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Flow Conditions (flow + condition)
Kinds of Flow Conditions Selected AbstractsPRESSURE DROP and FRICTION FACTOR IN HELICAL HEAT EXCHANGERS UNDER NONISOTHERMAL and TURBULENT FLOW CONDITIONS,JOURNAL OF FOOD PROCESS ENGINEERING, Issue 3 2003P. CORONEL ABSTRACT This study involved the determination of pressure drop and friction factor (f) in helical heat exchangers under turbulent flow conditions. the experiments were conducted in helical heat exchangers, with coils of two different curvatures ratios (d/D = 0.114 and 0.078) at various flow rates (9.46 × 10,5 - 6.31 × 10,4 m3/s) and end-point temperatures (20, 93.3, 121, 149C). the computed friction factor (f) in the helical heat exchanger was compared to published correlations, and it was found that the experimental data was in good agreement with them. In addition, correlations to determine pressure drop based on the Reynolds number, curvature ratio, and temperature were developed. [source] RADIO FREQUENCY (RF) HEATING OF STARCH SOLUTIONS UNDER CONTINUOUS FLOW CONDITIONS: EFFECT OF SYSTEM AND PRODUCT PARAMETERS ON TEMPERATURE CHANGE ACROSS THE APPLICATOR TUBEJOURNAL OF FOOD PROCESS ENGINEERING, Issue 3 2002G.B. AWUAH ABSTRACT Studies were conducted to evaluate the effect of system and product parameters on the temperature change (,T) across a 1.5 kW radio frequency heater operating at 27.12 MHz. Starch solutions (1 to 4% w/w) were used at three different flow rates (0.35, 0.5 and 1 L/min) and four power levels (672, 912, 1152 and 1392 W). The average heating rate of starch solutions varied from 6 to 19C/min depending on flow rate, concentration and power level. The corresponding residence time varied from 1.5 to 4.3 min. Central composite designs involving power (830 to 1234 W) and starch concentration (1 to 4% w/w) at 0.5 L/min were used to study the effects of salt, pH and sugar. As expected fluid flow rate, power level and salt concentration had significant impact (P ± 0.05) on temperature change (,T) across the applicator tube. Although the interaction effect of salt and concentration influenced ,T (P < 0.05), observed trends were not clear cut. Sugar and pH had no significant (P >0.05) influence on ,T due probably to their relatively lower conductivities. However, the interaction effect of sugar and starch concentration affected ,T. Correlations were developed for estimating ,T across the tube as a function of power level, concentration, pH, added salt and sugar. Finally, dimensionless correlations involving the generalized Reynolds, Prandtl, Grashof numbers, dimensionless power and loss-factor ratios were developed for estimating the temperature ratio (U) across the RF applicator. [source] Mechanistic Insights into Copper(I)-Catalyzed Azide-Alkyne Cycloadditions using Continuous Flow ConditionsADVANCED SYNTHESIS & CATALYSIS (PREVIOUSLY: JOURNAL FUER PRAKTISCHE CHEMIE), Issue 2-3 2010Michael Fuchs Abstract The copper-catalyzed azide-alkyne cycloaddition (CuAAC, "click chemistry") was studied employing copper-in-charcoal (Cu/C) and a variety of copper metal sources as "heterogeneous" catalysts. The type and pretreatment conditions of the different copper sources on the CuAAC were investigated. In addition, the effect of copper leaching from the catalyst over time and in dependence on the reaction mixture composition was studied by ICP-MS analysis in the continuous flow mode. These investigations confirm a "homogeneous" mechanism and suggest surface layer copper(I) oxide as the catalytically active species in CuAAC chemistry involving zerovalent copper metal. [source] Influence of Particle Morphology and Flow Conditions on the Dispersion Behavior of Fumed Silica in Silicone PolymersPARTICLE & PARTICLE SYSTEMS CHARACTERIZATION, Issue 3 2004John Boyle Abstract The dispersion behavior of agglomerates of several grades of fumed silica in poly(dimethyl siloxane) liquids has been studied as a function of particle morphology and applied flow conditions. The effects of primary particle size and aggregate density and structure on cohesivity were probed through tensile and shear strength tests on particle compacts. These cohesivity tests indicated that the shear strength of particle compacts was two orders of magnitude higher than the tensile strength at the same overall packing density. Experiments carried out in both steady and time-varying simple-shear flows indicate that dispersion occurs through tensile failure. In the steady-shear experiments,enhanced dispersion was obtained at higher levels of applied stress and, at comparable levels of applied stress, dispersion was found to proceed faster at higher shear rates. Experiments conducted in time-varying flows further corroborated the results obtained in tensile cohesivity tests. Experiments in which the mean and maximum stresses in the time-varying flows were matched to the stresses produced in steady shear flows highlight the influence of flow dynamics on dispersion behavior. [source] Chute Performance and Design for Rapid Flow ConditionsCHEMICAL ENGINEERING & TECHNOLOGY (CET), Issue 2 2003A.W. Roberts Abstract Many industrial chute applications are characterised by rapid flow conditions in which the bulk solid stream thickness or depth is less than the chute width. Under these conditions, it is possible to describe the stream flow by means of a lumped parameter model which takes into account the frictional drag around the chute boundaries as well as making allowance for inter-particle friction. Equations of motion to describe the chute flow are presented and their application to the determination of chute profiles to achieve optimum flow is illustrated. By means of design examples, the problems associated with the feeding of bulk solids onto belt conveyors and conveyor transfers are discussed. Criteria for the selection of the most appropriate chute geometry to minimise chute wear and belt wear at the feed point are presented. The determination of optimum chute profiles to achieve specified performance criteria is outlined. [source] ChemInform Abstract: Baeyer,Villiger Oxidation of Ketones with a Silica-Supported Peracid in Supercritical Carbon Dioxide under Flow Conditions.CHEMINFORM, Issue 47 2009Rossella Mello Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a "Full Text" option. The original article is trackable via the "References" option. [source] Prediction method of critical power by film flow rate measurement and subchannel analysisHEAT TRANSFER - ASIAN RESEARCH (FORMERLY HEAT TRANSFER-JAPANESE RESEARCH), Issue 5 2005Miyuki Akiba Abstract This paper presents a method that can estimate the critical power of boiling water reactors, BWRs, with regard to spacer geometry. The current experimental method for estimating the critical power for BWR design requires many trained experts and expensive facilities to conduct the experiments. In the present method, the liquid film flow rate of adiabatic gas-liquid two-phase flow and a subchannel analysis of the actual BWR flow condition are measured experimentally and analyzed. In the experiment, deposition enhancement coefficients of three spacer geometries,a ferrule, an egg-crate, and a ferrule spacer with twisted tape (CYCLONE spacer),were estimated by measuring the liquid film flow rate of air-water two-phase flow flowing up in a vertical square (4 × 4) rod bundle that simulated the rod bundle of a BWR. Using these coefficients, the critical powers for bundles using each type of spacer geometry were calculated in the subchannel analysis. This method was validated using previous critical power data in the actual BWR flow condition. The critical powers predicted by this method agreed well with those of the experimental data. The result confirmed the effectiveness of this experiment-simulation combined method, as well as the advantage over current experimental methods in terms of human and facility costs. © 2005 Wiley Periodicals, Inc. Heat Trans Asian Res, 34(5): 309,323, 2005; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/htj.20069 [source] Numerical simulation of a dam break for an actual river terrain environmentHYDROLOGICAL PROCESSES, Issue 4 2007C. B. Liao Abstract A two-dimensional (2D) finite-difference shallow water model based on a second-order hybrid type of total variation diminishing (TVD) approximate solver with a MUSCL limiter function was developed to model flooding and inundation problems where the evolution of the drying and wetting interface is numerically challenging. Both a minimum positive depth (MPD) scheme and a non-MPD scheme were employed to handle the advancement of drying and wetting fronts. We used several model problems to verify the model, including a dam break in a slope channel, a dam break flooding over a triangular obstacle, an idealized circular dam-break, and a tide flow over a mound. Computed results agreed well with the experiment data and other numerical results available. The model was then applied to simulate the dam breaking and flooding of Hsindien Creek, Taiwan, with the detailed river basin topography. Computed flooding scenarios show reasonable flow characteristics. Though the average speed of flooding is 6,7 m s,1, which corresponds to the subcritical flow condition (Fr < 1), the local maximum speed of flooding is 14·12 m s,1, which corresponds to the supercritical flow condition (Fr , 1·31). It is necessary to conduct some kind of comparison of the numerical results with measurements/experiments in further studies. Nevertheless, the model exhibits its capability to capture the essential features of dam-break flows with drying and wetting fronts. It also exhibits the potential to provide the basis for computationally efficient flood routing and warning information. Copyright © 2006 John Wiley & Sons, Ltd. [source] An investigation of pulsatile flow in a model cavo-pulmonary vascular systemINTERNATIONAL JOURNAL FOR NUMERICAL METHODS IN BIOMEDICAL ENGINEERING, Issue 11 2009K. Chitra Abstract The complexities in the flow pattern in a cavo-pulmonary vascular system,after application of the Fontan procedure in the vicinity of the superior vena cava, inferior vena cava, and the confluence at the T-junction,are analysed. A characteristic-based split (CBS) finite element scheme involving the artificial compressibility approach is employed to compute the resulting flow. Benchmarking of the CBS scheme is carried out using standard problems and with the flow features observed in an experimental model with the help of a dye visualization technique in model scale. The transient flow variations in a total cavo-pulmonary connection (TCPC) under pulsatile conditions are investigated and compared with flow visualization studies. In addition to such qualitative flow investigations, quantitative analysis of energy loss and haemodynamic stresses have also been performed. The comparisons show good agreement between the numerical and experimental flow patterns. The numerically predicted shear stress values indicate that the pulsatile flow condition is likely to be more severe than steady flow, with regard to the long-term health of the surgically corrected TCPC. Copyright © 2008 John Wiley & Sons, Ltd. [source] Determination of the rate coefficients of the SO2 + O + M , SO3 + M reactionINTERNATIONAL JOURNAL OF CHEMICAL KINETICS, Issue 3 2010S. M. Hwang Rate coefficients of the title reaction R31 (SO2 + O + M , SO3 + M) and R56 (SO2 + HO2, SO3 + OH), important in the conversion of S(IV) to S(VI), were obtained at T = 970,1150 K and ,ave = 16.2 ,mol cm,3 behind reflected shock waves by a perturbation method. Shock-heated H2/O2/Ar mixtures were perturbed by adding small amounts of SO2 (1%, 2%, and 3%) and the OH temporal profiles were then measured using laser absorption spectroscopy. Reaction rate coefficients were elucidated by matching the characteristic reaction times acquired from the individual experimental absorption profiles via simultaneous optimization of k31 and k56 values in the reaction modeling (for satisfactory matches to the observed characteristic times, it was necessary to take into account R56). In the experimental conditions of this study, R31 is in the low-pressure limit. The rate coefficient expressions fitted using the combined data of this study and the previous experimental results are k31,0/[Ar] = 2.9 × 1035 T,6.0 exp(,4780 K/T) + 6.1 × 1024 T,3.0 exp(,1980 K/T) cm6 mol,2 s,1 at T = 300,2500 K; k56 = 1.36 × 1011 exp(,3420 K/T) cm3 mol,1 s,1 at T = 970,1150 K. Computer simulations of typical aircraft engine environments, using the reaction mechanism with the above k31,0 and k56 expressions, gave the maximum S(IV) to S(VI) conversion yield of ca. 3.5% and 2.5% for the constant density and constant pressure flow condition, respectively. Moreover, maximum conversions occur at rather higher temperatures (,1200 K) than that where the maximum k31,0 value is located (,800 K). This is because the conversion yield is dependent upon not only the k31,0 and k56 values (production flux) but also the availability of H, O, and HO2 in the system (consumption flux). © 2010 Wiley Periodicals, Inc., Int J Chem Kinet 42: 168,180, 2010 [source] The effect of recycle ratio on nitrogen removal in the combined pre-denitrification/nitrification biofilter systemJOURNAL OF CHEMICAL TECHNOLOGY & BIOTECHNOLOGY, Issue 6 2001Ren-Jie Chiou Abstract Previous research has shown that nitrogen in municipal wastewater could be eliminated by a biofilter system. This study investigates the effect of the recycle ratio on total nitrogen removal and the nitrogen component in the effluent. In this study, a system combining pre-denitrification/nitrification biofilters was set up. The experiments which varied the recycle ratio of the nitrifying solution to the influent were carried out in order to determine the amount of the total nitrogen removal and the form of nitrogen in the effluent. These experimental results show that total nitrogen removal might be dependent on nitrification but not on denitrification. Although the operation at a low recycle ratio would result in a lower value of total nitrogen removal, the NH3 -N content of the effluent would be lower and the flow condition would be more stable. In comparison, operation at a higher recycle ratio would result in a lower NO3, -N content in the effluent, while the NH3 -N content in the effluent would be higher. At a recycle ratio of 2.5, the total nitrogen removal is at its maximum. The relationship between specific nitrification rate and recycle ratio is also discussed. © 2001 Society of Chemical Industry [source] Miscible displacements with a chemical reaction in a capillary tubeAICHE JOURNAL, Issue 3 2008Yuichiro Nagatsu Abstract Miscible displacement of a more-viscous liquid by a less-viscous one with a chemical reaction in a capillary tube was investigated experimentally and theoretically. In such a flow field, the less-viscous liquid continuously leaks from the tip of the finger-shaped boundary between the two liquids to form another thin finger depending on flow condition. This is called a "spike." Experimental results show that in the spike product is clearly or scarcely observed when the initial reactant concentration in the less-viscous liquid is sufficiently larger or smaller than the stoichiometry, respectively. On the basis of theoretical results, a model is proposed in which the difference in the reaction plane's location in either the less-viscous liquid or in the boundary (determined by the variation in the initial reactant concentrations) results in a significant difference between the locations of the boundary and the reaction plane, this difference being affected by the spike configuration of the boundary. © 2008 American Institute of Chemical Engineers AIChE J, 2008 [source] Implantation of One Piece Biventricular Assist Device by Left Thoracotomy in an Ovine ModelARTIFICIAL ORGANS, Issue 9 2000Won Gon Kim Abstract: In this report, we describe an operative procedure for our implantable 1 piece biventricular assist device (BiVAD) based on a moving actuator mechanism, using an ovine model. Our implantable BiVAD is a volumetric coupled 1 piece unit including right and left blood sacs and an actuator assembly based on the moving actuator mechanism. The BiVAD was controlled by fixed rate control with 75 bpm for the most part. Both the left and the right full ejection modes with the maximum stroke angle were selected to minimize blood stasis in the blood sacs because of low assist flow condition. Three Corriedale sheep were used for the device implantation by a left thoracotomy incision. Cannulation was successfully performed in all cases. Although exposability of the right atrial appendage varied from animal to animal, the insertion of the cannula was easily performed. The cannulas were connected to the pump-actuator assembly in the preperitoneal pocket. All 3 animals survived the experimental procedure. During implantation of the device, in the 1 month survival animal, pump flow was maintained between 2.0 L/min and 2.5 L/min, mean aortic pressure was 90,110 mm Hg, and mean pulmonary artery pressure was 20,30 mm Hg. The left and right atrial pressure were maintained between 0 and 5 mm Hg. In conclusion, this ovine model for implantation of the 1 piece BiVAD can be an effective alternative for testing in vivo biocompatibility of the device although it needs more consideration for anatomical fittability for future human application. [source] Diagnosis of thrombotic thrombocytopenic purpura based on modulation by patient plasma of normal platelet adhesion under flow conditionBRITISH JOURNAL OF HAEMATOLOGY, Issue 4 2003Boris Shenkman Summary. We have designed a simple test for the early diagnosis and treatment monitoring of thrombotic thrombocytopenic purpura (TTP). We examined plasma from 24 TTP patients and normal plasma using a cone and plate(let) analyser (CPA). Test plasma was mixed with citrated normal whole blood (group O) and subjected to flow at a shear rate of 1800/s. Mixing normal plasma (12·5, 25, 50 or 75 µl) with heterologous normal whole blood (final volume of 200 µl) resulted in a decrease of surface coverage (SC, maximally by 63%) and, to a lesser extent, of average size (AS, maximally by 37%) due to dilution of the blood sample. In contrast, mixing the same quantities of acute TTP plasma with normal blood yielded an increase in both SC (up to 125%) and AS (up to 130%). Increased SC and/or AS were detected in all 15 patients in acute phase and in three out of 14 patients in remission. Following repeated plasmapheresis, the enhanced platelet deposition in five patients with acute TTP returned to almost normal patterns. Mixing plasma from patients with other thrombocytopenic conditions in this way resulted in a decrease in both SC and AS, and did not differ from control subjects. In conclusion, the CPA is a simple and specific laboratory test that can be used for the diagnosis and monitoring of plasma exchange therapy in TTP. [source] Speed Estimation from Single Loop Data Using an Unscented Particle FilterCOMPUTER-AIDED CIVIL AND INFRASTRUCTURE ENGINEERING, Issue 7 2010Zhirui Ye The Kalman filters used in past speed estimation studies employ a Gaussian assumption that is hardly satisfied. The hybrid method that combines a parametric filter (Unscented Kalman Filter) and a nonparametric filter (Particle Filter) is thus proposed to overcome the limitations of the existing methods. To illustrate the advantage of the proposed approach, two data sets collected from field detectors along with a simulated data set are utilized for performance evaluation and comparison with the Extended Kalman Filter and the Unscented Kalman Filter. It is found that the proposed method outperforms the evaluated Kalman filter methods. The UPF method produces accurate speed estimation even for congested flow conditions in which many other methods have significant accuracy problems. [source] The distribution and prevalence of sponges in relation to environmental gradients within a temperate sea lough: vertical cliff surfacesDIVERSITY AND DISTRIBUTIONS, Issue 6 2000James J. Bell Abstract. The prevalence and distribution of sponges was surveyed on vertical cliff surfaces at Lough Hyne Marine Nature Reserve, Co. Cork, Ireland. The number of sponge species was recorded at 6-metre depth intervals at four sites within Lough Hyne, and at one site on the adjacent Atlantic coastline to examine differences in abundance and zonation patterns. Sites ranged from an exposed turbulent regime to sheltered, sedimented environments. Individual species showed different distributions and prevalence between sites and with increasing depth. Greatest differences were observed between the most- and least-disturbed sites. Distinct sponge zonation patterns were evident at all sites sampled. Twenty-five species were considered dominant at all five sites with the remaining 48 species considered rare. Only four of the 25 most-dominant species occurred at the site experiencing the most turbulent flow conditions, whereas 12 species were found at the site of unidirectional fast flow. At sites of moderate to slight water movement and high sedimentation, between 18 and 24 of the most dominant species were present. Encrusting forms constituted high proportions of sponge communities at all five sites sampled (although consisting of different species). At sites of turbulent and unidirectional fast flow massive forms also dominated whereas at the least turbulent sites, where sedimentation was high, arborescent sponges were abundant. Few species showed exclusive distribution to a single depth and site, but there was some degree of correlation between species distributions and abiotic factors such as sedimentation rate and flow regimes. Sponge distributions and densities are discussed with respect to the suitability of species' morphologies to particular environments, intra-specific and inter-specific competition and physiological adaptations that enable them to survive in different habitats. [source] Modelling increased soil cohesion due to roots with EUROSEMEARTH SURFACE PROCESSES AND LANDFORMS, Issue 13 2008S. De Baets Abstract As organic root exudates cause soil particles to adhere firmly to root surfaces, roots significantly increase soil strength and therefore also increase the resistance of the topsoil to erosion by concentrated flow. This paper aims at contributing to a better prediction of the root effects on soil erosion rates in the EUROSEM model, as the input values accounting for roots, presented in the user manual, do not account for differences in root density or root architecture. Recent research indicates that small changes in root density or differences in root architecture considerably influence soil erosion rates during concentrated flow. The approach for incorporating the root effects into this model is based on a comparison of measured soil detachment rates for bare and for root-permeated topsoil samples with predicted erosion rates under the same flow conditions using the erosion equation of EUROSEM. Through backwards calculation, transport capacity efficiencies and corresponding soil cohesion values can be assessed for bare and root-permeated topsoils respectively. The results are promising and present soil cohesion values that are in accordance with reported values in the literature for the same soil type (silt loam). The results show that grass roots provide a larger increase in soil cohesion as compared with tap-rooted species and that the increase in soil cohesion is not significantly different under wet and dry soil conditions, either for fibrous root systems or for tap root systems. Power and exponential relationships are established between measured root density values and the corresponding calculated soil cohesion values, reflecting the effects of roots on the resistance of the topsoil to concentrated flow incision. These relationships enable one to incorporate the root effect into the soil erosion model EUROSEM, through adapting the soil cohesion input value. A scenario analysis shows that the contribution of roots to soil cohesion is very important for preventing soil loss and reducing runoff volume. The increase in soil shear strength due to the binding effect of roots on soil particles is two orders of magnitude lower as compared with soil reinforcement achieved when roots mobilize their tensile strength during soil shearing and root breakage. Copyright © 2008 John Wiley & Sons, Ltd. [source] Determining friction coefficients for interrill flows: the significance of flow filaments and backwater effectsEARTH SURFACE PROCESSES AND LANDFORMS, Issue 5 2003Dr David L. Dunkerley Abstract Friction coefficients in overland flows are customarily estimated from mean flow properties (depth, velocity, slope) that subsume spatial variations in flow arising from two major causes: microtopography and obstacles. This paper uses laboratory experiments in shallow flumes to examine the extent of non-uniformity in flow conditions associated with each cause. Randomly placed emergent obstacles in a flume with a shallow axial channel generally yielded higher hydraulic roughness than the same pattern of obstacles on a planar flume, as well as greater variation in roughness as the obstacle locations were altered. In both flumes, hydraulic roughness fell with increasing Reynolds number for 10% obstacle cover, showed a flattening trend at 20% cover, and exhibited a convex-downward trend at 30% obstacle cover. These results indicate the progressive onset of flow controls at narrow gaps in the obstacle field. In such flows, the use of mean flow properties conceals the existence of two main subdivisions of flow: flow filaments and backwater flows. In the experiments, flow filaments involved velocities more than twice the overall mean, whereas backwater flows were much slower than the mean. The existence of fast-moving flow filaments may be significant in understanding soil transport in surface runoff, and backwater depths may modify splash detachment. Similarly, friction coefficients that fail to reflect these important non-uniform flow components may not be optimal for hydraulic calculations or in erosion models. It is concluded that new approaches to observing and processing flow data may be required, in order to avoid the loss of important flow detail that is entailed in assuming uniform flow conditions. Copyright © 2003 John Wiley & Sons, Ltd. [source] Spatial patterns of water surface topography at a river confluenceEARTH SURFACE PROCESSES AND LANDFORMS, Issue 9 2002Dr Pascale M. Biron Abstract Understanding flow structures in river confluences has largely been the product of interpretations made from measured flow velocity data. Here, we turn the attention to the investigation of the patterns of both the average and standard deviations of the micro-topography of the water surface at an asymmetrical natural discordant confluence for different flow conditions. Water surface topography is measured using a total station to survey the position of a reflector mounted on a custom-built raft. To limit error problems related to changes in the water level, measurements are taken and analysed by cross-stream transects where five water surface profiles are taken before moving to the next transect. Three-dimensional numerical simulations of the flow dynamics at the field site are used to examine predicted water surface topography for a steady-state situation. The patterns are interpreted with respect to flow structure dynamics, visual observations of boils, and bed topography. Results indicate that coherent patterns emerge at the water surface of a discordant bed confluence for different flow conditions. The zone of stagnation and the mixing layer are characterized by super-elevation, a lateral tilt is present at the edge of the mixing layer, and a zone of super-elevation is present on the tributary side at the downstream junction corner. The latter seems associated with periodical upwelling and is not present in the numerical simulations that do not take into account instantaneous velocity fluctuations. Planform curvature, topographic steering related to the tributary mouth bar, and turbulent structures associated with the mixing layer all play a key role in the pattern of both the average and standard deviation of the water surface topography at confluences. Copyright © 2002 John Wiley & Sons, Ltd. [source] The influence of groundwater on surface flow erosion processes during a rainstormEARTH SURFACE PROCESSES AND LANDFORMS, Issue 5 2002D. L. RockwellArticle first published online: 27 MAY 200 Abstract Surface erosion rates on a disturbed natural soil in a 10 m indoor flume increased by an order of magnitude when a water table developed at a 10 cm depth during simulated rainstorms. Erosion rate increases did not correlate well with surface hydraulic flow conditions, and all significant erosion increases began before the full soil depth was saturated, before the water table reached the soil surface, and before seepage was possible. Groundwater influenced erosion processes primarily by increasing unsaturated pore-water pressures and decreasing soil shear strength in surface rainflow, rather than through the direct entrainment of soil particles by seepage flow. There was no unique morphologic expression of the influence of groundwater during a rainstorm. Subsurface processes influencing surface erosion were detected only by appropriate subsurface instrumentation, which included micropiezometers, tensiometers and time domain reflectometry. Erosion rate increases occurred all along the slope, and were not concentrated at the base of slope due to a seepage zone. Soil depth was crucial to determining surface erosion increase. It is likely that confusing trends in surface flow erosion rates in past studies have occurred due to unrecorded groundwater development or an emphasis on seepage effects. Groundwater must be monitored along hillslopes under all moisture and soil conditions in order to avoid misleading and inconsistent conclusions derived solely from surface flow or seepage data. Copyright © 2002 John Wiley & Sons, Ltd. [source] Estimating the mean speed of laminar overland flow using dye injection-uncertainty on rough surfacesEARTH SURFACE PROCESSES AND LANDFORMS, Issue 4 2001David Dunkerley Abstract A common method for estimating mean flow speeds in studies of surface runoff is to time the travel of a dye cloud across a measured flow path. Motion of the dye front reflects the surface flow speed, and a correction must be employed to derive a value for the profile mean speed, which is always lower. Whilst laminar flow conditions are widespread in the interrill zone, few data are available with which to establish the relationship linking surface and profile mean speeds, and there are virtually none for the flow range 100,<,Re,<,500 (Re,=,Reynolds number) which is studied here. In laboratory experiments on a glued sand board, mean flow speeds were estimated from both dye speeds and the volumetric flow relation v,=,Q/wd with d measured using a computer-controlled needle gauge at 64 points. In order to simulate conditions applicable to many dryland soils, the board was also roughened with plant litter and with ceramic tiles (to simulate surface stone cover). Results demonstrate that in the range 100,<,Re,<,500, there is no consistent relation between surface flow speeds and the profile mean. The mean relationship is v,=,0·56 vsurf, which departs significantly from the theoretical smooth-surface relation v,=,0·67 vsurf, and exhibits a considerable scatter of values that show a dependence on flow depth. Given the inapplicability of any fixed conversion factor, and the dependence on flow depth, it is suggested that the use of dye timing as a method for estimating v be abandoned in favour of precision depth measurement and the use of the relation v,=,Q/wd, at least within the laminar flow range tested. Copyright © 2001 John Wiley & Sons, Ltd. [source] The Influence of Flowing Water on the Resource Pursuit-Risk Avoidance Tradeoff in the Crayfish Orconectes virilisETHOLOGY, Issue 4 2006Keith W. Pecor The influence of hydrodynamics on chemically mediated behavioral tradeoffs has received little attention. We tested the hypothesis that individuals of the crayfish Orconectes virilis would be more sensitive to chemical cues in flowing water than in still water. Orconectes virilis is a good subject for this test, because it is found in both still water (e.g. ponds), and flowing water (e.g. rivers). A factorial design was used, with two stimulus treatments and two habitat types. Crayfish were exposed to either food cue or food + alarm cue in either still water or flowing water in an artificial stream arena. Habitat use and activity were significantly influenced by stimulus treatment, with more time spent away from the stimulus source and less activity in the food + alarm treatment than in the food treatment. Neither habitat type nor the interaction of stimulus treatment and habitat type had a significant effect on the response variables. Given the natural history of O. virilis, we suggest that selection has favored the ability to equally utilize chemical cues in both still and flowing water. We acknowledge that different flow conditions may influence chemical ecology in this species and caution against the view that tests in flowing waters necessarily provide a more accurate approximation of natural responses. [source] Simulation of water flow and solute transport in free-drainage lysimeters and field soils with heterogeneous structuresEUROPEAN JOURNAL OF SOIL SCIENCE, Issue 2 2004H. M. Abdou Summary Lysimeters are valuable for studying the fate and transport of chemicals in soil. Large-scale field lysimeters are used to assess pesticide behaviour and radionuclide transport, and are assumed to represent natural field conditions better than laboratory columns. Field lysimeters are usually characterized by a free-draining lower boundary. As a result, the hydraulic gradient is disrupted, and leachate cannot be collected until the bottom of the lysimeter becomes saturated. We compared heterogeneously structured, free-drainage lysimeters and field soils with respect to water flow and solute transport. Numerical simulations were carried out in a two-dimensional heterogeneous sandy soil under unsaturated water flow conditions with the CHAIN_2D code. Three different soil structures (isotropic, horizontal, and vertical) were generated, and Miller,Miller similitude was used to scale the hydraulic properties of the soil. The results showed that ponding occurs at the bottom of the lysimeter for the three soil structures and that it occurred faster and was more pronounced with the vertical structure (preferential flow effect). Breakthrough curves of a conservative solute (bromide) showed that solutes are moving faster in the field than in the lysimeters. Fewer differences between lysimeters and field soils were found with the horizontal soil structure than with the isotropic and vertical structures. [source] Diurnal stream habitat use of juvenile Atlantic salmon, brown trout and rainbow trout in winterFISHERIES MANAGEMENT & ECOLOGY, Issue 5 2009J. H. JOHNSON Abstract, The diurnal winter habitat of three species of juvenile salmonids was examined in a tributary of Skaneateles Lake, NY to compare habitat differences among species and to determine if species/age classes were selecting specific habitats. A total of 792 observations were made on the depth, velocity, substrate and cover (amount and type) used by sympatric subyearling Atlantic salmon, subyearling brown trout and subyearling and yearling rainbow trout. Subyearling Atlantic salmon occurred in shallower areas with faster velocities and less cover than the other salmonid groups. Subyearling salmon was also the only group associated with substrate of a size larger than the average size substrate in the study reach during both winters. Subyearling brown trout exhibited a preference for vegetative cover. Compared with available habitat, yearling rainbow trout were the most selective in their habitat use. All salmonid groups were associated with more substrate cover in 2002 under high flow conditions. Differences in the winter habitat use of these salmonid groups have important management implications in terms of both habitat protection and habitat enhancement. [source] Ethanol and Acetaldehyde Adsorption on a Carbon-Supported Pt Catalyst: A Comparative DEMS StudyFUEL CELLS, Issue 1-2 2004H. Wang Abstract The adsorption of ethanol and acetaldehyde on carbon Vulcan supported Pt fuel cell catalyst and the electrochemical desorption of the adsorption products were studied, using electrochemical measurements and differential electrochemical mass spectrosmetry (DEMS), under continuous flow conditions. Faradaic current adsorption transients at different constant adsorption potentials, which also include CO adsorption for comparison, show pronounced effects of the adsorption potential and the nature of the reactant molecule. Acetaldehyde adsorption is much faster than ethanol adsorption at all potentials. Pronounced Had induced blocking effects for ethanol adsorption are observed at very cathodic adsorption potentials, < 0.16,V, while for acetaldehyde adsorption this effect is much less significant. Comparison of the adsorption charge for CO adsorption with the H-upd charge allows differentiation between H-displacement and double-layer charging effects. Continuous bulk oxidation is observed for both reactants at potentials > 0.31,V; for acetaldehyde adsorption, increasing bulk reduction is found at low potentials. Based on the electron yield per CO2 molecule formed and on the similarity with the CO stripping characteristics the dominant stable adsorbate is CO, coadsorbed with smaller amounts of (partly oxidized) hydrocarbon decomposition fragments, which are also oxidized at higher potentials (> 0.85,V) and which can be reductively desorbed as methane or, to a very small extent, as ethane. The presence of small amounts of adsorbed C2 species and the oxidative dissociation of these species in the main CO oxidation potential range is clearly demonstrated by increased methane desorption after a potential shift to 0.85,V. The data demonstrate that the Pt/Vulcan catalyst is very reactive for C-C bond breaking upon adsorption of these reactants. [source] Epitaxial Growth of Highly Oriented Fibers of Semiconducting Polymers with a Shish-Kebab-Like SuperstructureADVANCED FUNCTIONAL MATERIALS, Issue 17 2009Martin Brinkmann Abstract Highly oriented fibers of regioregular poly(3-alkylthiophene)s (P3ATs) showing a "shish-kebab" morphology are prepared by oriented epitaxial crystallization in a mixture of 1,3,5-trichlorobenzene (TCB) and pyridine. The superstructure of the P3AT fibers consists of an oriented thread-like core several hundreds of micrometers long, the "shish", onto which lateral crystalline fibrils made of folded polymer chains, the "kebabs", are connected in a periodic way with a periodicity in the range 18,30,nm. The P3AT-chain axis is oriented parallel to the fiber axis whereas the ,-stacking direction is oriented perpendicular to it. The oriented character of the shish-kebab fibers results in polarized optical absorption and photoluminescence. The formation of oriented precursors by epitaxial orientation of polymer chains onto long needles of a molecular crystal,TCB in the present case,appears to be an original alternative to the crystallization usually performed under external flow conditions. [source] The role of thermochemical sulfate reduction in the origin of Mississippi Valley-type deposits.GEOFLUIDS (ELECTRONIC), Issue 1 2008Abstract The kinetics of thermochemical sulfate reduction (TSR) were studied in experiments at 205,250°C, with determination of both sulfate and sulfide at intervals during the runs of up to 430 h. Analysis of the data indicates the reaction to have first-order kinetics, and extrapolating these data, plus data from the literature, to 150°C gives a range of possible rate constants from 100 to 10,4 year,1. Although the rate law has not been well established, a reasonable estimate allows calculation of the amount of sulfide ore formed as a function of flow conditions and time. It is here concluded that TSR could happen during the formation of Mississippi Valley-type ore deposits, subject to several caveats. [source] Streaming potential dependence on water-content in Fontainebleau sandGEOPHYSICAL JOURNAL INTERNATIONAL, Issue 3 2010V. Allègre SUMMARY The electrokinetic potential results from the coupling between the water flow and the electrical current because of the presence of ions within water. The electrokinetic coefficient is well described in fluid-saturated media, however its behaviour under unsaturated flow conditions is still discussed. We propose here an experimental approach to investigate streaming potential variations in sand at unsaturated conditions. We present for the first time continuous records of the electrokinetic coefficient as a function of water content. Two drainage experiments have been performed within a column filled with a clean sand. Streaming potential measurements are combined with water pressure and water content measurements every 10 cm along the column. In order to model hydrodymanics during the experiments, we solve Richards equation coupled with an inverse problem to estimate the hydraulic parameters of the constitutive relations between hydraulic conductivity, water pressure and water content. The electrokinetic coefficient C shows a more complex behaviour for unsaturated conditions than it was previously reported and cannot be fitted by the existing models. The normalized electrokinetic coefficient increases first when water saturation decreases from 100 to about 65,80 per cent, and then decreases as the water saturation decreases, whereas all previous works described a monotone decrease of the normalized electrokinetic coupling as water saturation decreases. We delimited two water saturation domains, and deduced two different empirical laws describing the evolution of the electrokinetic coefficient for unsaturated conditions. Moreover, we introduce the concept of the electrokinetic residual saturation, Sr,ekw, which allows us to propose a new model derived from the approach of the relative permeability used in hydrodynamics. [source] Turbulent Flow Through Porous MediaGROUND WATER, Issue 5 2001Douglas W. Barr The pressure driving flow through porous media must be equal to the viscous resistance plus the inertial resistance. Formulas are developed for both the viscous resistance and the inertial resistance. The expression for the coefficient of permeability consists of parameters which describe the characteristics of the porous medium and the permeating fluid and which, for unconsolidated isotropic granular media, are all measurable. A procedure is proposed for testing for the occurrence of turbulence and calculating the effective permeability when it occurs. The formulas are applied to a set of data from 588 permeameter runs ranging from laminar to highly turbulent. The equations fit the data from the permeameter closely through the laminar flow conditions and quite closely through the turbulent conditions. In the turbulent range, the plotting of the data separates into three distinct lines for each of the three shapes of particles used in the tests. For the porous medium and fluid of these tests, turbulence begins at a head gradient of about 0.1. [source] Research on the thermal corridor of a hypersonic vehicleHEAT TRANSFER - ASIAN RESEARCH (FORMERLY HEAT TRANSFER-JAPANESE RESEARCH), Issue 4 2008Ling Jin Abstract The establishment of a reasonable physical model and an effective solution scheme for the thermal corridor is very important to thermal protection structure design, trajectory selection, aerodynamic configuration optimization design, etc. The concept of a thermal corridor for a hypersonic vehicle was analyzed and a physical model was proposed in this paper. Furthermore, the governing equations and the corresponding algorithm for the thermal corridor were discussed. The envelopes of the height,velocity curves at typical positions of the vehicle X43 were calculated, the characteristics of the thermal corridor were summarized, the effect of the thermal protection material on the thermal corridor was discussed, and the emission coefficient of the thermal protection material was defined. The results indicate that the thermal corridor depends on the emission coefficient of the surface material, the flow conditions, and turbulence transition position. © 2008 Wiley Periodicals, Inc. Heat Trans Asian Res, 37(4): 218,223, 2008; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/htj.20203 [source] | |||||||||||||||||||||||||