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Heterogeneous Surface (heterogeneous + surface)

Distribution by Scientific Domains
Chemistry40%

Selected Abstracts

Aircraft observations of the atmospheric boundary layer over a heterogeneous surface in eastern Siberia

HYDROLOGICAL PROCESSES, Issue 14 2003
T. Hiyama
Abstract This paper outlines specifications and gives preliminary results of aircraft observations made during the Intensive Observation Period in 2000 (IOP2000) over the Yakutsk area of eastern Siberia. The observations were part of the GAME-Siberia project. Spatial and seasonal variation in the fluxes of sensible heat, latent heat, and carbon dioxide were determined using a Russian aircraft equipped with turbulence sensors. Two flight paths covered 12 × 32 km2 grids over heterogeneous forest and grass surfaces on the left- and right-hand banks of the Lena River. The spatial flux distributions were consistent with the underlying vegetation cover. A video camera recorded aerial images of the land, while a spectrometer observed the spectral reflectance of the land surface. These data helped describe the relationship between the atmosphere and the land surface. The vertical structure of the atmospheric boundary layer (ABL) was also observed on long flight paths between the left and right banks of the Lena River. Thermally induced internal boundary layers (TIBLs) developed in the ABL under different thermal and dynamic conditions near the Lena River. The horizontal and vertical distributions of sensible and latent heats in the ABL were consistent with the generation of cumulus, which appeared over the forested area, but not over the Lena River lowland. Copyright © 2003 John Wiley & Sons, Ltd. [source]

Application of heterogeneous adsorbents in removal of dimethyl phthalate: Equilibrium and heat

AICHE JOURNAL, Issue 10 2010
Jun Wu
Abstract Aminated resin (NDA-101) and oxidized resin (NDA-702) were synthesized to remove Dimethyl phthalate (DMP) from the contaminated water. The equilibrium and heat properties in the course of adsorption process were examined and compared with two commercial heterogeneous adsorbents, namely an acrylic ester resin (Amberlite XAD-7) and a coal-based granular activated carbon (AC-750). The associated equilibrium isotherms can be well fitted by Freundlich equation and the adsorption capacities for DMP followed the order: NDA-702 > NDA-101 > AC-750 > XAD-7. The surface of XAD-7 was demonstrated to be relatively homogeneous through surface energy heterogeneity analysis, offering the sole hydrogen bonding interaction. Contrarily, heterogeneous surface of oxidized resins NDA-702 and the aminated resins NDA-101 exhibited a promising adsorption capacity and affinity toward DMP probably derived by multiple hydrogen bonding, ,,, stacking, and micropore filling interactions. © 2010 American Institute of Chemical Engineers AIChE J, 2010 [source]

Equilibrium and heat of adsorption of phosphine on CaCl2 -modified molecular sieve

ASIA-PACIFIC JOURNAL OF CHEMICAL ENGINEERING, Issue 5 2009
Qiongfen Yu
Abstract Adsorption characteristics of the virgin and CaCl2 -immersed molecular sieves at 298 K were investigated to select the adsorbent with high adsorption capacity to phosphine. Adsorption isobars and adsorption isotherms over the phosphine partial pressure and temperature ranged 0 , 1000 Pa and 298 , 343 K were measured. The adsorption equilibrium data for phosphine at various temperatures were fitted to Langmuir and Freundlich isotherm models and their isosteric heats of adsorption were determined by the Clausius-Clapeyron equation. It was found the Freundlich was more suitable for description of phosphine adsorption process through calculating average absolute relative error, and the fitted result about Langmuir model showed the heterogeneous characteristics of modified adsorbent. The isosteric heat of adsorption was about 15 kJ/mol, which indicated adsorptive phosphine removal performance may be a dominant of physical adsorption being easy for desorption. The isosteric heat of adsorption decreased with an increase of the surface loading on CaCl2/5A, which means that CaCl2/5A molecular sieve had an energetically heterogeneous surface. The present study confirmed that the CaCl2/5A molecular sieves would be one of the candidates for separation and recycle of phosphine. Copyright © 2009 Curtin University of Technology and John Wiley & Sons, Ltd. [source]

Nanotribology , Fundamental Studies of Friction and Plasticity,

ADVANCED ENGINEERING MATERIALS, Issue 5 2010
Roland Bennewitz
Nanotribology explores the mechanical properties of materials at small length scales, where deviations from the scaling laws of macroscopic descriptions are observed. Atomic force microscopy is introduced as an important instrument in nanotribology for imaging friction contrasts on heterogeneous surfaces, for quantitative friction studies, and for the observation of single dislocation processes in plastic deformation. Recent experimental results for the frictional properties of carbon-based materials are discussed. Friction studies using microstructured surfaces are presented as an attempt to bridge the gap between nanotribological and macroscopic friction studies. [source]

Sensitivity of an Arctic regional climate model to the horizontal resolution during winter: implications for aerosol simulation

INTERNATIONAL JOURNAL OF CLIMATOLOGY, Issue 11 2005
Eric Girard
Abstract Our ability to properly simulate current climate and its future change depends upon the exactitude of the physical processes that are parameterized on the one hand, and on model configuration on the other hand. In this paper, we focus on the latter and investigate the effect of the horizontal grid resolution on the simulation of a month of January over the Arctic. A limited-area numerical climate model is used to simulate the month of January 1990 over a grid that includes the Arctic and sub-Arctic regions. Two grid resolutions are used: 50 km and 100 km. Results show that finer details appear for regional circulation, temperature, and humidity when increasing horizontal resolution. This is particularly true for continental and sea ice boundaries, which are much better resolved by high-resolution model simulations. The Canadian Archipelago and rivers in northern Russia appear to benefit the most from higher horizontal resolution. High-resolution simulations capture some frozen rivers and narrow straits between islands. Therefore, much colder surface air temperature is simulated over these areas. Precipitation is generally increased in those areas and over topography due to a better representation of surface heterogeneities when increasing resolution. Large-scale atmospheric circulation is substantially changed when horizontal resolution is increased. Feedback processes occur between surface air temperature change over heterogeneous surfaces and atmospheric circulation. High-resolution simulations develop a stronger polar vortex. The mean sea-level pressure increases over the western Arctic and Iceland and decreases over the eastern Arctic. This circulation leads to a substantial cooling of the eastern Arctic and enhanced synoptic activity over the Arctic associated with an intensification of the baroclinic zone. Aerosol mass loading, which is simulated explicitly in this model, is significantly altered by the grid resolution change with the largest differences in aerosol concentration over areas where precipitation and atmospheric circulation are the most affected. The implications of this sensitivity study to the evaluation of indirect radiative effects of anthropogenic aerosols are discussed. Copyright © 2005 Royal Meteorological Society. [source]