht therapierbaren Infektion von Mensch und Tier. Die Aufnahme selbst mobiler Antibiotika in die Pflanzen ist sehr gering. Dennoch wurden bei einigen Pflanzenarten Wirkungen von Antibiotika auf das Wachstum nachgewiesen. [source]

Enhanced control of porous silicon morphology from macropore to mesopore formation

PHYSICA STATUS SOLIDI (A) APPLICATIONS AND MATERIALS SCIENCE, Issue 8 2005
Huimin Ouyang
Abstract Porous silicon (PSi) is a versatile material that possesses a wide range of morphologies. There are two main types of microstructures that are widely used and well studied: branchy mesoporous silicon with pore sizes from 10 nm to 50 nm and classical macroporous silicon with pore sizes from 500 nm to 20 µm. Much less work has been done on structures with intermediate pore sizes from 100 nm to 300 nm. Applications such as immunoassays biosensing can greatly benefit from the intermediate morphology due to the larger pore openings compared to mesopores, and increased internal surface compared to classical macropores. In this work we demonstrate well-defined macropore of 150 nm diameter in average and precise control of the porous silicon morphology transition from smooth macropores to branchy mesopores on one substrate with one electrolyte. A multilayer structure (microcavity) consisting of both mesopores and macropores is presented. (© 2005 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) [source]

Preparation of Medium Cation Exchange Stationary Phase of Polymeric Matrix and Their Chromatographic Properties

CHINESE JOURNAL OF CHEMISTRY, Issue 1 2007
Gang Chen
Abstract Based on the monodisperse poly(glycidyl methacrylate-co-ethylenedimethacrylate) beads (PGMA/EDMA) with macropore as a medium, a new hydrophilic medium cation exchange (MCX) stationary phase for HPLC was synthesized by a new chemically modified method. The stationary phase was evaluated with the property of ion exchange, separability, reproducibility, hydrophilicity, effect of salt concentration, salt types, column loading and pH on the separation and retention of proteins in detail. It was found that it follows ion exchange chromatographic (IEC) retention mechanism. The measured bioactivity recovery for lysozyme was (96±5)%. The dynamic protein loading capacity of the synthesized MCX packings was 21.8 mg/g. Five proteins were almost completely separated within 6.0 min at a flow rate of 4 mL/min using the synthesized MCX resin. The MCX resin was also used for the rapid separation and purification of lysozyme from egg white with only one step. The purity and specific bioactivity of the purified lysozyme was found more than 95% and 70345 U/mg, respectively. [source]

Healing of rabbit calvarial bone defects using biphasic calcium phosphate ceramics made of submicron-sized grains with a hierarchical pore structure

CLINICAL ORAL IMPLANTS RESEARCH, Issue 3 2010
Jin-Woo Park
Abstract Objectives: This study investigated the efficacy of new bone graft substitutes , biphasic calcium phosphates (BCP) made of submicron-sized grains with fully interconnected wide-range micron-scale pores in two different macrodesigns: donut shaped with a 300,400 ,m central macropore (n-BCP-1) or rod-shaped (n-BCP-2) , in the healing of rabbit calvarial defects, and compared their bone-healing properties with those of various commercial bone substitutes, which included substitutes with similar BCP composition (MBCP and Osteon), anorganic bovine bone (Bio-Oss), and ,-TCP (Cerasorb). Material and methods: The surface morphology of the bone substitutes was investigated using scanning electron microscopy (SEM). Defects 8 mm in diameter were created in the calvaria of 30 adult male New Zealand White rabbits and were filled with six types of bone substitutes. The percentage of newly formed bone (NB%) was evaluated histomorphometrically 4 and 8 weeks after implantation. Results: SEM observation showed submicron-sized grains with fully interconnected micropore structures in the n-BCP-1 and n-BCP-2 groups; these groups also showed considerable new bone formation in inner micropores as well as on the outer surfaces. The n-BCP-1 group exhibited enhanced new bone formation and direct ingrowth of bone tissue with blood vessels into central pores. Histomorphometric analysis showed significantly greater NB% in the n-BCP-1 group when compared with the other groups at 4 and 8 weeks (P<0.05). Conclusion: A new BCP ceramics made of submicron-sized grains with a hierarchical pore structure was an effective osteoconductive material for the treatment of osseous defects of rabbit calvaria. To cite this article: Park J-W, Kim E-S, Jang J-H, Suh J-Y, Park K-B, Hanawa T. Healing of rabbit calvarial bone defects using biphasic calcium phosphate ceramics made of submicron-sized grains with a hierarchical pore structure. Clin. Oral Impl. Res. 21, 2010; 268,276. doi: 10.1111/j.1600-0501.2009.01846.x [source]

Topographic controls upon soil macropore flow

Monodisperse Mesoporous Silica Spheres Inside a Bioactive Macroporous Glass,Ceramic Scaffold,

ADVANCED ENGINEERING MATERIALS, Issue 7 2010
Renato Mortera
In the field of bone tissue engineering, monosized MCM-41 spheres have been incorporated inside a bioactive glass,ceramic macroporous scaffold belonging to the SiO2CaOK2O (SCK) system so obtaining a multiscale hierarchical composite. The MCM-41-SCK system was prepared by dipping the glass,ceramic scaffold into the MCM-41 synthesis solution and was characterized by means of XRD, micro-XRD, N2 sorption and scanning electron microscopy. The MCM-41 spheres inside the scaffold are highly uniform in diameter, as those synthesized in powder form. The adsorption capacity of the composite toward ibuprofen is three times higher than that of the MCM-41-free scaffold, because of the presence of the ordered mesoporous silica. Also the release behavior in SBF at 37,°C is strongly affected by the presence of MCM-41 inside the scaffold macropores. [source]

Impact of stone content on water movement in water-repellent sand

EUROPEAN JOURNAL OF SOIL SCIENCE, Issue 3 2009
E. Urbanek
Summary Soils are commonly stony, especially in steep upland or heavily degraded sites. The hydrological effect of large stone contents has been previously investigated in wettable but not in water-repellent soils. For the latter, the focus has instead been on the impact of other soil characteristics (e.g. cracks and macropores) likely to promote water percolation. This paper investigates stone effects on water flow in water-repellent sand under laboratory conditions. Seventy-five experiments were performed on a water-repellent sand mixed with a range of quantities of different-sized wettable and water-repellent stones. The time taken for water to pass through each sand,stone mix, the percolated water volumes and numbers of dry and wet stones following each 60-minute experiment were recorded. At large stone contents (> 55% or > 65% by weight, depending on stone wettability), percolation occurred relatively quickly and in comparatively large quantities. At intermediate stone contents (45,65%) percolation response was variable and at stone contents < 45% for wettable and < 55% for water-repellent soils no water percolation occurred. We argue that with large stone contents flow pathways develop along sand,stone interfaces and a continuous preferential flow path can form provided there are sufficient stone-to-stone connections. The distribution and alignment of the stones, especially at intermediate stone contents, are important for promoting water movement. Water repellency determinations based only on the fine sediment component in stony soils could therefore be misleading as regards determining their hydrological response: the influence of the clastic component must also be considered. [source]

Mass fractal dimension of soil macropores using computed tomography: from the box-counting to the cube-counting algorithm

EUROPEAN JOURNAL OF SOIL SCIENCE, Issue 3 2003
J.S. Perret
Summary Transport phenomena in porous media depend strongly on three-dimensional pore structures. Macropore networks enable water and solute to move preferentially through the vadose zone. A complete representation of their geometry is important for understanding soil behaviour such as preferential flow. Once we know the geometrical, topological and scaling attributes of preferential flow paths, we can begin computer simulations of water movement in the soil. The box-counting method is used in three dimensions (i.e. cube-counting algorithm) to characterize the mass fractal dimension of macropore networks using X-ray computed tomography (CT) matrices. We developed an algorithm to investigate the mass fractal dimension in three dimensions and to see how it compares with the co-dimensions obtained using the box-counting technique in two dimensions. For that purpose, macropore networks in four large undisturbed soil columns (850 mm × 77 mm diameter) were quantified and visualized, in both two and three dimensions, using X-ray CT. We observed an increasing trend between the fractal dimension and macroporosity for the four columns. Moreover, similar natural logarithm functions were obtained for the four cores by a least squares fit through plots of mass fractal dimension against macroporosity. [source]

Single- and dual-porosity modelling of multiple tracer transport through soil columns: effects of initial moisture and mode of application

EUROPEAN JOURNAL OF SOIL SCIENCE, Issue 1 2001
T. Kätterer
Summary We investigated the effect of initial moisture contents and mode of application on the displacement of multiple conservative tracers through undisturbed columns of a Humic Gleysol. Bromide was applied at the soil surface and chloride was injected at 5 cm depth. The columns were irrigated with deuterium-enriched water. A dual-porosity model and two single-porosity models were calibrated separately to Br, and Cl, elution curves in the two columns. Elution curves were almost identical for Br, and Cl, under initially wet conditions, whereas the displacement of Br, was faster than that of Cl, in the initially dry column, indicating rapid transport with preferential flow. Only the dual-porosity model described the long-tailing breakthrough of Cl, in the initially dry column adequately. The parameter values giving acceptable fits for ,Br dry' were not compatible with the description of the three other elution curves, which could be adequately modelled with a single set of parameter values. The estimated set of common parameters was validated by comparing with the elution curves of deuterium water, nitrate and sulphate, as well as with resident tracer concentrations at four depths. The results showed that solutes can be displaced much faster when applied at the surface of initially dry soil than when applied to wet soil or when resident in the soil matrix. The simulation results suggest that solute transport under initially dry conditions was governed by preferential flow of infiltration water through macropores by-passing the matrix due to shrinkage cracks and water repellence of matrix surfaces. [source]

Porous Structures: In situ Porous Structures: A Unique Polymer Erosion Mechanism in Biodegradable Dipeptide-Based Polyphosphazene and Polyester Blends Producing Matrices for Regenerative Engineering (Adv. Funct.

ADVANCED FUNCTIONAL MATERIALS, Issue 17 2010
Mater.
Abstract Synthetic biodegradable polymers serve as temporary substrates that accommodate cell infiltration and tissue in-growth in regenerative medicine. To allow tissue in-growth and nutrient transport, traditional three-dimensional (3D) scaffolds must be prefabricated with an interconnected porous structure. Here we demonstrated for the first time a unique polymer erosion process through which polymer matrices evolve from a solid coherent film to an assemblage of microspheres with an interconnected 3D porous structure. This polymer system was developed on the highly versatile platform of polyphosphazene-polyester blends. Co-substituting a polyphosphazene backbone with both hydrophilic glycylglycine dipeptide and hydrophobic 4-phenylphenoxy group generated a polymer with strong hydrogen bonding capacity. Rapid hydrolysis of the polyester component permitted the formation of 3D void space filled with self-assembled polyphosphazene spheres. Characterization of such self-assembled porous structures revealed macropores (10,100 ,m) between spheres as well as micro- and nanopores on the sphere surface. A similar degradation pattern was confirmed in vivo using a rat subcutaneous implantation model. 12 weeks of implantation resulted in an interconnected porous structure with 82,87% porosity. Cell infiltration and collagen tissue in-growth between microspheres observed by histology confirmed the formation of an in situ 3D interconnected porous structure. It was determined that the in situ porous structure resulted from unique hydrogen bonding in the blend promoting a three-stage degradation mechanism. The robust tissue in-growth of this dynamic pore forming scaffold attests to the utility of this system as a new strategy in regenerative medicine for developing solid matrices that balance degradation with tissue formation. [source]

In situ Porous Structures: A Unique Polymer Erosion Mechanism in Biodegradable Dipeptide-Based Polyphosphazene and Polyester Blends Producing Matrices for Regenerative Engineering

ADVANCED FUNCTIONAL MATERIALS, Issue 17 2010
Meng Deng
Abstract Synthetic biodegradable polymers serve as temporary substrates that accommodate cell infiltration and tissue in-growth in regenerative medicine. To allow tissue in-growth and nutrient transport, traditional three-dimensional (3D) scaffolds must be prefabricated with an interconnected porous structure. Here a unique polymer erosion process through which polymer matrices evolve from a solid coherent film to an assemblage of microspheres with an interconnected 3D porous structure is demonstrated for the first time. This polymer system is developed on the highly versatile platform of polyphosphazene-polyester blends. Co-substituting a polyphosphazene backbone with both hydrophilic glycylglycine dipeptide and hydrophobic 4-phenylphenoxy group generates a polymer with strong hydrogen bonding capacity. Rapid hydrolysis of the polyester component permits the formation of 3D void space filled with self-assembled polyphosphazene spheres. Characterization of such self-assembled porous structures reveals macropores (10,100 ,m) between spheres as well as micro- and nanopores on the sphere surface. A similar degradation pattern is confirmed In vivo using a rat subcutaneous implantation model. 12 weeks of implantation results in an interconnected porous structure with 82,87% porosity. Cell infiltration and collagen tissue in-growth between microspheres observed by histology confirms the formation of an in situ 3D interconnected porous structure. It is determined that the in situ porous structure results from unique hydrogen bonding in the blend promoting a three-stage degradation mechanism. The robust tissue in-growth of this dynamic pore forming scaffold attests to the utility of this system as a new strategy in regenerative medicine for developing solid matrices that balance degradation with tissue formation. [source]

Pure-Phase Transport and Dissolution of TCE in Sedimentary Rock Saprolite

GROUND WATER, Issue 3 2006
M. Lenczewski
The objective of this study was to experimentally determine the influence of pore structure on the transport and dissolution of trichloroethylene (TCE) in clay-rich saprolite. In order to simulate a "spill," pure-phase TCE containing a water-insoluble fluorescent dye was injected into two heterogeneous 24-cm-diameter by 37-cm-long undisturbed columns of water-saturated saprolite. TCE entry occurred at capillary pressures of 2.7 and 4.0 kPa. Ten or 28 d after injection, the column was sliced horizontally into three sections and visually examined. The distribution of fluorescent dye indicated that pure-phase TCE migrated mainly through fractures in the shale saprolite and through fine root holes or other macropores in the limestone saprolite residuum. Analysis of saprolite subsamples indicated that TCE was present throughout much of the saprolite column but usually at concentrations less than the solubility of TCE. This spreading was caused by diffusion, which also contributed to the rapid dissolution of TCE in the fractures and macropores. Modeling was carried out using previously published dissolution and diffusion equations. The calculations confirm that rapid disappearance of immiscible TCE can occur in this type of material because of the small size of fracture or macropore openings and the high porosity of the fine-grained material. This study indicates that industrial solvents can readily enter fractures and macropores in otherwise very fine-grained subsoils and then rapidly dissolve and diffuse into the fine-pore structure, fromc which they may be very difficult to remove. [source]

Spheres of Microporous Titanosilicate Umbite with Hierarchical Pore Systems,

ADVANCED FUNCTIONAL MATERIALS, Issue 8 2008
Víctor Sebastián
Abstract Micrometric polycrystalline spheres of up to 1,mm diameter of microporous titanosilicate K2TiSi3O9·H2O with umbite structure have been prepared without the use of organic structuring agents. These spheres are organized as micro/macroporous hierarchical materials with macropores in the 0.2,1.4,µm range of average size, showing that intraparticular resistance to water transport is not limiting. Also, similar ion exchange performance can be observed in the Ti-umbite spheres and in the single crystals obtained under the same synthesis conditions. [source]

Preparation, Bioactivity, and Drug Release of Hierarchical Nanoporous Bioactive Glass Ultrathin Fibers

ADVANCED MATERIALS, Issue 6 2010
Youliang Hong
Hierarchical nanoporous bioactive glass ultrathin fibers with different pore diameters from 1.5-nm micropores up to 65-nm macropores are synthesized using P123,PEO co-templates and an electrospinning technique (see image). Experiments demonstrate that the prepared bioactive glass fibers are highly homogenous and bioactive and their nanopores can control drug release well. [source]

Tracing solute infiltration using a combined method of dye tracer test and electrical resistivity tomography in an undisturbed forest soil profile

HYDROLOGICAL PROCESSES, Issue 21 2010
Jae Gon Kim
Abstract An accurate prediction of solute infiltration in a soil profile is important in the area of environmental science, groundwater and civil engineering. We examined the infiltration pattern and monitored the infiltration process using a combined method of dye tracer test and electrical resistivity tomography (ERT) in an undisturbed field soil (1 m × 1 m). A homogeneous matrix flow was observed in the surface soil (A horizon), but a preferential flow along macropores and residual rock structure was the dominant infiltration pattern in the subsurface soil. Saturated interflow along the slopping boundaries of A and C1 horizons and of an upper sandy layer and a lower thin clay layer in the C horizon was also observed. The result of ERT showed that matrix flow started first in A horizon and then the infiltration was followed by the preferential flows along the sloping interfaces and macropores. The ERT did not show as much detail as the dye-stained image for the preferential flow. However, the area with the higher staining density where preferential flow was dominant showed a relatively lower electrical resistivity. The result of this study indicates that ERT can be applied for the monitoring of solute transportation in the vadose zone. Copyright © 2010 John Wiley & Sons, Ltd. [source]

Modelling investigation of water partitioning at a semiarid ponderosa pine hillslope

HYDROLOGICAL PROCESSES, Issue 9 2010
Huade Guan
Abstract The effects of vegetation root distribution on near-surface water partitioning can be two-fold. On the one hand, the roots facilitate deep percolation by root-induced macropore flow; on the other hand, they reduce the potential for deep percolation by root-water-uptake processes. Whether the roots impede or facilitate deep percolation depends on various conditions, including climate, soil, and vegetation characteristics. This paper examines the effects of root distribution on deep percolation into the underlying permeable bedrock for a given soil profile and climate condition using HYDRUS modelling. The simulations were based on previously field experiments on a semiarid ponderosa pine (Pinus ponderosa) hillslope. An equivalent single continuum model for simulating root macropore flow on hillslopes is presented, with root macropore hydraulic parameterization estimated based on observed root distribution. The sensitivity analysis results indicate that the root macropore effect dominates saturated soil water flow in low conductivity soils (Kmatrix below 10,7 m/s), while it is insignificant in soils with a Kmatrix larger than 10,5 m/s, consistent with observations in this and other studies. At the ponderosa pine site, the model with simple root-macropore parameterization reasonably well reproduces soil moisture distribution and some major runoff events. The results indicate that the clay-rich soil layer without root-induced macropores acts as an impeding layer for potential groundwater recharge. This impeding layer results in a bedrock percolation of less than 1% of the annual precipitation. Without this impeding layer, percolation into the underlying permeable bedrock could be as much as 20% of the annual precipitation. This suggests that at a surface with low-permeability soil overlying permeable bedrock, the root penetration depth in the soil is critical condition for whether or not significant percolation occurs. Copyright © 2010 John Wiley & Sons, Ltd. [source]

Solute movement through intact columns of cryoturbated Upper Chalk

HYDROLOGICAL PROCESSES, Issue 13 2008
M. Mahmood-ul-Hassan
Abstract Cryoturbated Upper Chalk is a dichotomous porous medium wherein the intra-fragment porosity provides water storage and the inter-fragment porosity provides potential pathways for relatively rapid flow near saturation. Chloride tracer movement through 43 cm long and 45 cm diameter undisturbed chalk columns was studied at water application rates of 0·3, 1·0, and 1·5 cm h,1. Microscale heterogeneity in effluent was recorded using a grid collection system consisting of 98 funnel-shaped cells each 3·5 cm in diameter. The total porosity of the columns was 0·47 ± 0·02 m3 m,3, approximately 13% of pores were , 15 µm diameter, and the saturated hydraulic conductivity was 12·66 ± 1·31 m day,1. Although the column remained unsaturated during the leaching even at all application rates, proportionate flow through macropores increased as the application rate decreased. The number of dry cells (with 0 ml of effluent) increased as application rate decreased. Half of the leachate was collected from 15, 19 and 22 cells at 0·3, 1·0, 1·5 cm h,1 application rates respectively. Similar breakthrough curves (BTCs) were obtained at all three application rates when plotted as a function of cumulative drainage, but they were distinctly different when plotted as a function of time. The BTCs indicate that the columns have similar drainage requirement irrespective of application rates, as the rise to the maxima (C/Co) is almost similar. However, the time required to achieve that leaching requirement varies with application rates, and residence time was less in the case of a higher application rate. A two-region convection,dispersion model was used to describe the BTCs and fitted well (r2 = 0·97,0·99). There was a linear relationship between dispersion coefficient and pore water velocity (correlation coefficient r = 0·95). The results demonstrate the microscale heterogeneity of hydrodynamic properties in the Upper Chalk. Copyright © 2007 John Wiley & Sons, Ltd. [source]

Application of a coil-type TDR probe for measuring the volumetric water content in weathered granitic bedrock

HYDROLOGICAL PROCESSES, Issue 6 2008
Shin'ya Katsura
Abstract As a first step toward describing water flow processes in bedrock, a coil-type time domain reflectometry (TDR) probe capable of measuring volumetric water content, ,, in weathered bedrock at three depths was prepared. Because the coil-type TDR probe is large in diameter (19 mm), it can be installed even in highly weathered bedrock more easily and appropriately than conventional TDR probes that consists of two or three rods of small diameter (5-8 mm). The probe calibrations suggest that the values measured by the probe are very sensitive to changes in ,. Using the calibrated probe together with commercially available profile soil moisture sensors, the , profile was monitored for 1 year. Even rainfall events with relatively small cumulative rainfall of 15 mm increased the bedrock ,, and the increments were comparable to those in the soil. After the end of the rainfall events, the bedrock , displayed a more rapid drop than the soil, and varied little during the period of no rainfall. The water storage showed similar tendencies. These observations suggest that the bedrock , is controlled by clearly distinguishable macropores and micropores within the bedrock. It is concluded that the coil-type TDR probe is very effective in determining , in weathered bedrock, and that bedrock, conventionally defined by conducting cone penetration tests and treated as impermeable, does conduct and hold substantial amounts of water, and therefore contribute greatly to hydrological processes in headwater catchments. Copyright © 2007 John Wiley & Sons, Ltd. [source]

Field and laboratory estimates of pore size properties and hydraulic characteristics for subarctic organic soils

HYDROLOGICAL PROCESSES, Issue 19 2007
Sean K. Carey
Abstract Characterizing active and water-conducting porosity in organic soils in both saturated and unsaturated zones is required for models of water and solute transport. There is a limitation, largely due to lack of data, on the hydraulic properties of unsaturated organic soils in permafrost regions, and in particular, the relationship between hydraulic conductivity and pressure head. Additionally, there is uncertainty as to what fraction of the matrix and what pores conduct water at different pressure heads, as closed and dead-end pores are common features in organic soil. The objectives of this study were to determine the water-conducting porosity of organic soils for different pore radii ranges using the method proposed by Bodhinayake et al. (2004) [Soil Sci. Soc. Am. J. 68:760,769] and compare these values to active pore size distributions from resin-impregnated laboratory thin sections and pressure plate analysis. Field experiments and soil samples were completed in the Wolf Creek Research Basin, Yukon. Water infiltration rates were measured 16 times using a tension infiltrometer (TI) at 5 different pressure heads from , 150 to 0 mm. This data was combined with Gardiner's (1958) exponential unsaturated hydraulic conductivity function to provide water-conducting porosity for different pore-size ranges. Total water-conducting porosity was 1·1 × 10,4, which accounted for only 0·01% of the total soil volume. Active pore areas obtained from 2-D image analysis ranged from 0·45 to 0·60, declining with depth. Macropores accounted for approximately 65% of the water flux at saturation, yet all methods suggest macropores account for only a small fraction of the total porosity. Results among the methods are highly equivocal, and more research is required to reconcile field and laboratory methods of pore and hydraulic characteristics. However, this information is of significant value as organic soils in permafrost regions are poorly characterized in the literature. Copyright © 2007 John Wiley & Sons, Ltd. [source]

Soil water repellency in a Japanese cypress plantation restricts increases in soil water storage during rainfall events

HYDROLOGICAL PROCESSES, Issue 17 2007
Masahiro Kobayashi
Abstract Forest soils in Japan are often water repellent. Substantial water repellency frequently occurs and impedes water infiltration into the soil matrix, but continuous overland flow is not necessarily observed because forest soils usually have macropores through which the water can enter the subsoil. Although this flow pattern may influence the manner of water storage in forest soils at the solum scale, field evidence has not yet indicated this process. We monitored soil water storage during natural rainfall events in a 60-cm deep solum using time domain reflectometry (TDR) moisture sensors, and observed stained flow patterns in the soil following simulated rainfall containing a colour dye, on a slope planted with Japanese cypress (Chamaecyparis obtusa). The surface soil at the research plot exhibited strong water repellency at water contents lower than the threshold critical water content of 0·29 m3 m,3. Under dry antecedent moisture conditions, increases in soil water storage were small compared to the cumulative rainfall, despite the low wetness of the soil matrix. In contrast, under moderate moisture conditions, increases in the water content corresponded to the cumulative rainfall. Under dry conditions, rainwater may have entered the subsoil at a few limited locations connected with continuous vertical macropores, such as decayed root channels or interstructural voids. Therefore, the water seemed to bypass a large part of the soil matrix away from the macropores. Such preferential water flow was confirmed by the stained flow patterns after the rainfall simulation. The flow patterns visualized by the dye were discontinuous and scattered under dry conditions and diffuse under moderate moisture conditions. Repellency induced preferential flow led to restricted increases in solum scale water storage during rainfall events, reflecting a physical nonequilibrium in soil water storage. Copyright © 2007 John Wiley & Sons, Ltd. [source]

The potential roles of biological soil crusts in dryland hydrologic cycles

HYDROLOGICAL PROCESSES, Issue 15 2006
Jayne Belnap
Abstract Biological soil crusts (BSCs) are the dominant living cover in many drylands of the world. They possess many features that can influence different aspects of local hydrologic cycles, including soil porosity, absorptivity, roughness, aggregate stability, texture, pore formation, and water retention. The influence of biological soil crusts on these factors depends on their internal and external structure, which varies with climate, soil, and disturbance history. This paper presents the different types of biological soil crusts, discusses how crust type likely influences various aspects of the hydrologic cycle, and reviews what is known and not known about the influence of biological crusts on sediment production and water infiltration versus runoff in various drylands around the world. Most studies examining the effect of biological soil crusts on local hydrology are done by comparing undisturbed sites with those recently disturbed by the researchers. Unfortunately, this greatly complicates interpretation of the results. Applied disturbances alter many soil features such as soil texture, roughness, aggregate stability, physical crusting, porosity, and bulk density in ways that would not necessarily be the same if crusts were not naturally present. Combined, these studies show little agreement on how biological crusts affect water infiltration or runoff. However, when studies are separated by biological crust type and utilize naturally occurring differences among these types, results indicate that biological crusts in hyperarid regions reduce infiltration and increase runoff, have mixed effects in arid regions, and increase infiltration and reduce runoff in semiarid cool and cold drylands. However, more studies are needed before broad generalizations can be made on how biological crusts affect infiltration and runoff. We especially need studies that control for sub-surface soil features such as bulk density, micro- and macropores, and biological crust structure. Unlike the mixed effects of biological crusts on infiltration and runoff among regions, almost all studies show that biological crusts reduce sediment production, regardless of crust or dryland type.Copyright © 2006 John Wiley & Sons, Ltd. [source]

Comparing the hydrology of grassed and cultivated catchments in the semi-arid Canadian prairies

HYDROLOGICAL PROCESSES, Issue 3 2003
G. van der Kamp
Abstract At the St Denis National Wildlife Area in the prairie region of southern Saskatchewan, Canada, water levels in wetlands have been monitored since 1968. In 1980 and 1983 a total of about one-third of the 4 km2 area was converted from cultivation to an undisturbed cover of brome grass. A few years after this conversion all the wetlands within the area of grass dried out; they have remained dry since, whereas wetlands in adjacent cultivated lands have held water as before. Field measurements show that introduction of undisturbed grass reduces water input to the wetlands mainly through a combination of efficient snow trapping and enhanced infiltration into frozen soil. In winter, the tall brome grass traps most of the snowfall, whereas in the cultivated fields more wind transport of snow occurs, especially for short stubble and fallow fields. Single-ring infiltration tests were conducted during snowmelt, while the soil was still frozen, and again in summer. The infiltrability of the frozen soil in the grassland is high enough to absorb most or all of the snowmelt, whereas in the cultivated fields the infiltration into the frozen soil is limited and significant runoff occurs. In summer, the infiltrability increases for the cultivated fields, but the grassland retains a much higher infiltrability than the cultivated land. The development of enhanced infiltrability takes several years after the conversion from cultivation to grass, and is likely due to the gradual development of macropores, such as root holes, desiccation cracks, and animal burrows. Copyright ©2002 Crown in the right of Canada. Published by John Wiley & Sons, Ltd. [source]

Using time-domain reflectometry to characterize shallow solute transport in an oak woodland hillslope in northern California, USA

HYDROLOGICAL PROCESSES, Issue 15 2002
Chris G. Campbell
Abstract The natural heterogeneity of water and solute movement in hillslope soils makes it difficult to accurately characterize the transport of surface-applied pollutants without first gathering spatially distributed hydrological data. This study examined the application of time-domain reflectometry (TDR) to measure solute transport in hillslopes. Three different plot designs were used to examine the transport of a conservative tracer in the first 50 cm of a moderately sloping soil. In the first plot, which was designed to examine spatial variability in vertical transport in a 1·2 m2 plot, a single probe per meter was found to adequately characterize vertical solute travel times. In addition, a dye and excavation study in this plot revealed lateral preferential flow in small macropores and a transport pattern where solute is focused vertically into preferential flow pathways. The bypass flow delivers solute deeper in the soil, where lateral flow occurs. The second plot, designed to capture both vertical and lateral flow, provided additional evidence confirming the flow patterns identified in the excavation of the first plot. The third plot was designed to examine lateral flow and once again preferential flow of the tracer was observed. In one instance rapid solute transport in this plot was estimated to occur in as little as 3% of the available pore space. Finally, it was demonstrated that the soil anisotropy, although partially responsible for lateral subsurface transport, may also homogenize the transport response across the hillslope by decreasing vertical solute spreading. Copyright © 2002 John Wiley & Sons, Ltd. [source]

A classification of drainage and macropore flow in an agricultural catchment

A conceptual model of preferential flow systems in forested hillslopes: evidence of self-organization

HYDROLOGICAL PROCESSES, Issue 10 2001
Roy C. Sidle
Abstract Preferential flow paths are known to be important conduits of subsurface stormflow in forest hillslopes. Earlier research on preferential flow paths focused on vertical transport; however, lateral transport is also evident in steep forested slopes underlain by bedrock or till. Macropores consisting of decayed and live roots, subsurface erosion, surface bedrock fractures, and animal burrows form the basis of a ,backbone' for lateral preferential flow in such sites. Evidence from field studies in Japan indicates that although individual macropore segments are generally <0·5 m in length, they have a tendency to self-organize into larger preferential flow systems as sites become wetter. Staining tests show clear evidence of interconnected macropore flow segments, including: flow within decayed root channels and subsurface erosion cavities; flow in small depressions of the bedrock substrate; fracture flow in weathered bedrock; exchange between macropores and mesopores; and flow at the organic horizon,mineral soil interface and in buried pockets of organic material and loose soil. Here we develop a three-dimensional model for preferential flow systems based on distributed attributes of macropores and potential connecting nodes (e.g. zones of loose soil and buried organic matter). We postulate that the spatially variable and non-linear preferential flow response observed at our Japan field site, as well as at other sites, is attributed to discrete segments of macropores connecting at various nodes within the regolith. Each node is activated by local soil water conditions and is influenced strongly by soil depth, permeability, pore size, organic matter distribution, surface and substrate topography, and possibly momentum dissipation. This study represents the first attempt to characterize the spatially distributed nature of preferential flow paths at the hillslope scale and presents strong evidence that these networks exhibit complex system behaviour. Copyright © 2001 John Wiley & Sons, Ltd. [source]

Fabric evolution during hydromechanical loading of a compacted silt

INTERNATIONAL JOURNAL FOR NUMERICAL AND ANALYTICAL METHODS IN GEOMECHANICS, Issue 6 2004
Olivier Cuisinier
Abstract A study was undertaken on a compacted silt to determine fabric modifications induced by suction and/or stress variations. The link between fabric and hydromechanical behaviour was also investigated. A suction-controlled oedometer, using air overpressure, was developed for this purpose and mercury intrusion porosimetry was employed to determine sample fabric. The initial samples fabric was made of macro and micropores. It was shown that suction increase produced a strong decrease in the macroporosity associated with an increase in microporosity. However, some macropores were not significantly affected by the suction increase; this phenomenon might be related to the initial fabric of the samples. Second, it appears that loading under saturated conditions also produces strong fabric modification: the higher the applied stress, the lower the macroporosity. Soil fabric depends on the maximum stress experienced by the soil. Finally, some tests have shown the influence of suction, as well as the role of the degree of saturation, on the deformation process and the mechanical behaviour. The test results show that in the case of unsaturated mechanical loading, all macropores are not destroyed by the mechanical loading. Copyright © 2004 John Wiley & Sons, Ltd. [source]