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Selected AbstractsSynthetic Explorations Towards Sterically Crowded 1,2,3-Substituted Bis(indenyl)zirconium(IV) DichloridesEUROPEAN JOURNAL OF INORGANIC CHEMISTRY, Issue 9 2005Andreas C. Möller Abstract The systematic synthesis of 1,3-dialkyl-substituted 2-silylindenes and their suitability as zirconocene ligands is discussed. Unexpected reactivities rendered a number of substitution patterns unfeasible, especially for alkyl groups other than methyl in 2-(trimethylsilyl)indene derivatives, and essentially for all derivatives of 2-(dimethylsilyl)indene. The syntheses of rac/meso -bis[1-methyl-2-(trimethylsilyl)indenyl]zirconium(IV) dichloride (12) and bis[1,3-dimethyl-2-(trimethylsilyl)indenyl]zirconium(IV) dichloride (13b) are described. The solid-state structure of the latter displays strong deformations within the ligand framework and an unusually large Cpcentroid -Zr,Cpcentroid angle. Both, 12/MAO and 13b/MAO, displayed ethene and ethene-co-1-hexene polymerization activity. Curiously, 13b/MAO shows an extraordinary monomer selectivity, which can be rationalized by means of DFT calculations on the active site. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005) [source] Abolishing the Tax-Free Threshold in Australia: Simulating Alternative Reforms,FISCAL STUDIES, Issue 2 2009John Creedy H24; H31 Abstract This paper examines the role of the tax-free income tax threshold in a complex tax and transfer system consisting of a range of taxes and benefits, each with its own taper rates and thresholds. Considering a tax and benefit system with benefit taper rates whereby some benefits are received by income groups other than those at the bottom of the distribution, it is suggested that a tax-free threshold is not a necessary requirement to achieve redistribution. Four alternative policy changes, each involving the elimination of the tax-free threshold in Australia and designed to achieve approximate revenue neutrality, were examined using the Melbourne Institute Tax and Transfer Simulator. A range of implications were examined, including labour supply responses to tax changes and the effects of policy changes on inequality and social welfare. The results demonstrate that it is possible to eliminate the tax-free threshold under approximate overall revenue and distribution neutrality, but that it is impossible to improve labour supply incentives at the same time. In order to achieve improved incentives, either revenue or distribution neutrality has to be sacrificed. [source] Development of Geriatric Competencies for Emergency Medicine Residents Using an Expert Consensus ProcessACADEMIC EMERGENCY MEDICINE, Issue 3 2010Teresita M. Hogan MD Abstract Background:, The emergency department (ED) visit rate for older patients exceeds that of all age groups other than infants. The aging population will increase elder ED patient utilization to 35% to 60% of all visits. Older patients can have complex clinical presentations and be resource-intensive. Evidence indicates that emergency physicians fail to provide consistent high-quality care for elder ED patients, resulting in poor clinical outcomes. Objectives:, The objective was to develop a consensus document, "Geriatric Competencies for Emergency Medicine Residents," by identified experts. This is a minimum set of behaviorally based performance standards that all residents should be able to demonstrate by completion of their residency training. Methods:, This consensus-based process utilized an inductive, qualitative, multiphase method to determine the minimum geriatric competencies needed by emergency medicine (EM) residents. Assessments of face validity and reliability were used throughout the project. Results:, In Phase I, participants (n = 363) identified 12 domains and 300 potential competencies. In Phase II, an expert panel (n = 24) clustered the Phase I responses, resulting in eight domains and 72 competencies. In Phase III, the expert panel reduced the competencies to 26. In Phase IV, analysis of face validity and reliability yielded a 100% consensus for eight domains and 26 competencies. The domains identified were atypical presentation of disease; trauma, including falls; cognitive and behavioral disorders; emergent intervention modifications; medication management; transitions of care; pain management and palliative care; and effect of comorbid conditions. Conclusions:, The Geriatric Competencies for EM Residents is a consensus document that can form the basis for EM residency curricula and assessment to meet the demands of our aging population. ACADEMIC EMERGENCY MEDICINE 2010; 17:316,324 © 2010 by the Society for Academic Emergency Medicine [source] The black,white "achievement gap" as a perennial challenge of urban science education: A sociocultural and historical overview with implications for research and practice,JOURNAL OF RESEARCH IN SCIENCE TEACHING, Issue 10 2001Obed Norman A perennial challenge for urban education in the United States is finding effective ways to address the academic achievement gap between African American and White students. There is widespread and justified concern about the persistence of this achievement gap. In fact, historical evidence suggests that this achievement gap has existed at various times for groups other than African Americans. What conditions prevailed when this achievement gap existed for these other groups? Conversely, under what conditions did the gap diminish and eventually disappear for these groups? This article explores how sociocultural factors involved in the manifestation and eventual disappearance of the gap for these groups may shed some light on how to address the achievement gap for African American students in urban science classrooms. Our conclusion is that the sociocultural position of groups is crucial to understanding and interpreting the scholastic performance of students from various backgrounds. We argue for a research framework and the exploration of research questions incorporating insights from Ogbu's cultural, ecological theory, as well as goal theory, and identity theory. We present these as theories that essentially focus on student responses to societal disparities. Our ultimate goal is to define the problem more clearly and contribute to the development of research-based classroom practices that will be effective in reducing and eventually eliminating the achievement gap. We identify the many gaps in society and the schools that need to be addressed in order to find effective solutions to the problem of the achievement gap. Finally, we propose that by understanding the genesis of the gap and developing strategies to harness the students' responses to societal disparities, learning can be maximized and the achievement gap can be significantly reduced, if not eliminated entirely, in urban science classrooms. © 2001 John Wiley & Sons, Inc. J Res Sci Teach 38: 1101,1114, 2001 [source] Culture and Women's SexualitiesJOURNAL OF SOCIAL ISSUES, Issue 2 2000Evelyn Blackwood Anthropological studies of women's same-sex relations in non-Western societies provide an important source for theorizing women's sexuality because they allow us to go beyond a narrow focus on Western cultures and concepts. Looking at studies from groups other than the dominant societies of Europe and America, I explore the diversity of women's sexualities and the sociocultural factors that produce sexual beliefs and practices. This article argues that sexual practices take their meaning from particular cultures and their beliefs about the self and the world. Cultural systems of gender, in particular, construct different sexual beliefs and practices for men and women. I conclude the article by suggesting some broad patterns at work in the production of women's sexualities across cultures. [source] Spontaneously changing muscular activation pattern in patients with cervical dystoniaMOVEMENT DISORDERS, Issue 6 2001A. Münchau MD Abstract The objective of this study was to determine stability of the neck muscle activation pattern in a given dystonic head position in patients with cervical dystonia (CD). We assessed 26 patients with CD and botulinum toxin (BT) treatment failure before surgical denervation. None of them had received BT injections for at least 4 months. To relate dystonic head position to underlying neck muscle activity, we used synchronised video and poly-electromyographic (EMG) recording over a period of 10 minutes. The muscle activation pattern during constant ("stable") maximal dystonic excursions was analysed. EMG data of nine patients was excluded from the analysis, as these patients had a constantly changing head position or marked head tremor. In the remaining 17 patients, who had a fairly stable dystonic position, muscular activation patterns during the recording spontaneously changed in nine (Group A) while in eight it remained stable (Group B). There was no significant difference in demographic variables between the two groups other than a male predominance in Group A. However, the retrospectively determined initial response to BT treatment (before BT treatment failure had occurred) was significantly worse in Group A as compared with Group B. Neck muscle activation patterns can spontaneously change in CD patients despite constant dystonic head position, implying an inherent variability of the underlying central motor program in some patients. This should be considered when BT treatment response is unsatisfactory, and should also be taken into account when interpreting results of EMG recordings of neck muscles in these patients. © 2001 Movement Disorder Society. [source] Recent trends and racial/ethnic differences in the incidence and treatment of ductal carcinoma in situ of the breast in California women ,CANCER, Issue 4 2003Kaire Innos M.D., Ph.D. Abstract BACKGROUND The rapid increase in the incidence of ductal carcinoma in situ (DCIS) of the breast in the U.S. has been associated with the widespread adoption of screening mammography. Little is known regarding the incidence and treatment of DCIS in women of racial/ethnic groups other than white and black. The current investigation examined recent trends and racial/ethnic differences in the incidence and treatment of DCIS in California. METHODS All cases of DCIS diagnosed in women age , 40 years in California between 1988,1999 were included. Age-adjusted incidence rates for white, black, Hispanic, and Asian-Pacific Islander women were calculated using the 2000 U.S. female population as the standard. The estimated annual percent change (EAPC) in the rates was calculated using least squares regression. RESULTS The average annual age-adjusted incidence of DCIS (1988,1999) was 45.3 per 100,000 in white women, 35.0 in black women, 30.9 in Asian-Pacific Islander women, and 21.8 in Hispanic women. Although a steady increase in the incidence of DCIS was noted in all racial/ethnic groups over the study period, Asian-Pacific Islander women were found to have experienced the steepest increase (EAPC = 9.1%), particularly in the age group 50,64 years (EAPC = 12.0%). The DCIS incidence was reported to increase with age in white, black, and Hispanic women, but remained fairly constant after the age of 50 years in Asian-Pacific Islanders. The proportion of women with DCIS treated with mastectomy decreased from 53% in 1988 to 32% in 1999. Younger women and Asian-Pacific Islander women reportedly were more likely to undergo mastectomy. CONCLUSIONS Considerable differences by race/ethnicity and age were observed in DCIS incidence and the change in the incidence in California between 1988 and 1999. Further information is needed to determine whether these differences are because of differential utilization of screening mammography or biologic characteristics of DCIS lesions. Cancer 2003;97:1099,106. © 2003 American Cancer Society. DOI 10.1002/cncr.11104 [source] Prevalence of Japanese cedar pollinosis in Tokyo: a survey conducted by the Tokyo Metropolitan GovernmentCLINICAL & EXPERIMENTAL ALLERGY REVIEWS, Issue 1 2010S. Nishihata Summary In 2006, a survey was conducted to estimate the prevalence of Japanese cedar pollinosis in three target areas in Tokyo, namely Akiruno-shi, Chofu-shi, and Ota-ku; this survey was similar to two surveys conducted previously, in 1983,1987 (first survey) and 1996 (second survey). In the most recent survey, the overall prevalence of Japanese cedar pollinosis in Tokyo, except the islands of Tokyo, was estimated as 28.2%. This prevalence rate exceeds that estimated by the first and second surveys by 18.2 and 8.8 percentage points, respectively. The prevalence of Japanese cedar pollinosis in the three survey target areas increased by 2.3,10.8 percentage points vs. the rates obtained in the second survey. Furthermore, differences among the prevalence rates in the three areas decreased. Compared with the results obtained in the second survey, increases in the prevalence rate were noted in all age groups other than in people aged 30,44 years. In particular, the prevalence rate in children aged 0,14 years increased markedly, showing a threefold increase. The prevalence rate exceeded 30% in all age groups between 15 and 59 years. [source] | ||||||||||