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Fused Silica (fused + silica)

Distribution by Scientific Domains

Polymers and Materials Science	37%

Terms modified by Fused Silica

fused silica capillary

fused silica capillary column

fused silica substrate

Selected Abstracts

In Situ Cube-Corner Indentation of Soda,Lime Glass and Fused Silica

JOURNAL OF THE AMERICAN CERAMIC SOCIETY, Issue 8 2004
Dylan J. Morris
Indentation fracture with a cube-corner diamond pyramid on soda,lime silicate glass and fused silica is investigated during the entire indentation cycle in both silicone oil and ambient-air environments. Radial cracks form immediately on loading in all cases. The two-component, elastic-contact + elastic-plastic mismatch (residual) stress field model that has been used successfully to describe radial crack evolution at Vickers indentations fails to describe the fracture response with the cube-corner. The amplitudes of both elastic-contact and residual stress-intensity factors as deduced from these cube-corner experiments are up to a factor of 10 greater than have been previously observed. [source]

Determination of iodide in samples with complex matrices by hyphenation of capillary isotachophoresis and zone electrophoresis

ELECTROPHORESIS, Issue 20 2007
Pavla Pant
Abstract A method has been developed for the determination of iodide in mineral water, seawater, cooking salt, serum, and urine based on hyphenation of capillary ITP and zone electrophoresis. A commercially available instrumentation for capillary ITP with column-switching system was used. ITP served for removal of chloride present in the analyzed samples in a ratio of 106,107:1 to iodide, zone electrophoresis was used for evaluation. Isotachophoretic separation proceeded in a capillary made of fluorinated ethylene,propylene copolymer of 0.8,mm id and 90,mm total length to the bifurcation point filled with a leading electrolyte (LE) composed of 8,mM HCl,+,16,mM ,-alanine (,-Ala),+,10% PVP,+,2.86,mM N2H4×2HCl, pH,3.2; and a terminating electrolyte composed of 8,mM H3PO4,+,16,mM ,-Ala,+,10% PVP,+,5,mM N2H4, pH,3.85 for all the matrices except seawater. For ITP of seawater the LE consisted of 50,mM HCl,+,100,mM ,-Ala,+,10% PVP +,2.86,mM N2H4×2HCl, pH,3.52. Distance of conductivity detector from the injection point and bifurcation point was 52 and 38,mm, respectively. Zone electrophoresis was performed in a capillary made of fused silica of 0.3,mm id and 160,mm total length filled with LE from isotachophoretic step. LODs reached for all matrices were 2,3×10,8,M concentration (2.5,4,,g/L) enabled monitoring of iodide in all analyzed samples with RSD 0.4,9.3%. Estimated concentrations of iodide in individual matrices were 10,6,10,8,M. [source]

Internal electrolyte temperatures for polymer and fused-silica capillaries used in capillary electrophoresis

ELECTROPHORESIS, Issue 22 2005
Christopher J. Evenhuis
Abstract Polymers are important as materials for manufacturing microfluidic devices for electrodriven separations, in which Joule heating is an unavoidable phenomenon. Heating effects were investigated in polymer capillaries using a CE setup. This study is the first step toward the longer-term objective of the study of heating effects occurring in polymeric microfluidic devices. The thermal conductivity of polymers is much smaller than that of fused silica (FS), resulting in less efficient dissipation of heat in polymeric capillaries. This study used conductance measurements as a temperature probe to determine the mean electrolyte temperatures in CE capillaries of different materials. Values for mean electrolyte temperatures in capillaries made of New Generation FluoroPolymer (NGFP), poly-(methylmethacrylate) (PMMA), and poly(ether ether ketone) (PEEK) capillaries were compared with those obtained for FS capillaries. Extrapolation of plots of conductance versus power per unit length (P/L) to zero power was used to obtain conductance values free of Joule heating effects. The ratio of the measured conductance values at different power levels to the conductance at zero power was used to determine the mean temperature of the electrolyte. For each type of capillary material, it was found that the average increase in the mean temperature of the electrolyte (,TMean) was directly proportional to P/L and inversely proportional to the thermal conductivity (,) of the capillary material. At 7.5,W/m, values for ,TMean for NGFP, PMMA, and PEEK were determined to be 36.6, 33.8, and 30.7°C, respectively. Under identical conditions, ,TMean for FS capillaries was 20.4°C. [source]

In Situ Cube-Corner Indentation of Soda,Lime Glass and Fused Silica

Computational modeling of supercontinuum generation in fused silica by a femtosecond laser pulse of a few optical cycles

MICROWAVE AND OPTICAL TECHNOLOGY LETTERS, Issue 1 2004
David Hovhannisyan
Abstract The numerical solution of a wave equation describing the propagation of the laser pulse of a few optical cycles in fused silica is obtained. Our numerical simulations closely follow the published experimental data. A shifting of the spectrum peak of the broadened pulse, depending on the input-pulse central wavelength, is observed. © 2004 Wiley Periodicals, Inc. Microwave Opt Technol Lett 42: 60,64, 2004; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/mop.20207 [source]

Optical properties of TiO2 thin films prepared by chemical spray pyrolysis from aqueous solutions

PHYSICA STATUS SOLIDI (C) - CURRENT TOPICS IN SOLID STATE PHYSICS, Issue 3-4 2010
R. Ayouchi
Abstract Titanium dioxide (TiO2) is known to have three different kinds of polymorphous crystalline forms: rutile, anatase, and brookite. The rutile phase is always formed at higher temperatures, while the anatase phase is formed at lower temperatures and transformed into rutile phase above 800 ºC. Various deposition techniques have been developed for depositing TiO2 thin films, including evaporation, sputtering, chemical vapour deposition and thermal oxidation of titanium. Among them, the Chemical Spray Pyrolysis (CSP) technique has many advantages, such as good conformal coverage, the possibility of epitaxial growth and the application to large area deposition. Also, this method is low cost and it is easy to control the deposition growth parameters. In the present work, TiO2 thin films have been deposited on p-Si (001) and fused silica substrates by Chemical Spray Pyrolysis (CSP) method from aqueous solution containing titanium (IV) isopropoxide (Ti[OCH(CH3)2]4. As-deposited thin films show anatase polycrystalline structure, and rutile phase formed for films annealed at 750ºC. SEM images have confirmed a smooth and crack-free surface with low surface roughness. X-ray photoelectron spectroscopy (XPS) combined with 4 keV Ar+ depth profiling has shown that crystallized films correspond to TiO2. Residual carbon coming from the organic precursor solution is only detected at the surface of the film. Thin films deposited on fused silica were highly transparent (more than 85%), with an indirect optical band gap of 3,43 and 3,33 eV for as-deposited and annealed films, respectively, and refractive indexes in the range between 2.01,2.29. Spectroscopic Ellipsometry (SE) also has been used to extract optical parameters. SE data fitted to triple-layer physical model revealed the same tendency to increase refractive index in annealed films. (© 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) [source]

Polydimethylsiloxane,cristobalite composite adhesive system for aerospace applications

POLYMERS FOR ADVANCED TECHNOLOGIES, Issue 5 2009
Seema Ansari
Abstract The effect of phase-pure cristobalite (a high temperature crystalline polymorph of silica) on the adhesive characteristics of hydroxyl terminated polydimethylsiloxane (PDMS) was studied. The potential advantages of PDMS/cristobalite composite system as an adhesive for aerospace applications are also discussed. A PDMS/cristobalite composite adhesive system containing different filler contents (0,46 volume percentage, vol%) was prepared. The filler material, phase-pure cristobalite, was synthesized by the pyrolysis of fused silica at 1400°C. The mechanical, rheological, and thermal characteristics of the composites were studied. A high yield stress (0.151,Pa), shear-thinning index (1.051), and fast recovery rate were observed for ,34,vol% cristobalite loading, which indicate that PDMS retains its excellent adhesive and flow characteristics even at high filler loading with enhanced mechanical characteristics. Thermal analysis shows the onset of degradation of PDMS shifts to higher temperatures, 372,438°C and 317,417°C in nitrogen and air atmosphere respectively, which shows excellent thermal stability. The residual component yields after thermal degradation of PDMS/cristobalite composite system in nitrogen and air atmosphere show different degradation mechanisms. Copyright © 2008 John Wiley & Sons, Ltd. [source]