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Geochemical Processes (geochemical + process)

Distribution by Scientific Domains

Engineering	50%
Earth and Environmental Science	33%

Selected Abstracts

Manaus'99 Symposium ,Hydrological and Geochemical Processes in Large-Scale River Basins'

HYDROLOGICAL PROCESSES, Issue 7 2003
Patrick T. Seyler
No abstract is available for this article. [source]

Geochemical Factors Controlling Radium Activity in a Sandstone Aquifer

GROUND WATER, Issue 4 2006
Tim Grundl
Geochemical processes behind the occurrence of radium activities in excess of the U.S. EPA's drinking water limit of 5 pCi/L combined radium were investigated in a regional sandstone aquifer located in southeastern Wisconsin. Geochemical speciation modeling (PHREEQC 2.7) combined with a detailed understanding of the regional flow system provided by recent flow modeling efforts was used to determine that radium coprecipitation into barite controls radium activity in the unconfined portion of the aquifer. As the aquifer transitions from unconfined to confined conditions, radium levels rise and the water becomes more sulfate rich yet the aquifer remains at saturation with barite throughout. Calculations based on published distribution coefficients and the observed Ra:Ba atomic ratios indicate that barite contains ,12 ,g/kg coprecipitated radium. Confined portions of the aquifer have high concentrations of sulfate, and barium concentrations become too low to be an effective control on radium activity. Additional, as yet undefined, controls on radium are operative in the downgradient, confined portion of the aquifer. [source]

Determination of isotope fractionation factors and quantification of carbon flow by stable carbon isotope signatures in a methanogenic rice root model system

GEOBIOLOGY, Issue 2 2006
H. PENNING
ABSTRACT Methanogenic processes can be quantified by stable carbon isotopes, if necessary modeling parameters, especially fractionation factors, are known. Anoxically incubated rice roots are a model system with a dynamic microbial community and thus suitable to investigate principal geochemical processes in anoxic natural systems. Here we applied an inhibitor of acetoclastic methanogenesis (methyl fluoride), calculated the thermodynamics of the involved processes, and analyzed the carbon stable isotope signatures of CO2, CH4, propionate, acetate and the methyl carbon of acetate to characterize the carbon flow during anaerobic degradation of rice roots to the final products CO2 and CH4. Methyl fluoride inhibited acetoclastic methanogenesis and thus allowed to quantify the fractionation factor of CH4 production from H2/CO2. Since our model system was not affected by H2 gradients, the fractionation factor could alternatively be determined from the Gibbs free energies of hydrogenotrophic methanogenesis. The fractionation factor of acetoclastic methanogenesis was also experimentally determined. The data were used for successfully modeling the carbon flow. The model results were in agreement with the measured process data, but were sensitive to even small changes in the fractionation factor of hydrogenotrophic methanogenesis. Our study demonstrates that stable carbon isotope signatures are a proper tool to quantify carbon flow, if fractionation factors are determined precisely. [source]

Transformations of runoff chemistry in the Arctic tundra, Northwest Territories, Canada

HYDROLOGICAL PROCESSES, Issue 14 2006
W. L. Quinton
Abstract The transformation of snowmelt water chemical composition during melt, elution and runoff in an Arctic tundra basin is investigated. The chemistry of the water flowing along pathways from the surface of melting snow to the 95·5 ha basin outlet is related to relevant hydrological processes. In so doing, this paper offers physically based explanations for the transformation of major ion concentrations and loads of runoff water associated with snowmelt and rainfall along hydrological pathways to the stream outlet. Late-lying snowdrifts were found to influence the ion chemistry in adjacent reaches of the stream channel greatly. As the initial pulse of ion-rich melt water drained from the snowdrift and was conveyed through hillslope flowpaths, the concentrations of most ions increased, and the duration of the peak ionic pulse lengthened. Over the first 3 m of overland flow, the concentrations of all ions except for NO increased by one to two orders of magnitude, with the largest increase for K+, Ca2+ and Mg2+. This was roughly equivalent to the concentration increase that resulted from percolation of relatively dilute water through 0·25 m of unsaturated soil. The Na+ and Cl, were the dominant ions in snowmelt water, whereas Ca2+ and Mg2+ dominated the hillslope runoff. On slopes below a large melting snowdrift, ion concentrations of melt water flowing in the saturated layer of the soil were very similar to the relatively dilute concentrations found in surface runoff. However, once the snowdrift ablated, ion concentrations of subsurface flow increased above parent melt-water concentrations. Three seasonally characteristic hydrochemical regimes were identified in a stream reach adjacent to late-lying snowdrifts. In the first two stages, the water chemistry in the stream channel strongly resembled the hillslope drainage water. In the third stage, in-stream geochemical processes, including the weathering/ion exchange of Ca2+ and Mg2+, were the main control of streamwater chemistry. Copyright © 2006 John Wiley & Sons, Ltd. [source]

Geochemical changes in white seabream (Diplodus sargus) earth ponds during a production cycle

AQUACULTURE RESEARCH, Issue 15 2007
Dalila Serpa
Abstract The knowledge of geochemical processes in fishponds is important in defining farming strategies and the carrying capacity of these systems, and is therefore essential for the management and sustainability of semi-intensive aquaculture in earth ponds. The main purpose of the present work, developed in the Aquaculture Research Station located in Ria Formosa, was to study the geochemical changes in semi-intensive earth ponds of white seabream Diplodus sargus L. during a production cycle, and relate it to farming conditions (fish biomass and feeding rate). Settled material and sediment samples were collected in a fish production pond and in a non-fish production pond during 2 years. The results obtained showed that particle-settling rates (S, g m,2 day,1) increased linearly with time (t, days): S=0.7t,34, in the fishpond. Increasing deposition of particulate material increased the organic matter content of bottom sediments, particularly during the second production year. Organic matter mineralization, during periods of high temperatures, led to high nutrient concentrations in porewater (NH4+, 965 ,M; NO3,, 40 ,M; HPO42,, 39 ,M) and subsequently to an increase in benthic primary production in the fishpond. The geochemical similarities between fishpond sediments and shallow coastal system's sediments, along with the high fish survival rate (94%), suggest that for the assayed farming conditions there were no environmental constraints within the pond. However, some impact on bottom sediments, namely, an increase in settled material, organic matter deposition, nutrients in porewater and microphytobentos production, was evident above a fish biomass of 500 g m,3 and a feeding rate of 150 kg month,1, indicating that pond environmental conditions should be carefully monitored from this point on. [source]

Regional Spatial Modeling of Topsoil Geochemistry

BIOMETRICS, Issue 1 2009
C. A. Calder
Summary Geographic information about the levels of toxics in environmental media is commonly used in regional environmental health studies when direct measurements of personal exposure is limited or unavailable. In this article, we propose a statistical framework for analyzing the spatial distribution of topsoil geochemical properties, including the concentrations of various toxicants. Due to the small-scale heterogeneity of most geochemical topsoil processes, direct measurements of the processes themselves only provide highly localized information; it is thus financially prohibitive to study the spatial patterns of these processes across a large region using traditional geostatistical analyses of point-referenced topsoil data. Instead, it is standard practice to assess geochemical patterns at a regional scale using point-referenced measurements collected in stream sediment because, unlike topsoil data, individual stream sediment geochemical measurements are representative of the surrounding area. We propose a novel multiscale soils (MSS) model that formally synthesizes data collected in topsoil and stream sediment and allows the richer stream sediment information to inform about the topsoil process, which in environmental health studies is typically more relevant. Our model accommodates the small-scale heterogeneity of topsoil geochemical processes by modeling spatial dependence at an aggregate resolution corresponding to hydrologically similar regions known as watersheds. We present an analysis of the levels of arsenic, a toxic heavy metal, in topsoil across the midwestern United States using the MSS model and show that this model has better predictive abilities than alternative approaches using more conventional statistical models for point-referenced spatial data. [source]