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Fluorescent Receptor (fluorescent + receptor)
Selected AbstractsA New Cuburbit[8]uril-Based Fluorescent Receptor for Indole DerivativesCHEMINFORM, Issue 23 2007Yonghua Ling Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF. [source] Ratiometric Dual Fluorescent Receptors for Anions under Intramolecular Charge Transfer Mechanism.CHEMINFORM, Issue 10 2005Zhen-Chang Wen Abstract For Abstract see ChemInform Abstract in Full Text. [source] Different Morphological Organic,Inorganic Hybrid Nanomaterials as Fluorescent Chemosensors and Adsorbents for CuII IonsEUROPEAN JOURNAL OF INORGANIC CHEMISTRY, Issue 10 2008Soo Jin Lee Abstract Functionalized silica nanotubes (FSNT), functionalized mesoporous silica (FMS), and functionalized silica nanoparticles (FSNP-15) with an immobilized phenanthroline moiety as a fluorescent receptor were fabricated by a sol,gel reaction, and their binding abilities with metal ions were evaluated by fluorophotometry in water/acetonitrile (8:2, v/v) at pH 7. They selectively recognized Cu2+ ions among other metal cations such as Co2+, Cd2+, Hg2+, Ni2+, Fe3+, Ag+, Pb2+, and Zn2+, because the Cu2+ ion selectively binds to the nitrogen atoms of the phenanthroline moiety. Among the three silica nanomaterials with the immobilized receptor 1, the sensitivity of FSNT for Cu2+ ions is better than those of FMS and FSNP-15, indicating that the adsorption capacity for metal ions is dependent on the shape and surface area of the supporting nanomaterials. FSNT (10 mg) adsorb 75,% of the Cu2+ ions (2.0,×,10,4 mM) while FSNP-15 (10 mg) adsorb only 36,%. The detection limit of FSNT for Cu2+ ions was ca. 3.0,×,10,8M. FSNT and FMS can be easily renewed by treatment with a solution of HCl and tetrabutylammonium hydroxide. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008) [source] Fluorescent, molecularly imprinted thin-layer films based on a common polymer,JOURNAL OF APPLIED POLYMER SCIENCE, Issue 1 2007Piotr Cywinski Abstract Fluorescent, molecularly imprinted polymer thin films, with cyclic guanosine 3,,5,-monophosphate (cGMP) as a template and 1,2-diphenyl-6-vinyl-1H -pyrazole-[3,4- b]-quinoline as a fluorescent receptor, were prepared according to a method based on commercially available poly (methyl methacrylate). This method of preparation predicts photoinduced crosslinking in the mixture of polymer chains and involved components. The advantages of this method are the relative simplicity of its preparation and the fact that a common polymer can be used. The spin-coated thin-layer films of imprinted and nonimprinted polymers were studied with the use of fluorescence microscopy with a scanning range of 80 × 80 ,m. A strong fluorescence quenching effect was observed when a cGMP-imprinted film was incubated in aqueous solutions of cGMP, but a comparatively small effect was observed for a nonimprinted polymer and when an imprinted film was incubated with cyclic adenosine 3,,5,-monophosphate (cAMP). The separation factor by the imprinted polymer was determined to be 2.55 for cGMP against cAMP. The obtained polymeric sensor appeared to be stable during subsequent measurements after rewashing and readsorption. The homogeneity of the surface of the polymer film, dependent on the method of film preparation, was also studied. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 105: 229,235, 2007 [source] |