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Hard Phases (hard + phase)

Distribution by Scientific Domains

Engineering	66%
Polymers and Materials Science	33%

Selected Abstracts

Thermoplastic Polyurethanes with Poly(butylene terephthalate) as Crystallizable Hard Phase

MACROMOLECULAR MATERIALS & ENGINEERING, Issue 3 2008
Debasish De
Abstract Polyurethanes were prepared from poly(tetramethylene oxide) end-capped with MDI and PBT extenders. The PBT extenders were random-disperse in length and their length varied from three to seven repeating units. The structure of the polyurethanes was studied by FT-IR and AFM, their thermal and thermomechanical responses were measured by DSC and DMTA, and their elastic behavior was assessed by compression set measurements. The MDI-PBT-MDI hard segments had a ribbon-like crystalline morphology. Increasing the PBT length gave rise to an increase of the storage modulus at room temperature and the melting point. The storage modulus depended strongly on temperature. [source]

A new Cosserat-like constitutive model for bedded salt rocks

INTERNATIONAL JOURNAL FOR NUMERICAL AND ANALYTICAL METHODS IN GEOMECHANICS, Issue 15 2009
Yin-Ping Li
Abstract Salt rocks are commonly used as geologic host rocks for storage of gas and crude oil, and are being considered for the disposal of radioactive waste. Different from the salt rock domes in many countries, the salt rock formations in China are usually laminar with many alternating layers, i.e. rock salt, anhydrite, and/or mudstone. Considering the unique stratigraphic characteristics of these salt rocks, a new Cosserat-like medium constitutive model is proposed in order to facilitate efficient modeling of the mechanical behavior of these formations. In this model, a new representative volume element, containing two different layers, is employed to simulate the compatibility of the meso-displacement between two different layers and also the bending effect. A new method for the deformation and failure analysis of bedded salt rocks is derived therefrom. Having the macro-average stresses, the conventional stresses in the different layers can be obtained in sequence. The conventional stresses can then be utilized in a routine way for the strength and failure analysis. For the initial numerical modeling, the new Cosserat-like medium is reduced to a transversely isotropic one. The simplified constitutive model for layered media is then implemented into FLAC3D codes. A test sample validates that the results by using the numerical model are in good agreement with that by using the built-in model, and the mesh size for the new model is reduced greatly. Finally, an application for the stability of oil storage caverns in deep thinly bedded salt rocks is carried out. The effects on convergence of storage caverns and on the failure of surrounding rock due to the presence of the mudstone interlayers (hard phase) are discussed in detail. Copyright © 2009 John Wiley & Sons, Ltd. [source]

Vacuum tribological behaviour of self-lubricating quasicrystalline composite coatings

LUBRICATION SCIENCE, Issue 2 2004
F. J. Ía Garc de Blas
Abstract High-temperature-resistant self-lubricating coatings are needed in space vehicles for components that operate at high temperatures and/or under vacuum. Thick composite lubricant coatings containing quasicrystalline alloys as the hard phase for wear resistance can be deposited by a thermal spray technique. The coatings also contain lubricating materials (silver and BaF2CaF2 eutectic) and NiCr as the tough component. This paper describes the vacuum tribological properties of TH103, a coating of this type, with a very good microstructural quality. The coating was deposited by high-velocity oxygen fuel spraying and tested under vacuum using a pin-on-disc tribometer. Different loads, linear speeds, and pin materials were studied. The pin scars and disc wear tracks were characterised using a combination of scanning electron microscopy and energy dispersive spectrometry. A minimum mean steady friction coefficient of 0.32 was obtained when employing an X750 Ni superalloy pin in vacuum conditions under 10 N load and 15 cm/s linear speed, showing moderate wear of the disc and low wear of the pin. [source]

New Routes for Fabricating Ultrafine-Grained Microstructures in Bulky Steels without Very-High Strains,

ADVANCED ENGINEERING MATERIALS, Issue 8 2010
Nobuhiro Tsuji
Abstract Several routes to produce ultrafine-grained structures in steels without severe plastic deformation are introduced. The key point of the ideas is to combine plastic deformation with the phase transformation of matrix phases. When as-quenched martensite in steels is used as a starting microstructure, sub-micrometer grain-sized structures can be obtained easily. Another example using a dual-phase steel composed of soft and hard phases is also discussed. Repeating plastic deformation and phase transformation is also effective in obtaining nanostructures in an austenitic stainless steel. Examples of strips of UFG stainless steels in industry and their applications are presented. [source]

The comparison of wear properties of different Fe-based hardfacing alloys in four kinds of testing methods

LUBRICATION SCIENCE, Issue 4 2008
E. Badisch
Abstract Iron-based hardfacing alloys are widely used to protect machinery equipment. A strong correlation is given between microstructure and chemical composition of welding deposit with the resulting wear behaviour. Concerning precipitation of metallurgical hard phases and synthetic added hard particles, the bonding strength of the hard phases in the metallic matrix seems to play a dominating role to obtain high wear resistance. The main objective of this study was to evaluate the wear behaviour for pure abrasion, combined impact/abrasion and high impact wear, respectively, for four different Fe-based hardfacing alloys. Tests were performed with a standard ASTM G65 dry-sand/rubber-wheel tester. An impeller,tumbler apparatus enabled investigation of impact abrasion wear tests. Additional wear tests with high impact loading were performed on a drop hammer apparatus. Fracture surface analysis was carried out after drop hammer testing and results were correlated with microstructure and interfacial bonding behaviour of precipitations in metallic matrix. Copyright © 2008 John Wiley & Sons, Ltd. [source]