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Selected AbstractsDetermination of Uric Acid in the Presence of Ascorbic Acid Using Poly(3,4-ethylenedioxythiophene)-Modified ElectrodesELECTROANALYSIS, Issue 24 2005Senthil Kumar, Shanmugam Abstract A poly(3,4-ethylenedioxythiophene) (PEDOT) modified glassy carbon electrode (GCE) was used to determine uric acid in the presence of ascorbic acid at physiological pH facilitating a peak potential separation of ascorbic acid and uric acid oxidation (ca. 365,mV), which is the largest value reported so far in the literature. Also, an analytical protocol involving differential pulse voltammetry has been developed using a microchip electrode for the determination of uric acid in the concentration range of 1 to 20,,M in presence of excess of ascorbic acid. [source] Fabrication of Highly Conductive 12CaO·7Al2O3 Thin Films Encaging Hydride Ions by Proton ImplantationADVANCED MATERIALS, Issue 13 2003M. Miyakawa Thin films of a new transparent oxide semiconductor 12CaO·7Al2O3 consisting of subnanometer-sized cages (see Figure inset) have been fabricated, and their light-induced insulator,conductor conversion is described. Proton implantation at a fluence of 1,×,1018 cm,2 followed by UV-light irradiation increases the electrical conductivity by more than eleven orders of magnitude to the largest value ,,10 S,cm,1 (see Figure). The conducting state is erasable by heating. [source] Isotope and disorder effects in the Raman spectra of LiHxD1,x crystalsJOURNAL OF RAMAN SPECTROSCOPY, Issue 8 2001V. G. Plekhanov Most of the physical properties of a solid depend on its isotopic composition in some way or another. Scientific interest, technological promise and increased availability of highly enriched isotopes have led to a sharp rise in the number of experimental and theoretical studies with isotopically controlled crystals. A great number of stable isotopes and well-developed methods for their separation have made it possible to grow crystals of C, LiH, ZnO, ZnSe, CuCl, GaN, GaAs, CdS, Cu2O, Si, Ge and ,-Sn with a controllable isotopic composition. Among these compounds, LiH possesses the largest value of the isotope effect. The great number of theoretical and experimental data suggest that the isotopic composition of a crystal lattice exerts some influence on the vibrational properties of crystals. These effects are fairly large and can be readily measured by modern experimental techniques (ultrasound, Brillouin and Raman scattering and neutron scattering). In addition, crystals of different isotopic compositions possess different Debye temperatures. This difference between an LiH crystal and its deuterated analogue exceeds a 100 K. Very pronounced and general effects of isotopic substitution are observed in phonon spectra. The scattering lines in isotopically mixed crystals are not only shifted (the shift of LO lines exceeds 100 cm,1) but are also broadened. This broadening is related to the isotopic disorder of the crystal lattice. It is shown that the degree of a change in the scattering potential is different for different isotopic mixed crystals. In the case of germanium and diamond crystals, phonon scattering is weak, which allows one to apply successfully the coherent potential approximation (CPA) for describing the shift and broadening of scattering lines. In the case of lithium hydride, the change in the scattering potential is so strong that it results in phonon localization, which is directly observed in experiments. The common nature of the isotopic and disorder effects in a wide range of crystals is emphasized. Copyright © 2001 John Wiley & Sons, Ltd. [source] Prediction of gas chromatographic retention times of capillary columns of different inside diametersJOURNAL OF SEPARATION SCIENCE, JSS, Issue 18 2003Kornkanok Aryusuk Abstract The retention times (t R) of n -alkanes (C16,C22) eluted from capillary columns of different diameters are accurately predicted by using the equation proposed by Krisnangkura et al. (J. Chromatogr. Sci.1997, 35, 329,332). The numerical values of four thermodynamically related constants (a, b, c, and d) of the BP-1 (100% dimethylpolysiloxane) capillary column (0.32 mm ID×25 m, film thickness, 0.25 ,m) are ,6.169, ,0.512, 226.98, and 410.30, respectively. For columns of the same stationary phase but of different inside diameters and film thickness, accurate tR values can be predicted by using the same numerical values of the last three constants but the first constant (a) is changed by the difference in the natural logarithm of the column phase ratios (,). All the derived numerical values of each column were tested with FAMEs and with n -alkanes in temperature-programmed GC (TPGC). All the predicted tR values agree well with the experimental values. About 77% of the TPGC data have errors lower than 0.5% and the largest value is ,1.04%. [source] A Combinatorial Searching Method for Detecting a Set of Interacting Loci Associated with Complex TraitsANNALS OF HUMAN GENETICS, Issue 5 2006Qiuying Sha Summary Complex diseases are presumed to be the results of the interaction of several genes and environmental factors, with each gene only having a small effect on the disease. Mapping complex disease genes therefore becomes one of the greatest challenges facing geneticists. Most current approaches of association studies essentially evaluate one marker or one gene (haplotype approach) at a time. These approaches ignore the possibility that effects of multilocus functional genetic units may play a larger role than a single-locus effect in determining trait variability. In this article, we propose a Combinatorial Searching Method (CSM) to detect a set of interacting loci (may be unlinked) that predicts the complex trait. In the application of the CSM, a simple filter is used to filter all the possible locus-sets and retain the candidate locus-sets, then a new objective function based on the cross-validation and partitions of the multi-locus genotypes is proposed to evaluate the retained locus-sets. The locus-set with the largest value of the objective function is the final locus-set and a permutation procedure is performed to evaluate the overall p-value of the test for association between the final locus-set and the trait. The performance of the method is evaluated by simulation studies as well as by being applied to a real data set. The simulation studies show that the CSM has reasonable power to detect high-order interactions. When the CSM is applied to a real data set to detect the locus-set (among the 13 loci in the ACE gene) that predicts systolic blood pressure (SBP) or diastolic blood pressure (DBP), we found that a four-locus gene-gene interaction model best predicts SBP with an overall p-value = 0.033, and similarly a two-locus gene-gene interaction model best predicts DBP with an overall p-value = 0.045. [source] Analysis of historical landslide time series in the Emilia-Romagna region, northern ItalyEARTH SURFACE PROCESSES AND LANDFORMS, Issue 10 2010Mauro Rossi Abstract A catalogue of historical landslides, 1951,2002, for three provinces in the Emilia-Romagna region of northern Italy is presented and its statistical properties studied. The catalogue consists of 2255 reported landslides and is based on historical archives and chronicles. We use two measures for the intensity of landsliding over time: (i) the number of reported landslides in a day (DL) and (ii) the number of reported landslides in an event (Sevent), where an event is one or more consecutive days with landsliding. From 1951,2002 in our study area there were 1057 days with 1 , DL ,?45 landslides per day, and 596 events with 1 , Sevent , 129 landslides per event. In the first set of analyses, we find that the probability density of landslide intensities in the time series are power-law distributed over at least two-orders of magnitude, with exponent of about ,2·0. Although our data is a proxy for landsliding built from newspaper reports, it is the first tentative evidence that the frequency-size of triggered landslide events over time (not just the landslides in a given triggered event), like earthquakes, scale as a power-law or other heavy-tailed distributions. If confirmed, this could have important implications for risk assessment and erosion modelling in a given area. In our second set of analyses, we find that for short antecedent rainfall periods, the minimum amount of rainfall necessary to trigger landslides varies considerably with the intensity of the landsliding (DL and Sevent); whereas for long antecedent periods the magnitude is largely independent of the cumulative amount of rainfall, and the largest values of landslide intensity are always preceded by abundant rainfall. Further, the analysis of the rainfall trend suggests that the trigger of landslides in the study area is related to seasonal rainfall. Copyright © 2010 John Wiley & Sons, Ltd. [source] IMPACT OF IRON LIMITATION ON THE PHOTOSYNTHETIC APPARATUS OF THE DIATOM CHAETOCEROS MUELLERI (BACILLARIOPHYCEAE)JOURNAL OF PHYCOLOGY, Issue 6 2001Margaret Davey Iron starvation induced marked increases in flavodoxin abundance and decreases in light-saturated and light-limited photosynthesis rates in the diatom Chaetoceros muelleri. Consistent with the substitution of flavodoxin for ferredoxin as an early response to iron starvation, increases of flavodoxin abundance were observed before declines of cell division rate or chl a specific photosynthesis rates. Changes in the abundance of flavodoxin after the addition of iron to iron-starved cells indicated that flavodoxin was not actively degraded under iron-replete conditions. Greater declines in light-saturated oxygen evolution rates than dark oxygen consumption rates indicated that the mitochondrial electron transfer chain was not affected as greatly by iron starvation as the photosynthetic electron transfer chain. The carbon:nitrogen ratio was unaffected by iron starvation, suggesting that photosynthetic electron transfer was a primary target of iron starvation and that reductions in nitrate assimilation were due to energy limitation (the C:N ratio would be expected to rise under nitrogen-limited but energy-replete conditions). Parallel changes were observed in the maximum light-saturated photosynthesis rate and the light-limited initial slope of the photosynthesis-light curve during iron starvation and recovery. The lowest photosynthesis rates were observed in iron-starved cells and the highest values in iron-replete cells. The light saturation parameter, Ik, was not affected by iron starvation, nor was the chl-to-C ratio markedly reduced. These observations were consistent with iron starvation having a similar or greater effect on photochemical charge separation in PSII than on downstream electron transfer steps. Declines of the ratio of variable to maximum fluorescence in iron-starved cells were consistent with PSII being a primary target of iron starvation. The functional cross-section of PSII was affected only marginally (<20%) by iron starvation, with the largest values observed in iron-starved cells. The rate constant for electron transfer calculated from fast repetition rate fluorescence was found to covary with the light-saturated photosynthesis rate; it was lowest in the most severely starved cells. [source] Different intermolecular interactions in azido[2-(diphenylphosphino)benzaldehyde semicarbazonato-,2P,N1,O]nickel(II)ACTA CRYSTALLOGRAPHICA SECTION C, Issue 7 2009Sladjana B. Novakovi The title compound, [Ni(C20H17N3OP)(N3)], is the first complex with a semicarbazide-based ligand having a P atom as one of the donors. The influence of the P atom on the deformation of the coordination geometry of the NiII ion is evident but less expressed than in the cases of complexes with analogous seleno- and thiosemicarbazide ligands. The torsion angles involving the two bonds formed by the P atom within the six-membered chelate ring have the largest values [C,P,Ni,N = 24.3,(2)° and C,C,P,Ni = ,24.2,(4)°], suggesting that the P atom considerably influences the conformation of the ring. Two types of N,H...N hydrogen bond connect the complex units into chains. [source] A diagnosis of warm-core and cold-core extratropical cyclone development using the Zwack,Okossi equationATMOSPHERIC SCIENCE LETTERS, Issue 4 2009Roohollah Azad Abstract In this study, the development of a warm-core and cold-core extratropical cyclone over North Atlantic is examined. The geostrophic relative vorticity tendency used to diagnose the development is calculated utilizing the so-called extended form of the Zwack,Okossi development equation. In both cases, the cyclonic vorticity advection acted to develop the system, but warm-air advection (diabatic heating) made the largest contribution to explosive development in the cold-core (warm-core) case. Further, a vertical cross section of the temperature advection in the warm-core case reveals that the largest values of this contributor are located far and ahead of the cyclone center. Copyright © 2009 Royal Meteorological Society [source] | ||||||||||||||||