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Liquid Viscosity (liquid + viscosity)
Selected AbstractsThe effect of viscosity on surface tension measurements by the drop weight methodJOURNAL OF APPLIED POLYMER SCIENCE, Issue 3 2007T. Kaully Abstract Viscosity is one of the parameters affecting the measured surface tension, as fluid mechanics affects the measurement process using conventional methods. Several methods including the selected planes (SPM) and WDSM which combines the weight drop method (WDM) and SPM, are applied to surface tension measurement of high viscous liquids. Yet, none of them treats the viscosity effect separately. The current publication presents a simple, easy to apply empirical approach of satisfactory accuracy, for evaluation of surface tension of liquids having wide range of viscosities up to 10 Pa s. The proposed method is based on Tate's law and the "drop weight" method using calibration curves of known liquids having similar surface tensions but different viscosities. Drop weight of liquids having viscosity ,0.05 Pa s, was found to be significantly affected by the liquid viscosity. The shape factor, f, of high viscosity liquids was found to correlate linearly with the logarithm of viscosity, pointing the importance of viscosity correction. The experimental correlation presented in the current work can be used as a tool for the evaluation of surface tension for high viscosity liquids such as prepolymers. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2007 [source] Flow and mass transfer in aerated viscous Newtonian liquids in an unbaffled agitated vessel having alternating forward,reverse rotating impellersJOURNAL OF CHEMICAL TECHNOLOGY & BIOTECHNOLOGY, Issue 11 2001Masanori Yoshida Abstract Flow and mass transfer characteristics in aerated viscous Newtonian liquids were studied for an unbaffled aerated agitated vessel with alternating rotating impellers (AAVAI), ie with multiple forward,reverse rotating impellers having four delta blades. The effects of operating conditions such as gas sparging rate, agitation rate and the number of impeller stages, and the liquid physical properties (viscosity) on the gas hold-up, ,gD, and volumetric oxygen transfer coefficient, kLaD were evaluated experimentally. The dependences of ,gD and kLaD on the specific total power input and superficial gas velocity differed, depending on the ranges of liquid viscosity. Empirical relationships are presented for each viscosity range to predict ,gD and kLaD as a function of the specific total power input, superficial gas velocity and viscosity of liquid. Based on a comparative investigation of the volumetric coefficient in terms of the specific total power input between the AAVAI and conventional aerated agitated vessels (CAAVs) having unidirectionally rotating impellers, the usefulness of AAVAI as a gas,liquid agitator treating viscous Newtonian liquids is also discussed. © 2001 Society of Chemical Industry [source] HEAT TRANSFER TO CANNED PARTICULATES IN HIGH-VISCOSITY NEWTONIAN FLUIDS DURING AGITATION PROCESSINGJOURNAL OF FOOD PROCESSING AND PRESERVATION, Issue 6 2006YANG MENG ABSTRACT Heat transfer to canned particulate-laden Newtonian high-viscous fluids (Nylon particles suspended in aqueous glycerin solution [40, 60, 80, 90 and 100%, v/v] and motor oil [85W140]) during end-over-end rotation was studied in a pilot-scale, full water-immersion single-cage rotary retort. Computations of conventional fluid-to-particle heat transfer coefficient (hfp) and overall heat transfer coefficient (U) were successful with multiple particles for an entire range of viscosity, but the predicted particle lethality was underestimated. With a single particle in the can, hfpand U calculations were successful only for low-viscosity fluids (40 and 60% glycerin solutions), but again resulted in underestimation of particle lethality. Apparent heat transfer coefficients (hap) between retort and particle surface and apparent overall heat transfer coefficient (Ua) were also evaluated, and this methodology worked well for all cases. Further, the particle lethality predicted using hap better matched the measured values. With a single particle in the can, the associated hap was significantly (P < 0.05) influenced by rotation speed, retort temperature, liquid viscosity, particle material and can size. Ua was significantly (P < 0.05) influenced by rotation speed and liquid viscosity. The effects of headspace, radius of rotation and particle size were not significant (P > 0.05) on hap and Ua values. [source] Computational investigation of the mechanisms of particle separation and "fish-hook" phenomenon in hydrocyclonesAICHE JOURNAL, Issue 7 2010B. Wang Abstract The motion of solid particles and the "fish-hook" phenomenon in an industrial classifying hydrocyclone of body diameter 355 mm is studied by a computational fluid dynamics model. In the model, the turbulent flow of gas and liquid is modeled using the Reynolds Stress Model, and the interface between the liquid and air core is modeled using the volume of fluid multiphase model. The outcomes are then applied in the simulation of particle flow described by the stochastic Lagrangian model. The results are analyzed in terms of velocity and force field in the cyclone. It is shown that the pressure gradient force plays an important role in particle separation, and it balances the centrifugal force on particles in the radial direction in hydrocyclones. As particle size decreases, the effect of drag force whose direction varies increases sharply. As a result, particles have an apparent fluctuating velocity. Some particles pass the locus of zero vertical velocity (LZVV) and join the upward flow and have a certain moving orbit. The moving orbit of particles in the upward flow becomes wider as their size decreases. When the size is below a critical value, the moving orbit is even beyond the LZVV. Some fine particles would recircuit between the downward and upward flows, resulting in a relatively high separation efficiency and the "fish-hook" effect. Numerical experiments were also extended to study the effects of cyclone size and liquid viscosity. The results suggest that the mechanisms identified are valid, although they are quantitatively different. © 2009 American Institute of Chemical Engineers AIChE J, 2010 [source] Hydrodynamics and mass transfer of gas,liquid flow in a falling film microreactorAICHE JOURNAL, Issue 5 2009Haocui Zhang Abstract In this article, flow pattern of liquid film and flooding phenomena of a falling film microreactor (FFMR) were investigated using high-speed CCD camera. Three flow regimes were identified as "corner rivulet flow," "falling film flow with dry patches," and "complete falling film flow" when liquid flow rate increased gradually. Besides liquid film flow in microchannels, a flooding presented as the flow of liquid along the side wall of gas chamber in FFMR was found at high liquid flow rate. Moreover, the flooding could be initiated at lower flow rate with the reduction of the depth of the gas chamber. CO2 absorption was then investigated under the complete falling flow regime in FFMR, where the effects of liquid viscosity and surface tension on mass transfer were demonstrated. The experimental results indicate that kL is in the range of 5.83 to 13.4 × 10,5 m s,1 and an empirical correlation was proposed to predict kL in FFMR. © 2009 American Institute of Chemical Engineers AIChE J, 2009 [source] Two-phase flow electrosynthesis: Comparing N -octyl-2-pyrrolidone,aqueous and acetonitrile,aqueous three-phase boundary reactionsJOURNAL OF PHYSICAL ORGANIC CHEMISTRY, Issue 1 2009Stuart M. MacDonald Abstract A microfluidic double channel device is employed to study reactions at flowing liquid,liquid junctions in contact with a boron-doped diamond (BDD) working electrode. The rectangular flow cell is calibrated for both single-phase liquid flow and biphasic liquid,liquid flow for the case of (i) the immiscible N -octyl-2-pyrrolidone (NOP),aqueous electrolyte system and (ii) the immiscible acetonitrile,aqueous electrolyte system. The influence of flow speed and liquid viscosity on the position of the phase boundary and mass transport-controlled limiting currents are examined. In contrast to the NOP,aqueous electrolyte case, the acetonitrile,aqueous electrolyte system is shown to behave close to ideal without ,undercutting' of the organic phase under the aqueous phase. The limiting current for three-phase boundary reactions is only weakly dependent on flow rate but directly proportional to the concentration and the diffusion coefficient in the organic phase. Acetonitrile as a commonly employed synthetic solvent is shown here to allow effective three-phase boundary processes to occur due to a lower viscosity enabling faster diffusion. N -butylferrocene is shown to be oxidised at the acetonitrile,aqueous electrolyte interface about 12 times faster when compared with the same process at the NOP,aqueous electrolyte interface. Conditions suitable for clean two-phase electrosynthetic processes without intentionally added supporting electrolyte in the organic phase are proposed. Copyright © 2008 John Wiley & Sons, Ltd. [source] Experimental studies of liquid flow maldistribution in a random packed columnTHE CANADIAN JOURNAL OF CHEMICAL ENGINEERING, Issue 3 2000Fuhe Yin Abstract Liquid flow distribution has been a major concern when scaling up random packed columns. This study concerns the measurements of liquid flow distribution in a large scale column packed with 25.4 mm stainless steel Pall rings. The liquid flow distribution was studied with packed bed height from 0.9 to 3.5 m, liquid flow rate from 2.91 to 6.66 kg/m2·s, and gas flow rate from 0 to 3.0 kg/m2·s. In addition, three systems, water/air, aqueous detergent solution/air and Isopar/air, were used to study the effect of liquid physical properties on liquid flow distribution, and two different liquid distributors were employed to test the effect of liquid distributor design. It was found that liquid flow distribution was strongly influenced by liquid distributor design, packed bed height, gas flow rate and liquid viscosity, slightly influenced by liquid flow rate, but not by liquid surface tension. La distribution de l'écoulement liquide pose un problème important pour la mise à l'échelle des colonnes garnies aléatoirement. Cette étude porte sur des mesures de distribution d'écoulement liquide dans une colonne de grande échelle garnie d'anneaux Pall en acier inoxydable de 25,4 mm de diamètre. La distribution de l'écoulement liquide a été étudiée pour une hauteur de lit garni entre 0,9 et 3,5 m, un débit liquide entre 2,91 et 6,66 kg/m2·s et un débit de gaz entre 0 et 3,0 kg/m2·s. En outre, on a eu recours à trois systèmes, soient eau/air, solution à base de détergent aqueuse/air et Isopar/air, pour étudier l'effet des propriétés physiques du liquide sur la distribution de l'écoulement liquide, et deux distributeurs de liquide différents ont été utilisés afin de tester l'effet de la conception du distributeur de liquide. On a trouvé que la distribution de l'écoulement liquide était fortement influenceé par la conception du distributeur de liquide, la hauteur de lit garni, le débit de gaz et la viscosité du liquide, était peu influencée par le débit du liquide, et n'était pas influencée par la tension de surface du liquide. [source] Prediction of Droplet Velocities and Rain Out in Horizontal Isothermal Free Jet Flows of Air and Viscous Liquid in Stagnant Ambient AirCHEMICAL ENGINEERING & TECHNOLOGY (CET), Issue 11 2007S. Al Rabadi Abstract Two-dimensional phase Doppler anemometer measurements of droplet size and velocity conducted under several nozzle conditions and a systematic variation of the air mass flow quality and liquid phase viscosity show that the air entrainment process is enhanced when keeping all test conditions constant except for increasing the Newtonian liquid viscosity above of that of water. A two-zone entrainment model based on a variable two-phase entrainment coefficient is proposed with the normalized axial distance allowing for a change in the jet angle. Thus, the jet perimeter is lower and the breakup length is longer in the case of air/relatively higher viscosity liquid phase. It provides the most accurate reproduction of the experimental droplet velocity in comparison with that of other models in the literature and, hence, is recommended for the prediction of the droplet velocity in the case of two-phase air/liquid phase free jet flow in stagnant ambient air. A model for predicting the droplet rain out, considering the droplet trajectories in the free jet flow, allows also for an adequate reproduction of the experimental data. [source] | ||||||||||