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Light Elements (light + element)
Selected AbstractsReference Minerals for the Microanalysis of Light ElementsGEOSTANDARDS & GEOANALYTICAL RESEARCH, Issue 2-3 2001M. Darby Dyar tourmaline; danburite; spodumène; muscovite; isotopes The quantitative determination of light element concentrations in geological specimens represents a major analytical challenge as the electron probe is generally not suited to this task. With the development of new in situ analytical techniques, and in particular the increasing use of secondary ion mass spectrometry, the routine determination of Li, Be and B contents has become a realistic goal. However, a major obstacle to the development of this research field is the critical dependence of SIMS on the availability of well characterized, homogeneous reference materials that are closely matched in matrix (composition and structure) to the sample being studied. Here we report the first results from a suite of large, gem crystals which cover a broad spectrum of minerals in which light elements are major constituents. We have characterized these materials using both in situ and wet chemical techniques. The samples described here are intended for distribution to geochemical laboratories active in the study of light elements. Further work is needed before reference values for these materials can be finalized, but the availability of this suite of materials represents a major step toward the routine analysis of the light element contents of geological specimens. La détermination quantitative des concentrations en éléments légers dans les échantillons géologiques représente un défi analytique majeur, la sonde électronique ne convenant généralement pas pour ce travail. Avec le développement de nouvelles techniques analytiques in situ, en particulier l'utilisation grandissante de la spectrométrie ionique secondaire, la détermination en routine des teneurs en Li, Be et B est devenue un objectif réaliste. Toutefois, un obstacle majeur dans le développement de cette recherche subsiste : la technique SIMS est dépendante de la disponibilité de matériaux de référence bien caractérisés et homogènes proches en composition et en structure de l'échantillon étudié. Nous rapportons ici les premiers résultats obtenus à partie d'un groupe de grands cristaux de qualité gemme recouvrant un large spectre de minéraux composés essentiellement d'éléments légers. Nous avons caractérisé ces matériaux en utilisant à la fois des techniques in situ et par voie humide. Les échantillons décrits ici vont être distribués dans les laboratoires de géochimie spécialisés dans l'étude des éléments légers. Avant la conclusion des valeurs de référence de ces matériaux, des travaux ultérieurs seront nécessaires, mais la disponibilité de l'ensemble de ces matériaux représente une étape importante vers l'analyse en routine des teneurs en éléments légers d'échantillons géologiques. [source] XAFS analysis of corroded metal surfaces with molten salts by conversion-electron-yield methodJOURNAL OF SYNCHROTRON RADIATION, Issue 2 2001Etsuya Yanase We have measured XAFS spectra of metal surfaces corroded with melting salt (NaCl, KCl, and Na2SO4). Steel samples used were S45C, SCM435, SUS310S, and SUS304. We measured the Fe K-edge XAFS spectra for all samples and the Ni K-edge for SUS310S and SUS304 samples before and after the corrosion. The XANES spectra of samples before the corrosion show metallic structure because surface oxide thickness is thinner than probing depth with a conversion yield XAFS method. Each result of these XAFS spectra gives good agreements with the FEFF calculation in the assumption of bcc and/or fcc structure. The Fe K-edge spectra of steel samples except SUS310S after corroded treatment show existence bonding between Fe and another light element although the spectra of SUS310S samples before and after corroded treatment are much the same. Keywords: metal, molten salts, corrosion. [source] Reference Minerals for the Microanalysis of Light ElementsGEOSTANDARDS & GEOANALYTICAL RESEARCH, Issue 2-3 2001M. Darby Dyar tourmaline; danburite; spodumène; muscovite; isotopes The quantitative determination of light element concentrations in geological specimens represents a major analytical challenge as the electron probe is generally not suited to this task. With the development of new in situ analytical techniques, and in particular the increasing use of secondary ion mass spectrometry, the routine determination of Li, Be and B contents has become a realistic goal. However, a major obstacle to the development of this research field is the critical dependence of SIMS on the availability of well characterized, homogeneous reference materials that are closely matched in matrix (composition and structure) to the sample being studied. Here we report the first results from a suite of large, gem crystals which cover a broad spectrum of minerals in which light elements are major constituents. We have characterized these materials using both in situ and wet chemical techniques. The samples described here are intended for distribution to geochemical laboratories active in the study of light elements. Further work is needed before reference values for these materials can be finalized, but the availability of this suite of materials represents a major step toward the routine analysis of the light element contents of geological specimens. La détermination quantitative des concentrations en éléments légers dans les échantillons géologiques représente un défi analytique majeur, la sonde électronique ne convenant généralement pas pour ce travail. Avec le développement de nouvelles techniques analytiques in situ, en particulier l'utilisation grandissante de la spectrométrie ionique secondaire, la détermination en routine des teneurs en Li, Be et B est devenue un objectif réaliste. Toutefois, un obstacle majeur dans le développement de cette recherche subsiste : la technique SIMS est dépendante de la disponibilité de matériaux de référence bien caractérisés et homogènes proches en composition et en structure de l'échantillon étudié. Nous rapportons ici les premiers résultats obtenus à partie d'un groupe de grands cristaux de qualité gemme recouvrant un large spectre de minéraux composés essentiellement d'éléments légers. Nous avons caractérisé ces matériaux en utilisant à la fois des techniques in situ et par voie humide. Les échantillons décrits ici vont être distribués dans les laboratoires de géochimie spécialisés dans l'étude des éléments légers. Avant la conclusion des valeurs de référence de ces matériaux, des travaux ultérieurs seront nécessaires, mais la disponibilité de l'ensemble de ces matériaux représente une étape importante vers l'analyse en routine des teneurs en éléments légers d'échantillons géologiques. [source] Structures and properties of the hydrides of light elementsINTERNATIONAL JOURNAL OF QUANTUM CHEMISTRY, Issue 4-5 2002Garry T. Smith Abstract Basic geometric and other properties for a number of neutral holovalent hydrides of light elements (M = Li , F)(MHn) are discussed. Their molecular geometries, energies, and vibrational frequencies have been determined from ab initio calculations of benchmark quality. We calculated harmonic vibrational frequencies, zero point vibrational energies, and atomization energies for the deuterides, tritiides, and combinations of them for these light elements. These isotopomers are of great interest for thermonuclear applications because they are often used as thermonuclear fuels or components of such fuels. In fact, only for these substances thermonuclear energy gain exceeds (at some densities and temperatures) the bremsstrahlung loss and other high-temperature losses, i.e., thermonuclear burn-up is possible. The vibrational frequencies are useful in determining the composition of mixed samples by means of spectroscopy. © 2002 Wiley Periodicals, Inc. Int J Quantum Chem, 2002 [source] Characterization of Portland cements by X-ray spectrometry allied to chemometricsJOURNAL OF CHEMOMETRICS, Issue 11-12 2006Karen Goraieb Abstract This work reports the use of X-ray spectrometry (XRS) allied to chemometric techniques to easily distinguish types of Portland cements, as well as to quantify some of their constituent elements. The samples were irradiated as powders for 200,s using two distinct irradiation conditions, one more adequate for heavier elements (condition 1) and the other (condition 2) for lighter elements, using a conventional bench top energy dispersive X-ray fluorescence (EDXRF) equipment. The spectra were processed via the software The Unscrambler, version 9.2. The PLS 1 LV1,×,LV2 scores graph shows a classification into five groups, in accordance with the calcium concentration, using condition 2. The classification of the cements by producer was feasible using the PLS1 LV1,×,LV3 scores graph, with condition 1. The elements Ca, Si, Al and Mg were successfully quantified using multivariate calibration of the whole spectra. However, for Fe, S and K, better results were obtained by correlating their corresponding K, peaks with concentrations in a univariate procedure, using irradiation condition 2. Chemometric tools allied to XRS are powerful techniques to classify Portland cements, regarding to their origins and their calcium concentration, which is related to the cement type. The PLS chemometric tool was very useful to easily quantify light elements, such as Al, Si and Mg, a challenge in most X-ray analytical methods, since their K, emission peaks are very close to each other. Copyright © 2007 John Wiley & Sons, Ltd. [source] Beam-size effects in radiation damage in insulin and thaumatin crystalsJOURNAL OF SYNCHROTRON RADIATION, Issue 3 2005A. Wagner Cryocooled insulin and thaumatin crystals were irradiated in a series of alternating data collections and high-dose-rate exposures using either a vertically focused or vertically defocused beam. The main result is that the radiation damage is limited to the exposed region, which can be explained by the short range of the photoelectrons and the Auger electron cascade produced by light elements. Consequently, the unexposed angular range provides significantly improved data quality and electron density compared with previously exposed angular wedges of the crystal when a vertically focused beam is used, while no differences are observed between a fresh wedge and an exposed region for the vertically defocused beam. On the other hand, the focused beam provides higher I/,I ratios at high resolution than homogeneous sample illumination but also causes more rapid sample deterioration. [source] Effects of Thermal Annealing on the Structure of Ferroelectric Thin FilmsJOURNAL OF THE AMERICAN CERAMIC SOCIETY, Issue 4 2006Jiang-Li Cao The effects of thermal annealing on the structure of polycrystalline Pb(Zr0.3Ti0.7)O3 (PZT) ferroelectric thin films prepared by chemical solution deposition on Pt/TiOx electrode stacks were studied using scanning electron microscopy, transmission electron microscopy (TEM), and grazing incidence X-ray specular and diffuse reflectivity of synchrotron radiation. The stratified multilayered structure and element diffusions in the sample were characterized by TEM. Global statistical structural parameters including the density, surface or interface roughness and thickness of each layer in the samples were obtained from fitting the X-ray specular reflectivity using a homogeneous stratified multilayer model of PZT/Pt/TiOx/SiO2. The results showed that the PZT surface and PZT/Pt interface roughness changed slightly during thermal annealing in oxygen at 700°C. By contrast, the density increase of the PZT ceramic and density decrease of the Pt-bottom electrode during annealing were observed. A high density value of the PZT ceramic film after the annealing was found, up to 99.8% of the theoretical value of the corresponding bulk ceramics. The density changes of the PZT and Pt layers were further confirmed by X-ray diffuse reflectivity. The influences of the annealing treatment on the density changes of the PZT and Pt layers were attributed to the further densification of the PZT ceramic and incorporation of light elements such as Zr, Ti and O from the neighboring layers into the Pt layer, respectively, as discussed in correlation with the TEM analyses. [source] Investigation of ion beam techniques for the analysis and exposure of particles encapsulated by silica aerogel: Applicability for StardustMETEORITICS & PLANETARY SCIENCE, Issue 9 2004G. A. GRAHAM These particles will be the first sample return from a solid planetary body since the Apollo missions. In preparation for the return, analogue particles were implanted into a keystone of silica aerogel that had been extracted from bulk silica aerogel using the optical technique described in Westphal et al. (2004). These particles were subsequently analyzed using analytical techniques associated with the use of a nuclear microprobe. The particles have been analyzed using: a) scanning transmission ion microscopy (STIM) that enables quantitative density imaging; b) proton elastic scattering analysis (PESA) and proton backscattering (PBS) for the detection of light elements including hydrogen; and c) proton-induced X-ray emission (PIXE) for elements with Z > 11. These analytical techniques have enabled us to quantify the composition of the encapsulated particles. A significant observation from the study is the variable column density of the silica aerogel. We also observed organic contamination within the silica aerogel. The implanted particles were then subjected to focused ion beam (FIB) milling using a 30 keV gallium ion beam to ablate silica aerogel in site-specific areas to expose embedded particles. An ion polished flat surface of one of the particles was also prepared using the FIB. Here, we show that ion beam techniques have great potential in assisting with the analysis and exposure of Stardust particles. [source] Mass loss and yield uncertainty in low-mass asymptotic giant branch starsMONTHLY NOTICES OF THE ROYAL ASTRONOMICAL SOCIETY, Issue 4 2007Richard J. Stancliffe ABSTRACT We investigate the uncertainty in surface abundances and yields of asymptotic giant branch (AGB) stars. We apply three different mass-loss laws to a 1.5-M, star of metallicity Z= 0.008 at the beginning of the thermally pulsing-asymptotic giant branch (TP-AGB) phase. Efficient third dredge-up is found even at very low envelope mass, contrary to previous simulations with other evolution codes. We find that the yield of carbon is uncertain by about 15 per cent and for most other light elements the yield is uncertain at the level of 20,80 per cent. For iron group elements, the uncertainty varies from around 30 per cent for the more-abundant species to over a factor of 2 for the less-abundant radioactive species, like 60Fe. The post-AGB surface abundances for this mass and metallicity are much more uncertain due to the dilution of dredged-up material in differing envelope masses in the later stages of the models. Our results are compared to known planetary nebula and post-AGB abundances. We find that the models are mostly consistent with observations but we are unable to reproduce observations of some of the isotopes. [source] Minimal models of cooling neutron stars with accreted envelopesMONTHLY NOTICES OF THE ROYAL ASTRONOMICAL SOCIETY, Issue 4 2006A. D. Kaminker ABSTRACT We study the ,minimal' cooling scenario of superfluid neutron stars with nucleon cores, where the direct Urca process is forbidden and enhanced cooling is produced by neutrino emission due to the Cooper pairing of neutrons. Extending our recent previous work, we include the effects of surface accreted envelopes of light elements. We employ the phenomenological density-dependent critical temperatures Tcp(,) and Tcnt(,) of singlet-state proton and triplet-state neutron pairing in a stellar core, as well as the critical temperature Tcns(,) of singlet-state neutron pairing in a stellar crust. We show that the presence of accreted envelopes simplifies the interpretation of observations of thermal radiation from isolated neutron stars in the scenario of our recent previous work and widens the class of models for nucleon superfluidity in neutron star interiors consistent with the observations. [source] Surface abundances of light elements for a large sample of early B-type stars , III.MONTHLY NOTICES OF THE ROYAL ASTRONOMICAL SOCIETY, Issue 2 2004An analysis of helium lines in spectra of 102 stars ABSTRACT Non-local thermodynamic equilibrium analysis of He i lines in spectra of 102 B stars is implemented in order to derive the helium abundance He/H, the microturbulent parameter Vt and the projected rotation velocity v sin i. A simultaneous determination of He/H and Vt for the stars is effected by analysing equivalent widths of the 4471- and 4922-Å lines primarily as indicators of He/H and the 4713-, 5016-, 5876- and 6678-Å lines primarily as indicators of Vt. The rotation velocities v sin i are found from profiles of the same lines. It is shown that, when Vt > 7 km s,1, the Vt(He i) values determined from He i lines are systematically overestimated as compared with the Vt(O ii, N ii) values derived from O ii and N ii lines. This discrepancy is especially appreciable for hot evolved B giants with Vt(He i) = 16,23 km s,1 and may indicate a failure of classical model atmospheres to represent the strong He i lines for these stars. Two programme stars, HR 1512 and 7651, are found to be helium-weak stars. The remaining 100 stars are divided into three groups according to their masses M. The microturbulent parameter Vt(He i) is low for all stars of group A (M= 4.1,6.9 M,) and for all stars with the relative ages t/tMS < 0.8 of group B (M= 7.0,11.2 M,). Their Vt(He i) values are within the 0 to 5 km s,1 range, as a rule; the mean value is Vt= 1.7 km s,1. Only evolved giants of group B, which are close to the termination of the main-sequence (MS) evolutionary phase (t/tMS > 0.8), show Vt(He i) up to 11 km s,1. The helium abundance He/H is correlated with the relative age t/tMS in both groups; the averaged He/H enhancement during the MS phase is 26 per cent. For group C, containing the most massive stars (M= 12.4,18.8 M,), the Vt(He i) values display a correlation with t/tMS, varying from 4 to 23 km s,1. The He/H determination for hot evolved B giants of the group with Vt(He i) > 15 km s,1 depends on a choice between the Vt(He i) and Vt(O ii, N ii) scales. The mean He/H enrichment by 67 per cent during the MS phase is found, if the abundances He/H are based on the Vt(O ii, N ii) scale; however, two evolved giants with especially high v sin i, HR 7446 and 7993, show the He/H enhancement by about a factor of 2.5. When using the same Vt scale, we found a trend of He/H with projected rotational velocities v sin i; a large dispersion for v sin i > 150 km s,1 can result from differences in masses M. A comparison with the stellar model computations with rotationally induced mixing shows that the observed helium enrichment during the MS phase can be explained by rotation with initial velocities 250,400 km s,1. The He/H distribution on M and v sin i based on the Vt(O ii, N ii) scale seems to be in better agreement with the theory than one based on the Vt(He i) scale. The mean value He/H = 0.10 derived for stars in the zero age main sequence (ZAMS) vicinity can be adopted as the typical initial helium abundance for early B stars in the solar neighbourhood. [source] Neutron diffraction studies of magnetic and superconducting compoundsPHYSICA STATUS SOLIDI (A) APPLICATIONS AND MATERIALS SCIENCE, Issue 7 2004W. B. Yelon Abstract Neutron diffraction is an extremely valuable tool for the investigation of magnetic and superconducting materials, because of its ability to directly observe periodic magnetic structures, determine magnetic moment directions and magnitudes, to observe light elements that are otherwise difficult to locate from X-ray diffraction due to the strong scattering of heavy elements, or to distinguish nearby elements in the periodic chart. This talk will focus on recent studies of superconducting and magnetic oxides that may provide insight into the interaction of magnetism and superconductivity, and into important changes in other transport properties (colossal magneto-resistance, ionic conductivity, etc.). These materials appear to show promise for a wide range of applications, and the neutron studies may not only help to understand their properties, but may also provide direction for synthesis of compounds that may overcome the limitations of those already discovered. (© 2004 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) [source] Elemental abundance analyses with Coudé Echelle spectrograms from the TÜB,TAK National Observatory of Turkey: I. The HgMn stars 11 Per, HR 2801, and , Cnc,ASTRONOMISCHE NACHRICHTEN, Issue 8 2010S.J. Adelman Abstract Using coadded spectrograms taken with the Coudé Echelle Spectrograph (CES) of the 1.50-m Russian-Turkish Telescope of the TÜB,TAK National Observatory (TUG) near Antalya in Turkey, elemental abundance analyses of three HgMn stars 11 Per, HR 2801, and , Cnc were performed. Comparisons are made with spectra obtained with the long camera of the Dominion Astrophysical Observatory (DAO) coudé spectrograph and its SITe4 CCD. The CES equivalent widths are about 12% larger than that for the DAO long camera. Our first results from TUG data/spectra show that all three stars exhibit the Hg II ,3984 line and somewhat diverse abundance patterns. 11 Per tends to have underabundant light elements with underabundant and overabundant Fe-peak elements. HR 2801 has mostly underabundant elements, with a few elements having solar abundances while N and Mn are overabundant. The coolest star , Cnc has light elements having mostly solar abundances, overabundant iron group abundances, and very overabundant SrYZr and Ba. Comparisons with the abundance patterns of other HgMn stars show that they have a wide diversity of abundance patterns (© 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) [source] | |||||||||||||