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K Values (k + value)

Distribution by Scientific Domains

Polymers and Materials Science	27%
Chemistry	22%
Life Sciences	11%
Earth and Environmental Science	11%

Selected Abstracts

Compositional constraints on the equation of state and thermal properties of the lower mantle

GEOPHYSICAL JOURNAL INTERNATIONAL, Issue 1 2001
Frank D. Stacey
SUMMARY By extrapolating the lower mantle equation of state (EoS) to P=0, T=290 K, we determine the EoS parameters that are compatible with a mixture of (Mg, Fe)SiO3 perovskite (with a small admixture of Al2O3), (Mg, Fe)O magnesiowüstite and CaSiO3 perovskite in arbitrary proportions and with arbitrary Fe/(Fe+Mg) ratio. The parameters fitted are density, ,, adiabatic incompressibility, KS, and its pressure derivative, K,S,(,KS/,P)S. The first stage is adiabatic extrapolation to P=0, T=T0, that is, to the foot of the lower mantle adiabat, at which K,0(T0) is allowed to have any value between 3.8 and 4.6, and 1500 K,T0,2000 K. It is important to use an equation for which the lower mantle fitting does not prescribe K,0(T0) and this rules out the third-order Birch theory, which gives a seriously wrong value. The further extrapolation to 290 K at P=0 uses thermodynamic relationships with maximum generality, allowing all of the following thermoelastic parameters to be arbitrary functions of temperature: K;,; Grüneisen parameter, ,;q=(, ln ,/, ln V)T, where V is volume; volume coefficient of thermal expansion, ,; adiabatic Anderson,Grüneisen parameter, ,S=(1/,) (, ln KS/,T)P; and the mixed P, T derivative (,K,S/,T)P. The heat capacity at constant volume, CV, is assumed to follow the Debye function, so , is controlled by that. The temperature dependences of the dimensionless parameters ,, q and ,S at P=0 are slight. We find , to be precisely independent of T at constant V. The parameter dK,0/dT increases strongly with T, as well as with the assumed value of K,0(T0), where K,0 is K,S at P=0. The fitting disallows significant parameter ranges. In particular, we find solutions only if K,0(T0),4.2 and the 290 K value of K,0 for Mg perovskite is less than 3.8. Conclusions about composition are less secure, partly because of doubt about individual mineral properties. The volume of magnesiowüstite is found to be between 10 and 25 per cent for respective T0 values of 2000 and 1500 K, but the Ca-perovskite volume is no more than 6 per cent and has little influence on the other conclusions. The resulting overall Fe/(Fe+Mg) ratio is 0.12 to 0.15. Although this ratio is higher than expected for a pyrolite composition, the ratio depends critically on the assumed mineral densities; some adjustment of the mineral mix may need to be considered. [source]

Mechanical and morphological properties for sandwich composites of wood/PVC and glass fiber/PVC layers

JOURNAL OF APPLIED POLYMER SCIENCE, Issue 6 2010
Narudol Mongkollapkit
Abstract This work manufactured sandwich composites from glass fiber/poly(vinyl chloride) (GF/PVC) and wood/PVC layers, and their mechanical and morphological properties of the composites in three GF orientation angles were assessed. The effects of K value (or viscosity index) of PVC and Dioctyl phthalate (DOP) loading were of our interests. The GF/PVC was used as core layer whereas wood/PVC was the cover layers. The experimental results indicated that PVC with low K value was recommended for the GF/PVC core layer for fabrication of GF/WPVC sandwich composites. The improvement of PVC diffusion at the interface between the GF and the PVC core layer was obtained when using PVC with K value of 58. This was because it could prevent de-lamination between composite layers which would lead to higher mechanical properties of the sandwich composites, except for the tensile modulus. The sandwich composites with 0° GF orientation possessed relatively much higher mechanical properties as compared with those with 45° and 90° GF orientations, especially for the impact strength. Low mechanical properties of the sandwich composites with 45° and 90° GF orientation angles could be overcome by incorporation of DOP plasticizer into the GF/PVC core layer with the recommended DOP loadings of 5,10 parts per hundred by weight of PVC components. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2010 [source]

The effect of surface,solute interactions on the transport of solutes through porous materials

EUROPEAN JOURNAL OF SOIL SCIENCE, Issue 3 2009
D. A. Rose
Summary We have investigated the effect of differences in surface charge, valency of ion, solute concentration, solution flux and physical structure on the leaching and uptake of individual ions from simple solutions flowing through porous materials. We studied the miscible displacement of solutions of four salts (KBr, K2SO4, CaBr2 and CaSO4) having different cation : anion ratios separately through three inert materials (ballotini, pumice and ceramic) and two sizes of a reactive material (sepiolite) over several ranges of concentration (c) and at many pore-water velocities (v) under steady vertical saturated flow. Breakthrough curves of individual effluent ions (K+, Br,, Ca2+ and SO42,) were analysed by CXTFIT 2.0 to optimize transport parameters (retardation factor, R; dispersion coefficient, K) assuming that transport was governed by the convective,dispersion equation. In the inert materials, R did not differ significantly from 1 irrespective of c. In sepiolite, R was < 1 for anions and > 1 for cations, and became more extreme as c decreased. R varied with the valency of the anions, as predicted by diffuse double layer theory, and with that of the cations by a simple charge balance. Freundlich isotherms, reconstructed from R values, described the sorption of the cations and exclusion of the anions. For the inert materials, K did not depend on the ion or c and increased monotonically with v. For sepiolite, K also increased with v and with small but non-significant differences between ions and concentrations. The K(v) functions were consistent with Passioura's theory of dispersion in aggregated media, and the transport was reversible as R and K values did not depend on whether the media were being leached or resalinized. The effective dispersion coefficient of an ion is K* = K/R so, although K(v) appears to be unaffected by ion or concentration of solute in sepiolite, K*(v) will be affected. Thus, the controlling factor of these surface,solute interactions is R. [source]

Fatigue behaviour of friction stir welded AA2024-T3 alloy: longitudinal and transverse crack growth

FATIGUE & FRACTURE OF ENGINEERING MATERIALS AND STRUCTURES, Issue 7 2008
M. T. MILAN
ABSTRACT The fatigue crack growth properties of friction stir welded joints of 2024-T3 aluminium alloy have been studied under constant load amplitude (increasing -,K), with special emphasis on the residual stress (inverse weight function) effects on longitudinal and transverse crack growth rate predictions (Glinka's method). In general, welded joints were more resistant to longitudinally growing fatigue cracks than the parent material at threshold ,K values, when beneficial thermal residual stresses decelerated crack growth rate, while the opposite behaviour was observed next to KC instability, basically due to monotonic fracture modes intercepting fatigue crack growth in weld microstructures. As a result, fatigue crack growth rate (FCGR) predictions were conservative at lower propagation rates and non-conservative for faster cracks. Regarding transverse cracks, intense compressive residual stresses rendered welded plates more fatigue resistant than neat parent plate. However, once the crack tip entered the more brittle weld region substantial acceleration of FCGR occurred due to operative monotonic tensile modes of fracture, leading to non-conservative crack growth rate predictions next to KC instability. At threshold ,K values non-conservative predictions values resulted from residual stress relaxation. Improvements on predicted FCGR values were strongly dependent on how the progressive plastic relaxation of the residual stress field was considered. [source]

The effect of truck traffic and road water content on sediment delivery from unpaved forest roads

HYDROLOGICAL PROCESSES, Issue 8 2006
Gary J. Sheridan
Abstract A study investigated the effect of truck-traffic intensity and road water-content on the quality of runoff water from unsealed forest roads. Three sections of a gravel-surfaced forest road were instrumented and exposed to low and high levels of truck traffic during wet winter conditions and dry summer conditions between July 2001 and December 2002. Rainfall, runoff, road moisture, and traffic were measured continuously, and suspended and bedload sediments were integrated measurements over 2-week site-service intervals. The median suspended sediment concentration from the three road segments under low truck-traffic conditions (less than nine return truck passes prior to a storm) was 269 mg l,1, increasing 2·7-fold to a median of 725 mg l,1 under high truck-traffic conditions (greater than or equal to nine return truck passes prior to a storm). These concentrations, and increases due to traffic, are substantially less than most previously reported values. When these data are expressed as modified universal soil loss equation (MUSLE) erodibility values K, accounting for differences in rainfall energy, site characteristics and runoff, high traffic resulted in a road surface that was four times more erodible than the same road under low traffic conditions. Using multiple regression, traffic explained 36% of the variation in MUSLE erodibility, whereas road water content was not significant in the model. There was little difference in the erodibility of the road when trafficked in low water-content compared with high water-content conditions (MUSLE K values of 0·0084 versus 0·0080 respectively). This study shows that, for a good quality well-maintained gravel forest road, the level of truck traffic affects the sediment concentration of water discharging from the road, whereas the water content of the road at the time of that traffic does not (note that traffic is not allowed during runoff events in Victoria). These conclusions are conditional upon the road being adequately maintained so that trafficking does not compromise the lateral drainage of the road profile. Copyright © 2005 John Wiley & Sons, Ltd. [source]

Kinetics and mechanism of myristic acid and isopropyl alcohol esterification reaction with homogeneous and heterogeneous catalysts

INTERNATIONAL JOURNAL OF CHEMICAL KINETICS, Issue 3 2008
Tuncer Yalçinyuva
The reaction of myristic acid (MA) and isopropyl alcohol (IPA) was carried out by using both homogeneous and heterogeneous catalysts. For a homogeneously catalyzed system, the experimental data have been interpreted with a second order, using the power-law kinetic model, and a good agreement between the experimental data and the model has been obtained. In this approach, it was assumed that a protonated carboxylic acid is a possible reaction intermediate. After a mathematical model was proposed, reaction rate constants were computed by the Polymath* program. For a heterogeneously catalyzed system, interestingly, no pore diffusion limitation was detected. The influences of initial molar ratios, catalyst loading and type, temperature, and water amount in the feed have been examined, as well as the effects of catalyst size for heterogeneous catalyst systems. Among used catalysts, p -toluene sulfonic acid (p -TSA) gave highest reaction rates. Kinetic parameters such as activation energy and frequency factor were determined from model fitting. Experimental K values were found to be 0.54 and 1.49 at 60°C and 80°C, respectively. Furthermore, activation energy and frequency factor at forward were calculated as 54.2 kJ mol,1 and 1828 L mol,1 s,1, respectively. © 2008 Wiley Periodicals, Inc. 40: 136,144, 2008 [source]

NUCLEOTIDE CATABOLISM IN COLD STORED ADDUCTOR MUSCLE OF SCALLOP (ZYGOCHLAMYS PATAGONICA)

JOURNAL OF FOOD BIOCHEMISTRY, Issue 4 2002
AGUEDA E. MASSA
ABSTRACT The postmortem catabolism of adenosine triphosphate (ATP) in cold stored scallop adductor muscles was examined. The change In the pH of stored muscles was also investigated. The ATP content increased for a short time after death and afterwards decreased up to 24 h of storage. Thereafter, the nucleotide level remained unchanged up to 120 h of storage. The ADP content slightly decreased up to 48 h and after that remained unchanged. The AMP slowly accumulated to around 15% of the total nucleotide concentration when the ATP decreased. Small amounts of IMP were detected in all samples. Conversely, adenosine (Ado) was not detected. Inosine (HxR) slightly increased after 48 h of storage and hypoxanthine (Hx.) significantly increased after 24 h. The 260/250-absorbance ratio of muscle extracts and the pH of stored muscles fell sharply up to 24 h and then decreased slowly. The Hx contents were positively correlated (P < 0.01) with both the Hx/AMP ratios and the K values. [source]

MEL-type Pure-Silica Zeolite Nanocrystals Prepared by an Evaporation-Assisted Two-Stage Synthesis Method as Ultra-Low- k Materials,

ADVANCED FUNCTIONAL MATERIALS, Issue 12 2008
Yan Liu
Abstract A MEL-type pure-silica zeolite (PSZ), prepared by spin-on of nanoparticle suspensions, has been shown to be a promising ultra-low-dielectric-constant (k) material because of its high mechanical strength, hydrophobicity, and chemical stability. In our previous works, a two-stage synthesis method was used to synthesize a MEL-zeolite nanoparticle suspension, in which both nanocrystal yield and particle size of the zeolite suspension increased with increasing synthesis time. For instance, at a crystal yield of 63%, the particle size is 80,nm, which has proved to be too large because it introduces a number of problems for the spin-on films, including large surface roughness, surface striations, and large mesopores. In the current study, the two-stage synthesis method is modified into an evaporation-assisted two-stage method by adding a solvent-evaporation process between the two thermal-treatment steps. The modified method can yield much smaller particle sizes (e.g., 14,vs. 80,nm) while maintaining the same nanocrystal yields as the two-stage synthesis. Furthermore, the nanoparticle suspensions from the evaporation-assisted two-stage synthesis show a bimodal particle size distribution. The primary nanoparticles are around 14,nm in size and are stable in the final suspension with 60% solvent evaporation. The factors that affect nanocrystal synthesis are discussed, including the concentration, pH value, and viscosity. Spin-on films prepared by using suspensions synthesized this way have no striations and improved elastic modulus (9.67,±,1.48,GPa vs. 7.82,±,1.30,GPa), as well as a similar k value (1.91,±,0.09 vs. 1.89,±,0.08) to the previous two-stage synthesized films. [source]

Predicting immunosuppressant dosing in the early postoperative period with noninvasive indocyanine green elimination following orthotopic liver transplantation

LIVER TRANSPLANTATION, Issue 1 2008
Brian M. Parker
Twenty adult patients undergoing orthotopic liver transplantation (OLT) were enrolled in this study, with the noninvasive indocyanine green plasma disappearance rate (ICG-PDR) measured both during and after OLT to assess the relationship between ICG-PDR and the ability of patients to achieve therapeutic postoperative tacrolimus immunosuppressant blood levels. Liver function was determined at both 2 and 18 hours post reperfusion with the ICG-PDR k value (1/min). Postoperative standard serum measures of liver function as well as liver biopsies were also collected and analyzed. The median ICG-PDR k value for the study group at 2 hours post reperfusion was 0.20 (0.16, 0.27), whereas at 18 hours post reperfusion, it was 0.22 (0.18, 0.35). The median change in the k value between the two ICG-PDR measurements was 0.05 (,0.02, 0.07) with P = 0.02. There was an interaction between the postoperative day 1 (18 hours post reperfusion) ICG-PDR k value and the linear increase in the tacrolimus blood level, such that the greater the k value was, the more gradual the observed rise was in tacrolimus over time [that is, the longer it took to achieve a therapeutic blood level (>12 ng/mL), P = 0.003]. Of the 16 patients that received tacrolimus, comparable dosing on a per kilogram body weight basis was observed. Also, no significant association between ICG-PDR k values and postoperative liver biopsy results was seen. This study demonstrates that the ICG-PDR measurement is a modality with the potential to assist in achieving adequate blood levels of tacrolimus following OLT. Liver Transpl 14:46,52, 2008. © 2007 AASLD. [source]

Lability of organic carbon in lakes of different trophic status

FRESHWATER BIOLOGY, Issue 6 2009
A. P. OSTAPENIA
Summary 1. We used first-order kinetic parameters of biological oxygen demand (BOD), the constant of aerobic decomposition (k) and the asymptotic value of BOD (BODult), to characterise the lability of organic carbon pools in six lakes of different trophic state: L. Naroch, L. Miastro and L. Batorino (Belarus), L. Kinneret (Israel), L. Ladoga (Russia) and L. Mendota (U.S.A.). The relative contributions of labile and refractory organic carbon fractions to the pool of total organic carbon (TOC) in these lakes were quantified. We also determined the amounts of labile organic carbon within the dissolved and particulate TOC pools in the three Belarus lakes. 2. Mean annual chlorophyll concentrations (used as a proxy for lake trophic state) ranged from 2.3 to 50.6 ,g L,1, labile organic carbon (OCL = 0.3BODult) from 0.75 to 2.95 mg C L,1 and k from 0.044 to 0.14 day,1. 3. Our data showed that there were greater concentrations of OCL but lower k values in more productive lakes. 4. In all cases, the DOC fraction dominated the TOC pool. OCL was a minor component of the TOC pool averaging about 20%, irrespective of lake trophic state. 5. In all the lakes, most (c. 85%) of the DOC pool was refractory, corresponding with published data based on measurements of bacterial production and DOC depletion. In contrast, a larger fraction (27,55%) of the particulate organic carbon (POC) pool was labile. The relative amount of POC in the TOC pool tended to increase with increasing lake productivity. 6. Long-term BOD incubations can be valuable in quantifying the rates of breakdown of the combined particulate and dissolved organic carbon pools and in characterising the relative proportions of the labile and recalcitrant fractions of these pools. If verified from a larger number of lakes our results could have important general implications. [source]

Tunable transport of glucose through ionically-crosslinked alginate gels: Effect of alginate and calcium concentration

JOURNAL OF APPLIED POLYMER SCIENCE, Issue 5 2008
Mari-Kate E. McEntee
Abstract Alginate beads have numerous biomedical applications, ranging from cell encapsulation to drug release. The present study focuses on the controlled release of glucose from calcium-alginate beads. The effects of alginate concentrations (1,6 wt %) and calcium chloride concentrations (0.1,1.0M) on glucose release from beads were examined. It was found that the time required for complete glucose release from beads could be tuned from 15 min to over 2 h, simply by varying alginate and calcium chloride concentrations in beads. For calcium-alginate beads with sodium alginate concentrations of 1,4 wt %, higher sodium alginate concentrations lead to more prolonged release of glucose and thus a smaller value of a rate constant k, a parameter shown to be proportional to the diffusion coefficient of glucose in the alginate gel. For beads with sodium alginate concentrations of 4,6 wt %, there was no statistically significant difference in k values, indicating a lower limit for glucose release from calcium-alginate beads. Similarly, higher calcium chloride concentrations appear to extend glucose release, however, no conclusive trend can be drawn from the data. In a 50 : 50 mixture of calcium-alginate beads of two different alginate concentrations (1 and 4 wt %), glucose release showed a two-step profile over the time range of 20,50 min, indicating that the pattern and time of glucose release from beads can be tuned by making combinations of beads with varying alginate and/or calcium chloride concentrations. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 [source]

THERMAL INACTIVATION KINETICS OF ALKALINE PHOSPHATASE IN BUFFER AND MILK

JOURNAL OF FOOD PROCESSING AND PRESERVATION, Issue 3 2006
S. FADILO
ABSTRACT A detailed kinetic study on the thermal inactivation of alkaline phosphatase (ALP) added into buffer and pasteurized milk and for ALP naturally present in raw cow's milk has been performed. Kinetic parameters (rate constant, k; decimal reduction time, D; activation energy, Ea; and z value) were evaluated based on the first-order rate model at 50,80C. The temperature sensitivity of the kinetic parameters was evaluated considering the Arrhenius-type Ea model. All kinetic behaviors were well described by the first-order model (r2 > 0.91). The D values increased with increasing temperature. Higher temperatures resulted in higher rates of enzyme inactivation as indicated by lower D values and higher k values. There are significant differences (P < 0.01) among the D values for ALP in buffer and milk at treated temperatures. The rate of enzyme inactivation was much more rapid in buffer than in pasteurized milk. The evaluated Ea values for ALP added into the buffer and pasteurized milk, and for ALP naturally present in raw milk were 97.2, 149.9 and 207.8 kJ/mol, respectively. The inactivation kinetics of ALP during heat treatment was found to be dependent on the composition of the medium, and the time and temperature of the heat treatment. [source]

The lipophilicity indices of flavonoids estimated by reversed-phase liquid chromatography using different computation methods

JOURNAL OF SEPARATION SCIENCE, JSS, Issue 12 2009
Rodica Domnica Briciu
Abstract The chromatographic behavior of some flavonoids was established by RP-HPLC on RP-18 (LiChroCART, LiChrosphere RP-18e), RP-8 (Zorbax, Eclipse XDB-C8), CN (Säulentechnik, LiChrosphere CN100) columns. The mobile phases were mixtures of methanol-water in different volume proportions from 70 to 80% v/v for RP-18 and RP-8, while for the CN column the proportions were between 66 and 70% v/v. The lipophilicity was expressed through different lipophilicity descriptors such as mean of k (mk), mean of log k (mlog k), log kW, S, f0, and scores of k and log k corresponding to the first principal component. The experimental lipophilicity indices are directly correlated with the computed values, via computer software and internet module, at a high analytical level. Furthermore, the results obtained applying principal component analysis to k and/or log k values allow the prediction and explanation of the interaction involved in the retention mechanism which takes place between the compounds and the employed stationary phases during the development. [source]

Predicting immunosuppressant dosing in the early postoperative period with noninvasive indocyanine green elimination following orthotopic liver transplantation

In situ ellipsometric studies of formation kinetics of rare earth metal conversion coatings on magnesium alloy

PHYSICA STATUS SOLIDI (C) - CURRENT TOPICS IN SOLID STATE PHYSICS, Issue 5 2008
Lingjie Li
Abstract In situ spectroscopic ellipsometry was employed to investigate the initial regime of rare earth metal (REM) conversion coatings formation on AZ31 magnesium alloy. Three REM salts solutions, 0.05 mol·dm -3 Ce(NO3)3, La(NO)3 and Sm(NO)3 solutions, were used for REM conversion coatings preparation. By deconvoluting the ellipsometric data, the surface of the fresh well-polished AZ31 magnesium alloy was found to be covered with 15.80 nm thick native (hydr)oxide film; the refractive indices and the thickness of Ce, La and Sm conversion coatings were obtained. The formation kinetics of three REM coatings follows different exponential functions and the coatings exhibit different optical properties. La conversion coating has the largest n values and the lowest k values while Sm conversion coating is just opposite. Moreover, the pH variation of the bulk conversion solutions upon the coatings formation was recorded. It is confirmed that the reduction of protons leads to the interfacial pH increasing and further results in the precipitation of REM hydroxide gel, which is critical for the REM conversion coatings formation. (© 2008 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) [source]

The hydraulic architecture of Juniperus communis L. ssp. communis: shrubs and trees compared

PLANT CELL & ENVIRONMENT, Issue 11 2008
BARBARA BEIKIRCHER
ABSTRACT Juniperus communis ssp. communis can grow like a shrub or it can develop a tree-like habit. In this study, the hydraulic architecture of these contrasting growth forms was compared. We analysed the hydraulic efficiency (leaf-specific conductivity, kl; specific conductivity, ks; Huber value, HV) and the vulnerability to cavitation (the water potential corresponding to a 50% loss of conductivity, ,50), as well as anatomical parameters [mean tracheid diameter, d; mean hydraulic diameter, dh; cell wall reinforcement (t/b)h2] of shrub shoots, tree stems and tree branches. Shrub shoots were similar to tree branches (especially to lower branches) in growth form and conductivity (kl = 1.93 ± 0.11 m2 s,1 MPa,1 10,7, ks = 5.71 ± 0.19 m2 s,1 MPa,1 10,4), but were similar to tree stems in their vulnerability to cavitation (,50 = ,5.81 ± 0.08 MPa). Tree stems showed extraordinarily high kl and ks values, and HV increased from the base up. Stem xylem was more vulnerable to cavitation than branch xylem, where ,50 increased from lower (,50 = ,6.44 ± 0.19 MPa) to upper branches (,50 = ,5.98 ± 0.13 MPa). Conduit diameters were correlated with kl and ks. Data indicate that differences in hydraulic architecture correspond to changes in growth form. In some aspects, the xylem hydraulics of tree-like Juniperus communis differs from that of other coniferous tree species. [source]