Largest Contribution (largest + contribution)

Distribution by Scientific Domains


Selected Abstracts


Projected population-level effects of thiobencarb exposure on the mysid, Americamysis bahia, and extinction probability in a concentration-decay exposure system

ENVIRONMENTAL TOXICOLOGY & CHEMISTRY, Issue 3 2005
Sandy Raimondo
Abstract Population-level effects of the mysid, Americamysis bahia, exposed to varying thiobencarb concentrations were estimated using stage-structured matrix models. A deterministic density-independent matrix model estimated the decrease in population growth rate (,) with increasing thiobencarb concentration. An elasticity analysis determined that survival of middle stages provided the largest contribution to ,. Decomposing the effects of , in terms of changes in the matrix components determined that reduced reproduction had a large influence on population dynamics at lower thiobencarb concentrations, whereas reduced survivorship had the largest impact on populations at higher concentrations. A simulation model of a concentration-decay system was developed to demonstrate the importance of integrating chemical half-life and management practices in determining population viability. In this model, mysids were originally exposed to a high thiobencarb concentration (300 ,g/L) that decayed an order of magnitude in the number of mysid generations corresponding to thiobencarb half-life values under three different exposure regimes. Environmental stochasticity was added to the model to estimate the cumulative extinction probability of mysids exposed to fluctuating concentrations of thiobencarb in random environments. The cumulative extinction probability increased with thiobencarb half-life, stochasticity, and concentration present at the time of a new exposure. The model demonstrated the expansion of population projection models in determining the ecological impact of a population exposed to pesticides. [source]


Atmospheric moisture budget over Antarctica and the Southern Ocean based on the ERA-40 reanalysis

INTERNATIONAL JOURNAL OF CLIMATOLOGY, Issue 15 2008
Hanna Tietäväinen
Abstract The atmospheric moisture budget over Antarctica and the Southern Ocean was analysed for the period 1979,2001 on the basis of the ERA-40 reanalysis of the European Centre for Medium-Range Weather Forecasts. Meridional transport by transient eddies makes the largest contribution to the southward water vapour transport. The mean meridional circulation contributes to the northward transport in the Antarctic coastal areas, but this effect is compensated by the southward transport by stationary eddies. The convergence of meridional water vapour transport is at its largest at 64,68°S, while the convergence of zonal transport is regionally important in areas of high cyclolysis. Inter-annual variations in water vapour transport are related to the southern annular mode (SAM). The eastward transport has a significant (95% confidence level) positive correlation with the SAM index, while the northward transport has a significant negative correlation with SAM near 60°S. Hydrological balance is well-achieved in the ERA-40 reanalysis: the difference between the water vapour flux convergence (based on analysis) and the net precipitation (precipitation minus evaporation, based on 24-h forecasts) is only 13 mm yr,1 (3%) over the Southern Ocean and , 8 mm yr,1 (5%) over the continental ice sheet. Over the open ocean, the analysis methodology favours the accuracy of the flux convergence. For the whole study region, the annual mean flux convergence exceeded net precipitation by 11 mm yr,1 (3%). The ERA-40 result for the mean precipitation over the Antarctic continental ice sheet in 1979,2001 is 177 ± 8 mm yr,1, while previous estimates range from 173 to 215 mm yr,1. For the period 1979,2001, the ERA-40 data do not show any statistically significant trend in precipitation over the Antarctic grounded ice sheet and ice shelves. From the ERA-40 data, the annual average net evaporation (evaporation minus condensation) is positive over the whole continent. Copyright © 2008 Royal Meteorological Society [source]


Ab initio crystal structure predictions for flexible hydrogen-bonded molecules.

JOURNAL OF COMPUTATIONAL CHEMISTRY, Issue 8 2001
Part III.
Abstract In crystal structure predictions possible structures are usually ranked according to static energy. Here, this criterion has been replaced by the free energy at any temperature. The effects of harmonic lattice vibrations were found by standard lattice-dynamical calculations, including a rough estimate of the effects of thermal expansion. The procedure was tested on glycol and glycerol, for which accurate static energies had been obtained previously (Part II of this series). It was found that entropy and zero-point energy give the largest contribution to free energy differences between hypothetical crystal structures, adding up to about 3 kJ/mol for the structures with lowest energy. The temperature-dependent contribution to the energy and the effects of thermal expansion showed less variation among the structures. The overall accuracy in relative energies was estimated to be a few kJ/mol. The experimental crystal structure for glycol corresponded to the global free energy minimum, whereas for glycerol it ranked second at 1 kJ/mol. © 2001 John Wiley & Sons, Inc. J Comput Chem 22: 816,826, 2001 [source]


The characteristics of Hessian singular vectors using an advanced data assimilation scheme

THE QUARTERLY JOURNAL OF THE ROYAL METEOROLOGICAL SOCIETY, Issue 642 2009
A. R. Lawrence
Abstract Initial condition uncertainty is a significant source of forecast error in numerical weather prediction. Singular vectors of the tangent linear propagator can identify directions in phase-space where initial errors are likely to make the largest contribution to forecast-error variance. The physical characteristics of these singular vectors depend on the choice of initial-time metric used to represent analysis-error covariances: the total-energy norm serves as a proxy to the analysis-error covariance matrix, whereas the Hessian of the cost function of a 4D-Var assimilation scheme represents a more sophisticated estimate of the analysis-error covariances, consistent with observation and background-error covariances used in the 4D-Var scheme. This study examines and compares the structure of singular vectors computed with the European Centre for Medium-Range Weather Forecasts (ECMWF) Integrated Forecasting System using these two types of initial metrics. Unlike earlier studies that use background errors derived from lagged forecast differences (the NMC method), the background-error covariance matrix in the Hessian metric is based on statistics from an ensemble of 4D-Vars using perturbed observations, which produces tighter correlations of background-error statistics than in previous formulations. In light of these new background-error statistics, this article re-examines the properties of Hessian singular vectors (and their relationship to total-energy singular vectors) using cases from different periods between 2003 and 2005. Energy profiles and wavenumber spectra reveal that the total-energy singular vectors are similar to Hessian singular vectors that use all observation types in the operational 4D-Var assimilation. This is in contrast to the structure of Hessian singular vectors without observations. Increasing the observation density tends to reduce the spatial scale of the Hessian singular vectors. Copyright © 2009 Royal Meteorological Society [source]


A diagnosis of warm-core and cold-core extratropical cyclone development using the Zwack,Okossi equation

ATMOSPHERIC SCIENCE LETTERS, Issue 4 2009
Roohollah Azad
Abstract In this study, the development of a warm-core and cold-core extratropical cyclone over North Atlantic is examined. The geostrophic relative vorticity tendency used to diagnose the development is calculated utilizing the so-called extended form of the Zwack,Okossi development equation. In both cases, the cyclonic vorticity advection acted to develop the system, but warm-air advection (diabatic heating) made the largest contribution to explosive development in the cold-core (warm-core) case. Further, a vertical cross section of the temperature advection in the warm-core case reveals that the largest values of this contributor are located far and ahead of the cyclone center. Copyright © 2009 Royal Meteorological Society [source]


Phylogeny of Mysis (Crustacea, Mysida): history of continental invasions inferred from molecular and morphological data

CLADISTICS, Issue 6 2005
Asta Audzijonyt
We studied the phylogenetic history of opossum shrimps of the genus Mysis Latreille, 1802 (Crustacea: Mysida) using parsimony analyses of morphological characters, DNA sequence data from mitochondrial (16S, COI and CytB) and nuclear genes (ITS2, 18S), and eight allozyme loci. With these data we aimed to resolve a long-debated question of the origin of the non-marine (continental) taxa in the genus, i.e., "glacial relicts" in circumpolar postglacial lakes and "arctic immigrants" in the Caspian Sea. A simultaneous analysis of the data sets gave a single tree supporting monophyly of all continental species, as well as monophyly of the taxa from circumpolar lakes and from the Caspian Sea. A clade of three circumarctic marine species was sister group to the continental taxa, whereas Atlantic species had more distant relationships to the others. Small molecular differentiation among the morphologically diverse endemic species from the Caspian Sea suggested their recent speciation, while the phenotypically more uniform "glacial relict" species from circumpolar lakes (Mysis relicta group) showed deep molecular divergences. For the length-variable ITS2 region both direct optimization and a priori alignment procedures gave similar topologies, although the former approach provided a better overall resolution. In terms of partitioned Bremer support (PBS), mitochondrial protein coding genes provided the largest contribution (83%) to the total tree resolution. This estimate however, appears to be partly spurious, due to the concerted inheritance of mitochondrial characters and probable cases of introgression or ancestral polymorphism. © The Willi Hennig Society 2005. [source]


Heterogeneous grazing causes local extinction of edible perennial shrubs: a matrix analysis

JOURNAL OF APPLIED ECOLOGY, Issue 2 2001
L.P. Hunt
Summary 1Population modelling and field measurements of births, growth and deaths were used to investigate the long-term change in abundance of Atriplex vesicaria (Chenopodiaceae), a long-lived, palatable, perennial shrub, under sheep grazing. Of particular interest was whether A. vesicaria is at risk of being eliminated throughout grazed paddocks when the recommended practice of continuous grazing at conservative stocking rates is employed. 2Time-invariant matrix population models indicated that the A. vesicaria population was in decline over much of the study paddock, but the rate of decline was greatest nearer to the water point (population growth rate , , 0·8). Time-varying stochastic matrix models projected that the A. vesicaria population would become locally extinct at most sites up to approximately 2200 m from water, occurring first closer to water (within 12,29 years). The population was stable (i.e. , , 1) at sites greater than 2200 m from water over the projection period of 100 years. 3Decreases in adult survival and recruitment made the largest contributions to reductions in the population growth rate. However, there were spatial patterns centred on the water point in the degree to which particular demographic processes contributed to these reductions, because of a grazing gradient and the differential sensitivity of demographic processes to grazing. Thus decreases in recruitment contributed to reductions in the population growth rate at greater distances. Such responses, together with the sensitivity of the population growth rate to these processes, determined the spatial pattern in population growth. 4The results suggest that piospheres (i.e. the zone of impact) continue to expand over many years under set-stocking so that the area around the water point that is devoid of A. vesicaria becomes larger. The process of expansion appears to first involve the inhibition of recruitment, followed by eventual mortality of established shrubs. 5The large contribution of adult survival to the population growth rate in A. vesicaria suggests that minimizing the mortality of established adults should be a priority for management. This is likely to involve resting from grazing at critical times such as during extended dry periods. This may also permit increased levels of recruitment during subsequent moister periods. [source]