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General Process (general + process)
Selected AbstractsA General Process for the Fabrication of Air-Stable Metallic Particles (Cd, Zn and Al) by the Decomposition of Alkyl,Metal CompoundsEUROPEAN JOURNAL OF INORGANIC CHEMISTRY, Issue 15 2008Aharon Gedanken Abstract The thermolysis of alkyl,metal compounds under autogenic pressure, with the three metals Cd, Zn, and Al as examples, suggest that this might become a general method for preparing a composite where the metal is the core and carbon the shell. The air-stability of these composites is also demonstrated. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008) [source] TRAJECTORIES OF CRIME AT PLACES: A LONGITUDINAL STUDY OF STREET SEGMENTS IN THE CITY OF SEATTLE,CRIMINOLOGY, Issue 2 2004DAVID WEISBURD Studies of crime at micro places have generally relied on cross-sectional data and reported the distributions of crime statistics over short periods of time. In this paper we use official crime data to examine the distribution of crime at street segments in Seattle, Washington, over a 14-year period. We go beyond prior research in two ways. First, we view crime trends at places over a much longer period than other studies that have examined micro places. Second, we use group-based trajectory analysis to uncover distinctive developmental trends in our data. Our findings support the view that micro places generally have stable concentrations of crime events over time. However, we also find that a relatively small proportion of places belong to groups with steeply rising or declining crime trajectories and that these places are primarily responsible for overall city trends in crime. These findings are particularly important given the more general decline in crime rates observed in Seattle and many other American cities in the 1990s. Our study suggests that the crime drop can be understood not as a general process that occurred across the city landscape but one that was generated in a relatively small group of micro places with strong declining crime trajectories over time. [source] Elite hotels: painting a self-portraitINTERNATIONAL JOURNAL OF TOURISM RESEARCH, Issue 2 2001Cailein Gillespie Abstract Commercial hospitality provision arose from a general process of modernisation, the gradual breakdown of the importance of kinship and social obligation relative to a common duty of care for those travelling away from home, and the process of urbanisation. Consequently market demand evolved for the provision of accommodation, food and beverage for those persons temporarily removed from their domestic environment. What is argued in this paper is that the original function of commercial hospitality bears scant resemblance to sophisticated potentialities for socio-economic self-expression, which manifest themselves in the form of the elite hotel sector. The manner in which contemporary consumption of elite hotels revolves around the notion of self, with multiple identities and group affiliations is explored. Conclusions focus on the elite hotel sector as a means of defining self-identities and the management implications therein for the provision of commercial hospitality in elite hotels. Copyright © 2001 John Wiley & Sons, Ltd. [source] "Tel Aviv Is Not Foreign to You": Urban Incorporation Policy on Labor Migrants in Israel,INTERNATIONAL MIGRATION REVIEW, Issue 1 2004Adriana Kemp This article addresses the growing disjuncture between urban and national policies regarding the incorporation of labor migrants in Israel. Drawing on fieldwork, in-depth interviews with Tel Aviv municipal officials, and archive analysis of Tel Aviv municipality minutes, we argue that urban migrant-directed policy elicits new understandings of membership and participation, other than those envisaged by national parameters, which bear important, even if unintended, consequences for the de facto incorporation of non-Jewish labor migrants. The crux of the Tel Aviv case is that its migrant-directed policy bears especially on undocumented labor migrants, who make up approximately 16 percent of the city's population and who are the most problematic category of resident from the state's point of view. In demanding recognition for the rights of migrant workers in the name of a territorial category of "residence," and by activating channels of participation for migrant communities, local authorities in Tel Aviv are introducing definitions of "urban membership" for noncitizens which conflict sharply with the hegemonic ethnonational policy. We suggest that the disjuncture between urban and national incorporation policies on labor migrants in Israel is part of a general process of political realignment between the urban and the national taking place within a globalized context of labor migration. [source] Heterotachy and Functional Shift in Protein EvolutionIUBMB LIFE, Issue 4-5 2003Hervé Philippe Abstract Study of structure/function relationships constitutes an important field of research, especially for modification of protein function and drug design. However, the fact that rational design (i.e. the modification of amino acid sequences by means of directed mutagenesis, based on knowledge of the three-dimensional structure) appears to be much less efficient than irrational design (i.e. random mutagenesis followed by in vitro selection) clearly indicates that we understand little about the relationships between primary sequence, three-dimensional structure and function. The use of evolutionary approaches and concepts will bring insights to this difficult question. The increasing availability of multigene family sequences that has resulted from genome projects has inspired the creation of novel in silico evolutionary methods to predict details of protein function in duplicated (paralogous) proteins. The underlying principle of all such approaches is to compare the evolutionary properties of homologous sequence positions in paralogs. It has been proposed that the positions that show switches in substitution rate over time--i.e., 'heterotachous sites'--are good indicators of functional divergence. However, it appears that heterotachy is a much more general process, since most variable sites of homologous proteins with no evidence of functional shift are heterotachous. Similarly, it appears that switches in substitution rate are as frequent when paralogous sequences are compared as when orthologous sequences are compared. Heterotachy, instead of being indicative of functional shift, may more generally reflect a less specific process related to the many intra- and inter-molecular interactions compatible with a range of more or less equally viable protein conformations. These interactions will lead to different constraints on the nature of the primary sequences, consistently with theories suggesting the non-independence of substitutions in proteins. However, a specific type of amino acid variation might constitute a good indicator of functional divergence: substitutions occurring at positions that are generally slowly evolving. Such substitutions at constrained sites are indeed much more frequent soon after gene duplication. The identification and analysis of these sites by complementing structural information with evolutionary data may represent a promising direction to future studies dealing with the functional characterization of an ever increasing number of multi-gene families identified by complete genome analysis. IUBMB Life, 55: 257-265, 2003 [source] Pattern and process in Norwegian upland grasslands: a functional analysisJOURNAL OF VEGETATION SCIENCE, Issue 1 2002Vigdis Vandvik Lid & Lid (1994) Abstract. Four classes of functional and morphological plant traits , established strategies (the CSR scheme sensu Grime 1979), life-forms (sensu Raunkiaer 1934), morphology, and regenerative strategies , are used as tools for explaining vegetation gradients at summer farms in the mountains of western Norway. These farms are assembly points for free-ranging domestic grazers, and differ floristically and ecologically from the surrounding heath or woodland vegetation. DCA and TWINSPAN are used to relate major gradients in a floristic data set from 12 summer farms to two sets of explanatory variables: (1) environmental variables representing physical factors, plot position, soils, and land use, and (2) the 4 classification schemes. The main floristic gradient parallels a spatial gradient from the centres of the farms to the surrounding vegetation. A functional interpretation based on the concurrent use of the 2 sets of explanatory variables suggests that the gradient is one of decreasing disturbance and increasing environmental stress caused by decreasing grazing and manure effects away from farms. Partial CCA is used to investigate the relationships between the 4 functional/morphological plant trait classes. The 4 classification schemes are partially redundant, and do not represent different trends of specialization within the landscape. There is no strong evidence for decoupling of the traits of the vegetative and regenerative phases within the data. The combination of general process-based theories and specific plant attribute responses enhances the generality and interpretability of the study. [source] The Completely Decentralized City: The Case for Benefits Based Public FinanceAMERICAN JOURNAL OF ECONOMICS AND SOCIOLOGY, Issue 1 2001Fed E. Foldvary An alternative to centralized top-down city governance is a multi-level bottom-up structure based on small neighborhood contractual communities. This paper analyzes the voting rules and public finances of decentralized, contractual urban governance and the likely outcome of such a constitutional structure, substantially reduced transfer seeking or rent seeking. Tax and service substitution, with lower-level funding and services substituting for higher-level public finance, is the general process by which the governance would devolve. Land rent is the most feasible source of such decentralized public finance, and local communities could also engage in local currency and credit services. Some empirical examples demonstrate the implementation of some of these governance structures. [source] The evolution of intelligence: adaptive specializations versus general processBIOLOGICAL REVIEWS, Issue 3 2001EUAN M. MAGPHAIL ABSTRACT Darwin argued that between-species differences in intelligence were differences of degree, not of kind. The contemporary ecological approach to animal cognition argues that animals have evolved species-specific and problem-specific processes to solve problems associated with their particular ecological niches: thus different species use different processes, and within a species, different processes are used to tackle problems involving different inputs. This approach contrasts both with Darwin's view and with the general process view, according to which the same central processes of learning and memory are used across an extensive range of problems involving very different inputs. We review evidence relevant to the claim that the learning and memory performance of non-human animals varies according to the nature of the stimuli involved. We first discuss the resource distribution hypothesis, olfactory learning-set formation, and the ,biological constraints' literature, but find no convincing support from these topics for the ecological account of cognition. We then discuss the claim that the performance of birds in spatial tasks of learning and memory is superior in species that depend heavily upon stored food compared to species that either show less dependence upon stored food or do not store food. If it could be shown that storing species enjoy a superiority specifically in spatial (and not non-spatial) tasks, this would argue that spatial tasks are indeed solved using different processes from those used in non-spatial tasks. Our review of this literature does not find a consistent superiority of storing over non-storing birds in spatial tasks, and, in particular, no evidence of enhanced superiority of storing species when the task demands are increased, by, for example, increasing the number of items to be recalled or the duration of the retention period. We discuss also the observation that the hippocampus of storing birds is larger than that of non-storing birds, and find evidence contrary to the view that hippocampal enlargement is associated with enhanced spatial memory; we are, however, unable to suggest a convincing alternative explanation for hippocampal enlargement. The failure to find solid support for the ecological view supports the view that there are no qualitative differences in cognition between animal species in the processes of learning and memory. We also argue that our review supports our contention that speculation about the phylogenetic development and function of behavioural processes does not provide a solid basis for gaining insight into the nature of those processes. We end by confessing to a belief in one major qualitative difference in cognition in animals: we believe that humans alone are capable of acquiring language, and that it is this capacity that divides our intelligence so sharply from non-human intelligence. [source] The Zirconium Alkoxide-Catalyzed Aldol-Tishchenko Reaction of Ketone AldolsCHEMISTRY - A EUROPEAN JOURNAL, Issue 10 2005Christoph Schneider Prof. Dr. Abstract The aldol-Tishchenko reaction of ketone aldols as enol equivalents has been developed as an efficient strategy to furnish differentiated 1,3- anti -diol monoesters in one step. The thermodynamically unstable ketone aldols undergo a facile retro-aldolization to yield a presumed zirconium enolate in situ, which then undergoes the aldol-Tishchenko reaction in typically high yields and with complete 1,3- anti diastereocontrol. Evaluation of a broad range of metal alkoxides as catalysts and optimization of the reaction protocol led to a modified zirconium alkoxide catalyst with attenuated Lewis acidity and dichloromethane as solvent, which resulted in suppression of the undesired acyl migration to a large extent. Various ketone aldols have been prepared and subjected to the general process, giving rise to a broad range of differently substituted 1,3- anti -diol monoesters, which may be hydrolyzed to the corresponding 1,3- anti -diols. [source] The intersensory origins of word-comprehension: an ecological,dynamic systems viewDEVELOPMENTAL SCIENCE, Issue 1 2001Lakshmi J. Gogate How do infants begin to understand spoken words? Recent research suggests that word comprehension develops from the early detection of intersensory relations between conventionally paired auditory speech patterns (words) and visible objects or actions. More importantly, in keeping with dynamic systems principles, the findings suggest that word comprehension develops from a dynamic and complementary relationship between the organism (the infant) and the environment (language addressed to the infant). In addition, parallel findings from speech and non-speech studies of intersensory perception provide evidence for domain general processes in the development of word comprehension. These research findings contrast with the view that a lexical acquisition device with specific lexical principles and innate constraints is required for early word comprehension. Furthermore, they suggest that learning of word,object relations is not merely an associative process. The data support an alternative view of the developmental process that emphasizes the dynamic and reciprocal interactions between general intersensory perception, selective attention and learning in infants, and the specific characteristics of maternal communication. [source] Differential activity in left inferior frontal gyrus for pseudowords and real words: An event-related fMRI study on auditory lexical decisionHUMAN BRAIN MAPPING, Issue 2 2005Zhuangwei Xiao Abstract After Newman and Twieg ([2001]: Hum Brain Mapp 14:39,47) and others, we used a fast event-related functional magnetic resonance imaging (fMRI) design and contrasted the lexical processing of pseudowords and real words. Participants carried out an auditory lexical decision task on a list of randomly intermixed real and pseudo Chinese two-character (or two-syllable) words. The pseudowords were constructed by recombining constituent characters of the real words to control for sublexical code properties. Processing of pseudowords and real words activated a highly comparable network of brain regions, including bilateral inferior frontal gyrus, superior, middle temporal gyrus, calcarine and lingual gyrus, and left supramarginal gyrus. Mirroring a behavioral lexical effect, left inferior frontal gyrus (IFG) was significantly more activated for pseudowords than for real words. This result disconfirms a popular view that this area plays a role in grapheme-to-phoneme conversion, as such a conversion process was unnecessary in our task with auditory stimulus presentation. An alternative view was supported that attributes increased activity in left IFG for pseudowords to general processes in decision making, specifically in making positive versus negative responses. Activation in left supramarginal gyrus was of a much larger volume for real words than for pseudowords, suggesting a role of this region in the representation of phonological or semantic information for two-character Chinese words at the lexical level. Hum Brain Mapp 25:212,221, 2005. © 2005 Wiley-Liss, Inc. [source] Where do the feral oilseed rape populations come from?JOURNAL OF APPLIED ECOLOGY, Issue 2 2008A large-scale study of their possible origin in a farmland area Summary 1Many cultivated species can escape from fields and colonize seminatural habitats as feral populations. Of these, feral oilseed rape is a widespread feature of field margins and roadside verges. Although considered in several studies, the general processes leading to the escape and persistence of feral oilseed rape are still poorly known. Notably, it remains unclear whether these annuals form transient populations resulting mainly from seed immigration (either from neighbouring fields or during seed transport), or whether they show real ability to persist (either through self-recruitment or seed banks). 2We conducted a 4-year large-scale study of factors involved in the presence of feral oilseed rape populations in a typical open-field area of France. The results were subjected to statistical methods suitable for analysing large data sets, based on a regression approach. We subsequently addressed the relative contribution of the ecological processes identified as being involved in the presence of feral populations. 3Many feral oilseed rape populations resulted from seed immigration from neighbouring fields (about 35,40% of the observed feral populations). Immigration occurred at harvest time rather than at sowing. Around 15% of such populations were attributed to immigration through seed transport. 4The other half resulted from processes of persistence, mainly through persistent seed banks (35,40% of the observed feral populations). This was all the more unexpected because seed banks have not yet been documented on road verges (despite being frequent within fields). Local recruitment was rare, accounting for no more than 10% of the feral populations. 5Synthesis and applications. Understanding the dynamics of feral oilseed rape populations is crucial for evaluating gene flow over an agro-ecosystem. Our results show that, while many feral populations do come from annual seed dispersal, a significant number also result from seeds stored in the soil for several years. In the current context of coexistence and management of transgenic with non-transgenic crops, feral persistence and, especially, the seed bank contribution to the dynamics of feral populations need to be considered seriously. The latter, combined with self-recruitment, indicates a high potential for the persistence of transgenes and the possible emergence of gene-stacking. [source] Tests of a Dynamic Systems Account of the A-not-B Error: The Influence of Prior Experience on the Spatial Memory Abilities of Two-Year-OldsCHILD DEVELOPMENT, Issue 5 2001John P. Spencer Recently, Smith, Thelen, and colleagues proposed a dynamic systems account of the Piagetian "A-not-B" error in which infants' errors result from general processes that make goal-directed actions to remembered locations. Based on this account, the A-not-B error should be a general phenomenon, observable in different tasks and at different points in development. Smith, Thelen, et al.'s proposal was tested using an A-not-B version of a sandbox task. During three training trials and three "A" trials, 2-year-olds watched as a toy was buried in a sandbox at Location A. Following a 10-s delay, children searched for the object. Across five experiments, children's (total N= 92) performance on the A trials was accurate. After the A trials, children watched as a toy was hidden at Location B, 8 to 10 inches from Location A. In all experiments, children's searches after a 10-s delay were significantly biased in the direction of Location A. Furthermore, this bias toward Location A decreased with repeated trials to Location B, as well as when children completed fewer trials to Location A. Together, these data suggest that A-not-B,type errors are pervasive across tasks and development. [source] | |||||||||||||||||||