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Glass Phase (glass + phase)
Selected AbstractsExperimental Study of the Aging and Self-Healing of the Glass/Ceramic Sealant Used in SOFCsINTERNATIONAL JOURNAL OF APPLIED CERAMIC TECHNOLOGY, Issue 1 2010Wenning N. Liu High operating temperatures of solid oxide fuel cells (SOFCs) require that the sealant must function at a high temperature between 600°C and 900°C and in the oxidizing and reducing environments of fuel and air. This paper describes tests to investigate the temporal evolution of the volume fraction of ceramic phases, the evolution of micro-damage, and the self-healing behavior of the glass,ceramic sealant used in SOFCs. It was found that after the initial sintering process, further crystallization of the glass,ceramic sealant does not stop, but slows down and reduces the residual glass content while boosting the ceramic crystalline content. Under a long-term operating environment, distinct fibrous and needle-like crystals in the amorphous phase disappeared, and smeared/diffused phase boundaries between the glass phase and ceramic phase were observed. Meanwhile, the micro-damage was induced by the cooling down process from the operating temperature to room temperature, which can potentially degrade the mechanical properties of the glass/ceramic sealant. The glass/ceramic sealant exhibited self-healing upon reheating to the SOFC operating temperature, which can restore the mechanical performance of the glass/ceramic sealant. [source] Rapid and accurate quantitative phase analysis using a fast detectorJOURNAL OF APPLIED CRYSTALLOGRAPHY, Issue 1 2004A. F. Gualtieri The accuracy of the weight fractions calculated with the Rietveld method for various polycrystalline systems using data collected for very short times (5,45,min) with an RTMS (real-time multiple strip) detector was verified. The weight estimates were compared with those obtained using the same conventional Bragg,Brentano geometry, a gas proportional detector and a 13,h data acquisition. The analysed samples were monophasic and polyphasic mixtures with different degrees of complexity: the standard corundum NIST 676; a sample (labelled 1g) provided as a standard sample for the IUCr CPD Quantitative Phase Analysis Round Robin; a natural pyroclastic rock from Riano (Rome, Italy) containing zeolitic minerals and a glass phase; and a hydraulic lime. The results of the refinements show estimated weights consistent with both those obtained with a gas proportional detector and with the nominal values, indicating a very good accuracy. Only when variable slits are used, the accuracy of the estimated weights slightly decreases. The outcome of this work is a very important step forward towards fast and accurate QPA for production control and quality management, obtained by combining the use of a rapid detector and existing user-friendly software. [source] Lifetime prediction of CAD/CAM dental ceramics,JOURNAL OF BIOMEDICAL MATERIALS RESEARCH, Issue 6 2002Ulrich Lohbauer Abstract The dynamic fatigue method was used to obtain subcritical crack growth parameters n and A for a commercial feldspathic dental porcelain and for a lanthanum-glass-infiltrated alumina glass ceramic. Five stress rates d,/dt ranging from 50 to 0.01 MPa s,1 were applied. The inert strength values were calculated with the use of Weibull statistics and maximum-likelihood approaches for the Weibull parameter m. Strength,probability,time (SPT) diagrams were derived for both materials. The alumina glass composite showed a high fracture strength ,0 (442 MPa) at a failure probability of PF = 63.2% and a high resistance against subcritical crack growth (n = 36.5). The development of strength under fatigue conditions was calculated for exemplary 1 year. The strength of the alumina glass material dropped to 228 MPa within this period. This fact is due to a low content of infiltrated lanthanum glass phase in the composite material (25 wt%). In contrast, for the high-silica-glass-containing porcelain a distinct decrease of strength ,0 from initial 133 to 47 MPa after 1 year was predicted. This, mainly because of a low crack growth resistance (n = 16.8) of the feldspathic porcelain. Much lower strength values were calculated, assuming a failure probability of PF = 5%. The decrease is mainly caused by the sensitivity of high,glass-containing ceramics against water corrosion. © 2002 Wiley Periodicals, Inc. J Biomed Mater Res (Appl Biomater) 63: 780,785, 2002 [source] High-Temperature Oxidation Behavior of High-Purity ,-, ,-, and Mixed Silicon Nitride CeramicsJOURNAL OF THE AMERICAN CERAMIC SOCIETY, Issue 2 2002M. Backhaus-Ricoult High-temperature oxidation behavior, microstructural evolution, and oxidation kinetics of additive-free ,-, ,-, and mixed silicon nitride ceramics is investigated. The oxidation rate of the ceramics depends on the allotropic ratio; best oxidation resistance is achieved for ceramics rich in ,-phase. Variations in the oxidation kinetics are directly related to average grain size and glass distribution in the oxidation scale. The oxygen contents incorporated into the Si3N4 phase before its dissolution at the oxidation front affects the local glass composition and thereby yields nucleation and growth rates of SiO2 crystallites within the glass phase and a final oxidation scale microstructure, which depend on the incorporated oxygen contents. For the ,-polymorph, the dynamic oxygen solubility is found to remain negligible; therefore, a nitrogen-rich glass forms at the oxidation front, which promotes devitrification and yields a scale with small grain size and thin intergranular glass films. ,-Si3N4 is observed to form oxygen-rich solid solutions on oxidation, which are in contact with silicon oxynitride or oxygen-rich glass. Nucleation of cristobalite in the latter is sluggish, yielding coarse-grained oxidation scales with thick intergranular glass film. [source] Crystallization and Dielectric Properties of SrO,BaO,Nb2O5,SiO2 Tungsten-Bronze Glass-CeramicsJOURNAL OF THE AMERICAN CERAMIC SOCIETY, Issue 12 2000Jiin-Jyh Shyu The crystallization and dielectric properties of SrO,BaO,Nb2O5,SiO2 glass-ceramics have been investigated. Glass-ceramics that contain strontium barium niobate (SBN) as a primary crystalline phase, which has a tungsten bronze structure, are produced. The formation of crystalline secondary phases also has been studied. The SBN phase shows evidence of both surface nucleation and bulk nucleation, and the crystals have an average composition of Sr0.47Ba0.53Nb2O6. The dendritic morphology of the SBN crystals has been examined. The SBN content and composite dielectric constant each has been studied as a function of heating temperature/time. The highest SBN content and dielectric constant obtained in the present study are 42 vol% and 180, respectively. The dielectric constant of the glass-ceramics is determined primarily by the SBN content and the residual glass phase. The dielectric constant of the randomly oriented SBN crystal in the glass-ceramics is calculated, using dielectric mixture rules, to be ,400. [source] Forming Al2O3,Al Composites with Controlled Compositions by Reactive Metal Penetration of Dense Aluminosilicate PreformsJOURNAL OF THE AMERICAN CERAMIC SOCIETY, Issue 5 2000William G. Fahrenholtz Alumina,Al composites with controlled compositions containing 17 to 31 vol% Al were formed by reactive metal penetration (RMP) of molten Al into dense aluminosilicate preforms. A reaction model has been developed to accurately predict composite Al content from the SiO2:Al2O3 ratio of the preform. The model was tested and validated by comparing predicted composite compositions to those measured for RMP composites made from preforms of known compositions. Aluminosilicate preforms containing 28.1, 39.0, and 54.1 wt% SiO2 were reacted with Al to produce composites with 17, 25, and 31 vol% Al, respectively. These values compare favorably to Al contents of 17.7, 22.7, and 28.6 vol% Al predicted using the reaction model. The differences between predicted and measured values are attributed to the presence of porosity and Si in the composites, as well as impurities in the SiO2 glass phase and porosity in the preforms, none of which is specifically accounted for in the reaction model. [source] Grain-Boundary Viscosity of BaO-Doped SiCJOURNAL OF THE AMERICAN CERAMIC SOCIETY, Issue 3 2000Giuseppe Pezzotti Internal friction characterization of the viscosity of a residual SiO2/BaO glass, segregated to grain boundaries of polycrystalline SiC, is presented. The anelastic relaxation peak of internal friction, arising from viscous slip along grain boundaries wetted by a glass phase, is analyzed. Two SiC polycrystals, containing SiO2/BaO glasses with different compositions, are studied and compared with a SiC polycrystal containing only pure SiO2. The internal friction peak is first analyzed with respect to its shift upon frequency change. This analysis allows quantitative assessment of both the intrinsic viscosity and the activation energy for viscous flow of the grain-boundary phase. Both parameters markedly decrease with increasing amounts of BaO dopant, which is consistent with data reported in the literature on SiO2 and SiO2/BaO bulk glasses with the same nominal composition. Analysis of the peak morphology is also attempted, considering the evolution of peak width while varying the grain-boundary glass composition. Moreover, the role of microstructural parameters, such as the distributions of grain size and grain-boundary angles, on the broadening of the internal friction peak is addressed, and a procedure is proposed that allows quantitative evaluation of the activation energy for viscous flow of intergranular glass merely from the width of the internal friction peak. [source] Purely electronic transport and localization in the Bose glassANNALEN DER PHYSIK, Issue 12 2009M. Müller Abstract We discuss transport and localization properties on the insulating side of the disorder dominated superconductor-insulator transition, described in terms of the dirty boson model. Analyzing the spectral properties of the interacting bosons in the absence of phonons, we argue that the Bose glass phase admits three distinct regimes. For strongest disorder the boson system is a fully localized, perfect insulator at any temperature. At smaller disorder, only the low temperature phase exhibits perfect insulation while delocalization takes place above a finite temperature. We argue that a third phase must intervene between these perfect insulators and the superconductor. This conducting Bose glass phase is characterized by a mobility edge in the many body spectrum, located at finite energy above the ground state. In this insulating regime purely electronically activated transport occurs, with a conductivity following an Arrhenius law at asymptotically low temperatures, while a tendency to superactivation is predicted at higher T. These predictions are in good agreement with recent transport experiments in highly disordered films of superconducting materials. [source] Re-creation of the 1744 Heylyn and Frye ceramic patent wares using Cherokee clay: Implications for raw materials, kiln conditions, and the earliest English porcelain productionGEOARCHAEOLOGY: AN INTERNATIONAL JOURNAL, Issue 7 2004W.R.H. Ramsay Porcelain wares have been produced following the directions contained in the Heylyn and Frye patent of 1744, using Cherokee clay and a lime-alkali glass frit. The wares were fired to the bisque (, 950°C), glazed using a clay-glass mixture, and then fired to a "heat-work" level of Orton cone 9,90° deflection at 150°C per hour (1279°C). Modal mineralogy comprises Caplagioclase and two glass phases, one relict frit and the other a melt phase. The bulk chemistry of the body comprises 64.3 wt % SiO2, 21.7 wt % Al2O3, and 5.6 wt % CaO. Molecular ratios are SiO2:Al2O3 5.0 and SiO2:CaO 10.7. It is concluded that the patent, whose significance has been questioned over many years, was a practical working recipe, that close comparison may be made with porcelains of the "A"-marked group, and that the patent represents a remarkable landmark in English ceramic history. © 2004 Wiley Periodicals, Inc. [source] Subcritical crack growth behavior of Al2O3 -glass dental compositesJOURNAL OF BIOMEDICAL MATERIALS RESEARCH, Issue 2 2003Qingshan Zhu Abstract The purpose of this study is to investigate the subcritical crack growth (SCG) behavior of alumina-glass dental composites. Alumina-glass composites were fabricated by infiltrating molten glass to porous alumina preforms. Rectangular bars of the composite were subject to dynamic loading in air, with stressing rates ranging from 0.01 MPa/s to 2 MPa/s. The SCG parameter n was determined to be 22.1 for the composite, which is substantially lower than those of high-purity dense alumina. Investigations showed that glass phases are responsible for the low n value as cracks propagate preferentially within glass phases or along the interface between glass phases and alumina phases, due to the fact that glasses are more vulnerable to chemical attacks by water molecules under stress corrosion conditions. The SCG behavior of the infiltration glass was also investigated and the SCG parameter n was determined to be 18.7. © 2003 Wiley Periodicals, Inc. J Biomed Mater Res Part B: Appl Biomater 65B: 233,238, 2003 [source] Magnetic properties of MxTiSe2 (M = Mn, Fe, Co)PHYSICA STATUS SOLIDI (C) - CURRENT TOPICS IN SOLID STATE PHYSICS, Issue 8 2006Y. Tazuke Abstract Magnetic properties of MxTiSe2 with M = Mn, Fe and Co are studied experimentally. MnxTiSe2 (0 < x , 0.5) and CoxTiSe2 (0 < x , 0.3) exhibited spin glass phases. FexTiSe2 exhibited spin glass phases for 0 < x , 0.22, reentrant spin glass phases for 0.23 , x , 0.26 and antiferromagnetic phases for 0.28 , x , 0.5 Possibility of explaining the exchange interactions of FexTiSe2 by the Ruderman-Kittel-Kasuya-Yosida (RKKY) interactions is discussed. (© 2006 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) [source] | |||||||||||||