Home About us Contact
|
Home About us Contact | ||
|
|
||
Longer Mixing Time (longer + mixing_time)
Selected AbstractsA reactive polymer for toughening epoxy resinJOURNAL OF APPLIED POLYMER SCIENCE, Issue 6 2010Hsu-Chiang Kuan Abstract Epoxy resins are hardly toughened by low weight content of tougheners. In this study, 5 wt % polyurea was adopted to significantly toughen piperidine-cured epoxy, as fracture toughness improved from 0.78 to 1.98 MPa m1/2. We focused on the reactions and morphology evolution of epoxy/polyurea mixture. The polyurea molecular weight was reduced by the exchange reactions of polyurea with epoxy during mixing, as evidenced by gel permeation chromatograph and Fourier transform infrared spectroscopy. As a result, epoxy molecules were chemically bonded with polyurea, improving particle content and interface thickness. Transmission electron microscope observation shows that (a) polyurea in situ formed nanoparticles in matrix which subsequently aggregate into micron-sized particles of thick interface with matrix; and (b) the particles became less stainable with increasing the mixing time, because the reactions promoted high levels of crosslink density of the particles which were thus more resistant to the diffusion of staining chemicals. Longer mixing time improved, obviously, the fracture toughness of epoxy/polyurea composite. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2010 [source] Microporous Silica Hollow Microspheres and Hollow Worm-Like Materials: A Simple Method for Their Synthesis and Their Application in Controlled ReleaseEUROPEAN JOURNAL OF INORGANIC CHEMISTRY, Issue 6 2010Mingwei Zhao Abstract Hollow silica microspheres and hollow worm-like materials were synthesized by using a simple method with the aid of 1-dodecyl-3-methylimidazolium bromide (C12mimBr). Hollow silica microspheres were initially produced by utilizing the combination of evaporation and an emulsion template. At a longer mixing time, the microspheres fused to form hollow worm-like silica materials due to the fusion of the emulsion templates. The resultant silica materials were characterized by transmission electron microscopy (TEM), scanning electron microscopy (SEM), and nitrogen adsorption/desorption. Both the hollow silica microspheres and the hollow worm-like materials are microporous. On the basis of experimental observations and the resulting products, a plausible formation mechanism is proposed. Preliminary tests demonstrate that the hollow silica microspheres and worm-like materials are capable of being loaded with Rhodamine B and releasing it, thus showing a great potential in controlled delivery applications. [source] Thermo-Mechanical Degradation of LDPE-Based NanocompositesMACROMOLECULAR MATERIALS & ENGINEERING, Issue 7 2007Nadka Tzankova Dintcheva Abstract Thermo-mechanical degradation of LDPE-based nanocomposites was studied by mainly investigating the rheological properties. For all of the investigated processing conditions, the viscosity of the nanocomposites was higher than that of the pure-LDPE matrix, but on increasing the severity of the mixing conditions, the difference between the viscosity of the nano-filled polymer and that of the pure LDPE decreased. The X-ray traces of the nanocomposites suggest that intercalation has been achieved during the melt, when less-severe processing conditions were used. At severe processing conditions (longer mixing time, high temperature and shear stress) the thermo-mechanical degradation was accelerated, possibly due to the loss of mass from the organoclay galleries. The variations of the viscosity in the presence of two organo-modified montmorillonite (MMt) clays were compared to the ones observed with a MMt clay at different processing conditions. [source] Precision 1H,1H distance measurement via 13C NMR signals: utilization of 1H,1H double-quantum dipolar interactions recoupled under magic angle spinning conditionsMAGNETIC RESONANCE IN CHEMISTRY, Issue 2 2004Yoh Matsuki Abstract We applied the POST-C7 DQ-dipolar recoupling pulse sequence to the measurement of 1H,1H distances with high precision. The spectral resolution is enhanced by detecting the 1H magnetization via 13C signals. A least-squares fitting of the build-up curve of the transferred magnetization to the exact numerical simulations yielded a 1H,,1H, distance of 248 ± 4 pm for fully 13C-labeled L -valine. This distance agrees with the neutron diffraction study. The negative transferred magnetization clearly indicates that the direct DQ 1H,1H dipolar couplings have the largest effect. The signal for the magnetization transfer builds up rapidly by the direct 1H,1H dipolar coupling, and decreases to zero at longer mixing time when the relayed magnetization transfer becomes significant. This large intensity change of the signal leads to the high precision in the distance measurement. We inspected factors that limit the effective bandwidth of the POST-C7 recoupling for the 1H and 13C homonuclear spin systems. The spin interactions at times shorter than the cycle time of the C7 sequence were also evaluated to measure the distances. The carbon-detected 2D 1H DQ mixing experiment was demonstrated for the measurement of multiple 1H,1H distances. Copyright © 2004 John Wiley & Sons, Ltd. [source] Polymer,nanofiller prepared by high-energy ball milling and high velocity cold compactionPOLYMER COMPOSITES, Issue 3 2008Bruska Azhdar High-energy ball milling using comilling in a solid state by low-temperature mechanical alloying to prepare nickel-ferrite (NiFe2O4) nanopowders and ultrafine poly(methyl methacrylate) (PMMA), dispersing nanoparticles in a polymer matrix, and a uniaxial high-velocity cold compaction process using a cylindrical, hardened steel die and a new technique with relaxation assists have been studied. The focus has been on the particle size distributions of the nanocomposite powder during the milling and on the surface morphology of the nanocomposite-compacted materials after compaction with and without relaxation assists. Experimental results for different milling systems are presented showing the effects of milling time and material ratio. It was found that a longer mixing time give a higher degree of dispersion of the nanopowder on the PMMA particle surfaces. Furthermore, with increasing content of NiFe2O4 nanopowder, the reduction of the particle size was more effective. Different postcompacting profiles, i.e. different energy distributions between the upper and lower parts of the compacted powder bed, lead to different movements of the various particles and particle layers. Uniformity, homogeneity, and densification on the surfaces in the compacted powder are influenced by the postcompacting magnitude and direction. It was found that the relaxation assist device leads to an improvement in the polymer powder compaction process by reducing the expansion of the compacted volume and by reducing the different opposite velocities, giving the compacted composite bed a more homogeneous opposite velocity during the decompacting stage and reducing the delay time between the successive pressure waves. POLYM. COMPOS., 2008. © 2007 Society of Plastics Engineers [source] Influence of melt-blending conditions on structural, rheological, and interfacial properties of polyamide-12 layered silicate nanocompositesPOLYMER ENGINEERING & SCIENCE, Issue 8 2006Pascal Médéric The influence of the melt-blending conditions on the structural, rheological, and interfacial properties of modified montmorillonite/Polyamide-12 nanocomposites has been studied performing transmission electron microscopy observation combined with X-Ray diffraction and rheological experiments. In the dilute regime, for short mixing times, the apparent aspect ratio of primary clay entities, determined from intrinsic viscosity measurements, is shown to increase with rotational speed. At high blade rotational speeds, the viscometric results suggest an almost achieved exfoliation, as confirmed by transmission electron microscopy micrographs. For longer mixing times, a significant drop of viscous dissipation is observed, which is very marked at high blade rotational speeds and attributed to a modification of the particle/matrix interface. In the concentrated regime, the rheological behavior of nanocomposites is attributed to the formation of a network of mesoscopic domains, composed of correlated clay entities. Upon increasing strain during mixing, the clay aggregates within these domains break into intercalated stacks and finally exfoliated layers, as shown by transmission electron microscopy micrographs and wide-angle X-ray diffraction patterns. The melt state elastic and viscous properties of the nanocomposites are mainly governed by the networked domains, and not by the nature and properties of the structure within the domains. POLYM. ENG. SCI. 46:986,994, 2006. © 2006 Society of Plastics Engineers. [source] | |||||||||||||