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Initial Temperature (initial + temperature)
Selected AbstractsTemperature sensitivity and substrate quality in soil organic matter decomposition: results of an incubation study with three substratesGLOBAL CHANGE BIOLOGY, Issue 6 2010J. Å. MARTIN WETTERSTEDT Abstract Kinetic theory suggests that the temperature sensitivity of decomposition of soil organic matter should increase with increasing recalcitrance. This ,temperature,quality hypothesis' was tested in a laboratory experiment. Microcosms with wheat straw, spruce needle litter and mor humus were initially placed at 5, 15 and 25 °C until the same cumulative amount of CO2 had been respired. Thereafter, microcosms from each single temperature were moved to a final set of incubation temperatures of 5, 15 and 25 °C. Straw decomposed faster than needle litter at 25 and 15 °C, but slower than needle litter at 5 °C, and showed a higher temperature sensitivity (expressed as Q10) than needle litter at low temperatures. When moved to the same temperature, needle litter initially incubated at 5 and 15 °C had significantly higher respiration rates in the final incubation than litters initially placed at 25 °C. Mor humus placed at equal temperatures during the initial and final incubations had higher cumulative respiration during the final incubation than humus experiencing a shift in temperature, both up- and downwards. These results indicate that other factors than substrate quality are needed to fully explain the temperature dependence. In agreement with the hypothesis, Q10 was always higher for the temperature step between 5 and 15 °C than between 15 and 25 °C. Also in agreement with the temperature,quality hypothesis, Q10 significantly increased with increasing degree of decomposition in five out of the six constant temperature treatments with needle litter and mor humus. Q10s for substrates moved between temperatures tended to be higher than for substrates remaining at the initial temperature and an upward shift in temperature increased Q10 more than a downward shift. This study largely supports the temperature,quality hypothesis. However, other factors like acclimation and synthesis of recalcitrant compounds can modify the temperature response. [source] Natural convection of a water-fine particle suspension in a rectangular cell heated and cooled from opposing vertical walls: The effect of distribution of particle sizeHEAT TRANSFER - ASIAN RESEARCH (FORMERLY HEAT TRANSFER-JAPANESE RESEARCH), Issue 8 2001Masashi Okada Abstract A water-fine particle suspension with a uniform initial temperature and concentration in a rectangular cell was heated from a vertical wall and cooled from the opposing vertical wall. The dispersed particles had a distribution in size. In this natural convection, many layers separated by almost-horizontal sharp interfaces were observed. In the beginning many layers appear, and each interface of the layers falls gradually with a constant velocity, and finally all layers vanish. To clarify this phenomenon, concentrations and mean diameters of the particles in each layer and temperature distributions were measured. Moreover, natural convection of the other suspension with particles which had a narrow size distribution was also investigated. © 2001 Scripta Technica, Heat Trans Asian Res, 30(8): 636,647, 2001 [source] Two-dimensional unsteady heat conduction analysis with heat generation by triple-reciprocity BEMINTERNATIONAL JOURNAL FOR NUMERICAL METHODS IN ENGINEERING, Issue 2 2001Yoshihiro Ochiai Abstract If the initial temperature is assumed to be constant, a domain integral is not needed to solve unsteady heat conduction problems without heat generation using the boundary element method (BEM).However, with heat generation or a non-uniform initial temperature distribution, the domain integral is necessary. This paper demonstrates that two-dimensional problems of unsteady heat conduction with heat generation and a non-uniform initial temperature distribution can be solved approximately without the domain integral by the triple-reciprocity boundary element method. In this method, heat generation and the initial temperature distribution are interpolated using the boundary integral equation. Copyright © 2001 John Wiley & Sons, Ltd. [source] A dimensionless factor characterizing the ignition of pulverized coal flow: Analytical model, experimental verification, and applicationINTERNATIONAL JOURNAL OF ENERGY RESEARCH, Issue 3 2009Qulan Zhou Abstract An analytical model describing the ignition process of pulverized coal is proposed, and a dimensionless condition number (Ncom) is obtained to describe the comprehensive effect of factors governing the ignition of pulverized coal flow, such as the initial temperature of flow, the sectional heat load of the furnace, and the flux of primary air, secondary air and recirculation flue gas. An optimized concentration of pulverized coal flow is derived explicitly, upon which the earliest ignition of pulverized coal flow is possible. The model is verified in a hot furnace experiment, where it is shown that the derived criterion (Ncom) can be used for different kinds of coal and different types of burner. For given coal and sectional heat load of furnace, when the value of Ncom increases, the condition of ignition is improved and both unburned carbon and NOx emission are reduced. The employment of Ncom in the optimization of burner operating conditions is demonstrated through two applications. In practice, the criterion Ncom can be used to guide the selection of the concentration and type of pulverized coal, as well as the choice of burner and desired aerodynamic field, so as to achieve an optimized performance. Copyright © 2008 John Wiley & Sons, Ltd. [source] The extraction of power from a hot streamINTERNATIONAL JOURNAL OF ENERGY RESEARCH, Issue 6 2001A. Bejan Abstract The solution to the problem of maximizing the extraction of exergy from a stream of hot gas showed that the hot stream must be cooled in a counterflow heat exchanger with optimal imbalance of capacity rates, i.e. with an optimal capacity rate on the cold side. This paper outlines the first few steps toward making this solution practical, by combining the optimized counterflow with conventional components for compressing and expanding the cold stream. In the first part of the paper, the cold stream is compressed in an isothermal compressor, expanded in an adiabatic turbine, and discharged into the ambient. In the second part, the cold stream is compressed in an adiabatic compressor. Both designs are optimized with respect to two degrees of freedom, the capacity-rate imbalance of the counterflow, and the pressure ratio maintained by the compressor. The effect of other constraints is documented, e.g. heat transfer area size, hot gas initial temperature and compressor and turbine efficiencies. This study shows the tradeoff between simplicity and increased performance, and outlines the path for further conceptual work on the extraction of exergy from a hot stream that is being cooled gradually. Copyright © 2001 John Wiley & Sons, Ltd. [source] The performance of a methyl cellulose-treated coating during the frying of a poultry productINTERNATIONAL JOURNAL OF FOOD SCIENCE & TECHNOLOGY, Issue 8 2005Mohamad Y. Maskat Summary The performance of coatings treated with a range of methyl cellulose (MC) concentrations during the frying of coated chicken breasts was investigated. Chicken breasts were immersed in 0, 1 and 2.5% MC solution and then coated with a commercial coating mix. The coated chicken breasts were then fried at an initial temperature of 190 °C. Parameters measured included coating pickup, coating loss, cooked yield and frying loss. Results showed a significant increase in coating pickup with the use of 1 and 2.5% MC, which may have been due to the higher viscosity and binding ability of the MC layer. The use of 2.5% MC produced lower coating loss and frying loss and also a higher cooked yield. [source] LETHALITY CONTRIBUTION FROM THE TUBULAR HEAT EXCHANGER DURING HIGH-TEMPERATURE SHORT-TIME PROCESSING OF A MODEL LIQUID FOODJOURNAL OF FOOD PROCESS ENGINEERING, Issue 4 2004G.B. AWUAH ABSTRACT Experiments were conducted using Bacillus stearothermophilus spores in 0.5% w/w carboxymethylcellulose suspension to evaluate come-up contributions from the tubular heat exchanger. A lab-scale UHT/HTST simulator that allowed samples to be collected at the exit of the heat exchanger and holding tube was used with operating temperatures up to 270F. The bulk mean residence time in the heat exchanger ranged from 30 to 89 sec, while that in the holding tube ranged from 4 to 14 sec. It was observed that between 40% and 51% of the cumulative lethality () at the exit of the holding tube, was contributed by come-up in the tubular heat exchanger. This come-up contribution was determined on the basis of having anof 8.5 min in the holding tube alone. It was evident that come-up lethality will depend on product initial temperature, residence time and temperature history in the heat exchanger, with higher temperatures obviously contributing more lethality. Therefore, the entire aseptic system becomes even more complex since several critical parameters need to be monitored, controlled and documented. Experimental data compared favorably with computer-simulated data using the AseptiCALÔ software, with the software package giving more conservative results. Ultimately, come-up credit (CUC) should be tested on a pilot scale or industrial setup by way of reduced residence time (i.e. increased fluid flow rate), reduced holding tube length or temperature in order to determine if CUC can be applied towards the lethality required for the product. Monitoring and control devices become critical to ensure consistency and reproducibility in product residence time and time,temperature history, in the tubular heat exchanger. [source] RETORTABILITY of THIN-WALLED ALUMINUM CONTAINERS PRESSURIZED WITH ADDED LIQUID NITROGEN (LN2)JOURNAL OF FOOD PROCESS ENGINEERING, Issue 2 2003G.B. AWUAH ABSTRACT Studies were conducted to investigate the effect of initial container pressure on heat penetration parameters using flexible aluminum containers. A pilot scale liquid nitrogen dispenser, regulated to discharge a fine stream of liquid nitrogen (LN2), provided approximately 10 to 15 psi pressure within the container prior to end-over-end processing in a computer-controlled retort using water immersion with 32 psi over pressure. Thermal process parameters including the heating rate index (fh), lag factor (jh), the cumulative lethality (Fo), cook-value (Co) and the overall heat transfer coefficient (Uo) were examined in relation to retort temperature (241,261F), rpm (0,15 rpm) and product initial temperature (54,121F) using 5% w/w bentonite suspension with or without liquid nitrogen. Generally, containers with added liquid nitrogen had no impact on evaluated data compared to their counterparts without LN2 under similar experimental conditions. Estimated overall heat transfer coefficient (Uo) compared favorably with published data, while the Co/Fo ratio decreased with increasing temperatures as expected. Product cold spot location migrated in either upward or downward direction depending on the mode of heat transfer. Although added LN2 generally had no limiting effect on both heat transfer and heat penetration data, processing aluminum containers with high initial pressure at high retort temperatures could create excessively high internal pressure that could compromise container seam integrity. [source] EFFECT OF RAPID COOLING ON THE GROWTH AND PENETRATION OF SALMONELLA ENTERITIDIS INTO EGG CONTENTSJOURNAL OF FOOD SAFETY, Issue 4 2002HAIQIANG CHEN ABSTRACT Shell eggs were inoculated internally with approximately 10 cells of Salmonella enterica serovar enteritidis (S. enteritidis) and subjected to three different cooling treatments. Eggs were cooled from an initial temperature of 27C to approximately 7.2C. After cooling, eggs were stored at approximately 7.2C for 36 days, or stored at 5.7,9.5C for 30 days plus 6 days at 37C to simulate temperature abuse. Rapid cooling and subsequent storage of eggs at approximately 7.2C inhibited the growth of S. enteritidis in eggs. Slow cooling, and/or temperature abuse promoted growth of S. enteritidis in eggs. The penetration study indicated that rapid cooling and subsequent storage at 7.2C for 30 days did not affect the penetration of S. enteritidis into egg contents. The S. enteritidis isolated from the eggshell with shell membranes was significantly higher (P < 0.05) than from the internal egg contents, indicating that most of the S. enteritidis cells were trapped within the shell pores and/or shell membranes. [source] Modeling Cooking Time to Inactivate Salmonella in Chicken Leg Quarters Cooked in an Air,Steam Impingement OvenJOURNAL OF FOOD SCIENCE, Issue 5 2006Tareq M. Osaili ABSTRACT:, Inadequate cooking of poultry products may lead to human foodborne infections. The use of mathematical models that describe heat transfer during cooking of chicken leg quarters may help in developing safer food products and minimizing time for cooking. The objective of this study was to develop regression models that predict cooking time required to reach internal temperatures of 71.1, 73.9, 76.7, and 82.2 °C in chicken leg quarters. Samples that had different weights, thicknesses, and initial internal temperatures were cooked in an air,steam impingement oven at temperature of 232.2 °C, humidity of 60%, and air velocity of 1.4 m/min. A thermocouple probe (type K) connected with a data acquisition system was inserted into the coldest point of each chicken leg quarter. Samples were cooked until they reached an internal temperature higher than 82.2 °C. The collected data of each sample in the data acquisition system were used to develop regression models that depend on sample weight, thickness, and initial temperature in predicting cooking times. Sample weight, thickness, and initial internal temperature had significant effects on the cooking time. The results of these models would be helpful for ready-to-eat poultry processors to meet lethality performance standards, and ensuring the safety and quality of skin on, bone in chicken leg quarters cooked via air,steam impingement ovens. [source] Improvement of port wine stain laser therapy by skin preheating prior to cryogen spray cooling: A numerical simulationLASERS IN SURGERY AND MEDICINE, Issue 2 2006Wangcun Jia PhD Abstract Background and Objectives Although cryogen spray cooling (CSC) in conjunction with laser therapy has become the clinical standard for treatment of port wine stain (PWS) birthmarks, the current approach does not produce complete lesion blanching in the vast majority of patients. The objectives of this study are to: (1) experimentally determine the dynamic CSC heat flux when a skin phantom is preheated, and (2) numerically study the feasibility of using skin preheating prior to CSC to improve PWS laser therapeutic outcome. Study Design/Materials and Methods A fast-response thin-foil thermocouple was used to measure the surface temperature and thus heat flux of an epoxy skin phantom during CSC. Using the heat flux as a boundary condition, PWS laser therapy was simulated with finite element heat diffusion and Monte Carlo light distribution models. Epidermal and PWS blood vessel thermal damage were calculated with an Arrhenius-type kinetic model. Results Experimental results show that the skin phantom surface can be cooled to a similar minimum temperature regardless of the initial temperature. Numerical simulation indicates that upon laser irradiation, the epidermal temperature increase is virtually unaffected by preheating, while higher PWS blood vessel temperatures can be achieved. Based on the damage criterion we assumed, the depth and maximum diameter of PWS vessels that can be destroyed irreversibly with skin preheating are greater than those without. Conclusions Skin preheating prior to CSC can maintain epidermal cooling while increasing PWS blood vessel temperature before laser irradiation. Numerical models have been developed to show that patients may benefit from the skin preheating approach, depending on PWS vessel diameter and depth. Lasers Surg. Med. 38:155,162, 2006. © 2006 Wiley-Liss, Inc. [source] A heuristic approach of calculating spray water flux needed to avert fire-induced runaway reactions,,PROCESS SAFETY PROGRESS, Issue 3 2006BChE (Honors), Dilip K. Das BSc (Honors), MSChE In general all reactions have some heat effects. When the ability of the equipment to remove the heat is exceeded by the heat generated by a reaction, a hazardous situation called a runaway reaction may take place. Sometimes the exothermicity of runaway reactions is so high that the size of an emergency vent becomes impractical to install. A water spray system can sometimes be used to avert a fire-induced runaway reaction. Because the water spray system has a finite activation time, insulation helps to prolong the time required to reach the decomposition temperature. This article concludes that the required water flux to avert the fire-induced runaway reaction may be conservatively estimated by adding the water flux necessary to maintain an unbroken water film on the external surface of the equipment and the water flux necessary to absorb the fire heat after allowing for the splash loss and the in-flight loss. When adequate spray water is used, the metal temperature of the insulation jacket cannot theoretically exceed the boiling point of water thereby ensuring the avoidance of fire-induced runaway reactions whose adjusted onset decomposition temperature exceeds 100 ° C. Fire-induced runaway reactions with lower onset temperature can also be avoided depending on the initial temperature of the contents, mass of the contents and equipment, insulation thickness, and fire duration, for example, but a detailed calculation including dynamic simulation is necessary and the burden of proof lies with the designer. The reliability of the spray water system must be maintained high to include its credit as an environmental factor defined according to NFPA 30 to avoid the fire-induced runaway reaction as a scenario. Although API RP 521 does not allow any credit for sprinkler water, it allows credit, unlike NFPA 30, for insulation thickness and thus a runaway reaction can be avoided by using insulation alone according to API RP 521. © 2006 American Institute of Chemical Engineers Process Saf Prog, 2006 [source] Further uses of the heat of oxidation in chemical hazard assessmentPROCESS SAFETY PROGRESS, Issue 1 2003Laurence G. Britton Flammability: The "net heat of oxidation" technique described in an earlier publication is extended to predicting the lower flammable limits, lower limit flame temperatures, and limiting oxygen concentrations of chlorinated organic fuels having H:Cl ratios greater than unity. A new Rule is derived for predicting the effect of initial temperature on the lower flammable limits and limiting oxygen concentrations of organic fuels. It is suggested that this Rule be used in preference to the modified "Burgess-Wheeler" Rule. The effect of initial pressure is discussed. Instability: Net heats of oxidation (kcal/mol oxygen) for a series of disparate fuel groups are compared with ",HD," the maximum heat of decomposition (cal/g) calculated using CHETAH methodology. Given the reasonable assumption that CHETAH's "maximum heat of decomposition" cannot exceed the net heat of combustion ",HC," examination is made as to whether the ratio of these parameters (each expressed in units of kcal/mol), coined the "Reaction Heat Ratio" (RH), provides a useful new indicator for instability assessment. Of these parameters, the net heat of oxidation (,HC/S) is the best indicator to help assign NFPA Instability Ratings. However, ,HC/S cannot generally be used to assign ratings for organo-peroxides. Also, its performance as an indicator for hazardous polymerization depends on the ,HC/S difference between the reacting monomer and the polymer product, so it should become increasingly unreliable as the monomer ,HC/S approaches -100 kcal/mol oxygen. The ranking method tacitly assumes organic polymers to have a constant heat of oxidation of about -100 kcal/mol oxygen. Errors in this assumption must invalidate the ranking approach where ,HC/S differences are small. Finally, separate "cut-offs" must be used at each NFPA Instability Rating for organo-nitrates versus other organics containing combinations of CHON atoms. Additional materials need to be examined to extend this preliminary analysis. The net heat of oxidation would be a useful additional output parameter of the CHETAH program, if only for its application in flammability assessment. No conclusions are drawn regarding the usefulness of net heat of oxidation or RH in conducting CHETAH hazard assessments, since this procedure requires consideration of several variables. However, the analysis may be helpful to the ASTM E 27.07 subcommittee responsible for developing the program. For example, the -,HD , 700 cal/g cut-off used to assign a "high" CHETAH hazard rating typically corresponds to organic materials rated NFPA 1, the second to lowest hazard rating. [source] Experimental 2D-Var assimilation of ARM cloud and precipitation observationsTHE QUARTERLY JOURNAL OF THE ROYAL METEOROLOGICAL SOCIETY, Issue 617 2006Philippe Lopez Abstract A two-dimensional variational method (2D-Var) based on 12-hour integrations of the single-column version of the European Centre forMedium-RangeWeather Forecasts model for adjusting initial temperature and specifichumidity profiles is used to identify the issues related to the assimilation of either high temporal frequency or time-accumulated observations that are directly affected by clouds and precipitation. 2D-Var experiments have been run using cloud-radar reflectivity profiles and microwave-radiometer brightness temperatures in nonprecipitating cloudy cases, and accumulated rain-gauge measurements and total column water-vapour retrievals from the Global Positioning System in precipitating situations. All observations have been obtained from the Atmospheric Radiation Measurement Program. In cloudy situations, the use of time sequences of cloud-radar reflectivities at half-hourly time steps is problematic because the variational assimilation minimization becomes overconstrained. Instead, it is better to assimilate time-averaged profiles of cloud radar reflectivities when background reflectivities are generally greater than the observations. When background reflectivities are lower than observed, the falling of the extra precipitation produced by 2D-Var hampers the convergence of the cost-function minimization. The assimilation of brightness temperatures seems more straightforward even at a half-hourly frequency. As regards the application of 2D-Var to accumulated rain-gauge measurements, the minimization is biased towards observations that are available at the beginning of the 12-hour assimilation window, due to the reduction of precipitation sensitivities in time. However, using three-dimensional adjoint sensitivity computations, it is shown that this problem should not be as critical in four-dimensional variational assimilation. It is also demonstrated that the combination of precipitation data with information about the moisture field produces more realistic 2D-Var increments than with rain gauges solely. Finally, the implications for the future assimilation of cloud and precipitation affected observations in direct 4D-Var are presented. Copyright © Royal Meteorological Society, 2006. [source] Frontal Polymerization Synthesis of Starch-Grafted Hydrogels: Effect of Temperature and Tube Size on Propagating Front and Properties of HydrogelsCHEMISTRY - A EUROPEAN JOURNAL, Issue 12 2006Qing-Zhi Yan Prof. Dr. Abstract The frontal polymerization process was used to produce superabsorbent hydrogels based on acrylic acid monomers grafted onto starch. Using a simple test tube which was nonadiabatic and permitted contact with air, the effects of initial temperature and tube size on the propagating front of grafting copolymerization and the properties of hydrogels were explored. The unrestricted access of the reaction mixture to oxygen delayed the formation of self-propagating polymerization front. The ignition time was markedly lengthened with the increasing of tube size attributed to the formation of large amounts of peroxy radicals. The front velocity dependence on initial temperature could be fit to an Arrhenius function with the average apparent activation energy of 24 kJ,mol,1, and on tube size to a function of higher order. The increase of the initial temperature increased the front temperature, which lead to more soluble oligomers and higher degree of crosslinking. The interplay of two opposite effects of oligomer and crosslinking determined the sol and gel content. An increase in tube size had two effects on the propagating front. One was to reduce heat loss. The other effect was to increase the number of escaping gas bubbles. The combined action of the two effects resulted in a maximum value of front temperature, an increase in sol content and a reduction in gel content with tube size. The highest swelling capacity of hydrogels was obtained when the initial temperature or tube size favored a formation of porous microstructure of hydrogels. [source] | |||||||||||||