Key Properties (key + property)

Distribution by Scientific Domains


Selected Abstracts


The interpretation, assessment and conservation of ecological communities

ECOLOGICAL MANAGEMENT & RESTORATION, Issue 2009
David A. Keith
Summary Ecological communities are assemblages of species that occur together in space and time. Their properties include composition, structure, habitat, distribution, biological interactions and ecosystem functions. The community concept has a central role in conservation planning, and is a key approach for biodiversity conservation above the species level. The relatively recent application of risk assessment and regulatory systems to conservation of ecological communities has highlighted a number of challenges related to intrinsic uncertainties in the definition, diagnosis and assessment of ecological communities. In this review, I aim to elucidate some key conceptual issues essential to the interpretation of communities. Effective description, diagnosis and assessment of communities rests on an understanding of community theory in relation to environmental gradients and ecosystem dynamics. Continuum and discrete models can both contribute to interpretation of communities for conservation. Different sources of uncertainty are inherent in the key properties that characterize communities. Although some of these are reducible, remaining uncertainty must be incorporated into assessments and decision-making processes for conservation. Protocols for assessing extinction risks of communities address rates of decline in distribution, size of distribution and rates of decline in ecological functions. Some protocols assess these factors in a manner that may be inconsistent with equivalent methods for assessing species. Communities may be viewed in a framework that distinguishes thematic, spatial and temporal scales. These scales influence the outcomes of risk assessment, the benefits and limitations of maps and how well communities perform their function in conservation planning. When applied effectively, ecological communities can be powerful tools for delivering cost-effective outcomes for land-use planning and biodiversity conservation. [source]


Solar Cell Blends: High-Resolution Spectroscopic Mapping of the Chemical Contrast from Nanometer Domains in P3HT:PCBM Organic Blend Films for Solar-Cell Applications (Adv. Funct.

ADVANCED FUNCTIONAL MATERIALS, Issue 3 2010
Mater.
The inside cover image presents a near-field spectroscopic map of a P3HT:PCBM solar cell blend film obtaining using a parabolic-mirror-assisted optical microscope. This technique allows for simultaneous recording of both morphological and spectroscopic information, and on page 492 Xiao Wang et al. use it to investigate local molecular distribution, photoluminescence quenching efficiency, and other key properties of the P3HT:PCBM blend film. [source]


Impact of summer warming on the thermal characteristics of a polymictic lake and consequences for oxygen, nutrients and phytoplankton

FRESHWATER BIOLOGY, Issue 2 2008
SUSANN WILHELM
Summary 1. The impact of long thermal stratification events on some key properties in a polymictic lake was studied by determining the mixing regime of Müggelsee, Germany, using water temperature profiles taken hourly over 4 years. The period included two exceptional summer heatwaves. 2. Long thermal stratification events lasted from about 1 week to 2 months, and exhibited a high variability in thermocline depth and stratification intensity within and between events. 3. During stratification events, hypolimnetic oxygen concentrations strongly decreased while hypolimnetic SRP accumulation increased, depending on the duration and intensity of stratification and on hypolimnetic water temperature. 4. The impact of stratification on the functional phytoplankton composition increased with increasing stratification duration, but was rather different for the heatwaves. 5. Stratification events were followed by strong nutrient pulses into the euphotic zone and intense phytoplankton growth, particularly after the heatwaves. Hence, the influence of the climate extremes counteracted effects of reduced external nutrient loading. [source]


GEOMETRICAL, THERMAL AND MECHANICAL PROPERTIES OF OLIVE FRUITS

JOURNAL OF FOOD PROCESS ENGINEERING, Issue 2 2010
MOHAMAD I. AL-WIDYAN
ABSTRACT In Mediterranean countries, olive trees play a significant economical role. Knowledge of olive fruits properties is essential for the efficient handling of the product and optimizing oil yield. The lack of such knowledge at the local level triggered this study in an attempt to report the fruit's chemical composition and some major engineering properties. Established procedures were followed in conducting the measurements and calculations on fruit samples. The study examined four major varieties of olive fruits, including Spanish, Black Spanish, improved Nabali and Nabali Baladi for their chemical composition and other properties, including geometrical, thermal and frictional properties. Thermal properties, including thermal conductivity, heat capacity and thermal diffusivity, ranged from 0.41 to 0.47 W/(m·K), 2.35 to 2.39 kJ/(kg·K) and 2.88 × 10,7to 2.779 × 10,7 m2/s, respectively. The geometrical properties of the Spanish and Black Spanish were quite similar except for roundness and sphericity. Similar results were found for improved Nabali and Nabali Baladi. The properties of weight, density and packing coefficient ranged from 2.22 to 8.60 g, 890 to 1,230 kg/m3 and 0.43 to 0.52, respectively. The fruit's static friction coefficient over mild steel, aluminum and softwood surfaces ranged from 0.20 to 0.30, 0.21 to 0.29 and 0.22 to 0.33, respectively. PRACTICAL APPLICATIONS In Jordan and other Mediterranean countries, olive fruits are produced in large quantities every season. They are very widely used as pickled fruits or are processed in mills to extract their oil. Despite the fact that fruit properties are a necessary prerequisite for the efficient handling and processing of fruits, literature search indicated the lack of a comprehensive study of scientific merit that reports on the engineering properties of olive fruits. In addition, it is established that knowledge of the fruit properties leads to optimized handling and processing and results in knowledge-based development of all processes and equipment that deal with the fruits. The practical merit of this study stems from the fact that it reports on the key properties of a major product (olive fruits) that has social, cultural and economical significance throughout a whole region and is expanding throughout the globe. [source]


Gas-solids flow behavior: CFB riser vs. downer

AICHE JOURNAL, Issue 9 2001
H. Zhang
Comparisons are made in a circulating fluidized-bed riser/downer system between a 15.1 m high, 0.10 m ID riser and a 9.3 m high, 0.10 m ID downer, based on the measurements of the radial distributions of the local solids holdups and local particle velocities along the two columns. Although the core-annulus flow structures exist in both the riser and downer, the radial flow structure in the downer differs largely from that in the riser. The radial distributions of solids holdup and particle velocity in the downer are much more uniform than those in the riser, thus ensuring the low back mixing and the narrow particle residence time distribution in the downer. The axial flow structure in the downer is also more uniform than that in the riser. Due to the high particle acceleration and the high particle velocity in the downer, the overall solids holdup is significantly lower than that in the riser. The microflow structure in the downer, characterized by the low intermittency indices, is also more uniform than that in the riser. These key properties of the downer make it a very promising candidate for industrial applications where short reaction times and high product selectivity are required. [source]


Probabilistic cross-link analysis and experiment planning for high-throughput elucidation of protein structure

PROTEIN SCIENCE, Issue 12 2004
Xiaoduan Ye
Abstract Emerging high-throughput techniques for the characterization of protein and protein-complex structures yield noisy data with sparse information content, placing a significant burden on computation to properly interpret the experimental data. One such technique uses cross-linking (chemical or by cysteine oxidation) to confirm or select among proposed structural models (e.g., from fold recognition, ab initio prediction, or docking) by testing the consistency between cross-linking data and model geometry. This paper develops a probabilistic framework for analyzing the information content in cross-linking experiments, accounting for anticipated experimental error. This framework supports a mechanism for planning experiments to optimize the information gained. We evaluate potential experiment plans using explicit trade-offs among key properties of practical importance: discriminability, coverage, balance, ambiguity, and cost. We devise a greedy algorithm that considers those properties and, from a large number of combinatorial possibilities, rapidly selects sets of experiments expected to discriminate pairs of models efficiently. In an application to residue-specific chemical cross-linking, we demonstrate the ability of our approach to plan experiments effectively involving combinations of cross-linkers and introduced mutations. We also describe an experiment plan for the bacteriophage , Tfa chaperone protein in which we plan dicysteine mutants for discriminating threading models by disulfide formation. Preliminary results from a subset of the planned experiments are consistent and demonstrate the practicality of planning. Our methods provide the experimenter with a valuable tool (available from the authors) for understanding and optimizing cross-linking experiments. [source]


Weather derivatives valuation and market price of weather risk

THE JOURNAL OF FUTURES MARKETS, Issue 11 2004
Melanie Cao
This paper has two objectives: (1) to propose and implement a valuation framework for temperature derivatives (a specific class of weather derivatives); and (2) to study the significance of the market price of weather risk. The objectives are accomplished by generalizing the Lucas model of 1978 to include the weather as another fundamental source of uncertainty in the economy. Daily temperature is modeled by incorporating such key properties as seasonal cycles and uneven variations throughout the year. The temperature variable is related to the aggregate dividend or output through both contemporaneous and lagged correlations, as corroborated by the data. Numerical analysis shows that the market price of weather risk is significant for temperature derivatives. © 2004 Wiley Periodicals, Inc. Jrl Fut Mark 24:1065,1089, 2004 [source]


Novel physiological function of fructooligosaccharides

BIOFACTORS, Issue 1-4 2004
Takahisa Tokunaga
Abstract Two key properties of short chain fructooligosaccharides (sc-FOS) which lead to physiological functions are indigestibility in the small intestine and fermentability in the colon. Sc-FOS is converted into short chain fatty acids (SCFAs) by intestinal bacteria in the colon and absorbed. Through the metabolic pathway, sc-FOS improves gastrointestinal (GI) condition such as relief from constipation, formation of preferable intestinal microflora and intestinal immunomodulation those are known as prebiotics' function. Besides improvement of GI condition, dietary sc-FOS influences on calcium and magnesium absorption in the colon. A major mineral absorption site is the small intestine, but the colon also works as a Ca and Mg absorption site with an aid of SCFAs made from sc-FOS. Furthermore dietary sc-FOS influences on bioavailability of soy-isoflavones. Plasma and urinal concentration of Genistein and Daidzein, aglycones of Daidzin and Genistin, are higher in the rat fed with sc-FOS than the control rat. An additive effect of dietary isoflavone and sc-FOS was observed on the bone mineral density in OVX mice and moreover sc-FOS increased ceacal ,-glycosidase activity and equol production. These results suggest that FOS increase the bioavailability of isoflavones. [source]


When brains expand: mind and the evolution of cortex

ACTA NEUROPSYCHIATRICA, Issue 3 2007
Matthew T. K. Kirkcaldie
Objective:, To critically examine the relationship between evolutionary and developmental influences on human neocortex and the properties of the conscious mind it creates. Methods:, Using PubMed searches and the bibliographies of several monographs, we selected 50 key works, which offer empirical support for a novel understanding of the organization of the neocortex. Results:, The cognitive gulf between humans and our closest primate relatives has usually been taken as evidence that our brains evolved crucial new mechanisms somehow conferring advanced capacities, particularly in association areas of the neocortex. In this overview of neocortical development and comparative brain morphometry, we propose an alternative view: that an increase in neocortical size, alone, could account for novel and powerful cognitive capabilities. Other than humans' very large brain in relation to the body weight, the morphometric relations between neocortex and all other brain regions show remarkably consistent exponential ratios across the range of primate species, including humans. For an increase in neocortical size to produce new abilities, the developmental mechanisms of neocortex would need to be able to generate an interarchy of functionally diverse cortical domains in the absence of explicit specification, and in this respect, the mammalian neocortex is unique: its relationship to the rest of the nervous system is unusually plastic, allowing great changes in cortical organization to occur in relatively short periods of evolution. The fact that even advanced abilities like self-recognition have arisen in species from different mammalian orders suggests that expansion of the neocortex quite naturally generates new levels of cognitive sophistication. Our cognitive and behavioural sophistication may, therefore, be attributable to these intrinsic mechanisms' ability to generate complex interarchies when the neocortex reaches a sufficient size. Conclusion:, Our analysis offers a parsimonious explanation for key properties of the human mind based on evolutionary influences and developmental processes. This view is perhaps surprising in its simplicity, but offers a fresh perspective on the evolutionary basis of mental complexity. [source]


Beyond Profiling: Using ADMET Models to Guide Decisions

CHEMISTRY & BIODIVERSITY, Issue 11 2009
Matthew Segall
Abstract ADMET Models, whether in silico or in vitro, are commonly used to ,profile' molecules, to identify potential liabilities or filter out molecules expected to have undesirable properties. While useful, this is the most basic application of such models. Here, we will show how models may be used to go ,beyond profiling' to guide key decisions in drug discovery. For example, selection of chemical series to focus resources with confidence or design of improved molecules targeting structural modifications to improve key properties. To prioritise molecules and chemical series, the success criteria for properties and their relative importance to a project's objective must be defined. Data from models (experimental or predicted) may then be used to assess each molecule's balance of properties against those requirements. However, to make decisions with confidence, the uncertainties in all of the data must also be considered. In silico models encode information regarding the relationship between molecular structure and properties. This is used to predict the property value of a novel molecule. However, further interpretation can yield information on the contributions of different groups in a molecule to the property and the sensitivity of the property to structural changes. Visualising this information can guide the redesign process. In this article, we describe methods to achieve these goals and drive drug-discovery decisions and illustrate the results with practical examples. [source]


Diffusion in Nanocrystalline Metals and Alloys,A Status Report,

ADVANCED ENGINEERING MATERIALS, Issue 5 2003
R. Würschum
Abstract Diffusion is a key property determining the suitability of nanocrystalline materials for use in numerous applications, and it is crucial to the assessment of the extent to which the interfaces in nanocrystalline samples differ from conventional grain boundaries. The present article offers an overview of diffusion in nanocrystalline metals and alloys. Emphasis is placed on the interfacial characteristics that affect diffusion in nanocrystalline materials, such as structural relaxation, grain growth, porosity, and the specific type of interface. In addition, the influence of intergranular amorphous phases and intergranular melting on diffusion is addressed, and the atomistic simulation of GB structures and diffusion is briefly summarized. On the basis of the available diffusion data, the diffusion-mediated processes of deformation and induced magnetic anisotropy are discussed. [source]


Brittle-to-Ductile Transition in Uniaxial Compression of Silicon Pillars at Room Temperature

ADVANCED FUNCTIONAL MATERIALS, Issue 15 2009
Fredrik Östlund
Abstract Robust nanostructures for future devices will depend increasingly on their reliability. While great strides have been achieved for precisely evaluating electronic, magnetic, photonic, elasticity and strength properties, the same levels for fracture resistance have been lacking. Additionally, one of the self-limiting features of materials by computational design is the knowledge that the atomistic potential is an appropriate one. A key property in establishing both of these goals is an experimentally-determined effective surface energy or the work per unit fracture area. The difficulty with this property, which depends on extended defects such as dislocations, is measuring it accurately at the sub-micrometer scale. In this Full Paper the discovery of an interesting size effect in compression tests on silicon pillars with sub-micrometer diameters is presented: in uniaxial compression tests, pillars having a diameter exceeding a critical value develop cracks, whereas smaller pillars show ductility comparable to that of metals. The critical diameter is between 310 and 400,nm. To explain this transition a model based on dislocation shielding is proposed. For the first time, a quantitative method for evaluating the fracture toughness of such nanostructures is developed. This leads to the ability to propose plausible mechanisms for dislocation-mediated fracture behavior in such small volumes. [source]


Large-scale plant light-use efficiency inferred from the seasonal cycle of atmospheric CO2

GLOBAL CHANGE BIOLOGY, Issue 8 2004
Christopher J. Still
Abstract We combined atmospheric CO2 measurements, satellite observations, and an atmospheric transport model in an inverse modeling framework to infer a key property of vegetation physiology, the light-use efficiency (LUE) of net primary production, for large geographic regions. We find the highest LUE in boreal regions and in the northern hemisphere tropics. Within boreal zones, Eurasian LUE is higher than North American LUE and has a distinctly different seasonal profile. This longitudinal asymmetry is consistent with ecological differences expected from the much greater cover of deciduous vegetation in boreal Eurasia caused by the vast Siberian forests of the deciduous conifer, Larch. Inferred LUE of the northern hemisphere tropics is also high and displays a seasonal profile consistent with variations of both cloud cover and C4 vegetation activity. [source]


Strategies to reduce the brightness reversion of industrial ECF bleached Eucalyptus globulus kraft pulp

JOURNAL OF CHEMICAL TECHNOLOGY & BIOTECHNOLOGY, Issue 3 2008
Isabel M. C. L. Sêco
Abstract BACKGROUND: Brightness stability is a key property of bleached chemical pulps and is primarily determined by wood species and bleaching process conditions. Eucalyptus globulus is becoming a very important raw material for hardwood pulp production. In spite of this importance, there is a relative lack of systematic studies in the literature dealing with the subject. This research aims to study the effect of some of the foremost bleaching parameters of a DEDD bleaching sequence as well as the effect of a final P stage (DEDP instead of DEDD) in the brightness stability of bleached E. globulus kraft pulps. RESULTS: The increase of the D0 stage temperature from 55 °C to 90 °C caused an increase in brightness stability. Increasing the ClO2 charges from 2.8% to 3.2% also improved significantly the brightness stability. A high H2SO4 charge in the D0 stage (10 kg tonne,1 pulp) diminished the brightness stability. The combination of H2O2 addition to the E stage and ClO2 reduction in the two final D stages does not affect brightness reversion. Raising the D2 stage temperature from 65 °C to 82 °C decreased the brightness reversion, while an increase was obtained when the temperature rose above 82 °C. Substitution of the last ClO2 stage in the DEDD sequence by a H2O2 stage (DEDP) significantly reduced the brightness reversion. CONCLUSION: For an existing pulp mill in which the implementation of new technologies to improve brightness reversion is considered, the results obtained showed that brightness stability can be improved without any significant capital investment. Copyright © 2007 Society of Chemical Industry [source]


Partial uniqueness in CANDECOMP/PARAFAC

JOURNAL OF CHEMOMETRICS, Issue 1 2004
Jos M. F. ten Berge
Abstract A key property of CANDECOMP/PARAFAC is the essential uniqueness it displays under certain conditions. It has been known for a long time that, when these conditions are not met, partial uniqueness may remain. Whereas considerable progress has been made in the study of conditions for uniqueness, the study of partial uniqueness has lagged behind. The only well known cases are those of overfactoring, when more components are extracted than are required for perfect fit, and those cases where the data do not have enough system variation, resulting in proportional components for one or more modes. The present paper deals with partial uniqueness in cases where the smallest number of components is extracted that yield perfect fit. For the case of K×K×2 arrays of rank K, randomly sampled from a continuous distribution, it is shown that partial uniqueness, with some components unique and others differing between solutions, arises with probability zero. Also, a closed-form CANDECOMP/PARAFAC solution is derived for 5×3×3 arrays when these happen to have rank 5. In such cases, any two different solutions share four of the five components. This phenomenon will be traced back to a sixth degree polynomial having six real roots, any five of which can be picked to construct a solution. Copyright © 2004 John Wiley & Sons, Ltd. [source]