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Flux Decreased (flux + decreased)
Selected AbstractsVapor phase transport of unexploded ordnance compounds through soilsENVIRONMENTAL TOXICOLOGY & CHEMISTRY, Issue 10 2002Raghunathan Ravikrishna Abstract Unexploded ordnance(UXO) is a source of concern at several U.S. Department of Defense(DOD) sites. Localization of munitions and fate and transport of the explosive compounds from these munitions are a major issue of concern. A set of laboratory experiments were conducted in specially designed flux chambers to measure the evaporative flux of three explosive compounds (2,4-dinitrotoluene, 2,6-dinitrotoluene, and 1,3-dinitrobenzene) from three different soils. The effect of different soil moisture contents, the relative humidity of air contacting the soil surface, and soil temperature on the chemical fluxes were evaluated. A diffusion model was used to describe the chemical transport mechanism in the soil pore air. The soil-air partition constant was treated as a fit parameter in the model because of the uncertainty in the a priori estimation. The model predicts the qualitative trends of the experimental fluxes satisfactorily. Under extremely dry conditions, the flux decreased more rapidly than that predicted by the model. The fluxes from soils at 24°C were higher than those at 14°C, indicating a larger volatilization driving force at the higher temperature. [source] Increased rainfall variability and reduced rainfall amount decreases soil CO2 flux in a grassland ecosystemGLOBAL CHANGE BIOLOGY, Issue 2 2005Christopher W. Harper Abstract Predicted climate changes in the US Central Plains include altered precipitation regimes with increased occurrence of growing season droughts and higher frequencies of extreme rainfall events. Changes in the amounts and timing of rainfall events will likely affect ecosystem processes, including those that control C cycling and storage. Soil carbon dioxide (CO2) flux is an important component of C cycling in terrestrial ecosystems, and is strongly influenced by climate. While many studies have assessed the influence of soil water content on soil CO2 flux, few have included experimental manipulation of rainfall amounts in intact ecosystems, and we know of no studies that have explicitly addressed the influence of the timing of rainfall events. In order to determine the responses of soil CO2 flux to altered rainfall timing and amounts, we manipulated rainfall inputs to plots of native tallgrass prairie (Konza Prairie, Kansas, USA) over four growing seasons (1998,2001). Specifically, we altered the amounts and/or timing of growing season rainfall in a factorial combination that included two levels of rainfall amount (100% or 70% of naturally occurring rainfall quantity) and two temporal patterns of rain events (ambient timing or a 50% increase in length of dry intervals between events). The size of individual rain events in the altered timing treatment was adjusted so that the quantity of total growing season rainfall in the ambient and altered timing treatments was the same (i.e. fewer, but larger rainfall events characterized the altered timing treatment). Seasonal mean soil CO2 flux decreased by 8% under reduced rainfall amounts, by 13% under altered rainfall timing, and by 20% when both were combined (P<0.01). These changes in soil CO2 flux were consistent with observed changes in plant productivity, which was also reduced by both reduced rainfall quantity and altered rainfall timing. Soil CO2 flux was related to both soil temperature and soil water content in regression analyses; together they explained as much as 64% of the variability in CO2 flux across dates under ambient rainfall timing, but only 38,48% of the variability under altered rainfall timing, suggesting that other factors (e.g. substrate availability, plant or microbial stress) may limit CO2 flux under a climate regime that includes fewer, larger rainfall events. An analysis of the temperature sensitivity of soil CO2 flux indicated that temperature had a reduced effect (lower correlation and lower Q10 values) under the reduced quantity and altered timing treatments. Recognition that changes in the timing of rainfall events may be as, or more, important than changes in rainfall amount in affecting soil CO2 flux and other components of the carbon cycle highlights the complex nature of ecosystem responses to climate change in North American grasslands. [source] The influence of large-scale atmospheric circulation on the surface energy balance of the King George Island ice capINTERNATIONAL JOURNAL OF CLIMATOLOGY, Issue 1 2001Matthias Braun Abstract During the austral summer 1997,1998 three automatic weather stations were operated at different altitudes on the sub-Antarctic ice cap of King George Island (South Shetland Islands). Snowmelt was derived from energy balance computations. Turbulent heat fluxes were calculated from meteorological measurements using the bulk aerodynamic approach, with net radiation being measured directly. Modelled ablation rates were compared with readings at ablation stakes and continuously measured snow height at a reference site. Snow depletion and daily snowmelt cycles could be well reproduced by the model. Generally, radiation balance provided the major energy input for snowmelt at all altitudes, whereas sensible heat flux was a second heat source only in lower elevations. The average latent heat flux was negligible over the entire measuring period. A strong altitudinal gradient of available energy for snowmelt was observed. Sensible heat flux as well as latent heat flux decreased with altitude. The measurements showed a strong dependence of surface energy fluxes and ablation rates on large-scale atmospheric conditions. Synoptic weather situations were analysed based on AVH RR infrared quicklook composite images and surface pressure charts. Maximum melt rates of up to 20 mm per day were recorded during a northwesterly advection event with meridional air mass transport. During this northwesterly advection, the contribution of turbulent heat fluxes to the energy available for snowmelt exceeded that of the radiation balance. For easterly and southerly flows, continentally toned, cold dry air masses dominated surface energy balance terms and did not significantly contribute to ablation. The link between synoptic situations and ablation is especially valuable, as observed climatic changes along the Antarctic Peninsula are attributed to changes in the atmospheric circulation. Therefore, the combination of energy balance calculations and the analysis of synoptic-scale weather patterns could improve the prediction of ablation rates for climate change scenarios. Copyright © 2001 Royal Meteorological Society [source] Development of thin film composite for CO2 separation in membrane gas absorption applicationASIA-PACIFIC JOURNAL OF CHEMICAL ENGINEERING, Issue 5 2009A.L. Ahmad Abstract The thin film composite (TFC) membrane based on polypropylene (PP) and polyvinylidenefluoride (PVDF) was prepared using glutaraldehyde as the selective layer. The percentages of glutaraldehyde were optimized to maximize the permeability of carbon dioxide (CO2) and selectivity as well. The TFC with 6% w/v of glutaraldehyde based on PVDF achieved the highest permeance of 881.70 GPU and 18.08 for selectivity through the increase in effective layer and skin layer thickness. This TFC promises to provide porous and hydrophobic membranes for use in membrane gas absorption (MGA) processes. The absorption of CO2 in deionized water was studied in MGA system in which the mass transfer coefficient (K) and CO2 flux decreased with increasing CO2 concentration in feed stream. Copyright © 2009 Curtin University of Technology and John Wiley & Sons, Ltd. [source] Pervaporation characteristics and structure of poly(vinyl alcohol)/poly(ethylene glycol)/tetraethoxysilane hybrid membranesJOURNAL OF APPLIED POLYMER SCIENCE, Issue 6 2007Li Yi Ye Abstract Poly(vinyl alcohol) (PVA) blended with poly(ethylene glycol) (PEG) was crosslinked with tetraethoxysilane (TEOS) to prepare organic,inorganic PVA/PEG/TEOS hybrid membranes. The membranes were then used for the dehydration of ethanol by pervaporation (PV). The physicochemical structure of the hybrid membranes was studied with Fourier transform infrared spectra (FT-IR), wide-angle X-ray diffraction WXRD, and scanning electron microscopy (SEM). PVA and PEG were crosslinked with TEOS, and the crosslinking density increased with increases in the TEOS content, annealing temperature, and time. The water permselectivity of the hybrid membranes increased with increasing annealing temperature or time; however, the permeation fluxes decreased at the same time. SEM pictures showed that phase separation took place in the hybrid membranes when the TEOS content was greater than 15 wt %. The water permselectivity increased with the addition of TEOS and reached the maximum at 10 wt % TEOS. The water permselectivity decreased, whereas the permeation flux increased, with an increase in the feed water content or feed temperature. The hybrid membrane that was annealed at 130°C for 12 h exhibited high permselectivity with a separation factor of 300 and a permeation flux of 0.046 kg m,2 h,1 in PV of 15 wt % water in ethanol. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2007 [source] | ||||||||||