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Selected AbstractsA pilot-scale demonstration of a membrane-based absorption- stripping process for removal and recovery of volatile organic compoundsENVIRONMENTAL PROGRESS & SUSTAINABLE ENERGY, Issue 1 2001S. Majumdar A new membrane-based continuous absorption-stripping process has been developed to separate gas/vapor mixtures, such as volatile organic compounds (VOCs), from a nitrogen/air stream. Two different hollow fiber membrane modules are needed in this process to remove the VOCs. In the first module, VOC-laden nitrogen/air stream flows through the bore of the hollow fibers. A suitable absorbent liquid with a high solubility for the VOC and essentially no solubility for nitrogen/air is pumped countercurrently over the outside of the fibers. This liquid is an inert, nontoxic, and essentially nonvolatile, organic solvent. The VOCs are effectively removed from nitrogen/air to a very low level and are concentrated in the absorbent for recovery, while the absorbent is regenerated by heating and subjecting it to vacuum in a separate hollow fiber membrane module called the stripping module. A pilot-scale membrane-based absorption-stripping unit was located next to a paint spray booth at Robins Air Force Base, Warner Robins, GA. Tests were performed on slip-streams of real-time air emissions from scheduled intermittent painting operations, so the concentration of VOC in the exhaust air fluctuated with time. The VOC removal efficiency was determined as a function of the feed air flow rate and the absorbent (silicone oil) flow rate. Depending on the gas/liquid flow rates and the inlet VOC concentration, the process successfully removed as much as 95+% of the VOC present. The experimental results have been compared with theoretical predictions. [source] Indices for bioavailability and biotransformation potential of contaminants in soilsENVIRONMENTAL TOXICOLOGY & CHEMISTRY, Issue 7 2004Washington J. Braida Abstract Bioavailability is an important consideration in risk assessment of soil contaminants and in the selection of appropriate remediation technologies for polluted sites. The present study examined the bioavailability and biodegradation potential of phenanthrene with respect to a pseudomonad in 15 different soils through separate measurements of mineralization, transformation, and desorption to a polymeric infinite sink (Tenax®) after 180-d sterile pre-equilibration with phenanthrene. Fractions strongly resistant to desorption and mineralization at long times were evident in all cases. After correcting for bioconversion (moles mineralized per mole transformed) determined in aqueous particle-free soil extracts, a correlation was found between the biotransformation-resistant fraction and the Tenax desorption-resistant fraction. Indices are proposed to assess bioavailability (BAt) and biotransformation potential (BTPt) of a compound in a soil based on parallel desorption and degradation studies over a selected period t. The BAt is the ratio of moles biotransformed to moles desorbed to an infinite sink, and it reflects the biotransformation rate relative to the maximal desorption rate. Values of BA30 (30-d values) ranged from 0.64 (for dark gray silt loam) to 1.12 (Wurtsmith Air Force Base [AFB] 2B, Oscoda, MI, USA). The BTPt is the ratio between moles biotransformed and moles of contaminant remaining sorbed after maximal desorption. The BTPt provides an indication of the maximum extent of biotransformation that may be expected in a system, assuming desorption is a prerequisite for biodegradation. Values of BTP30 ranged between 0.3 (Wurtsmith AFB 1B) and 13 (Mount Pleasant silt loam, NY, USA). The combination of BAt and BTPt provides insights regarding the relationship between physical availability (desorption) and biological processes (biotransformation kinetics, toxicity, other soil factors) that occur during biodegradation and are suggested to represent the remediation potential of the chemical. The BA30 values less than 0.9 and BTP30 values less than five indicate poor potential for site remediation. [source] Postdeployment, Self-Reporting of Mental Health Problems, and Barriers to CarePERSPECTIVES IN PSYCHIATRIC CARE, Issue 4 2009Rosanne Visco PhD PURPOSE., This study explored the relationship between self-reported mental health symptoms and help-seeking behaviors of active-duty Air Force members. DESIGN AND METHODS., Mixed-methods approach reviewed 200 postdeployment surveys from active-duty members assigned to Eglin Air Force Base, Florida, USA. Chi-square analysis examined significance between self-reporting mental health problems and accessing treatment. FINDINGS., As the rate of self-reported mental health symptoms increased, active-duty members were less inclined to seek help. There were inconsistencies among gender for self-reporting and accessing services. PRACTICE IMPLICATIONS., Air Force psychiatric nurses need to be at the forefront of outreach services when treating combat-stressed troops. [source] In situ chemical oxidation of residual LNAPL and dissolved-phase fuel hydrocarbons and chlorinated alkenes in groundwater using activated persulfate,REMEDIATION, Issue 2 2009Joan Siegal A treatablity study (TS) was conducted to evaluate the efficacy of in situ chemical oxidation (ISCO) using activated persulfate, alone and in combination with air sparging (AS), for treating a source area contaminated with residual light nonaqueous-phase liquid (LNAPL), dissolved-phase fuel hydrocarbons (HCs), and dissolved-phase chlorinated alkenes at Edwards Air Force Base (AFB), California. The TS was implemented in two phases. Phase I included injecting a solution of sodium persulfate and sodium hydroxide (NaOH) into groundwater via an existing well where residual LNAPL and dissolved-phase contaminants were present. Because the results of Phase I indicated a limited distribution of the activated persulfate, Phase II was performed to assess whether AS could enhance the distribution of the sodium persulfate. Each phase was followed by groundwater monitoring and sampling at the injection well and at three monitoring wells, located 20 to 44 feet from the injection well. Results from Phases I and II of the TS indicated that (1) alkaline-activated persulfate was effective in promoting the dissolution of LNAPL and the degradation of dissolved-phase contaminants, but only at the injection well; (2) the addition of AS was effective in enhancing the radius of persulfate distribution from less than 20 feet to greater than 44 feet, and (3) persulfate alone (i.e., not in an activated state) was effective in reducing the concentrations of dissolved-phase fuel HC and chlorinated alkenes. © 2009 Wiley Periodicals, Inc. [source] Pilot-scale evaluation of in situ cometabolic bioremediation of TCE in groundwater using PHOSter® technologyREMEDIATION, Issue 2 2008Karl W. Eggers A study was conducted to evaluate the efficacy of PHOSter® technology for treating groundwater contaminated with trichloroethene (TCE) at Edwards Air Force Base, California. The technology consists of injecting a gaseous mixture of air, methane, and nutrients into groundwater with the objective of stimulating the growth of methanotrophs, a naturally occurring microbial group that is capable of catalyzing the aerobic degradation of chlorinated solvents into nontoxic products. Injection operations were performed at one well for a period of three months. Six monitoring wells were utilized for groundwater and wellhead vapor monitoring and for groundwater and microbial sampling. In the five monitoring wells located within 44 feet of the injection well, the following results were observed: dissolved oxygen concentrations increased to a range between 6 and 8 milligrams per liter (,g/L); the biomass of target microbial groups increased by one to five orders of magnitude; and TCE concentrations decreased by an average of 92 percent, and to below the California primary maximum contaminant level (MCL; 5 micrograms per liter [µg/L]) in the well closest to the injection well. © 2008 Wiley Periodicals, Inc., [source] Site characterization to support permeable reactive barrier designREMEDIATION, Issue 4 2005Lynn A. Morgan Careful design studies and selection of an effective technique for the installation of permeable reactive barriers (PRBs) are important contributors to the overall success of zero-valent iron PRBs. This article provides a case study summarizing the successful design and construction of a PRB installed at the former Carswell Air Force Base located in Fort Worth, Texas. Expedited site characterization using a cone penetrometer rig equipped with a mass spectrometer was employed to provide real-time characterization and lithologic data. These data proved to be invaluable for the design of the PRB and allowed for the development of an accurate preconstruction cost estimate. Field data gained from the expedited water quality and geologic characterization along with aquifer testing and a bench-scale treatability study provided a comprehensive basis for the design. The biopolymer slurry construction technique provided additional unanticipated benefits to the designed zero- valent iron treatment by promoting the development of anaerobic conditions favorable for microbial degradation of trichloroethene. Postconstruction monitoring data are discussed to illustrate the successful performance of the PRB. © 2005 Wiley Periodicals, Inc. [source] Treatment of Perchlorate-Contaminated Groundwater Using Highly Selective, Regenerable Ion-Exchange Technology: A Pilot-Scale DemonstrationREMEDIATION, Issue 2 2002Baohua Gu Treatment of perchlorate-contaminated groundwater using highly selective, regenerable ion-exchange technology has been recently demonstrated at Edwards Air Force Base, California. At an influent concentration of about 450 ,g/l ClO4,, the bifunctional anion-exchange resin bed treated approximately 40,000 empty bed volumes of groundwater before a significant breakthrough of ClO4, occurred. The presence of relatively high concentrations of chloride and sulfate in site groundwater did not appear to affect the ability of the bifunctional resin to remove ClO4,. The spent resin bed was successfully regenerated using the FeCl3,HCl regeneration technique recently developed at the Oak Ridge National Laboratory, and nearly 100 percent of sorbed ClO4, was displaced or recovered after elution with as little as about two bed volumes of the regenerant solution. In addition, a new methodology was developed to completely destroy ClO4, in the FeCl3,HCl solution so that the disposal of perchlorate-containing hazardous wastes could be eliminated. It is therefore anticipated that these treatment and regeneration technologies may offer an efficient and cost-effective means to remove ClO4, from contaminated groundwater with significantly reduced generation of waste requiring disposal. © 2002 Wiley Periodicals, Inc. [source] Rosette Recruitment of a Rare Endemic Forb (Gaura neomexicana Subsp. coloradensis) with Canopy Removal of Associated SpeciesRESTORATION ECOLOGY, Issue 1 2002Linda M. Munk Abstract Gaura neomexicana subsp. coloradensis Munz (Onagraceae), (Colorado butterfly plant), a short-lived perennial forb, became listed as a threatened species by the U.S. Fish and Wildlife Service in October 2000 because of its small global range and population size. This endemic subspecies consists of only 18 extant populations within southeastern Wyoming, southwestern Nebraska, and northeastern Colorado. Wyoming occurrences are on private land with the exception of three occurrences on F. E. Warren Air Force Base, near Cheyenne. Gaura neomexicana subsp. coloradensis may be displaced by many competitors, including Cirsium arvense (L.) Scop. (Canada thistle), an invasive, noxious weed. In June 1998, three G. neomexicana subsp. coloradensis populations were examined for rosette establishment in the presence of and after removal of associated species. The four study treatments removed: (1) Cirsium arvense, (2) grass and forb canopy and associated litter, (3) grass and forb canopy, litter, and C. arvense, and (4) no removal of associated plant species (control). Mature G. neomexicana subsp. coloradensis plants were evaluated for height, number of leaves, and capsule production. The mature plant characteristics monitored in 1998 were not good indicators of subsequent G. neomexicana subsp. coloradensis rosette densities in the following spring. Recruitment was assessed by counting new rosettes in the fall 1999. Although both G. neomexicana subsp. coloradensis and the exotic C. arvense have comparable habitat, removal of C. arvense did not increase G. neomexicana subsp. coloradensis vegetative growth, seed capsule production, or rosette density. Removal of other forbs, grass, and litter, however, increased G. neomexicana subsp. coloradensis rosette density in the following two years, indicating that canopy removal of associated species can enhance rosette establishment of this rare native. The accumulation of dense vegetative cover and litter associated with the absence of herbivory and fire may contribute to the decline of rare species in rich riparian habitats. Return of herbivory and fire in mesic sites to reduce standing biomass accumulations should be considered in restoring recruitment potential to rare monocarpic species. [source] |