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Heating Process (heating + process)
Selected AbstractsPressureless Rapid Sintering of UO2 Assisted by High-frequency Induction Heating ProcessJOURNAL OF THE AMERICAN CERAMIC SOCIETY, Issue 10 2008Jae Ho Yang Heat generation of uranium dioxide (UO2) powder and its pressureless rapid sintering behaviors have been studied using a high-frequency induction heating apparatus. The porous graphite housing has been used to prevent heat loss and to preheat the uranium oxides, simultaneously. At an elevated temperature, UO2 powder generated extra heat by itself. The synergism of individual heat generation between the graphite and UO2 powder could effectively heat the UO2 to the sintering temperature of 1700°C. Using this process, densification behavior of cylindrical and disk-type UO2 green pellets according to the heating rate and grain structure of sintered UO2 pellets were investigated. Rapid sintering caused a large crack around the circumference of the sintered pellet. The formation of cracks could be avoided when the heating rate or sample dimension are properly reduced. A dense and crack-free UO2 pellet with a relative density of up to 96% was produced within 5 min of the process time. The induction heat sintering process can be a potential candidate for the rapid fabrication of ceramics and composites. [source] Proposed life prediction model for laser-formed high-strength low-alloy curved componentsFATIGUE & FRACTURE OF ENGINEERING MATERIALS AND STRUCTURES, Issue 4 2007P. J. McGRATH ABSTRACT Techniques employed for material processing using laser technology are progressing at a rapid pace. One such technique is that of forming sheet metal plates. This high-intensity localized heating process allows for forming of metallic sheet materials without the need for expensive tools and dies or any mechanical assistance. The fundamental mechanisms related to this process are reasonably well understood and documented but there remain areas that require further research and development. One such area is the fatigue behaviour of sheet materials manufactured by this novel process. Hence, the proceeds of this paper deal with fatigue life prediction of sheet metal components laser-formed to a radius with a curvature of approximately 120 mm. The approach to this proposed model considers the mean stress relationship as given by Gerber and a prediction model derived from combining the aspects of life prediction models according to Collins and Juvinall & Marshek. [source] The stress dependent elastic properties of thermally induced microfractures in aeolian Rotliegend sandstoneGEOPHYSICAL PROSPECTING, Issue 3 2007Colin MacBeth ABSTRACT The impact of thermally induced microfractures on the stress-sensitive elastic wave properties of aeolian Rotliegend sandstone samples is analysed. It is found that to identify the effects of the microfracture contribution accurately, a correction must first be made to account for water loss (representing a mass loss of 4,6%) from the pore throats and clays due to the heating process, despite care being taken to ensure that the thermally fractured samples re-adsorb room moisture. Both the original and thermally fractured rocks are stress-sensitive at the ultrasonic wave frequencies of the laboratory. However, a distinct shift in the estimated distribution of internal rock compliance indicates that the population of thermal microfractures differs in nature from that caused solely by core-plug extraction damage. In particular, the ratio of normal to tangential compliance is observed to be higher for the thermally generated microfractures than for the broken grain-grain contacts created by extraction unloading. This can be explained by the intragranular thermal-fracture surfaces being smoother when compared to the intergranular boundaries. Mechanical hysteresis is observed between the up- and downgoing test cycles for both the original and, to a greater extent, the thermally fractured rock. This indicates that there is compaction-induced movement of the fractures in the samples during application of stress in the laboratory. [source] An investigation on thermal-recycling of recycled plastic resin (spherically symmetric analysis of abrupt heating processes of a micro plastic-resin particle)HEAT TRANSFER - ASIAN RESEARCH (FORMERLY HEAT TRANSFER-JAPANESE RESEARCH), Issue 4 2006Ryuji Yamakita Abstract A fundamental understanding of the physical properties of a micro plastic-resin particle subjected suddenly to hot combustion gas, such as the temperature history in the micro particle and its lifetime, is necessary for effectively realizing thermal recycling of recycled plastic resin. However, micro plastic particles have such small diameters, ranging from 100 µm to 200 µm, that the measurement of temperature histories within them is extremely difficult. In this paper, therefore, a spherically symmetric one-dimensional analysis is applied to the abrupt heating process of a micro plastic resin particle in a high temperature inert atmosphere. Variations of the temperature history and the lifetime with the ambient gas temperature and the initial particle diameter are numerically analyzed, by dividing the entire heating process into four independent periods; the solid heating period, the melting period, the liquid heating period, and the vaporization period. Effects of the Nusselt number on the particle lifetime are also discussed. It is found that, by suitably taking account of the influences of heat transfer properties, the proposed simplified analysis is useful for estimating the fundamental and overall temperature characteristics of a micro plastic resin particle under abrupt heating. © 2006 Wiley Periodicals, Inc. Heat Trans Asian Res, 35(4): 279,293, 2006; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/htj.20113 [source] Characteristics of boiling curve in transition region between nucleate boiling and film boilingHEAT TRANSFER - ASIAN RESEARCH (FORMERLY HEAT TRANSFER-JAPANESE RESEARCH), Issue 1 2006M. Monde Abstract An experimental study has been carried out for estimating surface temperature and heat flux during both a transient heating process from nucleate boiling to film boiling and a cooling process in the reverse direction. Experiments were at atmospheric pressure, and calculations used a newly developed inverse solution. Three different materials, gold, copper, and brass, were employed to make clear the effect of thermal properties on the boiling curves in the transient region including the maximum and minimum heat fluxes. It was determined that the histories of surface temperature and heat flux for the transition boiling region during either heating or cooling process can be tracked well. The experiment shows that hysteresis exists in the heating and cooling processes for the transition region while no hysteresis exists in the nucleate boiling region, except that the maximum heat fluxes reached during the heating and cooling processes are much different. It was found that the characteristics for the heating process are minimally influenced by thermal properties, while characteristics of the cooling process are greatly affected. © 2005 Wiley Periodicals, Inc. Heat Trans Asian Res, 35(1): 20,34, 2006; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/htj.20097 [source] ELECTRICAL CONDUCTIVITY OF HEATED CORNSTARCH,WATER MIXTURESJOURNAL OF FOOD PROCESS ENGINEERING, Issue 6 2009EDUARDO MORALES-SANCHEZ ABSTRACT Electrical conductivity (EC) of cornstarch,water mixtures in the range 10:90 to 70:30 (w/w) was studied as a function of temperature. An external resistive heating system equipped with an electronic device capable of monitoring EC in real time was used and EC of the mixtures was measured while heated at a rate of 5C/min. Results showed that EC went through four different temperature-dependent stages (A, B, C and D). Stage B (41C to 64C) showed a lower EC increasing rate when compared with that of Stage A (from 25C to 41C), probably as a result of starch granule swelling. In Stage C (64C to 78C), EC behavior was found to be dependent on water content. When water content was more than 50%, the value for EC increased. On the other side, EC decreased when water content was less than 50%. Stage C was related to starch gelatinization, according to differential scanning calorimetry results obtained in this study. In Stage D (78C to 92C), a steady increase in EC was observed, probably as a result of the total solubilization of starch in water. It was concluded that Stage C in EC graphs corresponded to cornstarch gelatinization, so it might be possible to use EC monitoring as an alternative technique to measure cornstarch thermal characteristics with different contents of water. PRACTICAL APPLICATIONS Electrical conductivity can be used as an adequate technique to monitor gelatinization, granule swelling and phase change of starch as a function of temperature in corn starch,water mixtures with a wide range of water contents. With this technique, it is also possible to calculate important thermal parameters, such as the beginning and end of the gelatinization and the energy activation for the heating process of cornstarch. This can lead to a better design and control of important industrial corn processes such as alkaline cooking. [source] SPLITTING AND BREAKING OF PISTACHIO NUTS WITH STRIKING AND HEATINGJOURNAL OF FOOD PROCESS ENGINEERING, Issue 3 2008H.I. CEM BILIM ABSTRACT The objective of this study was to investigate the effects of heating process and striking on splitting and breaking of pistachio nuts and obtaining their kernels without damage. For this purpose, heating process (350C) was applied to pistachio nuts. Heated nuts were dropped onto the rotating disk and then thrown to strike the wall of the container by centrifuge effect . Striking velocity was adjusted with a rotating disk that was driven by an electrical engine. Three different disk rotations (400, 500 and 600/min) with three different moisture contents of pistachios (6.5, 22.0 and 42.5%) were evaluated in the experiments. Results indicated that the highest splitting rate was obtained as 29.33% at 22.0% moisture content with 400 1/min disk velocity. The most healthy kernel percentage obtained from unsplit pistachio nuts was 25.76% at 6.5% moisture content with 500 1/min disk velocity. Additionally, the study results showed that only the heating process had no affect while heating and crushing combinations increased splitting and obtaining the kernels. PRACTICAL APPLICATIONS Consumption of healthy foods is very important for human health. Kirmizi variety of pistachio nuts contains a high ratio of unsplit pistachio nuts after harvest. These pistachio nuts are either consumed as appetizers or used in the sweets sector after extracting the inner part (kernel). The economical value of unsplit pistachio nuts is very low. For this reason, pistachio nut processing plants try to split them or extract the inner part without causing any damage. Unsplit pistachio nuts are split by hand or by primitive hand tools, such as hammer or pliers, and then extracted. This method is not healthy. This study is one of the limited studies concerning automatic, quick and economic splitting and extraction of pistachio nuts. After handling problems like splitting and extracting the kernel of pistachio nuts, pistachio nut processing plants will achieve a healthy pistachio nut production. This study offers a new system for healthy pistachio nut production, with low initial cost, lower wages and in less time. [source] Heat transfer during microwave combination heating: Computational modeling and MRI experimentsAICHE JOURNAL, Issue 9 2010Vineet Rakesh Abstract Combination of heating modes such as microwaves, convection, and radiant heating can be used to realistically achieve the quality and safety needed for cooking processes and, at the same time, make the processes faster. Physics-based computational modeling used in conjunction with MRI experimentation can be used to obtain critical understanding of combination heating. The objectives were to: (1) formulate a fully coupled electromagnetics - heat transfer model, (2) use magnetic resonance imaging (MRI) experiments to determine the 3D spatial and temporal variation of temperatures and validate the numerical model, (3) use the insight gained from the model and experiments to understand the combination heating process and to optimize it. The different factors that affect heating patterns during combination heating such as the type of heating modes used, placement of sample, and microwave cycling were considered. Objective functions were defined and minimized for design and optimization. The use of such techniques can lead to greater control and automation of combination heating process benefitting the food process and product developers immensely. © 2010 American Institute of Chemical Engineers AIChE J, 2010 [source] Thermoresponsive brush copolymers with poly(propylene oxide- ran -ethylene oxide) side chains via metal-free anionic polymerization "grafting from" techniqueJOURNAL OF POLYMER SCIENCE (IN TWO SECTIONS), Issue 11 2010Junpeng Zhao Abstract Thermoresponsive brush copolymers with poly(propylene oxide- ran -ethylene oxide) side chains were synthesized via a "grafting from" technique. Poly(p -hydroxystyrene) was used as the backbone, and the brush copolymers were prepared by random copolymerization of mixtures of oxyalkylene monomers, using metal-free anionic ring-opening polymerization, with the phosphazene base (t -BuP4) being the polymerization promoter. By controlling the monomer feed ratios in the graft copolymerization, two samples with the same side-chain length and different compositions were prepared, both of which possessed high molecular weights and low molecular weight distributions. The results from light scattering and fluorescence spectroscopy indicated that the brush copolymers in their dilute aqueous solutions were near completely solvated at low temperature and underwent slight intramolecular chain contraction/association and much more profound intermolecular aggregation at different stages of the step-by-step heating process. Above 50 °C, very turbid solutions, followed by macrophase separation, were observed for both of the samples, which implied that it was difficult for the brush copolymers to form stable nanoscopic aggregates at high temperature. All these observations were attributed, at least partly, to the distribution of the oxyalkylene monomers along the side chains and the overall brush-like molecular architecture. © 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 48: 2320,2328, 2010 [source] Nonaqueous synthesis of nanosilica in epoxy resin matrix and thermal properties of their cured nanocompositesJOURNAL OF POLYMER SCIENCE (IN TWO SECTIONS), Issue 2 2006Tzong-Ming Lee Abstract Nonaqueous synthesis of nanosilica in diglycidyl ether of bisphenol-A epoxy (DGEBA) resin has been successfully achieved in this study by reacting tetraethoxysilane (TEOS) directly with DGEBA epoxy matrix, at 80 °C for 4 h under the catalysis of boron trifluoride monoethylamine (BF3MEA). BF3MEA was proved to be an effective catalyst for the formation of nanosilica in DGEBA epoxy under thermal heating process. FTIR and 29Si NMR spectra have been used to characterize the structures of nanosilica obtained from this direct thermal synthetic process. The morphology of the nanosilica synthesized in epoxy matrix has also been analyzed by TEM and SEM studies. The effects of both the concentration of BF3MEA catalyst and amount of TEOS on the diameters of nanosilica in the DGEBA epoxy resin have been discussed in this study. From the DSC analysis, it was found that the nanosilica containing epoxy exhibited the same curing profile as pure epoxy resin, during the curing reaction with 4,4,-diaminodiphenysulfone (DDS). The thermal-cured epoxy,nanosilica composites from 40% of TEOS exhibited high glass transition temperature of 221 °C, which was almost 50 °C higher than that of pure DGEBA,DDS,BF3MEA-cured resin network. Almost 60 °C increase in thermal degradation temperature has been observed during the TGA of the DDS-cured epoxy,nanosilica composites containing 40% of TEOS. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 757,768, 2006 [source] Reverse atom transfer radical solution polymerization of methyl methacrylate under pulsed microwave irradiationJOURNAL OF POLYMER SCIENCE (IN TWO SECTIONS), Issue 21 2002Zhenping Cheng Abstract The reverse atom transfer radical polymerization (RATRP) of methyl methacrylate (MMA) was successfully carried out under pulsed microwave irradiation (PMI) at 69 °C with N,N -dimethylformamide as a solvent and with azobisisobutyronitrile (AIBN)/CuBr2/tetramethylethylenediamine as an initiation system. PMI resulted in a significant increase in the polymerization rate of RATRP. A 10.5% conversion for a polymer with a number-average molecular weight of 34,500 and a polydispersity index of 1.23 was obtained under PMI with a mean power of 4.5 W in only 52 min, but 103 min was needed under a conventional heating process (CH) to reach a 8.3% conversion under identical conditions. At different [MMA]0/[AIBN]0 molar ratios, the apparent rate constant of polymerization under PMI was 1.5,2.3 times larger than that under CH. © 2002 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 40: 3823,3834, 2002 [source] Raman and infrared studies of synthetic Maya pigments as a function of heating time and dye concentrationJOURNAL OF RAMAN SPECTROSCOPY, Issue 9 2007F. S. Manciu Abstract Maya Blue is a famous indigo-based pigment produced by the ancient Mayas. The organic/inorganic complexes inspired by Maya Blue have led to a new class of surface compounds that have novel applications to pigment industries. Materials analyzed in the present work are made by a synthetic route, and demonstrate chemical stability similar to that of the ancient Maya Blue samples. However, we have learned that stable complexes can be synthesized at much higher dye concentrations than used by the Mayas. Analysis by FT-Raman and FT-IR spectroscopy demonstrates the partial elimination of the selection rules for the centrosymmetric indigo, indicating distortion of the molecule. This distortion accounts for the observed color changes, as the molecular orbital structure is modified, allowing the complex to stabilize. The spectroscopic data also shows the disappearance of the indigo NH bonding, as the organic molecules incorporate into palygorskite material. A structural change of indigo to dehydroindigo during heating is suggested by this result. Infrared data confirm the loss of zeolitic water and a partial removal of structural water after the heating process. Evidence of bonding between cationic aluminum and dehydroindigo through oxygen and nitrogen is revealed by FT-Raman measurements at higher dye concentrations. Copyright © 2007 John Wiley & Sons, Ltd. [source] Structure of new porous compounds after annealing in vacuumJOURNAL OF SYNCHROTRON RADIATION, Issue 2 2001S. B. Erenburg Dehydration process in recently synthesized porous inorganic salts formed by large cluster anions [Re6X8(CN)6]4- (X= S, Se), transition metal cations and water molecules has been investigated. Desolvation process of the complex Co(DMF)6[Mo6Br8(NCS)6], where DMF - dimethylformamide, has been studied. CoK, MoK and ReL3 XAFS measurements of these new complicated compounds before and after annealing in vacuum at temperature up to 250°C were performed. Changes of electronic and spatial structure of these compounds under the heating process have been established and adequate structural models of the amorphous compounds obtained are suggested and discussed. [source] Barium Holmium Zirconate, A New Complex Perovskite Oxide: I, Synthesis, Characterization, and Potential Use as a Substrate for High-Critical-Temperature SuperconductorsJOURNAL OF THE AMERICAN CERAMIC SOCIETY, Issue 10 2002Rajan Jose Barium holmium zirconate, a new complex perovskite ceramic oxide, has been synthesized through liquid-phase sintering for the first time. The conventional solid-state reaction method using constituent oxides and carbonates was found to be inadequate for the synthesis of Ba2HoZrO5.5 material. During high-temperature annealing, the development of stable BaZrO3 and BaHoO2.5 phases prevented the formation of Ba2HoZrO5.5 as a single-phase material, even at 1650°C. However, an addition of a small amount of CuO (1 wt%) in the reaction mixture has resulted in the formation of an ordered complex perovskite Ba2HoZrO5.5 phase during the heating process. The structure of Ba2HoZrO5.5 was studied by X-ray diffraction and found to have a cubic perovskite structure with a lattice constant of a= 8.482 Å. Dielectric constant and loss factor values of Ba2HoZrO5.5 are also in the range suitable for use as a substrate for microwave applications. The X-ray diffraction and resistivity measurements have shown that there is no detectable chemical reaction in YBa2Cu3O7,,,Ba2HoZrO5.5 and Bi(2212),Ba2HoZrO5.5 composites, even under extreme processing conditions. Dip-coated and melt-textured YBa2Cu3O7,, and Bi(2212) thick films developed on polycrystalline Ba2HoZrO5.5 gave zero-resistivity transition temperatures of Tc(0) = 92 and 85 K, respectively. [source] Sintering of Partially Stabilized Zirconia by Microwave Heating Using ZnO,MnO2,Al2O3 Plates in a Domestic Microwave OvenJOURNAL OF THE AMERICAN CERAMIC SOCIETY, Issue 8 2000Satoru Fujitsu Partially stabilized zirconia (PSZ) powders were fully densified by microwave heating using a domestic microwave oven. Pressed powder compacts of PSZ were sandwiched between two ZnO,MnO2,Al2O3 ceramic plates and put into the microwave oven. In the first step, PSZ green pellets were heated by self-heating of ZnO,MnO2,Al2O3 ceramics (1000°C). In the second step, the heated PSZ pellets absorbed microwave energy and self-heated up to a higher temperature (1250°C), leading to densification. The density of PSZ obtained by heating in the microwave oven for 16 min was 5.7 g/cm3, which was approximately equal to the density of bodies sintered at 1300°C for 4 h or 1400°C for 16 min by the conventional method. The average grain size of the sample obtained by this method was larger than the average grain size of samples sintered by the conventional method with a similar heating process. [source] A study on degradation kinetics of ascorbic acid in drumstick (Moringa olifera) leaves during cookingJOURNAL OF THE SCIENCE OF FOOD AND AGRICULTURE, Issue 11 2005Nisha P Bineesh Abstract The kinetics of ascorbic acid degradation in drumstick (Moringa olifera) leaves as well as in pure ascorbic acid solutions at the initial concentrations present in drumstick leaves over a temperature range of 50,120 °C (isothermal temperature process) has been studied. The degradation kinetics of ascorbic acid was also evaluated in normal open-pan cooking, pressure-cooking and a newly developed and patented fuel-efficient eco cooker (non-isothermal heating process). The ascorbic acid degradation followed first-order reaction kinetics where the rate constant increased with an increase in the temperature. The temperature dependence of degradation was adequately modelled by the Arrhenius equation. A mathematical model was developed using the isothermal kinetic parameters obtained to predict the losses of ascorbic acid from the time,temperature data of the non-isothermal heating/processing method. The results obtained indicate the ascorbic acid degradation is of similar order of magnitude in all the methods of cooking. Copyright © 2005 Society of Chemical Industry [source] Characterization of the respiration of 3T3 cells by laser-induced fluorescence during a cyclic heating processLASER PHYSICS LETTERS, Issue 4 2010J. Beuthan Abstract The use of lasers in the near infrared spectral range for laser-induced tumor therapy (LITT) demands a new understanding of the thermal responses to repetitive heat stress. The analysis of laser-induced fluorescence during vital monitoring offers an excellent opportunity to solve many of the related issues in this field. The laser-induced fluorescence of the cellular coenzyme NADH was investigated for its time and intensity behavior under heat stress conditions. Heat was applied to vital 3T3 cells (from 22 °C to 50 °C) according to a typical therapeutical time regime. A sharp increase in temperature resulted in non-linear time behavior when the concentration of this vital coenzyme changed. There are indications that biological systems have a delayed reaction on a cellular level. These results are therefore important for further dosimetric investigations. (© 2010 by Astro Ltd., Published exclusively by WILEY-VCH Verlag GmbH & Co. KGaA) [source] Crystallization study of amorphous Pd43Ni10Cu27P20 alloy by internal friction measurementPHYSICA STATUS SOLIDI (A) APPLICATIONS AND MATERIALS SCIENCE, Issue 10 2007K. W. Yang Abstract We have successfully measured the internal friction and electrical resistivity of Pd43Ni10Cu27P20 bulk metallic glass during a constant heating process. The results of electrical resistivity suggest that the position of the internal friction peak is the onset temperature of crystallization. The dependence of internal friction on frequencies show both linear and nonlinear relations. The internal friction at 623 K in the supercooled liquid region decreases monotonously with the increase of annealing time, indicating structural relaxation and subsequent crystallization occurs during isothermal annealing near the crystallization temperature. (© 2007 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) [source] Fullerene-functionalized polycarbonate: Synthesis under microwave irradiation and nonlinear optical propertyPOLYMER ENGINEERING & SCIENCE, Issue 4 2006Huixia Wu Fullerenation of polycarbonate (PC), a commercially important optical polymer, was achieved by direct reaction of C60 and PC in the presence of azo-bis-isobutyronitrile (AIBN), using 1,1,2,2-tetrachloroethane as the solvent under microwave irradiation (MI). Compared with conventional heating process, MI could significantly enhance the rate of the fullerenation under identical reaction conditions. The C60 content of the fullerene-functionalized polycarbonate (C60 -PC) could be controlled via varying the C60/PC feed ratio and the reaction time. The C60 -PCs are soluble in common organic solvents such as THF and chloroform. The products were characterized by gel permeation chromatography, UV,vis, FTIR, TGA, DSC, 1H NMR, and 13C NMR. The reaction of C60 with PC under MI was monitored by electron spin resonance spectra, the fullerene radicals were detected in reaction solutions and also in the solid product polymers, indicating the radical mechanism of the reaction. The nonlinear optical property of C60 -PCs in THF was investigated by the open-aperture z -scan technique at 527 nm, and its nonlinear absorption coefficient was found to be in the same order as that of C60. POLYM. ENG. SCI., 46:399,405, 2006. © 2006 Society of Plastics Engineers [source] Lower critical solution temperatures of thermo-responsive poly(N -isopropylacrylamide) copolymers with racemate or single enantiomer groupsPOLYMER INTERNATIONAL, Issue 2 2009Peng-Fei Li Abstract BACKGROUND: Thermo-responsive copolymers with racemate or single enantiomer groups are attracting increasing attention due to their fascinating functional properties and potential applications. However, there is a lack of systematic information about the lower critical solution temperature (LCST) of poly(N -isopropylacrylamide)-based thermo-responsive chiral recognition systems. In this study, a series of thermo-responsive chiral recognition copolymers, poly[(N -isopropylacrylamide)- co -(N -(S)- sec -butylacrylamide)] (PN- S -B) and poly[(N -isopropylacrylamide)- co -(N -(R,S)- sec -butylacrylamide)] (PN- R,S -B), with different molar compositions, were prepared. The effects of heating and cooling processes, optical activity and amount of chiral recognition groups in the copolymers on the LCSTs of the prepared copolymers were systematically studied. RESULTS: LCST hysteresis phenomena are found in the phase transition processes of PN- S -B and PN- R,S -B copolymers in a heating and cooling cycle. The LCSTs of PN- S -B and PN- R,S -B during the heating process are higher than those during the cooling process. With similar molar ratios of N -isopropylacrylamide groups in the copolymers, the LCST of the copolymer containing a single enantiomer (PN- S -B) is lower than that of the copolymer containing racemate (PN- R,S -B) due to the steric structural difference. The LCSTs of PN- R,S -B copolymers are in inverse proportion to the molar contents of the hydrophobic R,S -B moieties in these copolymers. CONCLUSION: The results provide valuable guidance for designing and fabricating thermo-responsive chiral recognition systems with desired LCSTs. Copyright © 2008 Society of Chemical Industry [source] Effect of sodium chloride on the formation and stability of n-dodecane nanoemulsions by the PIT methodASIA-PACIFIC JOURNAL OF CHEMICAL ENGINEERING, Issue 4 2010Jeffery Chin Long Liew Abstract This paper provides a fundamental study of the effect of sodium chloride on the formation and stability of n-dodecane/nonionic surfactant (Brij30)/NaCl nanoemulsions produced by the phase inversion temperature (PIT) method. Nanoemulsions are an emulsion system containing droplets from 20 to 200 nm and widely used in cosmetics and pharmaceutical industries. The PIT method was chosen due to its low energy and surfactant usage to produce the nanoemulsions by heating and quenching an emulsion system. The changes of conductivity with temperatures were continuously monitored to determine phase inversion, and are found to be the same in low surfactant concentrations. PIT point was found to decrease with NaCl concentration especially from 5 to 7 wt% Brij30. At the storage temperature (20 °C), the initial droplet size decreases with NaCl concentration; however, the decrement only occurs from 4 to 7 wt% Brij30 while no nanoemulsions can be produced at 8 wt%. By adding salt, the surfactant concentration needed for the most stable nanoemulsions is reduced to 6 wt% from 7 wt%. Therefore, similar stable nanoemulsions can be produced with less surfactant in a brine system. Furthermore, most of the ageing brine-continuous nanoemulsions could be reproduced to their freshly prepared state by heating process but not for the most stable nanoemulsions. Copyright © 2010 Curtin University of Technology and John Wiley & Sons, Ltd. [source] Effect of solvent on the viscosity changes of coal-oil slurry under high temperature,high pressure during heatingASIA-PACIFIC JOURNAL OF CHEMICAL ENGINEERING, Issue 5 2009Yingjie Ren Abstract Heating coal-oil slurry is an important step in direct coal liquefaction. Some physical and chemical properties and the viscosity of coal-oil slurry will be the changes in the heating process. A self-manufactured rotary viscometer that can measure the viscosity of coal slurry at high-pressure temperature was designed. Two kinds of solvents including anthracene oil, Shenhua recycled oil (the catalytic hydrogenation products of Shenhua direct coal liquefaction) and Yanzhou coal were used. The results show that the viscosity of Yanzhou coal-anthracene oil and Shenhua recycled oil slurry decrease firstly with the decreasing of solvent viscosity, then increase with measuring temperature for the absorption and volatilization of the solvent in atmosphere. Both of them have a viscosity peak with increasing measuring temperature in atmosphere. However, the Yanzhou coal-anthracene oil slurry has a viscosity peak at about 583 K under high pressure during heating, while the Yanzhou coal-Shenhua recycled oil slurry does not have a viscosity peak, but coke deposits appear at 623 K and above, under high pressure. In addition, the viscosity,temperature characteristics of thermally treated coal-oil slurry at different temperatures are the same; both have a viscosity peak with increasing heating temperature at the same measuring temperature. Copyright © 2009 Curtin University of Technology and John Wiley & Sons, Ltd. [source] Ohmic heating of dairy fluids,effects of local electric field on temperature distributionASIA-PACIFIC JOURNAL OF CHEMICAL ENGINEERING, Issue 5 2009Heng Jin Tham Abstract This paper presents the heat transfer model of a continuous flow ohmic heating process. The model fluid used was a mixture of reconstituted skimmed milk and whey protein concentrate solution. Two-dimensional numerical simulations of an annular ohmic heater were performed using a general purpose partial differential equation solver, FlexPDE. The momentum, energy, and electrical equations were solved for a laminar flow regime. Two models were used to determine the volumetric heating rate, one taking into account the local electric field by solving the Laplace equation while another model assumes an average voltage gradient applied between the two electrodes. Results show that while the wall temperature distribution is different for the two cases, the bulk fluid temperature and the average outlet temperature are the same. The predicted temperatures generally agree well with the measured temperatures. Copyright © 2009 Curtin University of Technology and John Wiley & Sons, Ltd. [source] Anwendungen der Magnetresonanz zur Untersuchung von Wasser-, Temperatur- und Porenverteilung bei lebensmittelverfahrenstechnischen ProzessenCHEMIE-INGENIEUR-TECHNIK (CIT), Issue 4 2004M. Regier Dr.-Ing. Abstract Es werden verschiedene Methoden der kernmagnetischen Resonanz (NMR) und ihrer Anwendung zur Bestimmung von Wasser-, Temperaturverteilungen und Selbstdiffusionskoeffizienten im Verlauf von Prozessen im Bereich der Lebensmittelverfahrenstechnik vorgestellt. Ausgehend von den physikalischen Grundlagen der Magnetresonanz werden verschiedene Anwendungen gezeigt, die das Potenzial besitzen, zum tieferen Verständnis der verfahrenstechnischen Prozesse beizutragen: Beispielhaft wird die Bestimmung von Wasserverteilungen bei der Rehydratation von getrockneten Proben, die Ermittlung von Temperaturverteilungen bei der Mikrowellenerwärmung und von beobachtungszeitabhängigen Selbstdiffusionskoeffizienten bei der Mikrowellen-Vakuumtrocknung gezeigt. Letztere können dazu genutzt werden, um weitere Aussagen über die innere Gewebestruktur wie Tortuosität und Porenradien zu erlangen. Applications of Magnetic Resonance for Investigating Water-, Temperature- and Poredistributions in Food Process Engineering Various methods of nuclear magnetic resonance (NMR) and their application for determinig water- and temperature distributions as well as self diffusion coefficients during food processing operations are presented. Starting from the physical basics of the magnetic resonance, various NMR applications are shown, which may contribute to a more comprehensive understanding of the food processes: Presented examples are the determination of water distributions during the rehydration of dried samples, of temperature distributions during a microwave heating process and of self diffusion coefficients during microwave vacuum drying. These observation time dependent self diffusion coefficients may be used to receive further information about the internal tissue structure, like tortuosity and pore radii. [source] An investigation on thermal-recycling of recycled plastic resin (spherically symmetric analysis of abrupt heating processes of a micro plastic-resin particle)HEAT TRANSFER - ASIAN RESEARCH (FORMERLY HEAT TRANSFER-JAPANESE RESEARCH), Issue 4 2006Ryuji Yamakita Abstract A fundamental understanding of the physical properties of a micro plastic-resin particle subjected suddenly to hot combustion gas, such as the temperature history in the micro particle and its lifetime, is necessary for effectively realizing thermal recycling of recycled plastic resin. However, micro plastic particles have such small diameters, ranging from 100 µm to 200 µm, that the measurement of temperature histories within them is extremely difficult. In this paper, therefore, a spherically symmetric one-dimensional analysis is applied to the abrupt heating process of a micro plastic resin particle in a high temperature inert atmosphere. Variations of the temperature history and the lifetime with the ambient gas temperature and the initial particle diameter are numerically analyzed, by dividing the entire heating process into four independent periods; the solid heating period, the melting period, the liquid heating period, and the vaporization period. Effects of the Nusselt number on the particle lifetime are also discussed. It is found that, by suitably taking account of the influences of heat transfer properties, the proposed simplified analysis is useful for estimating the fundamental and overall temperature characteristics of a micro plastic resin particle under abrupt heating. © 2006 Wiley Periodicals, Inc. Heat Trans Asian Res, 35(4): 279,293, 2006; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/htj.20113 [source] Three-dimensional MRI mapping of minimum temperatures achieved in microwave and conventional food processingINTERNATIONAL JOURNAL OF FOOD SCIENCE & TECHNOLOGY, Issue 3 2001John R. Bows Microbiological assurance protocols for food preservation are based on the ,worst-case' slowest heating point within the food product. For conduction-limited processing, this leads to well-known overheating near surface regions of products, with resultant quality loss. For volumetric heating processes such as microwave heating, it is practically impossible to guarantee where the slowest heating point will be. Consequently, microwave heating regimes are generally excessive and product quality is often similar to conventional conduction-limited heating processes. It is well known that Magnetic Resonance Imaging (MRI) can provide three-dimensional (3D) images which quantify the spatial distribution of water in foods, and also that the MRI parameters of water are temperature dependent. The present study demonstrates that a combination of these two concepts has led to a new approach for the validation of thermal processing in food manufacture. The potential for on-line assurance of minimum and maximum temperatures for manufacture of microbiologically assured, minimally processed, high quality food is discussed. [source] Detergent and Sanitizer Stresses Decrease the Thermal Resistance of Enterobacter sakazakii in Infant Milk FormulaJOURNAL OF FOOD SCIENCE, Issue 3 2008T.M. Osaili ABSTRACT:, This study determined the effect of acid, alkaline, chlorine, and ethanol stresses on the thermal inactivation of Enterobacter sakazakii in infant milk formula. Unstressed or stressed cells were mixed with reconstituted powdered infant milk formula (PIMF) at temperatures between 52 and 58 °C for various time periods or mixed with PIMF prior to reconstitution with hot water between 50 and 100 °C. D - and z -values were determined using liner regression analysis. In general, detergent and sanitizer stresses decreased the thermal resistance of E. sakazakii in infant milk formula. The results of this study may be of use to regulatory agencies, manufacturers, and infant caregivers to design heating processes to eliminate E. sakazakii. [source] Speciation of zinc in secondary fly ashes of municipal solid waste at high temperaturesJOURNAL OF SYNCHROTRON RADIATION, Issue 4 2009Meijuan Yu The evaporation aerosols produced during the vitrification process of municipal solid waste incinerators (MSWI) fly ash represent a potential environmental risk owing to their high content of heavy metals. In this research, high-temperature heating processes were carried out on fly ashes collected from bag houses in a Chinese MSWI plant and the secondary fly ashes (SFA) were separately collected at three high temperatures (1273,K, 1423,K and 1523,K) below the melting range. Elemental analysis showed that high contents of both zinc and chlorine were present in these SFA samples and, according to the standard of the heavy metals industrial grade of ore, SFAs can be re-used as metallurgical raw materials or rich ore. Moreover, as shown by XAS analysis and for different high temperatures, zinc environments in the three SFA samples were characterized by the same local structure of the zinc chloride. As a consequence, a zinc recycling procedure can be easily designed based on the configuration information. [source] Heating effects of the matrix of experimentally shocked Murchison CM chondrite: Comparison with micrometeoritesMETEORITICS & PLANETARY SCIENCE, Issue 1 2007Naotaka TOMIOKA However, if a major fraction of micrometeorites are produced by impacts on porous asteroids, they may have experienced shock heating before contact with the Earth's atmosphere (Tomeoka et al. 2003). A transmission electron microscope (TEM) study of the matrix of Murchison CM chondrite experimentally shocked at pressures of 10,49 GPa shows that its mineralogy and texture change dramatically, mainly due to shock heating, with the progressive shock pressures. Tochilinite is completely decomposed to an amorphous material at 10 GPa. Fe-Mg serpentine is partially decomposed and decreases in amount with increasing pressure from 10 to 30 GPa and is completely decomposed at 36 GPa. At 49 GPa, the matrix is extensively melted and consists mostly of aggregates of equigranular grains of Fe-rich olivine and less abundant low-Ca pyroxene embedded in Si-rich glass. The mineralogy and texture of the shocked samples are similar to those of some types of micrometeorites. In particular, the samples shocked at 10 and 21 GPa are similar to the phyllosilicate (serpentine)-rich micrometeorites, and the sample shocked at 49 GPa is similar to the olivine-rich micrometeorites. The shock heating effects also resemble the effects of pulse-heating experiments on the CI and CM chondrite matrices that were conducted to simulate atmospheric entry heating. We suggest that micrometeorites derived from porous asteroids are likely to go through both shock and atmospheric-entry heating processes. [source] A study of Mg and K isotopes in Allende CAIs: Implications to the time scale for the multiple heating processesMETEORITICS & PLANETARY SCIENCE, Issue 12 2006Motoo Ito The 7R-19,1 contains 16O-rich and 16O-poor melilite grains and define a single isochron corresponding to an initial 26Al/27Al ratio of (6.6 ± 1.3) × 10,5. The Al-Mg isochron, O isotope measurements and petrography of melilite in 7R-19,1 indicate that 16O-poor melilite crystallized within 0.4 Myr after crystallization of 16O-rich melilite, suggesting that oxygen isotopic composition of the CAI-forming region changed from 16O-rich to 16O-poor within this time interval. The 16O-poor melilite is highly depleted in K compared to the adjacent 16O-rich melilite, indicating evaporation during remelting of 7R-19,1. We determined the isochron for 41Ca- 41K isotopic systematics in EGG3 pyroxene with (4.1 ± 2.0) × 10,9 (2s,) as an initial ratio of 41Ca/40Ca, which is at least two times smaller than the previous result (Sahijipal et al. 2000). The ratio of 41Ca/40Ca in the EGG3 pyroxene grain agrees within error with the value obtained by Hutcheon et al. (1984). No evidence for the presence of 41K excess (decay product of a short-lived radionuclide 41Ca) was found in 7R-19,1 and HN3,1. We infer that the CAI had at least an order of magnitude lower than canonical 41Ca/40Ca ratio at the time of the CAI formation. [source] | |||||||||||||||||||||||||