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Homogenization Temperatures (homogenization + temperature)

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Earth and Environmental Science	100%

Selected Abstracts

HYDROTHERMALLY FLUORITIZED ORDOVICIAN CARBONATES AS RESERVOIR ROCKS IN THE TAZHONG AREA, CENTRALTARIM BASIN, NW CHINA

JOURNAL OF PETROLEUM GEOLOGY, Issue 1 2006
Zhijun Jin
Reservoir rocks at the Tazhong 45 oil pool, central Tarim Basin, consist of fluoritized carbonate strata of Middle - Late Ordovician age. Petrological observations indicate that the fluorite replaces calcite. Several other hydrothermal minerals including pyrite, quartz, sphalerite and chlorite accompany the fluorite. Two generations of fluid inclusions are present in the fluorite. Homogenization temperatures (Th) for primary inclusions are mostly between 260°C and 310°C and represent the temperature of the hydrothermal fluid responsible for fluorite precipitation. Th for secondary inclusions range from 100°C to 130°C, and represent the hydrocarbon charging temperature as shown by the presence of hydrocarbons trapped in some secondary inclusions. The mineral assemblage and the homogenization temperatures of the primary fluid inclusions indicate that the precipitation of fluorite is related to hydrothermal activity in the Tazhong area. Strontium isotope analyses imply that the hydrothermal fluids responsible for fluorite precipitation are related to late-stage magmatic activity, and felsic magmas were generated by mixing of mafic magma and crustal materials during the Permian. Theoretical calculations show that the molecular volume of a carbonate rock decreases by 33.5% when calcite is replaced by fluorite, and the volume shrinkage can greatly enhance reservoir porosity by the formation of abundant intercrystalline pores. Fluoritization has thus greatly enhanced the reservoir quality of Ordovician carbonates in the Tazhong 45 area, so that the fluorite and limestone host rocks have become an efficient hydrocarbon reservoir. According to the modelled burial and thermal history of the Tazhong 45 well, and the homogenization temperatures of secondary fluid inclusions in the fluorite, hydrocarbon charging at the Tazhong 45 reservoir took place in the Tertiary. [source]

Ag-rich Tetrahedrite in the El Zancudo Deposit, Colombia: Occurrence, Chemical Compositions and Genetic Temperatures

RESOURCE GEOLOGY, Issue 3 2010
Alba Nury Gallego Hernández
Abstract Chemical compositions of tetrahedrite,Ag-rich tetrahedrite,freibergite solid solutions (Ag-rich tetrahedritess) and homogenization temperatures of fluid inclusions in quartz and carbonates of seventeen samples from nine veins in the El Zancudo deposit, Antioquia, Colombia, were investigated to reveal the origin of silver in Ag-rich tetrahedritess, to derive their crystallization temperatures and to examine the relationship between chemical compositions of Ag-rich tetrahedritess and their crystallization temperatures. The ores consist of arsenopyrite, pyrite, sphalerite, Ag-rich tetrahedritess, galena, boulangerite, andorite, owyheeite, diaphorite, jamesonite, miargyrite, bournonite, chalcopyrite, and electrum. Ag-rich tetrahedritess forms about 10 volume % of the total ores and is one of the most common and widely distributed sulfosalts in this deposit. Ag-rich tetrahedritess is rich in Ag (1.13 to 31.02 wt%) and Sb (22.93 to 29.82 wt%), and poor in As (0.06 to 2.43 wt%), consistent with the reported incompatibilities of Ag and As in Ag-rich tetrahedritess. The Zn/(Zn + Fe)-, Ag/(Ag + Cu)- and Sb/(Sb + As + Bi)-atomic ratios exhibit some variations among the veins. Ag-rich tetrahedritess with higher Ag/(Ag + Cu) ratios coexist with diaphorite, whereas those with lower ratios are not associated with this sulfosalt. Ag-rich tetrahedritess in the assemblages of Ag-rich tetrahedritess+ sphalerite and of Ag-rich tetrahedritess+ bournonite + galena shows no Zn , Fe and Cu , Ag variations between core and rim, respectively, negating the possibility of solid state reaction during cooling. Ag-rich tetrahedritess is thus regarded as primary phase. Homogenization temperatures of primary fluid inclusions in quartz and carbonates co-existing with Ag-rich tetrahedritess define the mineralization temperatures of 134 to 263°C. Independent crystallization temperatures of Ag-rich tetrahedrite estimated based on Zn/(Zn + Fe) and Ag/(Ag + Cu) ratios of the Ag-rich tetrahedritess associated with silver minerals such as miargyrite, andorite and diaphorite using Sack's thermochemical database lie in a range between 170 and ,250°C. Both results are thus in good agreement. [source]

Infiltration of basinal fluids into high-grade basement, South Norway: sources and behaviour of waters and brines

GEOFLUIDS (ELECTRONIC), Issue 1 2003
S. A. Gleeson
Abstract Quartz veins hosted by the high-grade crystalline rocks of the Modum complex, Southern Norway, formed when basinal fluids from an overlying Palaeozoic foreland basin infiltrated the basement at temperatures of c. 220°C (higher in the southernmost part of the area). This infiltration resulted in the formation of veins containing both two-phase and halite-bearing aqueous fluid inclusions, sometimes with bitumen and hydrocarbon inclusions. Microthermometric results demonstrate a very wide range of salinities of aqueous fluids preserved in these veins, ranging from c. 0 to 40 wt% NaCl equivalent. The range in homogenization temperatures is also very large (99,322°C for the entire dataset) and shows little or no correlation with salinity. A combination of aqueous fluid microthermometry, halogen geochemistry and oxygen isotope studies suggest that fluids from a range of separate aquifers were responsible for the quartz growth, but all have chemistries comparable to sedimentary formation waters. The bulk of the quartz grew from relatively low ,18O fluids derived directly from the basin or equilibrated in the upper part of the basement (T < 200°C). Nevertheless, some fluids acquired higher salinities due to deep wall-rock hydration reactions leading to salt saturation at high temperatures (>300°C). The range in fluid inclusion homogenization temperatures and densities, combined with estimates of the ambient temperature of the basement rocks suggests that at different times veins acted as conduits for influx of both hotter and colder fluids, as well as experiencing fluctuations in fluid pressure. This is interpreted to reflect episodic flow linked to seismicity, with hotter dry basement rocks acting as a sink for cooler fluids from the overlying basin, while detailed flow paths reflected local effects of opening and closing of individual fractures as well as reaction with wall rocks. Thermal considerations suggest that the duration of some flow events was very short, possibly in the order of days. As a result of the complex pattern of fracturing and flow in the Modum basement, it was possible for shallow fluids to penetrate basement rocks at significantly higher temperatures, and this demonstrates the potential for hydrolytic weakening of continental crust by sedimentary fluids. [source]

DEVONIAN CARBONATES OF THE NIGEL PEAK AREA, ROCKY MOUNTAINS, CANADA: A FOSSIL PETROLEUM SYSTEM?

JOURNAL OF PETROLEUM GEOLOGY, Issue 3 2008
J. Köster
In this study we report on Devonian (Frasnian , Famennian) limestones and dolostones exposed near Nigel Peak in the Main Ranges of the Canadian Rocky Mountains. These carbonates are a proximal facies of the Southesk-Cairn Carbonate Complex. The investigated strata are stratigraphically equivalent to the oil- and gas bearing Nisku Formation in the subsurface of the Western Canada Sedimentary Basin, about 300 km to the east. The rocks were investigated by polarisation and cathodoluminescence microscopy, total organic carbon analysis, Rock-Eval pyrolysis, solid bitumen reflectance measurements, gas chromatography and fluid inclusion analysis. Thin section analyses showed that silt-grade quartz and saddle dolomite increase upward from the base of the stratigraphic section, and that porosities are generally low. This is due to reduction of pore space due to early cementation and extensive dolomitization. Cathodoluminescence identified up to four generations of calcite cements. TOC values ranged from 0.2 to 2.4 %. Rock-Eval pyrolysis of carbonate samples resulted in measurable S1 peaks but not S2 peaks, indicating that there was no residual petroleum generation potential. Organic petrographic analyses identified dispersed kerogen and migrabitumen, and calculated vitrinite reflectance values were around 4 % on average which implies peak temperatures of 234,262 °C (due to deep burial) or 309,352 °C (due to short term hydrothermal heating). Fluid inclusion data indicates at least one pulse of hot fluids with elevated homogenization temperatures of > 300 °C, and this may explain the high thermal maturity of the studied rocks. [source]

HYDROTHERMALLY FLUORITIZED ORDOVICIAN CARBONATES AS RESERVOIR ROCKS IN THE TAZHONG AREA, CENTRALTARIM BASIN, NW CHINA

Ag-rich Tetrahedrite in the El Zancudo Deposit, Colombia: Occurrence, Chemical Compositions and Genetic Temperatures

Ag-Cu-Pb-Bi-S Minerals Newly Discovered from the Ohori Base Metal Deposit, Yamagata Prefecture, NE Japan: Implications for Bi-metallogenesis in the Green-Tuff Region

RESOURCE GEOLOGY, Issue 1 2010
Yu Yokoro
Abstract The Ohori deposit, one of the base metal deposits in the Green-Tuff region, NE Japan, is composed of two types of mineralization; a skarn-type (Kaninomata orebody) made by the replacement of the Miocene calcareous layer, and a vein-type (Nakanomata orebody). While the ore mineral assemblage of the deposit (chalcopyrite, pyrite, sphalerite and galena) has been known for being rather simple, some Pb-Bi-S minerals have been discovered for the first time in the present study. The minerals mainly occur in the chalcopyrite-rich ores of both orebodies. They essentially belong to the Pb-Bi-S system and contain Cu and Ag in minor amounts, which correspond to the lillianite,gustavite solid solution series (phases Z and X), cosalite, neyite, felbertalite, krupkaite and Bi-bearing galena. The chalcopyrite-rich (Bi-bearing) ores from both orebodies are richer in chalcopyrite, pyrite and chlorite, and have higher homogenization temperatures (>300°C) of fluid inclusions, and higher FeS contents in sphalerite compared to the Bi-free ores. In the Green-Tuff region, Bi-minerals have been reported from many base metal deposits. Most of these Bi-bearing ore deposits are referred to as xenothermal-type deposits, and are characterized by the following common features; composite mineralization of high- and low-temperatures in the shallower environments, and close relationships with the Tertiary granitic rocks. The whole mineralization at the Ohori deposit also has a similar xenothermal character because of the coexistence of high-temperature chalcopyrite-rich ores with Pb-Bi-S minerals, which were formed by the influence of the Tertiary granitic rocks at a shallow depth. [source]

Geology, Wall-rock Alteration and Vein Paragenesis of the Bilimoia Gold Deposit, Kainantu Metallogenic Region, Papua New Guinea

RESOURCE GEOLOGY, Issue 3 2007
Joseph Onglo Espi
Abstract The Bilimoia deposit (2.23 Mt, 24 g/t Au), located in the eastern Central Mobile Belt of mainland Papua New Guinea, is composed of fault-hosted, NW,NNW-trending Irumafimpa,Kora and Judd,Upper Kora Au-quartz veins hosted by Middle,Late Triassic basement that was metamorphosed to medium-grade greenschist facies between Middle,Late Triassic and Early,Middle Jurassic. Mineralizing fluids were introduced during crustal thickening, rapid uplift, change of plate motions from oblique to orthogonal compression, active faulting and S3 and S4 events in an S1,S4 deformation sequence. The Bilimoia deposit is spatially and temporally related to I-type, early intermediate to felsic and late mafic intrusions emplaced in Late Miocene (9,7 Ma). Hydrothermal alteration and associated mineralization is divided into 10 main paragenetic stages: (1) chlorite,epidote-selvaged quartz,calcite,specularite vein; (2) local quartz,illite,pyrite alteration; (3) quartz,sericite,mariposite,fuchsite,pyrite wall-rock alteration that delimits the bounding shears; (4) finely banded, colloform-, crustiform- and cockade-textured and drusy quartz ± early wolframite ± late adularia; (5) hematite; (6) pyrite; (7) quartz ± amethyst-base metal sulfides; (8) quartz,chalcopyrite,bornite,Sn and Cu sulfides,Au tellurides and Te ± Bi ± Ag ± Cu ± Pb phases; (9) Fe ± Mn carbonates; and (10) supergene overprint. Fluid inclusions in stage 4 are characterized by low salinity (0.9,5.4 wt% NaCl equivalent), aqueous,carbonic fluids with total homogenization temperatures ranging from 210 to 330°C. Some of the inclusions that homogenized between 285 and 330°C host coexisting liquid- and vapor-rich (including carbonic) phases, suggesting phase separation. Fluid inclusions in quartz intergrown with wolframite have low salinity (0.9,1.2 wt% NaCl equivalent), aqueous,carbonic fluids at 240,260°C, defining the latter's depositional conditions. The ore fluids were derived from oxidized magmatic source initially contaminated by reduced basement rocks. Wall-rock alteration and involvement of circulating meteoric waters were dominant during the first three stages and early part of stage 4. Stage 5 hematite was deposited as a result of stage 4 phase separation or entrainment of oxygenated groundwater. Gold is associated with Te- and Bi-bearing minerals and mostly precipitated as gold-tellurides during stage 8. Gold deposition occurred below 350°C due to a change in the sulfidation and oxidation state of the fluids, depressurization and decreasing temperature and activities of sulfur and tellurium. Bisulfides are considered to be the main Au-transporting complexes. The Bilimoia deposit has affinities that are similar to many gold systems termed epizonal orogenic and intrusion-related. The current data allow us to classify the Bilimoia deposit as a fault-controlled, metamorphic-hosted, intrusion-related mesothermal to low sulfidation epithermal quartz,Au,Te,Bi vein system. [source]

Evolution of Hydrothermal System at the Dizon Porphyry Cu-Au Deposit, Zambales, Philippines

RESOURCE GEOLOGY, Issue 2 2005
Akira Imai
Abstract. Evolution of hydrothermal system from initial porphyry Cu mineralization to overlapping epithermal system at the Dizon porphyry Cu-Au deposit in western central Luzon, Zambales, Philippines, is documented in terms of mineral paragen-esis, fluid inclusion petrography and microthermometry, and sulfur isotope systematics. The paragenetic stages throughout the deposit are summarized as follows; 1) stockwork amethystic quartz veinlets associated with chalcopyrite, bornite, magnetite and Au enveloped by chlorite alteration overprinting biotite alteration, 2) stockwork quartz veinlets with chalcopyrite and pyrite associated with Au and chalcopyrite and pyrite stringers in sericite alteration, 3) stringer quartz veinlets associated with molybdenite in sericite alteration, and 4) WNW-trending quartz veins associated with sphalerite and galena at deeper part, while enargite and stibnite at shallower levels associated with advanced argillic alteration. Chalcopyrite and bornite associated with magnetite in quartz veinlet stockwork (stage 1) have precipitated initially as intermediate solid solution (iss) and bornite solid solution (bnss), respectively. Fluid inclusions in the stockwork veinlet quartz consist of gas-rich inclusions and polyphase inclusions. Halite in polyphase inclusions dissolves at temperatures ranging from 360d,C to >500d,C but liquid (brine) and gas (vapor) do not homogenize at <500d,C. The maximum pressure and minimum temperature during the deposition of iss and bnss with stockwork quartz veinlets are estimated to be 460 bars and 500d,C. Fluid inclusions in veinlet stockwork quartz enveloped in sericite alteration (stage 2) consist mainly of gas-rich inclusions and polyphase inclusions. In addition to the possible presence of saturated NaCl crystals at the time of entrapment of fluid inclusions that exhibit the liquid-vapor homogenization temperatures lower than the halite dissolution temperatures in some samples, wide range of temperatures of halite dissolution and liquid-vapor homogenization of polyphase inclusions from 230d,C to >500d,C and from 270d,C to >500d,C, respectively, suggests heterogeneous entrapment of gaseous vapor and hypersaline brine. The minimum pressure and temperature are estimated to be about 25 bars and 245d,C. Fluid inclusions in veinlet quartz associated with molybdenite (stage 3) are dominated by gas-rich inclusions accompanied with minor liquid-rich inclusions that homogenize at temperatures between 350d,C and 490d,C. Fluid inclusions in vuggy veinlet quartz associated with stibnite (stage 4) consist mainly of gas-rich inclusions with subordinate polyphase inclusions that do not homogenize below 500d,C. Fluid inclusions in veinlet quartz associated with galena and sphalerite (stage 4) are composed of liquid-rich two-phase inclusions, and they homogenize into liquid phase at temperatures ranging widely from 190d,C to 300d,C (suggesting boiling) and the salinity ranges from 1.0 wt% to 3.4 wt% NaCl equivalent. A pressure of about 15 bars is estimated for the dilute aqueous solution of 190d,C from which veinlet quartz associated with galena and sphalerite precipitated. In addition to a change in temperature-pressure regime from lithostatic pressure during the deposition of iss and bnss with stockwork quartz veinlets to hydrostatic pressure during fracture-controlled quartz veinlet associated with galena and sphalerite, a decrease in pressure is supposed to have occurred due to unroofing or removal of the overlying piles during the temperature decrease in the evolution of hydrothermal system. The majority of the sulfur isotopic composition of sulfides ranges from ±0 % to +5 %. Sulfur originated from an iso-topically uniform and homogeneous source, and the mineralization occurred in a single hydrothermal system. [source]

Chemical, Isotopic, and Fluid Inclusion Evidence for the Hydrothermal Alteration of the Footwall Rocks of the BIF-Hosted Iron Ore Deposits in the Hamersley District, Western Australia

RESOURCE GEOLOGY, Issue 2 2003
Makoto Haruna
Abstract. The petrography, chemical, fluid inclusion and isotope analyses (O, Rb-Sr) were conducted for the shale samples of the Mount McRae Shale collected from the Tom Price, Newman, and Paraburdoo mines in the Hamersley Basin, Western Australia. The Mount McRae Shale at these mines occurs as a footwall unit of the secondary, hematite-rich iron ores derived from the Brockman Iron Formation, one of the largest banded iron formations (BIFs) in the world. Unusually low contents of Na, Ca, and Sr in the shales suggest that these elements were leached away from the shale after deposition. The ,18O (SMOW) values fall in the range of + 15.0 to +17.9 per mil and show the positive correlation with calculated quartz/sericite ratios of the shale samples. This suggests that the oxygen isotopic compositions of shale samples were homogenized and equilibrated by postdepositional event. The pyrite nodules hosted by shales are often rimmed by thin layers of silica of varying crystallinity. Fluid inclusions in quartz crystals rimming a pyrite nodule show homogenization temperatures ranging from 100 to 240d,C for 47 inclusions and salinities ranging from 0.4 to 12.3 wt% NaCl equivalent for 18 inclusions. These fluid inclusion data give direct evidence for the hydrothermal activity and are comparable to those of the vein quartz collected from the BIF-derived secondary iron ores (Taylor et al, 2001). The Rb-Sr age for the Mount McRae Shale is 1,952 ± 289 Ma and at least 200 million years younger than the depositional age of the Brockman Iron Formation of , 2.5 Ga in age. All the data obtained in this study are consistent with the suggestion that high temperature hydrothermal fluids were responsible for both the secondary iron ore formation and the alteration of the Mount McRae Shale. [source]

Mineral Paragenesis, Fluid Inclusions and Sulfur Isotope Systematics of the Lepanto Far Southeast Porphyry Cu-Au Deposit, Mankayan, Philippines

RESOURCE GEOLOGY, Issue 3 2000
Akira IMAI
Abstract: The Lepanto Far Southeast porphyry Cu-Au deposit is located beneath and to the southeast of the Lepanto enargite-luzonite Cu,Au deposit in Mankayan, Benguet Province, Philippines. The principal orebody consists of potassic alteration subjected to partial retrograde chlorite alteration that rims stock-work of quartz-anhydrite veinlets. Fluid inclusions found in stockwork quartz and anhydrite in the biotitized orebody center are dominated by polyphase inclusions that homogenize at temperatures of >500C. Sulfur isotopic thermometry applied to the sulfides-anhydrite pairs suggests around 500C. The principal ore minerals associated with quartz-anhydrite stockworks are chalcopyrite and pyrite with minor bornite and Bi,Te,bearing tennantite, with trace of native gold. Rounded pyrite grains appear fractured and corroded and are interpreted as remnants of primary intermediate solid solution + pyrite assemblage. A breccia pipe truncates the deposit. Mineralization in the breccia pipe is brought by quartz-anhydrite veinlets and infilling in the interstices between clasts. Chalcopyrite-Au mineralization associated with molybdenite is recognized in the deeper zone in the breccia pipe. Fluid inclusion microthermometry on polyphase inclusions in veinlet quartz as well as sulfur isotope thermometry applied for the pair of anhydrite and sulfides suggests >450C. Fluid inclusions in veinlet quartz and anhydrite in the fringe advanced argillic alteration are chiefly composed of coexisting liquid-rich inclusions and gas-rich inclusions, in addition to coexisting polyphase inclusions and gas-rich inclusions. These inclusions exhibit a wide range of homogenization temperatures, suggesting heterogeneous entrapping in the two-fluid unmixing region. Sulfur isotopes of aqueous sulfide and sulfate exhibit a general trend from the smallest fractionation pairs (about 11%) in the biotitized orebody center to the largest fractionation (about 25%) pairs in the fringe advanced argillic alteration, suggesting a simple evolution of hydrothermal system. The slopes of arbitrary regression lines in ,34S versus 34S[SO4 = ,H2S] diagram suggest that the abundance ratio of aqueous sulfate to sulfide in the hydrothermal fluid has been broadly constant at about 1:3 through temperature decrease. The intersection of these two regression lines at the ,34S axis indicates that the bulk ,34S is about +6%. Thus, the Lepanto FSE deposit is a further example which confirms enrichment in 34S in the hydrous intermediate to silicic magmas and associated magmatic hydrothermal deposits in the western Luzon arc. [source]