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Longer Residence Time (longer + residence_time)
Selected AbstractsPartitioning sources of soil respiration in boreal black spruce forest using radiocarbonGLOBAL CHANGE BIOLOGY, Issue 2 2006Edward A.G. Schuur Abstract Separating ecosystem and soil respiration into autotrophic and heterotrophic component sources is necessary for understanding how the net ecosystem exchange of carbon (C) will respond to current and future changes in climate and vegetation. Here, we use an isotope mass balance method based on radiocarbon to partition respiration sources in three mature black spruce forest stands in Alaska. Radiocarbon (,14C) signatures of respired C reflect the age of substrate C and can be used to differentiate source pools within ecosystems. Recently-fixed C that fuels plant or microbial metabolism has ,14C values close to that of current atmospheric CO2, while C respired from litter and soil organic matter decomposition will reflect the longer residence time of C in plant and soil C pools. Contrary to our expectations, the ,14C of C respired by recently excised black spruce roots averaged 14, greater than expected for recently fixed photosynthetic products, indicating that some portion of the C fueling root metabolism was derived from C storage pools with turnover times of at least several years. The ,14C values of C respired by heterotrophs in laboratory incubations of soil organic matter averaged 60, higher than the contemporary atmosphere ,14CO2, indicating that the major contributors to decomposition are derived from a combination of sources consistent with a mean residence time of up to a decade. Comparing autotrophic and heterotrophic ,14C end members with measurements of the ,14C of total soil respiration, we calculated that 47,63% of soil CO2 emissions were derived from heterotrophic respiration across all three sites. Our limited temporal sampling also observed no significant differences in the partitioning of soil respiration in the early season compared with the late season. Future work is needed to address the reasons for high ,14C values in root respiration and issues of whether this method fully captures the contribution of rhizosphere respiration. [source] Urease immobilization on an ion-exchange textile for urea hydrolysisJOURNAL OF CHEMICAL TECHNOLOGY & BIOTECHNOLOGY, Issue 6 2006Kyeong-Ho Yeon Abstract Ion-exchange textiles are used as organic supports for urease immobilization with the aim of developing reactive fibrous materials able to promote urea removal. A non-woven, polypropylene-based cation-exchange textile was prepared using UV-induced graft polymerization. Urease was covalently immobilized onto the cation-exchange textile using three different coupling agents: N -(3-dimethylaminopropyl)- N,-ethylcarbodiimide hydrochloride (EDC), N -cyclohexyl- N,-(b -[N -methylmorpholino]ethyl)carbodiimide p -toluenesulfonate (CMC), and glutaraldehyde (GA). The immobilized biocatalyst was characterized by means of FT-IR spectrometry, SEM micrographs, dependence of the enzyme activity on pH and temperature, and according to the kinetic constants of the free and immobilized ureases. The biotextile prepared with EDC in the presence of N -hydroxysuccinimide performs best. The optimum pH was 7.2 for the free urease and 7.6 for the immobilized ureases. The reactivity was maximal at 45 °C for free urease, 50 °C for biotextiles prepared using EDC or CMC, and 55 °C for biotextiles prepared with GA. The activation energy for the immobilized ureases was 4.73,5.67 kcal mol,1, which is somewhat higher than 4.3 kcal mol,1 for free urease. The urea conversion for a continuous-flow immobilized urease reactor is nearly as good as a continuously stirred tank reactor having a much longer residence time, suggesting that the packed bed reactor had sufficient diffusive mixing and residence time to reach nearly optimal results. Urease immobilized on a biotextile using EDC has good storage and operational stability. Copyright © 2006 Society of Chemical Industry [source] Production of bio-crude from forestry waste by hydro-liquefaction in sub-/super-critical methanolAICHE JOURNAL, Issue 3 2009Yun Yang Abstract Hydro-liquefaction of a woody biomass (birch powder) in sub-/super-critical methanol without and with catalysts was investigated with an autoclave reactor at temperatures of 473,673 K and an initial pressure of hydrogen varying from 2.0 to 10.0 MPa. The liquid products were separated into water soluble oil and heavy oil (as bio-crude) by extraction with water and acetone. Without catalyst, the yields of heavy oil and water soluble oil were in the ranges of 2.4,25.5 wt % and 1.2,17.0 wt %, respectively, depending strongly on reaction temperature, reaction time, and initial pressure of hydrogen. The optimum temperature for the production of heavy oil and water soluble oil was found to be at around 623 K, whereas a longer residence time and a lower initial H2 pressure were found to be favorite conditions for the oil production. Addition of a basic catalyst, such as NaOH, K2CO3, and Rb2CO3, could significantly promote biomass conversion and increase yields of oily products in the treatments at temperatures less than 573 K. The yield of heavy oil attained about 30 wt % for the liquefaction operation in the presence of 5 wt % Rb2CO3 at 573 K and 2 MPa of H2 for 60 min. The obtained heavy oil products consisted of a high concentration of phenol derivatives, esters, and benzene derivatives, and they also contained a higher concentration of carbon, a much lower concentration of oxygen, and a significantly increased heating value (>30 MJ/kg) when compared with the raw woody biomass. © 2009 American Institute of Chemical Engineers AIChE J, 2009 [source] AN INTEGRATED STUDY OF DIAGENESIS AND DEPOSITIONAL FACIES IN TIDAL SANDSTONES: HAWAZ FORMATION (MIDDLE ORDOVICIAN), MURZUQ BASIN, LIBYAJOURNAL OF PETROLEUM GEOLOGY, Issue 1 2009A. Abouessa Studies of the impact of diagenesis on reservoir quality in tidal sandstones can be of great importance in successful hydrocarbon exploration. The study reported here shows that diagenetic alterations and bioturbation have induced considerable deterioration and heterogeneity in the reservoir quality of the sand-dominated tidal deposits of the Middle Ordovician Hawaz Formation in the Muruq Basin, Libya. Comparison is made between the diagenetic evolution of samples from the subsurface (present-day depth 1500 m) and from surface outcrops in order to study the impact of burial and uplift on the spatial and temporal distribution of reservoir quality in the Hawaz Formation sandstones. Eogenetic alterations, which were mediated by meteoric water circulation, included kaolinitization and dissolution of framework silicates and mechanical compaction. Mesogenetic alterations (T > 70°C; depth > 2 km) included pressure dissolution of quartz grains and concomitant quartz cementation, conversion of kaolinite into dickite, illitization of kaolinite and of grain-coating clays, and the precipitation of Mg-rich siderite cement. Reduction of intergranular porosity was due more to compaction than to cementation, yet quartz overgrowths are up to 16% in some of the sandstones. Bioturbation has resulted in a greater reduction in sandstone permeability in the lower part of the formation than the upper part. A higher ratio of dickite to kaolinite in subsurface samples than in outcrop samples is attributed to the longer residence time of the former sandstones under mesogenetic conditions. Telodiagenesis has not resulted in enhancement of reservoir quality of the Hawaz Formation Sandstones but in pseudomorphic calcitization of siderite and oxidation of pyrite to goethite. This study shows that the reservoir-quality evolution of tidal sandstones can best be elucidated when linked to depositional facies and distribution of diagenetic alterations. [source] Characterization of downflowing high velocity fluidized bedsAICHE JOURNAL, Issue 3 2000Chunshe Cao A downer-riser circulating high velocity fluidization apparatus was developed to study the fundamentals of downflowing gas-solid particle mixtures. The acceleration and deceleration of solids due to the influences of the entrance and exit sections result in a relatively uniform axial solids distribution. Radial solid density profiles detected with an X-ray imaging system in the downer show the existence of a core-annulus flow with a dilute core surrounded by a denser wall region. Local solids flux profiles were obtained with an aspirating probe device and the solid velocity profile obtained from the two measured quantities. These confirm that the majority of solids segregates in a wall region that flows faster than the dilute core region. Thus, the shorter residence time in the high-speed downer wall region is coupled with faster reaction rates due to the accompanying high concentration of catalyst, while the dilute core has slower reaction rates with longer residence time due to the lower catalyst concentration and flow velocity. This results in much more uniform reaction extent over the cross-sectional area of the downer and, therefore, should improve the product selectivity. [source] Melt processing effects on the structure and mechanical properties of PA-6/clay nanocompositesPOLYMER ENGINEERING & SCIENCE, Issue 8 2006Nitin K. Borse Polyamide-6 nanocomposites were prepared using two organoclays, Cloisite 30B and Cloisite 15A, and Cloisite Na+, which is unmodified sodium montmorillonite (Na-MMT) clay. Nanocomposites were prepared using two twin-screw extrusion systems: System B employing conventional mixing and residence time conditions, while System A was modified to achieve longer residence time and higher mixing efficiency. The work considers the effects of mixing conditions, residence time, and interactions between the polymer and clay surface on the structure and mechanical properties of polyamide-6 (PA-6)/clay nanocomposites. Furthermore, a comparison was made between experimental data and the predictions of composite models usually employed to predict mechanical properties of nanocomposites. The melt processing of Cloisite 30B in System A produced the highest degrees of exfoliation and the largest enhancement of mechanical properties. The aspect ratios of the filler particles in the nanocomposites were estimated from TEM micrographs and from composite models. Yield stress data were employed to calculate the values of parameter B in Pukanszky's equation, which incorporates the effects of the interfacial interaction, interfacial strength, and specific surface area of the filler particles. POLYM. ENG. SCI. 46:1094,1103, 2006. © 2006 Society of Plastics Engineers [source] Transient storage and downstream solute transport in nested stream reaches affected by beaver damsHYDROLOGICAL PROCESSES, Issue 17 2009Li Jin Abstract Transient storage constitutes a key element in the hydrologic cycle of watersheds. Both in-channel slow moving water (dead zones) and hyporheic zones can contribute to transient storage, which retains water and solutes, increases residence time and influences solute transport in streams. Beaver dams and other in-stream obstructions throughout low-order streams attenuate streamflow and provide dead zone storage in pools. In this article, we report the results of four tracer tests in nested stream reaches in Cherry Creek (Wyoming, USA) covering ,2·5 km of stream length to explore how the degree of beaver dam obstructions and their impoundments influence water transient storage and downstream solute transport in low-order streams in the Rocky Mountain region of the American West. Travel-time parameters for the tracer tests increased linearly with beaver dam number (N) and pond size (V). Linear regression of the travel time to the peak concentration (Tp), the leading (Tl) and tailing edge (Tt) of the dye cloud and the duration of the dye cloud (Td) versus N and V were all significant (R2 = 0·99). Slopes of the linear regressions of Tt versus N and V, were three times larger than those for Tl, suggesting that longer residence times may be caused, in part, by transient storage in the stream system. One-dimensional transport with inflow and storage (OTIS) modelled cross-sectional area of transient storage zone (As) and dispersion coefficients (D) increased linearly with N and V and reach length. Two transient storage metrics, Fmean and , also showed a general increase with N and V, although the relationship was not as strong. This suggests that in-channel dead zones associated with beaver dams provide opportunities for generating transient water storage. The linear relationship between dispersion coefficient and reach length suggests the dispersion process might be analogous to the hydrodynamic dispersion in groundwater settings. Copyright © 2009 John Wiley & Sons, Ltd. [source] Hydrological influences on hyporheic water quality: implications for salmon egg survivalHYDROLOGICAL PROCESSES, Issue 9 2004I. A. Malcolm Abstract The spatial and temporal variability of groundwater,surface-water (GW,SW) interactions was investigated in an intensively utilized salmon spawning riffle. Hydrochemical tracers, were used along with high-resolution hydraulic head and temperature data to assess hyporheic dynamics. Surface and subsurface hydrochemistry were monitored at three locations where salmon spawning had been observed in previous years. Temperature and hydraulic head were monitored in three nests of three piezometers located to characterize the head, the run and the tail-out of the riffle feature. Hydrochemical gradients between surface and subsurface water indicated increasing GW influence with depth into the hyporheic zone. Surface water was characterized by high dissolved oxygen (DO) concentrations, low alkalinity and conductivity. Hyporheic water was generally characterized by high levels of alkalinity and conductivity indicative of longer residence times, and low DO, indicative of reducing conditions. Hydrochemical and temperature gradients varied spatially over the riffle in response to changes in local GW,SW interactions at the depths investigated. Groundwater inputs dominated the head and tail of the riffle. The influence of SW increased in the area of accelerating flow and decreasing water depth through the run of the riffle. Temporal GW,SW interactions also varied in response to changing hydrological conditions. Gross changes in hyporheic hydrochemistry were observed at the weekly scale in response to changing flow conditions and surface water inputs to the hyporheic zone. During low flows, caused by freezing or dry weather, hyporheic hydrochemistry was dominated by GW inputs. During higher flows hyporheic hydrochemistry indicated that SW contributions increased. In addition, high-resolution hydraulic head data indicated that rapid changes in GW,SW interactions occurred during hydrological events. The spatial, and possibly the temporal, variability of GW,SW interactions had a marked effect on the survival of salmon ova. It is concluded that hyporheic dynamics and their effect on stream ecology should be given increased consideration by fisheries and water resource managers. Copyright © 2004 John Wiley & Sons, Ltd. [source] | ||||||||||