Fixed Position (fixed + position)

Distribution by Scientific Domains


Selected Abstracts


Illumination influences the ability of migrating juvenile salmonids to pass a submerged experimental weir

ECOLOGY OF FRESHWATER FISH, Issue 2 2009
P. S. Kemp
Abstract,,, The downstream migration of juvenile salmonids has previously been considered predominantly passive. It has been argued that passive displacement during periods of darkness is, partially at least, a result of an inability to maintain a fixed position in the absence of visual cues. In this study, behaviour of juvenile Pacific salmonids was assessed under conditions of light and dark as they passed through an artificial channel and encountered a submerged weir. Results indicated that when light, fish formed schools and actively explored the channel. Conversely, when dark (infrared illumination only) they did not form schools, but maintained randomly distributed positions holding station against the flow. As a consequence, more fish approached and either passed, or rejected, the weir when light. The majority of fish that passed the weir did so within the first minute of each trial. Fish predominantly passed through the channel facing downstream and changed orientation prior to passing tail first over the weir crest in the presence and absence of visual cues. The orientation switch was less common when dark. This study shows, at a fine-resolution scale, that downstream movement of juvenile salmonids can be inhibited as fish exhibit alternative behaviours in the absence of visual cues. Downstream movement was not predominantly passive. Fish passage design should not be based on the assumption that downstream migration is passive. [source]


Recovery of transition metal complex by reverse flow adsorption

AICHE JOURNAL, Issue 1 2008
Jeroen Dunnewijk
Abstract Reverse flow adsorption (RFA) is a technique with a definite potential to prevent the leaching of a homogenous catalyst. In this work, we model an RFA-process for a continuous ideally stirred tank reactor with an adsorption bed upstream and another one downstream from the reactor. The model parameters concerning adsorption equilibrium and kinetics are taken from previous experimental studies on CoCl2 adsorption on polymer-bound trifenylfosfine. We use this model to study the concentration profiles of CoCl2 in the adsorption beds during consecutive adsorption,desorption cycles. The model calculations show that the concentration profile eventually reaches a fixed position after a number of adsorption,desorption cycles, even though internal mass transfer was a limiting factor. Hence, the transition metal is kept within the system boundaries, which is an essential requirement for the application of RFA. © 2007 American Institute of Chemical Engineers AIChE J, 2008 [source]


Structural transformations in organic crystals during photochemical reactions

JOURNAL OF PHYSICAL ORGANIC CHEMISTRY, Issue 10 2004
Ilona Turowska-Tyrk
Abstract In the 1980s and 1990s, x-ray studies of the photochemical reaction course in crystals dealt with the analysis of changes in cell constants or movements of atom groups inside molecules. This review presents the results of crystallographic studies on the monitoring of the behaviour of whole molecules in organic crystals during photochemical reactions. Papers on this subject started to appear only a few years ago. The studies showed quantitatively that reactant and product molecules do not take a fixed position in a crystal during the reaction. The product molecules move smoothly to a position assumed in the pure product crystal and the reactant molecules move from a position occupied in the pure reactant crystal. Moreover, with the reaction progress the adjacent reactant molecules gradually come closer and change their mutual orientation to resemble the product. The analysis of the photoreaction kinetics in crystals is also presented. Copyright © 2004 John Wiley & Sons, Ltd. [source]


Simultaneous Measurement of Particle Size and Particle Velocity by the Spatial Filtering Technique,

PARTICLE & PARTICLE SYSTEMS CHARACTERIZATION, Issue 6 2002
Dieter Petrak
Abstract The objective of this study was to compare the measuring results of a fiber-optical probe based on a modified spatial filtering technique with given size distributions of different test powders and also with particle velocity values of laser Doppler measurements. Fiber-optical spatial filtering velocimetry was modified by fiber-optical spot scanning in order to determine simultaneously the size and the velocity of particles. The fiber-optical probe system can be used as an in-line measuring device for sizing of particles in different technical applications. Spherical test particles were narrow-sized glass beads in the range 30,100,,m and irregularly shaped test particles were limestone particles in the range 10,600,,m. Particles were dispersed by a brush disperser and the measurements were carried out at a fixed position in a free particle-laden air stream. Owing to the measurement of chord lengths and to the influence of diffraction and divergent angle, the probe results show differences from the given test particle sizes. Owing to the particle-probe collisions, the mean velocity determined by the probe is smaller than the laser Doppler mean velocity. [source]


Enhanced Crystallinity of PTFE by Ion Irradiation in a Dense Plasma Focus

PLASMA PROCESSES AND POLYMERS, Issue 2 2007
Mehboob Sadiq
Abstract Nitrogen-ion beam pulses emitted from a low-energy (1.45 kJ) Mather-type plasma focus device are used for the surface modification of PTFE polymer specimens. The specimens, placed at a fixed position, are implanted using different number of pulses. Raman spectroscopy and XRD are employed to probe the structural changes incurred during the ion implantation. Both techniques indicate that the crystalline order in the specimens increases with increasing the irradiation dose. The crystallinity degree of the irradiated specimens, as measured from the XRD data, is found to enhance monotonically from 40% to about 55%. Possible crystallinity enhancement mechanism of irradiated PTFE specimens via chain scission is discussed. [source]


Analysis of lattice-translocation disorder in the layered hexagonal structure of carboxysome shell protein CsoS1C

ACTA CRYSTALLOGRAPHICA SECTION D, Issue 9 2009
Yingssu Tsai
Lattice-translocation or crystal order,disorder phenomena occur when some layers or groups of molecules in a crystal are randomly displaced relative to other groups of molecules by a discrete set of vectors. In previous work, the effects of lattice translocation on diffraction intensities have been corrected by considering that the observed intensities are the product of the intensities from an ideal crystal (lacking disorder) multiplied by the squared magnitude of the Fourier transform of the set of translocation vectors. Here, the structure determination is presented of carboxysome protein CsoS1C from Halothiobacillius neapolitanus in a crystal exhibiting a lattice translocation with unique features. The diffraction data are fully accounted for by a crystal unit cell composed of two layers of cyclic protein hexamers. The first layer is fully ordered (i.e. has one fixed position), while the second layer randomly takes one of three alternative positions whose displacements are related to each other by threefold symmetry. Remarkably, the highest symmetry present in the crystal is P3, yet the intensity data (and the Patterson map) obey 6/m instead of symmetry; the intensities exceed the symmetry expected from combining the crystal space group with an inversion center. The origin of this rare phenomenon, known as symmetry enhancement, is discussed and shown to be possible even for a perfectly ordered crystal. The lattice-translocation treatment described here may be useful in analyzing other cases of disorder in which layers or groups of molecules are shifted in multiple symmetry-related directions. [source]


Tracking large solid constructs suspended in a rotating bioreactor: A combined experimental and theoretical study

BIOTECHNOLOGY & BIOENGINEERING, Issue 6 2009
L.J. Cummings
Abstract We present a combined experimental and theoretical study of the trajectory of a large solid cylindrical disc suspended within a fluid-filled rotating cylindrical vessel. The experimental set-up is relevant to tissue-engineering applications where a disc-shaped porous scaffold is seeded with cells to be cultured, placed within a bioreactor filled with nutrient-rich culture medium, which is then rotated in a vertical plane to keep the growing tissue construct suspended in a state of "free fall." The experimental results are compared with theoretical predictions based on the model of Cummings and Waters (2007), who showed that the suspended disc executes a periodic motion. For anticlockwise vessel rotation three regimes were identified: (i) disc remains suspended at a fixed position on the right-hand side of the bioreactor; (ii) disc executes a periodic oscillatory motion on the right-hand side of the bioreactor; and (iii) disc orbits the bioreactor. All three regimes are captured experimentally, and good agreement between theory and experiment is obtained. For the tissue engineering application, computation of the fluid dynamics allows the nutrient concentration field surrounding a tissue construct (a property that cannot be measured experimentally) to be determined (Cummings and Waters, 2007). The implications for experimental cell-culture protocols are discussed. Biotechnol. Bioeng. 2009; 104: 1224,1234. © 2009 Wiley Periodicals, Inc. [source]


The effects of momentum diffusers and flow guides on the efficiency of stratified hot water seasonal heat stores

INTERNATIONAL JOURNAL OF ENERGY RESEARCH, Issue 10 2008
V. Panthalookaran
Abstract Hot water seasonal heat stores (HWSHS) carry the solar thermal energy from energy-rich seasons of the year over to energy-poor seasons so as to ensure the availability of solar energy throughout the year. Momentum diffusers and flow guides are designed to charge and discharge the harvested solar thermal energy within HWSHS in a stratified manner to enhance the efficiency of the solar systems. To evaluate the efficiency of an HWSHS, a characterization scheme developed for general stratified thermal energy stores (TES) (Sol Energy 2007; 81:1043,1054) is used. It addresses the First Law and Second Law concerns over a TES simultaneously. This study is confined to systems that use the same nozzles at fixed positions in both charging and discharging cycles. Different parameters related to axial, conical and radial diffusers as well as a variety of flow-guide designs are studied. The results suggest that a nozzle that brings about better diffuser action by minimizing entropy generation may not necessarily improve the energy response and guarantee better overall efficiency of the HWSHS. Of all, the different nozzle designs experimented with the conical diffusers with smaller angles of diffusion produced the best overall efficiency. Copyright © 2008 John Wiley & Sons, Ltd. [source]