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Magnetic Susceptibility Studies (magnetic + susceptibility_studies)

Distribution by Scientific Domains

Earth and Environmental Science	50%

Selected Abstracts

A Polymer-Bound Oxidovanadium(IV) Complex Prepared from an L -Cysteine-Derived Ligand for the Oxidative Amination of Styrene

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, Issue 4 2008
Mannar R. Maurya
Abstract The ligand H2sal-cys (I) derived from salicylaldehyde and L -cysteine has been covalently bonded to chloromethylated polystyrene cross-linked with 5,% divinylbenzene. Upon treatment with [VO(acac)2] in dimethylformamide (DMF) the polystyrene-bound ligand PS-H2sal-cys (II) gave the oxidovanadium(IV) complex, PS-[VO(sal-cys)·DMF] (1). The corresponding neat complex, [VO(sal-eta)]2 (2), has also been prepared similarly in methanol. These complexes have been characterised by IR, electronic, EPR spectroscopic studies, magnetic susceptibility measurements and thermal as well as scanning electron micrographs studies. Complex [VO(sal-eta)]2 exhibits a medium intensity band at 980 cm,1 in the IR spectrum due to ,(V=O) stretch. Broad features of the EPR spectrum for the neat complex along with magnetic susceptibility studies suggest the presence of antiferromagnetic exchange interaction between two vanadium centers in close proximity. Both complexes catalyze the oxidative amination of styrene, in mild basic conditions, with secondary amines (diethylamine, imidazole, and benzimidazole) and gave a mixture of two aminated products in good yields. Amongst the two aminated products, the anti-Markovnikov product is favored over the Markovnikov one due to the steric hindrance posed by the secondary amines. The polymer-anchored heterogeneous catalyst is free from leaching during catalytic action and recyclable.(© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008) [source]

Dinuclear Complexes of MII Thiocyanate (M = Ni and Cu) Containing a Tridentate Schiff-Base Ligand: Synthesis, Structural Diversity and Magnetic Properties

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, Issue 12 2005
Suparna Banerjee
Abstract A dinuclear NiII complex, [Ni2(L)2(H2O)(NCS)2]·3H2O (1) in which the metal atoms are bridged by one water molecule and two ,2 -phenolate ions, and a thiocyanato-bridged dimeric CuII complex, [Cu(L)NCS]2 (2) [L = tridentate Schiff-base ligand, N -(3-aminopropyl)salicylaldimine, derived from 1:1 condensation of salicylaldehyde and 1,3-diaminopropane], have been synthesized and characterized by IR and UV/Vis spectroscopy, cyclic voltammetry and single-crystal X-ray diffraction studies. The structure of 1 consists of dinuclear units with crystallographic C2 symmetry in which each NiII atom is in a distorted octahedral environment. The Ni,O distance and the Ni,O,Ni angle, through the bridged water molecule, are 2.240(11) Å and 82.5(5)°, respectively. The structure of 2 consists of dinuclear units bridged asymmetrically by di-,1,3 -NCS ions; each CuII ion is in a square-pyramidal environment with , = 0.25. Variable-temperature magnetic susceptibility studies indicate the presence of dominant ferromagnetic exchange coupling in complex 1 with J = 3.1 cm,1, whereas complex 2 exhibits weak antiferromagnetic coupling between the CuII centers with J = ,1.7 cm,1. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005) [source]

Formation processes at the Ohalo II submerged prehistoric campsite, Israel, inferred from soil micromorphology and magnetic susceptibility studies

GEOARCHAEOLOGY: AN INTERNATIONAL JOURNAL, Issue 4 2003
Alexander Tsatskin
Soil-geomorphic analysis coupled with micromorphology, SEM/EDS, magnetic susceptibility, and conventional sedimentological studies allowed us to reconstruct the site formation history and validate the archaeologically observed variability of human activities in the prehistoric camp of Ohalo II (19.5 ka B.P.), Sea of Galilee, Israel. The cultural layers rest upon the Late Pleistocene Lake Lisan deposits that accumulated under conditions of changing water supply and increasing rate of sedimentation from deep-water varvelike deposits to basalt-derived, near-shore sandy lacustrine deposits. Intermittent occupation is recorded in some localities, indicating short-term inundation episodes, which led to partial truncation and deformation of the sediments, primarily in the eastern lakeward part of the site. On the elevated, landward positions, incipient soils with strongly bioturbated profiles formed. Micromorphology demonstrates that intentional flooring was applied within the remains of brush huts, where millimeter-sized, horizontally organized burnt and unheated vegetal tissues were likely to have been placed upon the compacted ground. In fireplaces, the cultural deposits in thin sections are composed of strongly mixed, abundant wood charcoal, ashes, and fishbone remains. Post-depositional alterations were controlled by intermittent inundation of the site and salinization, which induced gypsum and pyrite deposition, primarily along decayed roots, and eventual pyrite oxidation. Accumulation of sodium and chlorine in the post-occupation deposits is likely to have occurred because of discharge of saline groundwater. Although only suggestive at this stage of research, the conclusions drawn from magnetic susceptibility parameters of archaeologically related deposits at Ohalo II fit well with the micromorphological reconstructions and provide new information on the Late Pleistocene evolution of the Lake Lisan/Sea of Galilee fluctuating system. © 2003 Wiley Periodicals, Inc. [source]

Anisotropy of magnetic susceptibility and petrofabric studies in the Garhwal synform, Outer Lesser Himalaya: Evidence of pop-up klippen

ISLAND ARC, Issue 3 2009
Upasana Devrani
Abstract Geological field, petrographic, and anisotropy of magnetic susceptibility studies help in understanding the evolutionary history of the Garhwal synform that lies in the western Outer Lesser Himalaya. Orientations of the magnetic susceptibility axes reveal large variations at short distances as a result of superimposed deformation, and predominant stress conditions favorable for normal faulting. Rocks forming the outer limbs of the Garhwal Synform are metamorphosed up to the lower greenschist facies. The metamorphic grade increases to chlorite zone in the inner limb and the core is characterized by chlorite,biotite to garnet zones. The different grades of metamorphism are separated by thrusts and the structure is described as a pop-up klippen. [source]