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Individual Properties (individual + property)
Selected AbstractsIn vivo studies on the long-term persistence of volatiles in the breathFLAVOUR AND FRAGRANCE JOURNAL, Issue 6 2004M. Hodgson Abstract The long-term persistence of ,ve volatiles in the breath was studied to determine the effects of respiration and the physical properties of each of the volatiles. The long-term persistence of each of the volatiles in the breath was modelled successfully and used to show that the breath volatile concentration 1 min after consuming the solution was greater when panelists exhaled at a slower rate. The air,water partition coef,cient (Kaw) was in,uential in controlling the initial stages of persistence; compounds with a higher Kaw were found to decay at a much faster rate than compounds with a low Kaw. The decay rate during the later stages was constant for all the volatiles, which indicates that the rate-limiting factor during the later stages of persistence does not depend on the individual properties of the volatiles. Copyright © 2004 John Wiley & Sons, Ltd. [source] Rethinking what constitutes suspended sedimentHYDROLOGICAL PROCESSES, Issue 9 2001Ian G. Droppo Abstract Although cohesive suspended sediment is now known to be transported primarily as flocculated material, there is still a misconception of what constitutes suspended sediment. Flocs represent a complex matrix of microbial communities, organic particles (e.g. detritus, extracellular polymers and cellular debris), inorganic particles (e.g. clays and silts) and substantial interfloc spaces (pores), which allow for the retention or flow through of water. Flocculation results in significant alteration of the hydrodynamics of the constituent particles (by modifying their effective size, shape, density and porosity), thereby affecting the transport of sediment and associated contaminants. The composition and structure of a floc is in a continuous state of change as the medium in which it is transported provides the floc with further building materials, energy, nutrients and chemicals for biological growth, chemical reactions and morphological development. As such, a floc's physical (e.g. transport), chemical (e.g. contaminant adsorption) and biological (community development and contaminant biotransformation) behaviour are also in a continuous state of change, with concomitant effects on their aquatic environment as a whole. Although it is recognized that floc form will influence floc behaviour, there is still a basic lack of knowledge of the complex links between the structural components of a floc and how their individual properties and behaviours in combination with others will influence a floc's physical, chemical and biological behaviour. This paper provides a comprehensive conceptual model that links the many interrelated structural components of typical flocs and their interrelated behavioural aspects, in order to enhance our understanding of what constitutes suspended sediment. Copyright © 2001 John Wiley & Sons, Ltd. [source] Theoretical study in [C2H4,Tl]+ and [C2H2,Tl]+ complexesINTERNATIONAL JOURNAL OF QUANTUM CHEMISTRY, Issue 1 2007Fernando Mendizabal Abstract We studied the attraction between [C2Hn] and Tl(I) in the hypothetical [C2Hn,Tl]+ complexes (n = 2,4) using ab initio methodology. We found that the changes around the equilibrium distance C,Tl and in the interaction energies are sensitive to the electron correlation potential. We evaluated these effects using several levels of theory, including Hartree,Fock (HF), second-order Møller,Plesset (MP2), MP4, coupled cluster singles and doubles CCSD(T), and local density approximation augmented by nonlocal corrections for exchange and correlation due to Becke and Perdew (LDA/BP). The obtained interaction energies differences at the equilibrium distance Re (C,Tl) range from 33 and 46 kJ/mol at the different levels used. These results indicate that the interaction between olefinic systems and Tl(I) are a real minimum on the potential energy surfaces (PES). We can predict that these new complexes are viable for synthesizing. At long distances, the behavior of the [C2Hn],Tl+ interaction may be related mainly to charge-induced dipole and dispersion terms, both involving the individual properties of the olefinic ,-system and thallium ion. However, the charge-induced dipole term (R,4) is found as the principal contribution in the stability at long and short distances. © 2006 Wiley Periodicals, Inc. Int J Quantum Chem, 2007 [source] Spatial patterns of kangaroo density across the South Australian pastoral zone over 26 years: aggregation during drought and suggestions of long distance movementJOURNAL OF APPLIED ECOLOGY, Issue 5 2007ANTHONY R. POPLE Summary 1Wildlife surveys usually focus on estimating population size, and management actions such as commercial harvesting, culling and poison baiting are referenced commonly to population size alone, without taking into account the way in which those animals are distributed. This paper outlines how point-based aerial survey data can be converted to continuous density surfaces using spatial analysis techniques. Using this approach, we describe and explore the spatial patterns of density of two species of kangaroos in an area exceeding 200 000 km2 in South Australia over a 26-year period. 2Densities of red and western grey kangaroos were estimated in 2 km2 segments along aerial survey transect lines, yielding point density estimates. Universal kriging provided an unbiased interpolation of these data using the spatial autocorrelation structure described by the semi-variogram. The Getis statistic identified clusters of high and low kangaroo density. 3Considerable year-to-year variation in the spatial patterns of kangaroo density was observed. In many cases, annual rates of increase over large areas were too high to be explained by vital rates alone, implying immigration from surrounding areas. These large shifts in distribution were occasionally to areas that had received better rainfall than the surrounding areas. For both species, there was no obvious local spatial autocorrelation pattern or clustering of kangaroo density beyond that described by average density and the present set of management regions, suggesting the latter are appropriate divisions for harvest management. 4Data for both species fitted the power law relationship extremely well. During dry times, red kangaroos, but not western grey kangaroos, were more aggregated, supporting past ground observations at a fine spatial scale. 5Synthesis and applications. Kriged density surfaces enable estimation of kangaroo density on individual properties, which are the management units at which harvest quotas or culling approvals are allocated. These estimates will be marked improvements over systematic sampling estimates when sampling intensity is low. Predictions of shifts in kangaroo distribution using rainfall or satellite imagery will allow more accurate allocation of harvest quotas. Similarly, predictions of more even kangaroo dispersion following high rainfall will allow managers to anticipate downturns in harvest rate. [source] Empirical Modeling of Butyl Acrylate/Vinyl Acetate/Acrylic Acid Emulsion-Based Pressure-Sensitive AdhesivesMACROMOLECULAR MATERIALS & ENGINEERING, Issue 5 2004Renata Jovanovic Abstract Summary: Butyl acrylate/vinyl acetate/acrylic acid (BA/VAc/AA) emulsion latexes were produced in a semi-batch mode. The objective was to generate polymers with properties favoring their application as pressure-sensitive adhesives. The influence of the individual monomer concentrations on final properties such as glass transition temperature (Tg), peel strength, shear strength and tack was investigated. To obtain the maximum amount of information in a reasonable number of runs, a constrained three-component mixture design was used to define the experimental conditions. Latexes were coated onto a polyethylene terephthalate carrier and dried. Different empirical models (e.g. linear, quadratic and cubic mixture models) governing the individual properties (i.e. Tg, peel adhesion, shear resistance and tack) were developed and evaluated. In the given experimental region, no single model was found to fit all of the responses (i.e. the final properties). However, in all models the most significant factor affecting the final properties was the AA concentration, followed by the VAc concentration. Shear strength contour lines over the investigated region. [source] The properties of the heterogeneous Shakhbazyan groups of galaxies in the SDSSMONTHLY NOTICES OF THE ROYAL ASTRONOMICAL SOCIETY, Issue 2 2009D. Capozzi ABSTRACT We present a systematic study of the subsample of Shakhbazyan (SHK) groups covered by the Sloan Digital Sky Survey Data Release 5 (SDSS DR5). SHK groups probe an environment with characteristics which are intermediate between those of loose and very compact groups. Surprisingly, we found that several groups identifying algorithms, e.g. Berlind et al. and Tago et al., miss this type of structures. Using the SDSS DR5 spectroscopic data and the photometric redshifts derived in D'Abrusco et al., we identified possible group members in photometric redshift space and derived, for each group, several individual properties (richness, size, mean photometric redshift, fraction of red galaxies, etc.). We also combined pointed and stacked Rosat All Sky Survey (RASS) data to investigate the X-ray luminosities of these systems. Our study confirms that the majority of groups are physical entities with richness in the range 3,13 galaxies, and properties ranging between those of loose and compact groups. We confirm that SHK groups are richer in early-type galaxies than the surrounding environment and the field, as expected from the morphology,density relation and from the selection of groups of red galaxies. Furthermore, our work supports the existence of two subclasses of structures, the first one being formed by compact and isolated groups and the second formed by extended structures. We suggest that while the first class of objects dwells in less dense regions like the outer parts of clusters or the field, possibly sharing the properties of Hickson Compact Groups, the more extended structures represent a mixture of [core + halo] configurations and cores of rich clusters. X-ray luminosities for SHK groups are generally consistent with these results and with the expectations for the LX,,v relation, but also suggest the velocity dispersions reported in literature are underestimated for some of the richest systems. [source] | ||||||||||