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Homogeneous Mixture (homogeneous + mixture)

Distribution by Scientific Domains

Polymers and Materials Science	40%

Selected Abstracts

Atomic Layer Deposition, Characterization, and Dielectric Properties of HfO2/SiO2 Nanolaminates and Comparisons with Their Homogeneous Mixtures,

CHEMICAL VAPOR DEPOSITION, Issue 2-3 2006
L. Zhong
Abstract Nanolaminates of HfO2 and SiO2 were prepared using atomic layer deposition (ALD) methods. Successive exposure of substrates maintained at 120 or 160,°C to nitrogen flows containing Hf(NO3)4 and (tBuO)3SiOH led to typical bilayer spacings of 2.1,nm, with the majority of each bilayer being SiO2. The density of the SiO2 layers (measured using X-ray reflectometry (XRR)) was slightly higher than expected for amorphous silica, suggesting that as much as 10,% HfO2 was incorporated into the silica layers. Based on cross-sectional transmission electron microscopy (TEM) and XRR, oxidation of the silicon substrate was observed during its first exposure to Hf(NO3)4, leading to a SiO2 interfacial layer and the first HfO2 layer. Combining the ALD of Hf(NO3)4/(tBuO)3SiOH with ALD cycles involving Hf(NO3)4 and H2O allowed the systematic variation of the HfO2 thickness within the nanolaminate structure. This provided an approach towards controlling the dielectric constant of the films. The dielectric constant was modeled by treating the nanolaminate as a stack of capacitors wired in series. The nanolaminate structure inhibited the crystallization of the HfO2 in post-deposition annealing treatments. As the HfO2 thickness decreased, the preference for the tetragonal HfO2 phase increased. [source]

Investigations of Miscibility in Interpenetrated Systems of Polyurethane and Polystyrene Obtained at Room Temperature

MACROMOLECULAR SYMPOSIA, Issue 1 2004
Jean-Michel Widmaier
Abstract Interpenetrating polymer systems based on crosslinked polyurethane (PU) and polystyrene (PS) were prepared at room temperature by a one-shot (in situ) method, starting from an initial homogeneous mixture of reagents via non interfering mechanisms. Both polymerizations were performed either simultaneously or one after the other. Crosslinks and/or covalent bonds between components were deliberately introduced by the addition of appropriate monomers, in order to tailor the degree of microphase separation. Depending on the formation process, transluscent or transparent films were obtained, despite the difference in refractive index of the components. The maximum of miscibility, taken as from the glass transition criterion, was obtained for sequential tightly graft interpenetrating networks. [source]

Perfluorocarbon facilitated O2 transport in a hepatic hollow fiber bioreactor

BIOTECHNOLOGY PROGRESS, Issue 5 2009
Guo Chen
Abstract A mathematical model describing O2 transport in a hepatic hollow fiber (HF) bioreactor supplemented with perfluorocarbons (PFCs) in the circulating cell culture media was developed to explore the potential of PFCs in properly oxygenating a bioartificial liver assist device (BLAD). The 2-dimensional model is based on the geometry of a commercial HF bioreactor operated under steady-state conditions. The O2 transport model considers fluid motion of a homogeneous mixture of cell culture media and PFCs, and mass transport of dissolved O2 in a single HF. Each HF consists of three distinct regions: (1) the lumen (conducts the homogeneous mixture of cell culture media and PFCs), (2) the membrane (physically separates the lumen from the extracapillary space (ECS), and (3) the ECS (hepatic cells reside in this compartment). In a single HF, dissolved O2 is predominantly transported in the lumen via convection in the axial direction and via diffusion in the radial direction through the membrane and ECS. The resulting transport equations are solved using the finite element method. The calculated O2 transfer flux showed that supplementation of the cell culture media with PFCs can significantly enhance O2 transport to the ECS of the HF when compared with a control with no PFC supplementation. Moreover, the O2 distribution and subsequent analysis of ECS zonation demonstrate that limited in vivo-like O2 gradients can be recapitulated with proper selection of the operational settings of the HF bioreactor. Taken together, this model can also be used to optimize the operating conditions for future BLAD development that aim to fully recapitulate the liver's varied functions. © 2009 American Institute of Chemical Engineers Biotechnol. Prog., 2009 [source]

Investigations on the self-ignition of deposits containing combustibles

FIRE AND MATERIALS, Issue 4 2008
Anka Berger
Abstract Self-ignition of deposited combustibles is a possible reason for excessive fires occurring on deposits for recycling materials or on waste dumps. Two series of experiments were performed to assess the hazard of self-ignition: hot storage tests with different homogeneous mixtures of combustible material and inert material and tests with pockets of combustible material embedded in inert matter. In the first test series considerable exothermicity (,T>60K) was observed for mass fractions of combustible material as low as 2.5%. In the second series it could be shown that the heat transfer from a pocket of burning material through the inert matter can ignite a second pocket of combustible matter. Based on the experimental data, numerical simulations were performed to predict self-ignition on real-scale waste deposits. For a deposit of specific size and shape, the influence of the ambient temperature on the occurrence of self-ignition has been investigated. Copyright © 2008 John Wiley & Sons, Ltd. [source]

On the hyperbolic system of a mixture of Eulerian fluids: a comparison between single- and multi-temperature models

MATHEMATICAL METHODS IN THE APPLIED SCIENCES, Issue 7 2007
Tommaso Ruggeri
Abstract The first rational model of homogeneous mixtures of fluids was proposed by Truesdell in the context of rational thermodynamics. Afterwards, two different theories were developed: one with a single-temperature (ST) field of the mixture and the other one with several temperatures. The two systems are from the mathematical point of view completely different and the relationship between their solutions was not clarified. In this paper, the hyperbolic multi-temperature (MT) system of a mixture of Eulerian fluids will be explained and it will be shown that the corresponding single-temperature differential system is a principal subsystem of the MT one. As a consequence, the subcharacteristic conditions for characteristic speeds hold and this gives an upper-bound esteem for pulse speeds in an ST model. Global behaviour of smooth solutions for large time for both systems will also be discussed through the application of the Shizuta,Kawashima condition. Finally, as an application, the particular case of a binary mixture is considered. Copyright © 2006 John Wiley & Sons, Ltd. [source]