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High Absorption (high + absorption)
Selected AbstractsPerylene,Oligothiophene,Perylene Triads for Photovoltaic ApplicationsEUROPEAN JOURNAL OF ORGANIC CHEMISTRY, Issue 17 2005Jens Cremer Abstract A series of novel acceptor,donor,acceptor triad systems, consisting of head-to-tail-coupled oligo(3-hexylthiophene)s integrated between two terminal perylenemonoimides are described. These hybrid molecules, which differ by the length of the oligothiophene units from a quaterthiophene up to a dodecithiophene were synthesized by an effective palladium-catalyzed Ullmann-type homo-coupling reaction in good yields. The optical and electrochemical properties of these compounds were determined, and on the basis of this series structure-property relationships have been established which provide vital information for the fabrication of the corresponding photovoltaic devices. Because the synthesized perylenyl-oligothiophenes distinguish themselves by a high absorption between 300 and 550 nm and an almost complete fluorescence quenching of the perylene acceptor, they meet the requirements for organic solar cells. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005) [source] Determination of Scattering and Absorption Coefficients for Plasma-Sprayed Yttria-Stabilized Zirconia Thermal Barrier CoatingsJOURNAL OF THE AMERICAN CERAMIC SOCIETY, Issue 5 2008Jeffrey I. Eldridge Prediction of radiative transport through translucent thermal barrier coatings (TBCs) can only be performed if the scattering and absorption coefficients and index of refraction of the TBC are known. To date, very limited information on these coefficients, which depend on both the coating composition and the microstructure, has been available for the very commonly utilized plasma-sprayed 8 wt% yttria-stabilized zirconia (8YSZ) TBCs. In this work, the scattering and absorption coefficients of freestanding plasma-sprayed 8YSZ coatings were determined from room-temperature normal-incidence directional-hemispherical reflectance and transmittance spectra over the wavelength range from 0.8 to 7.5 ,m. Spectra were collected over a wide range of coating thickness from 60 to almost 900 ,m. From the reflectance and transmittance spectra, the scattering and absorption coefficients as a function of wavelength were obtained by fitting the reflectance and transmittance values predicted by a four flux model to the experimentally measured values at all measured 8YSZ thicknesses. While the combined effects of absorption and scattering were shown in general to exhibit a nonexponential dependence of transmittance on specimen thickness, it was shown that for sufficiently high absorption and optical thickness, an exponential dependence becomes a good approximation. In addition, the implications of the wavelength dependence of the plasma-sprayed 8YSZ scattering and absorption coefficients on (1) obtaining accurate surface-temperature pyrometer measurements and on (2) applying mid-infrared reflectance to monitor TBC delamination are discussed. [source] Computer Simulation of Dissociative Adsorption of Water on the Surfaces of Spinel MgAl2O4JOURNAL OF THE AMERICAN CERAMIC SOCIETY, Issue 7 2001Chang Ming Fang Atomistic simulation techniques have been used to model the dissociative adsorption of water onto the low-index {100}, {110}, and {111} surfaces of spinel MgAl2O4. The Born model of solids and the shell model for oxygen polarization have been used. The resulting structures and chemical bonding on the clean and hydrated surfaces are described. The calculations show that the dissociative adsorption of water on the low-index surfaces is generally energetically favorable. For the {110} and {111} orientations, the surfaces cleaved between oxygen layers show high absorption and stability. The calculations also show that, for the {111} orientation, the surfaces may absorb chemically water molecules up to ,90% coverage and have the highest stability. It is suggested that, during fracture, only partial hydration occurs, leading to cleavage preferentially along the {100} orientation. [source] The first broad-band X-ray study of the Supergiant Fast X-ray Transient SAX J1818.6,1703 in outburstMONTHLY NOTICES OF THE ROYAL ASTRONOMICAL SOCIETY, Issue 1 2009L. Sidoli ABSTRACT The Supergiant Fast X-ray Transient (SFXT) SAX J1818.6,1703 underwent an outburst on 2009 May 6 and was observed with Swift. We report on these observations which, for the first time, allow us to study the broad-band spectrum from soft to hard X-rays of this source. No X-ray spectral information was available on this source before the Swift monitoring. The spectrum can be deconvolved well with models usually adopted to describe the emission from HMXB X-ray pulsars, and is characterized by a very high absorption, a flat power law (photon index ,0.1,0.5) and a cut-off at about 7,12 keV. Alternatively, the SAX J1818.6,1703 emission can be described with a Comptonized emission from a cold and optically thick corona, with an electron temperature kTe= 5,7 keV, a hot seed photon temperature, kT0, of 1.3,1.4 keV and an optical depth for the Comptonizing plasma, ,, of about 10. The 1,100 keV luminosity at the peak of the flare is 3 × 1036 erg s,1 (assuming the optical counterpart distance of 2.5 kpc). These properties of SAX J1818.6,1703 resemble those of the prototype of the SFXT class, XTE J1739,302. The monitoring with Swift/XRT reveals an outburst duration of about 5 d, similar to other members of the class of SFXTs, confirming SAX J1818.6,1703 as a member of this class. [source] Investigation of graded index SiOxNy antireflection coating for silicon solar cell manufacturingPHYSICA STATUS SOLIDI (C) - CURRENT TOPICS IN SOLID STATE PHYSICS, Issue 4 2007M. Lipi Abstract An optimization of SiOxNy anti-reflective coatings with graded index layers for silicon solar cells based on the Bruggeman's effective medium approximation is presented. For simulation of reflectance and absorption of graded layer, the experimental optical data of silicon nitride SiNx:H and oxynitride SiOxNy obtained by Low Frequency (440 kHz) Plasma Enhanced Chemical Vapour Deposition (LF-PECVD) were used. We have shown that the graded index oxynitride antireflection coating can reduce the effective reflectance to about 2.5% but the high absorption due to high extinction coefficient compensates this improvement and reduces the short circuit current (Jsc) of the solar cell. The improvement in the Jsc can be obtained for graded SiNxOy layer with smaller value of refractive index of SiNx (n = 2.2). In this case the graded SiOxNy layer is characterized by an abrupt concentration profile and can be considered as a double antireflection coating SiO2/SiNx. (© 2007 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) [source] | ||||||||||