Anions

Distribution by Scientific Domains
Distribution within Chemistry

Kinds of Anions

  • Fluorinat anion
  • acid anion
  • adipate anion
  • borate anion
  • bromide anion
  • chloride anion
  • cluster anion
  • complex anion
  • coordinating anion
  • corresponding anion
  • counter anion
  • cyanide anion
  • dicarboxylate anion
  • different anion
  • dihydrogen phosphate anion
  • fluoride anion
  • halide anion
  • inorganic anion
  • iodide anion
  • malonate anion
  • monovalent anion
  • nitrate anion
  • organic anion
  • other anion
  • oxygen anion
  • perchlorate anion
  • phenolate anion
  • phosphate anion
  • radical anion
  • superoxide anion
  • tartrate anion
  • thiocyanate anion
  • various anion
  • weakly coordinating anion

  • Terms modified by Anions

  • anion binding
  • anion channel
  • anion concentration
  • anion efflux
  • anion exchange
  • anion exchange chromatography
  • anion exchange resin
  • anion exchanger
  • anion gap
  • anion interaction
  • anion layer
  • anion level
  • anion production
  • anion radical
  • anion receptor
  • anion secretion
  • anion transport
  • anion transporter
  • anion vacancy

  • Selected Abstracts


    Voltammetric Study of Nitro Radical Anion Generated from Some Nitrofuran Compounds of Pharmacological Significance

    ELECTROANALYSIS, Issue 1 2003
    S. Bollo
    Abstract The electrochemical behavior of 2-(5-amino- 1,3,4-oxadiazolyl)-5-nitrofuran (NF359) and its comparison with well-known drugs such as nifurtimox (NFX) and nitrofurazone (NFZ) in protic, mixed and aprotic media by cyclic voltammetry, tast and differential pulse polarography was studied. All the compounds were electrochemically reducible in all media being the reduction of the nitrofuran group the main voltammetric signal. The one-electron reduction couple due to the nitro radical anion formation was visualized in mixed (for NF359 and NFZ) and aprotic media (for all compounds). By applying a cyclic voltammetric methodology we have calculated the decay constants (k2) of the corresponding nitro radical anions in mixed and aprotic media. In mixed medium data fit well with a disproportionation reaction of the nitro radical anion but in aprotic medium fit better with a dimerization reaction. Also, considering cyclic voltammetric measurements in aprotic media we have estimated the reduction potential of the RNO2/RNO2., couple in aqueous medium, pH 7 (E17 values) finding very good correlation with E17 values obtained by pulse radiolysis. Furthermore we have calculated the equilibrium constants from the electron transfer from nitro radical anion to oxygen (kO2) finding that nitro radical anion from NF359 is thermodynamically favored to react with oxygen in respect to both NFZ and NFX. [source]


    Cubane-Like Bismuth-Iron Cluster: Synthesis, X-ray Crystal Structure and Theoretical Characterization of the [Bi4Fe8(CO)28]4, Anion

    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, Issue 20 2010
    Kirill Yu.
    Abstract The reaction of cyclo -Bi4[Si(SiMe3)3]4 (1) with Na2[Fe(CO)4] in the presence of nBu4NCl leads to the formation of the cage compound [nBu4N]4[Bi4Fe8(CO)28] (2). According to X-ray single-crystal structure analysis, the faces of the tetrahedral Bi4 core are capped by Fe(CO)3 moieties in a ,3 fashion to give a cubanoid Bi4Fe4 framework. The four Fe(CO)4 fragments are ,1 -coordinated to bismuth, each. With 12 skeletal electron pairs the [Bi4Fe8(CO)28]4, anion (2a) is a Bi4Fe4 cubane. The negative charge is localized within cluster 2a according to the NBO analysis of its derivatives. The strength of metal,ligand interactions Bi,,3 -Fe(CO)3 is responsible for the size of the cluster's cubic core. NICS computations at the cage centers of considered molecules show that 2a has paratropic character, whereas removal of four ,1 -Fe(CO)4 fragments from latter causes spherical aromaticity of the modified clusters [Bi4Fe4(CO)12]4, (2aa) and [Bi4Fe4(CO)12]2+ (2ab), mediated by a Bi4 cluster , orbital. [source]


    Synthesis and Characterisation of [XeF5]3[Ti4F19] Containing a Discrete [Ti4F19]3, Anion

    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, Issue 29-30 2009
    Zoran Mazej
    Abstract The complex [XeF5]3[Ti4F19] was prepared by reaction of XeF2, TiF4 and UV-irradiated elemental fluorine in anhydrous hydrogen fluoride as the solvent. The crystal structure of [XeF5]3[Ti4F19] consists of [XeF5]+ cations and discrete [Ti4F19]3, anions. The [XeF5] units have usual slightly distorted pseudo-octahedral symmetry. Contrary to the previously reported [Ti4F18]2, anion, where each TiF6 octahedron shares three apexes with three other octahedra, in [Ti4F19]3,, only two ,3 -[TiF6] octahedra share three apexes with three other [TiF6] units. Each of the remaining two ,2 -[TiF6] octahedra shares only two vertices with two of the above-mentioned ,3 -[TiF6] moieties. The Raman spectrum of [XeF5]3[Ti4F19] is in agreement with the presence of [XeF5]+ cations and [Ti4F19]3, anions. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009) [source]


    An Unusual Anion,, Interaction in an ;rido Organometallic Assembly: Synthesis, First Crystal Structure, and Computational Study

    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, Issue 25 2009
    Jamal Moussa
    Abstract The organometallic assembly [Cp*Ir(,6 -C6H2O4)(BF2)2(CF3SO3)][Cp*Ir(,-Cl)3IrCp*] (3) was prepared from [Cp*Ir(solvent)3][OTf]2 (2) and 1,2,4,5 tetrahydroxybenzene (THB, 1) in acetone, in the presence of an excess amount of BF3·2H2O. Assembly 3 was fully characterized by multinuclear NMR spectroscopy. Remarkably, the X-ray molecular structure of 3 shows that an anion,, interaction occurs between the neutral component Cp*Ir(,6 -C6H2O4)(BF2)2 of the assembly and the CF3SO3 anion of the cationic species [Cp*Ir(,-Cl)3IrCp*]. Computational analysis was carried out on 3 to unravel the nature of this noncovalent interaction. Such an example could serve as a model to explain the important role of anions in organometallic chemistry and asymmetric catalysis. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009) [source]


    Dual Supermesityl Stabilization: A Room-Temperature-Stable 1,2,4-Triphosphole Radical, Sigmatropic Hydrogen Rearrangements, and Tetraphospholide Anion,

    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, Issue 15 2008
    Alex S. Ionkin
    Abstract Cesium 3,5-bis(2,4,6-tri- tert -butylphenyl)-1,2,4-triphospholide (12) and cesium 5-(2,4,6-tri- tert -butylphenyl)tetraphospholide (13) were synthesized and isolated with flat five-membered rings, which are an indication of the aromaticity in these anions. Compound 13 is the first example of a stable tetraphospholide anion, which is structurally characterized. Kinetic stabilization of the 1,2,4-triphospholide system by two supermesityl groups resulted in the detection of the room-temperature-stable radical 17 and the observation of a series of successive sigmatropic hydrogen shifts in the first stable 1H -1,2,4-triphosphole 14 with a P,H bond.(© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008) [source]


    Solid-State Anion,Guest Encapsulation by Metallosupramolecular Capsules Made from Two Tetranuclear Copper(II) Complexes

    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, Issue 29 2007
    Emilio Pardo
    Abstract A new cationic tetranuclear copper(II) complex self-assembles from one 1,3-phenylenebis(oxamato) (mpba) bridging ligand and four CuII ions partially blocked with N,N,N,,N, -tetramethylethylenediamine (tmen) terminal ligands. In the solid state, two of these tetracopper(II) oxamato complexes of bowl-like shape and helical conformation then serve as a building block for the generation of either hetero- (MP) or homochiral (MM/PP) dimeric capsules depending on the nature of the encapsulated anion guest, perchlorate or hexafluorophosphate. The overall magnetic behaviour of these metallosupramolecular capsules does not depend on the nature of the encapsulated anion guest, but it is consistent with the dimer-of-dimer structure of the tetracopper(II) cation host, where the interdimer magnetic coupling through the meta -phenylenediamidate bridge is negligibly smallrelative to the reasonably strong intradimer one across the oxamato bridge.(© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007) [source]


    Variability in the Structures of Luminescent [2-(Aminomethyl)pyridine]silver(I) Complexes: Effect of Ligand Ratio, Anion, Hydrogen Bonding, and ,-Stacking

    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, Issue 16 2005
    Rodney P. Feazell
    Abstract The reaction of 2-(aminomethyl)pyridine (2-amp) with silver(I) salts of triflate (OTf,), trifluoroacetate (tfa,), and tetrafluoroborate (BF4,) produce monomeric, dimeric, bridged, and polymeric structural motifs. The structural characteristics are dependent upon the ratio of ligand/metal in the structure as well as the ability of the anion to coordinate to the metal centers and form hydrogen bonds to the bound ligands. The silver coordination environment takes on several geometries including near linear (6), trigonal (4), tetrahedral (1), and both trigonal-bipyramidal and square-based pyramidal in a single structure (2). Structures 2, 3, and 5 also display short Ag,Ag contacts ranging from 2.8958(3) to 3.0305(4) Å. The species with metal,metal interactions, which are connectively very similar to their metal-isolated counterparts of 1, 4, and 6, are held together only by weak ,-stacking interactions or hydrogen bonds to their respective anions. Low-temperature luminescence spectra were collected for all compounds and are compared. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005) [source]


    Towards Understanding of the Selective Precipitation of Alkali Metal Cations in Presence of Dipicrylamine Anion

    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, Issue 11 2005
    Suresh Eringathodi
    Abstract Dipicrylamine anion (DPA,) precipitates out [K(DPA)] with high selectivity from salt bitterns containing Na+, K+, and Mg2+, whereas the same ligand shows poor selectivity towards K+ , and much higher selectivity towards Cs+ , in studies conducted with a mixture of K+, Rb+, and Cs+. Their single-crystal structures reveal that the K+ and Rb+ salts have similar layered structures, with 8 oxygen atoms from seven DPA, anions encapsulating the metal cation, whereas the Cs+ salt possesses a channel-like structure with the metal ion encapsulated by ten oxygen atoms from six DPA,. The conformation of DPA, in the [Cs(DPA)] single crystal matches closely that of DPA in crystalline state. M···O and intermolecular C,H···O interactions together stabilize the structures. The 133Cs NMR spectrum of the poorly soluble [Cs(DPA)] shows an upfield shift of the peak with respect to CsCl as a result of the interaction with the oxygen atoms of DPA,, whereas 23Na NMR spectrum of the highly soluble [Na(DPA)] shows no such upfield shift compared to NaCl. Powder XRD patterns of bulk [M(DPA)] (M = K+, Rb+, and Cs+) precipitates show that these are similar to the patterns obtained by simulation of the single-crystal X-ray data. The selectivity of precipitation correlates qualitatively with the size and hydration enthalpies of the ions. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005) [source]


    Exchange Interactions at the Supramolecular Level , Synthesis, Crystal Structure, Magnetic Properties, and EPR Spectra of [Mn(MAC)(TCNQ)2] (MAC = Pentaaza Macrocyclic Ligand; TCNQ·, = Radical Anion of 7,7,8,8-Tetracyano- p -quinodimethane)

    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, Issue 10 2003
    Augustin M. Madalan
    Abstract The reaction between [Mn(MAC)(H2O)2]Cl2·4H2O and LiTCNQ (MAC = 2,13-dimethyl-3,6,9,12,18-pentaazabicyclo[12.3.1]octadeca-1(18),2,12,14,16-pentaene) affords a complex with the formula [Mn(MAC)(TCNQ)2] (1), whose crystal structure has been determined. Its structure consists of neutral mononuclear entities. The manganese(II) ion is heptacoordinated, with a pentagonal bipyramidal geometry. The apical positions are occupied by the TCNQ·, radicals, while the macrocyclic ligand is coordinated at the equatorial positions. The seven Mn,N distances range from 2.273(3) to 2.301(6) Å. The strong intermolecular ,,, stacking interactions between the TCNQ radicals (3.2 Å) leads to weave-like infinite chains, which propagate along the crystallographic c axis. The cryomagnetic investigation of 1 revealed a weak intermolecular antiferromagnetic coupling of the Mn2+ ions (J = ,0.18 cm,1), which is mediated by the diamagnetic (TCNQ)22, pairs resulting from the stacking interactions in the crystal. The intermolecular exchange interaction between the Mn2+ ions was further confirmed by variable temperature EPR spectroscopic measurements [|J| = 0.15(5) cm,1], which have been carried out in both the X and Q bands. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003) [source]


    Recoverable Phase-Transfer Catalysts with Fluorinated Anions: Generation and Reactions of Dichlorocarbene and CCl3 Anion in the Heterogeneous System KOH(s)/CHCl3/nBu4NPF6

    EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, Issue 10 2008
    Galina V. Kryshtal
    Abstract Tetraalkylammonium salts bearing PF6, and BF4, anions have been recognized as recoverable phase-transfer catalysts for the synthesis of 1,1-dichlorocyclopropane and ,-(trichloromethyl)carbinol derivatives from alkenes or aldehydes in the heterogeneous system KOH(s)/CHCl3. The catalysts retained their catalytic activity over several reactioncycles.(© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008) [source]


    A Combined Experimental and Theoretical Study of Anion,, Interactions in Bis(pyr­imidine) Salts

    EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, Issue 35 2007
    Angel Garcia-Raso
    Abstract We report the synthesis and X-ray characterization of an N,N, -tetramethylenebis(2-aminopyrimidinium) tetrafluoroborate salt that exhibits anion,, interactions that are responsible for the crystal packing. The anion forms a sandwich complex with two pyrimidine rings. When the anion is nitrate, the crystal packing is governed by anion,, interactions and hydrogen bonds, and the sandwich complex is not formed. Finally, a theoretical study of the anion,, interactions in charged pyrimidine rings is in good agreement with the experimental findings. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007) [source]


    Calix[4]arene-Based Chromogenic Chemosensor for the ,-Phenylglycine Anion: Synthesis and Chiral Recognition

    EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, Issue 6 2006
    Guang-Yan Qing
    Abstract Calix[4]arene-based two-armed chiral anion receptors 3a and 3b have been synthesized and examined for their chiral anion-binding abilities by UV/Vis absorption and 1H NMR spectroscopy. The results of nonlinear curve fitting indicate that 3a and 3b form 1:1 stoichiometric complexes with the L - or D -,-phenylglycine anion by multiple hydrogen-bonding interactions and exhibit good enantioselective recognition for the enantiomers of the ,-phenylglycine anions (3a: Kass(L)/Kass(D) = 4.76; 3b: Kass(D)/Kass(L) = 2.84). The marked colour changes observed for the complexation of 3a with the chiral anions and the good enantioselective recognition reveal that receptor 3a could be used as a good chiral chromogenic chemosensor for the enantiomers of the ,-phenylglycine anion. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006) [source]


    Domino Aza-Claisen/Mannich Cyclization Reaction from a Chiral ,-Alkoxy Enamine or Sequential Alkylation of an ,-Alkoxy Ester Enolate or Nitrile Anion, Followed by an Intramolecular Wittig Reaction: Two (3+2) Annulation Routes to Homochiral 4-Alkyl-4-hydroxy-2-cyclopentenone Synthesis

    EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, Issue 14 2003
    Cyrille Kuhn
    Abstract A study on the enantioselective synthesis of 4-alkyl-4-hydroxyalkylidene-cyclopentenone prostaglandins is reported. Two (3+2) annulation processes allow the synthesis of homochiral 4-alkyl-4-hydroxy-2-cyclopentenones 4,5, 10,11, and 17. The first process involves a domino aza-Claisen/Mannich cyclization reaction, resulting from the alkylation of an ,-alkoxy-enamine, derived from chiral ,-alkoxy aldehydes 1, 9, or 16 with 3-iodo-2-(methoxymethoxy)prop-1-ene (3) as the acetonyl equivalent. The second process is based on the sequential alkylation of esters 21, 39, or nitrile 20 with acetonyl equivalents 3 or 25, followed by an intramolecular Wittig reaction. As an application, the synthesis of the naturally occurring alkylidene-cyclopentenone prostaglandin clavulone II from the spiro[cyclopentene-furan]one 5 and the formal total synthesis of (+/-)-untenone 19 has been carried out. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003) [source]


    Activation of Elemental Sulfur by Electrogenerated Cyanomethyl Anion: Synthesis of Substituted 2-Aminothiophenes by the Gewald Reaction

    ADVANCED SYNTHESIS & CATALYSIS (PREVIOUSLY: JOURNAL FUER PRAKTISCHE CHEMIE), Issue 17 2008
    Marta Feroci
    Abstract The activation of elemental sulfur (S8) has been achieved by means of electrogenerated cyanomethyl anion [easily obtained by galvanostatic reduction from acetonitrile/tetraethylammonium hexafluorophosphate (MeCN-Et4NPF6)]. The "activated" sulfur reacted with ylidenemalononitriles to give substituted 2-aminothiophenes in very high yields. This variation of the Gewald reaction has been carried out using only catalytic amounts of electricity and supporting electrolyte. A proposed mechanism for the interaction between S8 and cyanomethyl anion is described. [source]


    Polymer-Supported Bisacetoxybromate(I) Anion ,-An Efficient Co-Oxidant in the TEMPO-Mediated Oxidation of Primary and Secondary Alcohols

    ADVANCED SYNTHESIS & CATALYSIS (PREVIOUSLY: JOURNAL FUER PRAKTISCHE CHEMIE), Issue 5 2003
    Marco Brünjes
    Abstract A polymer-bound reagent for the efficient oxidation of primary alcohols to aldehydes and secondary alcohols to ketones in the presence of a catalytic amount of 2,2,6,6-tetramethyl-1-piperidinyloxyl (TEMPO) is described. The oxidation process is particular mild and allows one to prepare aldehydes with ,-chirality without racemization. This also includes the synthesis of ,-aminoaldehydes. In most cases, work-up of this heavy metal-free oxidation is achieved by simple filtration followed by removal of the solvent. Insight into the role of the bromate(I) anion in the oxidation process was gained from the TEMPO-mediated oxidation of benzaldehyde in the presence of the hypochlorite anion loaded on an anion exchange resin. [source]


    Influence of Tithonia diversifolia and triple superphosphate on dissolution and effectiveness of phosphate rock in acidic soil

    JOURNAL OF PLANT NUTRITION AND SOIL SCIENCE, Issue 5 2006
    Isaac Savini
    Abstract An incubation and a pot experiment were conducted to evaluate the dissolution and agronomic effectiveness of a less reactive phosphate rock, Busumbu soft ore (BPR), in an Oxisol in Kenya. Resin (anion and anion + cation)-extractable P and sequentially extracted P with 0.5 M NaHCO3, 0.1 M NaOH, and 1 M HCl were analyzed. Dissolution was determined from the increase in anion resin (AER),, NaHCO3 -, and NaOH-extractable P in soil amended with PR compared with the control soil. Where P was applied, resin P significantly increased above the no-P treatment. Busumbu-PR solubility was low and did not increase significantly in 16 weeks. Anion + cation (ACER)-extractable P was generally greater than AER-P. The difference was greater for PR than for triple superphosphate (TSP). The ACER extraction may be a better estimate of plant P availability, particularly when poorly soluble P sources are used. Addition of P fertilizers alone or in combination with Tithonia diversifolia (TSP, BPR, TSP + Tithonia, and BPR + Tithonia) increased the concentration of labile inorganic P pools (NaHCO3 - and NaOH-Pi). Cumulative evolved CO2 was significantly correlated with cumulative N mineralized from Tithonia (r, 0.51, p < 0.05). Decrease in pH caused NH -N accumulation while NO -N remained low where Tithonia was incorporated at all sampling times. However, when pH was increased, NH -N declined with a corresponding rise in NO -N. Tithonia significantly depressed soil exchangeable acidity relative to control with time. A significant increase (p < 0.05) was observed for P uptake but not dry-mass production in maize where BPR was applied. The variations in yield and P uptake due to source and rates of application were statistically significant. At any given P rate, highest yields were obtained with Tithonia alone. Combination of Busumbu PR with TSP or Tithonia did not enhance the effectiveness of the PR. The poor dissolution and plant P uptake of BPR may be related to the high Fe content in the PR material. [source]


    The ,-Accepting Arene HAT(CN)6 as a Halide Receptor through Charge Transfer: Multisite Anion Interactions and Self-Assembly in Solution and the Solid State,

    ANGEWANDTE CHEMIE, Issue 40 2010
    Dr. Helen T. Chifotides
    Sensibles Selbstorganisat: Ihre außergewöhnliche ,-Elektronenakzeptorstärke macht die Titelverbindung zu einem exzellenten kolorimetischen Halogenidsensor. Neu daran ist, dass HAT(CN)6 mit Anionen multiple Wechselwirkungen (sowohl Charge-Transfer als auch Anion-,) in Lösung und im Festkörper eingeht. Die Halogenidionen bewirken die spontane Selbstorganisation der Sandwichkomplexe über ,2,,2 -Ladungstransferkontakte. [source]


    A Bowl-Shaped ortho -Semiquinone Radical Anion: Quantitative Evaluation of the Dynamic Behavior of Structural and Electronic Features,

    ANGEWANDTE CHEMIE, Issue 36 2010
    Akira Ueda Dr.
    Elegant aufgetischt: Das erste ,schüsselförmige" o -Semichinonradikal (siehe Bild; mit einem Na+ -Ion) wurde synthetisiert und bezüglich seiner elektronischen Eigenschaften charakterisiert. Das dynamische Verhalten (konkav,konvex) wurde mit EPR- und ENDOR/TRIPLE-Messungen sowie DFT-Rechnungen ebenfalls quantitativ untersucht. [source]


    Long-Lived Radical Cations of Monocyclic Arenes at Room Temperature Obtained by NbF5 Acting as an Oxidizing Agent and Counterion Precursor,

    ANGEWANDTE CHEMIE, Issue 31 2010
    Fabio Marchetti Dr.
    Das Salz der Erde: Eine Reaktion, in der Niobpentafluorid als Oxidationsmittel (Bildung von NbF4) und als Fluoridakzeptor (Bereitstellung des Gegenions [Nb2F11],) fungiert, lieferte Radikalkationensalze von monocyclischen Arenen, einschließlich Benzol (siehe Bild). Anion-,-Wechselwirkungen sind entscheidend für die einzigartige Inertheit der Radikalkationen. [source]


    Structurally Stimulated Deprotonation/Alumination of the TMP Anion,

    ANGEWANDTE CHEMIE, Issue 18 2010
    Ben Conway
    Aus Base wird Säure: Das Tetramethylpiperidin(TMP)-Anion, das seit langem als starke Brønsted-Base bekannt ist, kann durch Einwirkung eines Kalium-Aluminat-Gemischs in eine Brønsted-Säure umgewandelt werden. Im neuen Produkt [(TMEDA)K(,-TMP*)(,- iBu)Al(iBu)] steht TMP* für ein an CH3 und NH deprotoniertes TMP-Dianion (siehe Schema). [source]


    ChemInform Abstract: Al(HSO4)3/Silica Gel as a Novel Catalytic System for the Ring Opening of Epoxides with Thiocyanate Anion under Solvent-Free Conditions.

    CHEMINFORM, Issue 26 2010
    Ali Reza Kiasat
    Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a "Full Text" option. The original article is trackable via the "References" option. [source]


    ChemInform Abstract: Slow-Proton Dynamics within a Zirconium-Containing Sandwich-Like Complex Based on the Trivacant Anion ,-[SiW9O34]10- , Synthesis, Structure and NMR Spectroscopy.

    CHEMINFORM, Issue 4 2009
    Nathalie Leclerc-Laronze
    Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a "Full Text" option. The original article is trackable via the "References" option. [source]


    ChemInform Abstract: Syntheses of Acetonitrile-Ligated Copper Complexes with Perfluoroalkoxy Aluminate as Counter Anion and Their Catalytic Application for Olefin Aziridination.

    CHEMINFORM, Issue 3 2009
    Yang Li
    Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a "Full Text" option. The original article is trackable via the "References" option. [source]


    ChemInform Abstract: The HSSS Radical and the HSSS - Anion.

    CHEMINFORM, Issue 47 2008
    Giulia de Petris
    Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a "Full Text" option. The original article is trackable via the "References" option. [source]


    ChemInform Abstract: Recoverable Phase-Transfer Catalysts with Fluorinated Anions: Generation and Reactions of Dichlorocarbene and CCl3 Anion in the Heterogeneous System KOH(s)/CHCl3/nBu4NPF6.

    CHEMINFORM, Issue 29 2008
    Galina V. Kryshtal
    Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a "Full Text" option. The original article is trackable via the "References" option. [source]


    ChemInform Abstract: Recoverable Phase-Transfer Catalysts with Fluorinated Anions: Generation and Reactions of Dichlorocarbene and CCl3 Anion in the Heterogeneous System KOH(s)/CHCl3/nBu4NPF6.

    CHEMINFORM, Issue 29 2008
    Galina V. Kryshtal
    Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a "Full Text" option. The original article is trackable via the "References" option. [source]


    ChemInform Abstract: Synthesis and Structure of the Novel Pentaselenidohexaarsenate(I,II) Cluster Anion [As6Se5]2- .

    CHEMINFORM, Issue 24 2008
    Anna Kromm
    Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a "Full Text" option. The original article is trackable via the "References" option. [source]


    ChemInform Abstract: Structural and NMR Spectroscopic Investigations of Chair and Twist Conformers of the P2Se82- Anion.

    CHEMINFORM, Issue 21 2008
    Christiane Rotter
    Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a "Full Text" option. The original article is trackable via the "References" option. [source]


    ChemInform Abstract: Outer-Sphere Oxidation of the Superoxide Radical Anion.

    CHEMINFORM, Issue 13 2008
    Ira A. Weinstock
    Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a "Full Text" option. The original article is trackable via the "References" option. [source]


    ChemInform Abstract: Intramolecular Aza-anti-Michael Addition of an Amide Anion to Enones: A Regiospecific Approach to Tetramic Acid Derivatives.

    CHEMINFORM, Issue 7 2008
    Xihe Bi
    Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a "Full Text" option. The original article is trackable via the "References" option. [source]