Mn Content (mn + content)

Distribution by Scientific Domains


Selected Abstracts


The influence of curcumin and manganese complex of curcumin on cadmium-induced oxidative damage and trace elements status in tissues of mice

JOURNAL OF APPLIED TOXICOLOGY, Issue 3 2006
Vladislav Eybl
Abstract Curcumin (diferuoyl methane) from turmeric is a well-known biologically active compound. It has been shown to ameliorate oxidative stress and it is considered to be a potent cancer chemopreventive agent. In our previous study the antioxidative effects of curcumin in cadmium exposed animals were demonstrated. Also manganese exerts protective effects in experimental cadmium intoxication. The present study examined the ability of the manganese complex of curcumin (Mn-curcumin) and curcumin to protect against oxidative damage and changes in trace element status in cadmium-intoxicated male mice. Curcumin or Mn-curcumin were administered at equimolar doses (0.14 mmol/kg b.w.) for 3 days, by gastric gavages, dispersed in methylcellulose. One hour after the last dose of antioxidants, cadmium chloride (33 µmol/kg) was administered subcutaneously. Both curcumin and Mn-curcumin prevented the increase of hepatic lipid peroxidation , expressed as MDA level, induced by cadmium intoxication and attenuated the Cd-induced decrease of hepatic GSH level. No change in hepatic glutathione peroxidase or catalase activities was found in Cd-exposed mice. A decreased GSH-Px activity was measured in curcumin and Mn-curcumin alone treated mice. Neither curcumin nor Mn-curcumin treatment influenced cadmium distribution in the tissues and did not correct the changes in the balance of essential elements caused by Cd-treatment. The treatment with Mn-curcumin increased the Fe and Mn content in the kidneys of both control and Cd-treated mice and Fe and Cu content in the brain of control mice. In conclusion, regarding the antioxidative action, introducing manganese into the curcumin molecule does not potentiate the studied effects of curcumin. Copyright © 2005 John Wiley & Sons, Ltd. [source]


A method for calculating effective bulk composition modification due to crystal fractionation in garnet-bearing schist: implications for isopleth thermobarometry

JOURNAL OF METAMORPHIC GEOLOGY, Issue 6 2004
T. P. Evans
Abstract Quantitative P,T path determination in metamorphic rocks is commonly based on the variation in composition of growth-zoned garnet. However, some component of growth zoning in garnet is necessarily the result of an effective bulk composition change within the rock that has been generated by crystal fractionation of components into the core of garnet. Therefore, any quantitative calculation of the P,T regime of garnet growth should be completed using an accurate assessment of the composition of the chemical system from which garnet is growing. Consequently, a method for calculating the extent of crystal fractionation that provides a means of estimating the composition of the unfractionated rock at any stage during garnet growth is developed. The method presented here applies a Rayleigh fractionation model based on measured Mn content of garnet to generate composition v. modal proportion curves for garnet, and uses those curves to estimate the vectors of crystal fractionation. The technique is tested by calculating the precision of the equilibrium between three garnet compositional variables within the chemical system determined to be appropriate for each of a series of microprobe analyses from garnet. Application of the fractionation calculations in conjunction with the P,T estimates based on intersecting compositional isopleths provides a means of calculating P,T conditions of garnet growth that is based on individual point-analyses on a garnet grain. Such spatially precise and easily obtainable P,T data allow for detailed parallel studies of the microstructural, the P,T, and the chemical evolution of metamorphosed pelites. This method provides a means of studying the dynamics of orogenic systems at a resolution that was previously unattainable. [source]


Soil-plant relationships, micronutrient contents, and cardenolide production in natural populations of Digitalis obscura

JOURNAL OF PLANT NUTRITION AND SOIL SCIENCE, Issue 1 2004
Luis Roca-Pérez
Abstract The production of secondary metabolites by plants growing in natural populations is conditioned by environmental factors. In the present study, we have investigated the relationships among soil properties, micronutrients in soils and plants, and cardenolide production from wild Digitalis obscura (Scrophulariaceae) populations. Young and mature leaves and soil samples were collected in ten different populations, corresponding to three Mediterranean bioclimatic belts (Thermo-, Meso-, and Supramediterranean belts). Soil (total and EDTA-extractable) and leaf micronutrients (Fe, Mn, Zn, and Cu), and leaf cardenolide accumulation have been determined. Significant negative correlations were observed between Fe, Mn or Zn concentration in leaves and soil pH, as well as between Fe or Mn in leaves and carbonate content of soils. Only EDTA-extractable Mn was significantly correlated with Mn content in the plants. With regard to cardenolide content in leaves, this parameter was negatively correlated with Znleaf in young leaves and with Mnleaf in old leaves. Positively correlated, however, were Fe and cardenolide content in young leaves. The influence of environmental conditions and leaf micronutrient contents on cardenolide accumulation is discussed. Boden-Pflanze-Wechselwirkungen im Hinblick auf Mikroelement- und Cardenolidgehalte in wilden Digitalisobscura -Populationen Die Produktion von sekundären Stoffwechselprodukten in Pflanzen ist in hohem Grad abhängig von Umweltfaktoren. In dieser Studie wurde bei Wildtypen von Digitalis obscura der Einfluss bodenchemischer Eigenschaften (pH, Karbonatgehalt, Gesamt- und EDTA-extrahierbare Mikronährstoffgehalte) auf die Mikronährstoff- (Fe, Mn, Zn und Cu) und Cardenolidgehalte in den Pflanzen untersucht. Verwendet wurden Proben von jungen und reifen Blättern sowie Bodenproben aus zehn verschiedenen Populationen in drei bioklimatischen Zonen (Thermo-, Meso- und Supramittelmeergebiet). Festgestellt wurden signifikant negative Beziehungen zwischen Fe-, Mn- oder Zn-Gehalten in den Blättern und dem pH des Bodens, sowie zwischen Fe- oder Mn-Konzentration in den Blättern und dem Karbonatgehalt der Böden. Nur EDTA-extrahierbares Mn wies eine positive Beziehung zu den Mn-Gehalten in den Pflanzen auf. Die Ergebnisse deuten darauf hin, dass die Gehalte von Mikroelementen in den Blättern von D. obscura stärker vom pH des Bodens abhängig sind als von den Gesamt- oder den extrahierbaren Mikroelementgehalten der Böden. Ebenso wurden signifikant negative Beziehungen zwischen Cardenolidgehalten und Zn-Gehalten in jungen Blättern, sowie Mn-Gehalten in älteren Blättern festgestellt. Die Fe-Gehalte in jungen Blättern waren jedoch positiv mit dem Cardenolidgehalt korreliert. Diese Befunde werden im Hinblick auf die Cardenolidbiosynthese diskutiert. [source]


Effects of Fungal Phytase on Utilization of Dietary Protein and Minerals, and Dephosphorylation of Phytic Acid in the Alimentary Tract of Channel Catfish Ictalurus punctatus Fed an All-Plant-Protein Diet

JOURNAL OF THE WORLD AQUACULTURE SOCIETY, Issue 1 2002
Weibing Yan
A feeding trial was conducted to quantify the effects of phytase at levels of 0, 500, 1,000, 2,000, 4,000, and 8,000 units (U) per kg diet on utilization of dietary protein and minerals by fingerling (12 g) channel catfish Ictalurus punctatus fed an all-plant-protein diet composed of soybean meal, corn, and wheat middlings. The effects of phytase on dephosphorylation of phytic acid (phytate) in the alimentary tract of catfish also were determined. After 14 wk, mean weight gains (30.2,43.9 g/fish), feed conversion ratios (2.27,2.40 g feed consumed/g weight gain), protein efficiency ratios (1.47,1.61 g weight gaid/g protein consumed), and dietary protein retentions (23.8,26.7%) did not differ significantly (P > 0.05) among treatment groups. A digestibility trial conducted after the feeding trial showed no difference (P > 0.05) in mean digestibility of diet dry matter (49.0,58.3%) or crude protein (85.4-88.5%) among treatment groups. Concentrations of ash (46.7,48.6%), calcium (Ca, 17.9,18.5%), phosphorus (P, 9.1,9.5%), and manganese (Mn, 65.5,74.1 mg/kg) were significantly higher (P , 0.05) in bone of fish fed , 500 U/kg than in bone of fish fed 0 U/kg (ash, 43.5%; Ca, 16.4%; P, 8.4%; and Mn, 49.0 ma/kg), but concentrations of these minerals did not differ (P > 0.05) in bone of fish fed , 500 Uk/g. The magnesium (Mg) content of bone did not differ (P > 0.05) between fish fed 0 U/kg (0.29%) or 500 U/kg (0.34%), but was significantly lower in fish fed 0 U/kg than in fish fed , 1,000 U/kg (0.35,37%). Bone Mg levels did not differ (P > 0.05) among fish fed , 500 U/kg. The amount of zinc (Zn) in bone of fish fed 8,000 U/kg (153.3 mg/kg) was significantly higher than that in fish fed 0 U/kg (115.7 mg/kg) or 500 U/kg (130.3 mg/ kg), but did not differ from Zn levels in bone of fish fed 1,000,4,000 U/kg (134.5,135.8 mg/ kg). Dephosphorylation of phytate occurred primarily in the stomach within 2,8 h after diet ingestion, depending on the level of phytase supplementation. Initial levels of total phytate in the diet decreased 32,94% in stomach contents of fish fed l,000,8,000 U/kg within 2 h after feeding. Eight hours after feeding, stomach contents of fish fed , 1,000 U/kg contained less than 6% of initial total dietary phytate. Stomach contents of fish fed 500 U/kg retained 92% of initial total dietary phytate 2 h after feeding and 15% of total dietary phytate 8 h after feeding. Results of this study indicate that phytase supplementation at levels up to 8,000 U/kg diet did not increase weight gain or improve dietary protein utilization of channel catfish fed an all-plant-protein diet. Addition of phytase at a level of 1,000 U/kg diet was sufficient to significantly increase the Ca, P, Mg, and Mn content of bone, relative to fish fed an unsupplemented diet, and significantly decrease the quantity of total phytate in feces. A phytase level of 8,000 U/kg diet significantly increased the bioavailability of naturally occurring Zn in feed ingredients and increased the rate of phytate dephosphorylation in the stomach, compared with a diet containing no added phytase. Increased utilization of naturally occurring minerals in feed ingredients reduces the need for mineral supplements in diets and results in decreased elimination of minerals in feces. Thus, use of phytase in catfish feeds can be expected to provide both economic and environmental benefits. [source]


Whole Blood Manganese Concentrations in Dogs with Congenital Portosystemic Shunts

JOURNAL OF VETERINARY INTERNAL MEDICINE, Issue 1 2010
A.G. Gow
Background: Manganese (Mn) is an essential mineral that is a cofactor for many enzymes required in the synthesis of proteins, carbohydrates, and lipids. Because hepatic clearance is essential in Mn homeostasis, conditions in humans resulting in hepatic insufficiency including cirrhosis and both acquired and congenital portosystemic shunting have been reported to result in increased blood Mn concentrations and increased Mn content in the central nervous system. Because Mn toxicity causes neurologic disturbances, increased Mn concentrations have been implicated in the pathogenesis of hepatic encephalopathy. Hypotheses: Dogs with congenital portosystemic shunts (cPSS) have significantly higher whole blood Mn concentrations than do healthy dogs or those with nonhepatic illnesses. Animals: Eighteen dogs with cPSS, 26 dogs with nonhepatic illnesses, and 14 healthy dogs. Methods: Whole blood Mn was measured by graphite furnace atomic absorption spectrometry. The diagnosis of cPSS was made by ultrasonography or during celiotomy either by visual inspection of a shunting vessel or portovenography. Results: Dogs with a cPSS had significantly higher whole blood Mn concentrations than did healthy dogs and dogs with nonhepatic illnesses. Whole blood Mn concentrations were not significantly different between healthy dogs and dogs with nonhepatic illnesses. Conclusion and Clinical Importance: Dogs with a cPSS have significantly increased whole blood Mn concentrations. Additional studies are warranted to investigate the role of Mn in cPSS-associated hepatic encephalopathy. [source]


The Sirente crater field, Italy

METEORITICS & PLANETARY SCIENCE, Issue 11 2002
Jens ORMö
They are located in the Sirente plain within the mountains of the Abruzzo region, central Italy. The craters are distributed in a field 450 m long and 400 m wide. This field consists of ,17 smaller craters close to a larger main crater. The main crater is located in the southern end of the crater field and is 140 m long and 115 m wide, measured rim-to-rim. It has a well-developed, saddle-shaped rim that rises at a maximum 2.2 m above the surrounding plain. Radiocarbon dating of the target surface preserved below the rim gave a calibrated age of formation at about a.d. 412 (1650 ± 40 radiocarbon years b.p.). This young age is consistent with the apparent little modification of the rim. The morphology of the main crater and its relation to a crater field strongly points to its origin by impact from a projectile that broke up during its passage through the atmosphere. Quartz is very rare in the target and no planar deformation features have been found so far. The rim material and the upper 4 m of the main crater infill are impregnated with ferric oxides, which gives a more reddish colour compared to the other sediments of the plain. Rusty crusts with high Fe and Mn content occur in the rim material, but have not been found in the plain's sediments. Some of these crusts can be separated by magnet, and have sporadic micron-sized Ni-rich granules. The main crater is in the size range of the craters with explosive dispersion of the projectile and has many features comparable to both large experimental and meteoritic impact craters formed in loose sediments. We suggest that this crater represents a rare example of well-preserved, small impact crater formed in unconsolidated target materials. [source]


Manganese ions as intracellular contrast agents: proton relaxation and calcium interactions in rat myocardium

NMR IN BIOMEDICINE, Issue 2 2003
Wibeke Nordhųy
Abstract Paramagnetic manganese (Mn) ions (Mn2+) are taken up into cardiomyocytes where they are retained for hours. Mn content and relaxation parameters, T1 and T2, were measured in right plus left ventricular myocardium excised from isolated perfused rat hearts. In the experiments 5,min wash-in of MnCl2 were followed by 15,min wash-out to remove extracellular (ec) Mn2+ MnCl2, 25 and 100,µM, elevated tissue Mn content to six and 12 times the level of control (0,µM MnCl2). Variations in perfusate calcium (Ca2+) during wash-in of MnCl2 and experiments including nifedipine showed that myocardial slow Ca2+ channels are the main pathway for Mn2+ uptake and that Mn2+ acts as a pure Ca2+ competitor and a preferred substrate for slow Ca2+ channel entry. Inversion recovery analysis at 20,MHz revealed two components for longitudinal relaxation: a short T1,,,1 and a longer T1,,,2. Approximate values for control and Mn-treated hearts were in the range 600,125,ms for T1,,,1 and 2200,750,ms for T1,,,2. The population fractions were about 59 and 41% for the short and the long component, respectively. The intracellular (ic) R1,,,1 and R2,,,1 correlated best with tissue Mn content. Applying two-site exchange analyses on the obtained T1 data yielded results in parallel to, but also differing from, results reported with an ec contrast agent. The calculated lifetime of ic water (,ic) of about 10,s is compatible with a slow water exchange in the present excised cardiac tissue. The longitudinal relaxivity of Mn ions in ic water [60 (s mM),1] was about one order of magnitude higher than that of MnCl2 in water in vitro [6.9 (s mM),1], indicating that ic Mn-protein binding is an important potentiating factor in relaxation enhancement. Copyright © 2003 John Wiley & Sons, Ltd. [source]


Dynamics of spin interactions in diluted magnetic semiconductor heterostructures

PHYSICA STATUS SOLIDI (A) APPLICATIONS AND MATERIALS SCIENCE, Issue 1 2007
*Article first published online: 19 DEC 200, D. R. Yakovlev
Abstract This paper gives an overview of the recent studies of spin dynamics in diluted magnetic semiconductor heterostructures based on (Zn,Mn)Se and (Cd,Mn)Te. The spin dynamics is controlled by energy and spin transfer between systems of magnetic ions, lattice (phonon system) and free carriers. Spin,lattice relaxation time of the Mn spin system is a very strong function of the Mn content, it decreases by five orders of magnitude when the Mn content changes from 0.4 to 11%. Additionally this time can be tuned by the varying free carrier concentration and by the growth of heteromagnetic structures with inhomogeneous profile of Mn ions. (© 2007 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) [source]


Mn and Si influence on the hyperfine properties of the fcc and hcp phases in the Fe,Mn and Fe,Mn,Si systems

PHYSICA STATUS SOLIDI (B) BASIC SOLID STATE PHYSICS, Issue 6 2009
Javier Martķnez
Abstract A study of the hyperfine properties of the fcc and hcp phases of the Fe,Mn and Fe,Mn,Si systems, performed on a systematic and accurate set of samples belonging to the 15 at% to 30 at% Mn and 0 at% to 12 at% Si composition ranges, is presented. The samples were characterized using Conversion Electron Mössbauer Spectroscopy. The evolution with the Mn and Si contents of the hyperfine parameters of both phases has been determined. A constancy of the isomer shift parameter of the hcp phase with both constituents of the alloy was observed. While constancy and a linear decrease of the isomer shift values of the fcc phase with Mn and Si, respectively, were determined. The magnetic hyperfine field of the fcc phase presents two different values depending on the Mn content in the binary system and a decrease with the addition of Si when the ternary alloy is considered. (© 2009 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) [source]


Spin-lattice relaxation in diluted magnetic (Cd,Mn)Se quantum dots

PHYSICA STATUS SOLIDI (C) - CURRENT TOPICS IN SOLID STATE PHYSICS, Issue 2 2005
A. Hundt
Abstract The dynamics of spin-lattice relaxation (SLR) is investigated in diluted magnetic (Cd,Mn)Se quantum dot structures with different Mn content by photo-carrier induced spin gas heating. The acquired time constants in the µs range show a strong dependence of the Mn content and of the temperature. There is no hint for a specific zero-dimensional behavior. (© 2005 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) [source]


Spin and energy transfer between magnetic ions and freecarriers in diluted-magnetic semiconductor heterostructures

PHYSICA STATUS SOLIDI (C) - CURRENT TOPICS IN SOLID STATE PHYSICS, Issue 4 2004
D.R. Yakovlev
Abstract In this paper we give a brief overview of our studies on dynamical processes in diluted-magnetic-semiconductor heterostructures based on (Zn,Mn)Se and (Cd,Mn)Te. Presence of free carriers is an important factor which determines the energy- and spin transfer in a coupled systems of magnetic ions, lattice (the phonon system) and carriers. We report also new data on dynamical response of magnetic ions interacting with photogenerated electron-hole plasma. (Zn,Mn)Se/(Zn,Be)Se structures with relatively high Mn content of 11% provide spin-lattice relaxation time of about 20 ns, which is considerably shorter then the characterictic times of nonequilibrium phonons ranging to 1 ,s. (© 2004 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) [source]


Electrospray ionisation with selected reaction monitoring for the determination of Mn-citrate, Fe-citrate, Cu-citrate and Zn-citrate

RAPID COMMUNICATIONS IN MASS SPECTROMETRY, Issue 15 2009
Volker Nischwitz
Citrate complexes of Mn and Fe, and potentially those of Cu and Zn, are considered as important low molecular mass species in human serum and cerebrospinal fluid (CSF). For example, Mn is supposed to enter the brain under excess exposure as Mn-citrate leading to neurotoxic effects. Mn-citrate has been characterised in human CSF using chromatography and electrophoresis online with inductively coupled plasma mass spectrometry, but not yet with molecular mass spectrometry. Therefore, this study explores the potential of electrospray ionisation (ESI) with selected reaction monitoring (SRM) for the detection of metal-citrate complexes, in particular Mn-citrate. The collision-induced dissociation of precursor ions with various metal:citrate stoichiometries was studied for Mn-citrate, Fe-citrate, Cu-citrate and Zn-citrate. High selectivity was achieved for Mn(II)-citrate even in respect to Fe(III)-citrate which forms isobaric precursor ions. The limit of detection for Mn-citrate was estimated to be around 250,µg,L,1 (referring to the total Mn content in the standard) using flow injection. The sensitivity was sufficient for the determination of Mn-citrate in standard solutions and in an extract of an Mn-citrate-containing supplement. An improved ESI source design is expected to reduce the limits of detection significantly. The developed ESI-SRM method has the potential to provide complementary data for the quality control of current separation methods for metal citrates using element-selective detection, with application to biomedical samples and further matrices. Copyright © 2009 John Wiley & Sons, Ltd. [source]


Growth performance and tissue mineral content of juvenile grouper (Epinephelus coioides) fed diets supplemented with various levels of manganese

AQUACULTURE NUTRITION, Issue 6 2009
C.-X. YE
Abstract This study was conducted to investigate the effect of dietary manganese (Mn) on growth, vertebrae and whole-body Mn content of juvenile grouper, and to examine the effect of dietary Mn on copper (Cu), iron (Fe), zinc (Zn), calcium (Ca), phosphorus (P) and magnesium (Mg) content of vertebrae and whole body. Seven casein-gelatin-based diets were supplemented with 0, 5, 10, 15, 20, 50 and 1000 mg kg,1 of Mn from MnSO4·H2O. Grouper with an initial weight of 12.9 ± 0.4 g were fed to satiation with one of the seven diets for 8 weeks. Growth was not significantly affected by dietary Mn supplements. Vertebrae Mn increased from 31.7 to 118.1 mg kg,1 dry weight with dietary Mn supplement increasing from 0 to 50 mg kg,1 (y = ,0.0002x3 + 0.0162x2 + 1.3903x + 26.27, R2 = 0.9561, where y is the vertebrae Mn content and x is the dietary Mn content). Whole-body Mn increased from 2.5 to 7.8 mg kg,1 wet weight with dietary Mn supplement increasing from 0 to 50 mg kg,1 (y = 0.00001x3 , 0.00107x2 + 0.11054x + 2.24615, R2 = 0.9080, where y is the whole-body Mn content and x is the dietary Mn content). Dietary Mn had no significant effect on vertebrae Fe, Ca, P and Mg content, and whole-body Cu, Zn and Mg content. However, vertebrae Zn and whole body Ca, P were highest in fish fed diet supplemented with 15 mg kg,1 of Mn. Based on this, Mn supplement of 15 mg kg,1 might be the optimum when the basal diet contained 4 mg kg,1 of Mn. Fish fed diet supplemented with 1000 mg kg,1 of Mn did not show any gross abnormality or change in feeding behaviour, but Mn contents of vertebrae and whole body were as high as 695.1 mg kg,1 dry weight and 42.5 mg kg,1 wet weight, respectively. Also, whole body Fe decreased significantly when Mn supplement was up to 1000 mg kg,1. [source]


Labile soil organic carbon, soil fertility, and crop productivity as influenced by manure and mineral fertilizers in the tropics

JOURNAL OF PLANT NUTRITION AND SOIL SCIENCE, Issue 5 2010
Siba Prasad Datta
Abstract In recent years, organic agriculture has been receiving greater attention because of the various problems like deterioration in soil health and environmental quality under conventional chemical-intensive agriculture. However, little information is available on the comparative study related to the impact of use of mineral fertilizers and organic manures on the soil quality and productivity. A long-term field experiment was initiated in 2001 to monitor some of the important soil-quality parameters and productivity under soybean,wheat crop rotation. The treatments consisted of 0, 30, and 45,kg N ha,1 for soybean and of 0, 120, and 180,kg N ha,1 for wheat. The entire amount of N was supplied to both the crops through urea and farmyard manure (FYM) alone or in combination at 1:1 ratio. Results indicated that Walkley-and-Black C (WBC; chromic acid,oxidizable) exhibited a marginal increase under only organic treatments as compared to control treatment (without fertilizers and manure) after completion of five cropping cycles. In case of labile-C (KMnO4 -oxidizable) content in soil, relatively larger positive changes were recorded under organic, mixed inputs (integrated) and mineral fertilizers as compared to WBC. Maximum improvement in the values of C-management index (CMI), a measure of soil quality was recorded under organic (348,362), followed by mixed inputs (268,322) and mineral fertilizers (198,199) as compared to the control treatment after completion of five cropping cycles. Similarly there was a substantial increase in KCl-extractable N; in Olsen-P; as well as in DTPA-extractable Zn, Fe, and Mn under organic treatments. Although labile soil C positively contributed to the available N, P, K, Zn, Fe, and Mn contents in soil, it did not show any relationship with the grain yield of wheat. After completion of the sixth cropping cycle, organic treatments produced 23% and 39% lower grain yield of wheat as compared to that under urea-treated plots. Relatively higher amount of mineral N in soil at critical growth stages and elevated N content in plant under mineral-fertilizer treatments compared to FYM treatments were responsible for higher yield of wheat under mineral fertilizers. [source]


Growth performance and tissue mineral content of juvenile grouper (Epinephelus coioides) fed diets supplemented with various levels of manganese

AQUACULTURE NUTRITION, Issue 6 2009
C.-X. YE
Abstract This study was conducted to investigate the effect of dietary manganese (Mn) on growth, vertebrae and whole-body Mn content of juvenile grouper, and to examine the effect of dietary Mn on copper (Cu), iron (Fe), zinc (Zn), calcium (Ca), phosphorus (P) and magnesium (Mg) content of vertebrae and whole body. Seven casein-gelatin-based diets were supplemented with 0, 5, 10, 15, 20, 50 and 1000 mg kg,1 of Mn from MnSO4·H2O. Grouper with an initial weight of 12.9 ± 0.4 g were fed to satiation with one of the seven diets for 8 weeks. Growth was not significantly affected by dietary Mn supplements. Vertebrae Mn increased from 31.7 to 118.1 mg kg,1 dry weight with dietary Mn supplement increasing from 0 to 50 mg kg,1 (y = ,0.0002x3 + 0.0162x2 + 1.3903x + 26.27, R2 = 0.9561, where y is the vertebrae Mn content and x is the dietary Mn content). Whole-body Mn increased from 2.5 to 7.8 mg kg,1 wet weight with dietary Mn supplement increasing from 0 to 50 mg kg,1 (y = 0.00001x3 , 0.00107x2 + 0.11054x + 2.24615, R2 = 0.9080, where y is the whole-body Mn content and x is the dietary Mn content). Dietary Mn had no significant effect on vertebrae Fe, Ca, P and Mg content, and whole-body Cu, Zn and Mg content. However, vertebrae Zn and whole body Ca, P were highest in fish fed diet supplemented with 15 mg kg,1 of Mn. Based on this, Mn supplement of 15 mg kg,1 might be the optimum when the basal diet contained 4 mg kg,1 of Mn. Fish fed diet supplemented with 1000 mg kg,1 of Mn did not show any gross abnormality or change in feeding behaviour, but Mn contents of vertebrae and whole body were as high as 695.1 mg kg,1 dry weight and 42.5 mg kg,1 wet weight, respectively. Also, whole body Fe decreased significantly when Mn supplement was up to 1000 mg kg,1. [source]


ARCHAEOMETRICAL INVESTIGATION OF SICILIAN EARLY BYZANTINE GLASS: CHEMICAL AND SPECTROSCOPIC DATA*

ARCHAEOMETRY, Issue 1 2010
R. ARLETTI
A series of early Byzantine glasses, recovered in Ganzirri (Sicily, Italy), was analysed for major, minor and trace elements. All the analysed fragments were found to be natron-based silica,lime glass. Concerning minor and trace elements, the samples can be divided into two groups: glass with high Fe, Ti and Mn contents (HIMT glass) and glass with low levels of Fe, Ti and Mn. These results, strictly in agreement with literature data for glass of the Mediterranean region, can be interpreted as a consequence of the wide trade network established in this region and of the intense circulation of raw glass and artefacts from different Mediterranean areas. X-ray absorption spectroscopy studies at Fe and Mn K-edges, performed on HIMT glass, indicate that Fe is in the oxidized form while Mn is in the reduced form. [source]


Comparison of the nutrient ecology of coastal Banksia grandis elfinwood (windswept shrub-like form) and low trees, Cape Leeuwin-Naturaliste National Park, Western Australia

AUSTRAL ECOLOGY, Issue 3 2003
KENNETH A. BARRICK
Abstract Trees growing along windy coasts often have canopies that are greatly reduced in size by the sculpting effects of wind and salt spray. Trees with environmentally reduced stature are called elfinwood (windswept shrub-form or krummholz) and are ecologically important because they represent outposts growing at the limit of tree success. The purpose of this study was to assess if Banksia grandis elfinwood growing at Cape Leeuwin had a different nutrient status than normal low-form (LF) trees growing nearby, and if nutrient deficiencies, toxicities and/or imbalances were among the limiting factors imposed on elfinwood. The concentrations of N, P, K, Ca, Mg, Na, Cl,, Fe, Mn, Zn, Cu, Mo and B were analysed for mature green foliage, immature foliage, foliage litter, flowers and soil. When the elfinwood and LF trees were compared, the foliar nutrient status was generally similar, except that elfinwood foliage had significantly higher mean concentrations of N, Zn and Cu, while LF trees had higher Fe and Mn contents. Many nutrients were conserved before leaves were shed in both elfinwood and LF trees, including N, P, K, Na, Cl,, Mn and Cu (LF trees also conserved Ca and Mg). However, elfinwood and LF tree-litter contained significantly higher Fe concentrations than green foliage (elfinwood litter also had higher levels of Mg and B). It is tempting to suggest that the translocation of Fe into leaves before they were shed is a regulation mechanism to prevent Fe toxicity, or imbalance in the Fe : Mn ratio. Proteoid roots strongly acidify the soil to mobilize P, which also chemically reduces Fe+3 to plant-available Fe+2. The increased supply of Fe+2 in the rhizosphere, caused by the action of proteoid roots, might tend to defeat self-regulation of Fe uptake. It is possible that excess Fe accumulation in the plant might be regulated, in part, by exporting Fe into the leaves before they are shed. The nutrient status of B. grandis elfinwood is compared with mountain elfinwood of North America. The extreme habitat of coastal elfinwood provides many theoretical pathways for nutrient limitation, but B. grandis elfinwood at Cape Leeuwin does not appear to be nutrient deficient. [source]