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Ferromagnetic Phase (ferromagnetic + phase)
Selected AbstractsMultifunctional FeCo/TiN Multilayer Thin Films with Combined Magnetic and Protective Properties,ADVANCED ENGINEERING MATERIALS, Issue 12 2009Christian Klever Abstract Coatings with thicknesses ranging from a few nanometer up to several micrometer produced by physical vapor deposition (PVD) processes have been established in engineering technologies since the early 1980s. In particular, magnetron sputtered wear resistance coatings are industrially established and capable to enhance tool lifetimes significantly. However, in cases where optical inspection of a coating in use is not possible, an intrinsic sensor function of the film would be beneficial. Therefore, the development of wear resistant coatings with an integrated sensor functionality based on the insertion of a magnetoelastic ferromagnetic phase is suggested. In combination with appropriate read-out electronics such a film system would be ready for online monitoring of the coatings' actual state (e.g., strain, temperature, volume loss). This paper focuses on the development of wear resistance coatings which simultaneously supply beneficial mechanical properties as well as ferromagnetic properties optimized for online non-contact read-out applications. Multilayer coatings obtained through alternate stacking of magnetron sputtered TiN and FeCo layers with a nominal total thickness of 1000,nm were produced as a model system meeting the above conditions. The bilayer period was varied down to 2.6,nm while the individual layer thickness ratio tTiN/tFeCo was determined by the deposition rates and maintained constant at a value of about 3/1. The films were vacuum annealed ex situ in a static magnetic field subsequent to the deposition. The constitution of the as-deposited and annealed coatings as well as their mechanical (nanohardness, Young's modulus) and magnetic properties (magnetization hysteresis, frequency-dependent permeability) are described. Finally, the suitability of the coatings for the use in remote-interrogable wear sensor applications is briefly discussed. [source] Nitrided Amorphous Stainless Steel Coatings Deposited by Reactive Magnetron Sputtering from an Austenitic Stainless Steel TargetADVANCED ENGINEERING MATERIALS, Issue 1-2 2009Salvatore Cusenza Abstract Stainless steel films were reactively magnetron sputtered in argon/nitrogen gas flow onto oxidized silicon wafers using austenitic AISI 316 stainless-steel targets. The deposited films of about 300,nm thickness were characterized by conversion electron Mö-i;ssbauer spectroscopy, magneto-optical Kerr-effect, X-ray diffraction, Rutherford backscattering spectrometry, and resonant nuclear reaction analysis. These complementary methods were used for a detailed examination of the nitriding effects for the sputtered stainless-steel films. The formation of an amorphous and soft ferromagnetic phase in a wide range of the processing parameters was found. Further, the influence of postvacuum-annealing was examined by perturbed angular correlation to achieve a comprehensive understanding of the nitriding process and phase formation. The amorphous phase is not very stable and crystallization can be observed at 973,K. [source] Photoinduced Faraday rotation in the magnetic semiconductor CdCr2Se4PHYSICA STATUS SOLIDI (A) APPLICATIONS AND MATERIALS SCIENCE, Issue 4 2004L. L. Golik Abstract A growth of the excitonic peak in the absorption spectrum and an enhancement of the Faraday rotation band (approximately 50% of the linear effect value) were induced by intensive radiation of Nd3+ -laser (h, = 1.17 eV) in ferromagnetic phase of magnetic semiconductor CdCr2Se4. The photoinduced effects increased during a pumping pulse and also with growth of pump intensity. In studies of the non-linear Faraday rotation a change of the spectral band shape was observed along with the growth of the rotation angle. The observed effects can be explained by the screening of internal electric fields existing in CdCr2Se4 crystals by photoexcited charge carriers. (© 2004 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) [source] Quantum and thermal effects in the double exchange ferromagnetPHYSICA STATUS SOLIDI (B) BASIC SOLID STATE PHYSICS, Issue 2 2003N. Shannon Abstract The physics of the ferromagnetic phase of the "double exchange" model has been widely discussed in the context of the CMR manganites. Usually, the double exchange ferromagnet is treated is classically, by mapping it onto an effective Heisenberg model. However this mapping does not permit a correct treatment of quantum or thermal fluctuation effects, and the results obtained lack many of the interesting features seen in experiments on the manganites. Here we outline a new analytic approach to systematically evaluating quantum and thermal corrections to the magnetic and electronic properties of the double exchange ferromagnet. [source] Effect of hydrostatic pressure on the transport properties in magnetic semiconductorsPHYSICA STATUS SOLIDI (C) - CURRENT TOPICS IN SOLID STATE PHYSICS, Issue 12 2004M. Csontos Abstract The effect of pressure on the ferromagnetic phase transition has been studied in manganese doped III-V semiconductors by electrical conductance and Hall measurements. We found that the application of hydrostatic pressure shifts the transition temperature upwards both in (In,Mn)Sb and (Ga,Mn)As. The anomalous-Hall coefficient shows a dramatic increase in the hysteresis loops in the ferromagnetic phase and an enhanced magnetization both below and above the phase transition. As the normal-Hall results suggest that the pressure does not change the carrier density [in (In,Mn)Sb] or rather decreases it [in (Ga,Mn)As], all the above observations are indicative of a pressure-induced enhancement of magnetic coupling. [source] Chemical Bonding Assembly of Multifunctional Oxide NanocompositesADVANCED FUNCTIONAL MATERIALS, Issue 2 2010Gary Evans Abstract The synthesis, functionalization and assembly of metal oxide nanoparticles BaTiO3 and CoFe2O4 is presented. The ferroelectric (BaTiO3) and ferromagnetic (CoFe2O4) oxide nanoparticle surfaces are directly functionalized via the anchoring of phosphonic acid and aminosilane molecules that engender the nanoparticles with terminal carboxylic acid and amine functional groups, respectively. These promote the electrostatic self-assembly of the particles in non-polar solvents and permit the synthesis of more chemically robust assemblies linked by the covalent amide bond via the addition of the chemical coupling agent N - N, -dicyclohexylcarbodiimide. This functionalization and assembly procedure is applied to two systems: the first comprised of 50,nm BaTiO3 and 10,nm CoFe2O4 particles and the second of 200,nm BaTiO3 and 12.5,nm CoFe2O4 particles. The latter composites possess magnetoelectric properties when processed into dense ceramics and, as a direct result of the assembly performed in solution, have a high degree of homogeneity between the ferroelectric and ferromagnetic phases. The developed functionalization and assembly procedure is considered to be adaptable to the preparation of other hybrid oxide nanomaterials with different property combinations. [source] Paramagnetic and ferromagnetic anisotropy of magnetic susceptibility in migmatites: measurements in high and low fields and kinematic implicationsGEOPHYSICAL JOURNAL INTERNATIONAL, Issue 3 2004Eric C. Ferré SUMMARY The separation of paramagnetic and ferromagnetic anisotropy of magnetic susceptibility (AMS) is achieved in this study by using a vibrating sample magnetometer and a torque magnetometer performing directional anisotropy measurements in sufficiently high fields to saturate the ferromagnetic phases. The studied material, a migmatite from Minnesota, has a magnetic mineralogy characterized by ferrimagnetic multidomain titanomagnetite, paramagnetic biotite and a diamagnetic quartzo-feldspathic matrix. The low-field AMS represents the sum of ferromagnetic and paramagnetic contributions because the quartz contribution can be neglected, its magnetic susceptibility being two orders of magnitude smaller than that of biotite. In contrast, measurements in a high field isolate the paramagnetic component of the magnetic fabric. The high-field AMS is consistent between specimens and correlates well with measurements done using the torque magnetometer. The magnetic fabrics of the ferromagnetic and of the paramagnetic minerals are not co-axial, i.e. the subfabrics of the biotite and the magnetite are distinct. We propose that this non-coaxiality is due to a vorticity component during regional deformation and that it reflects the general conditions of deep crustal orogenic deformation. [source] Dilute Doping, Defects, and Ferromagnetism in Metal Oxide SystemsADVANCED MATERIALS, Issue 29 2010Satishchandra B. Ogale Over the past decade intensive research efforts have been carried out by researchers around the globe on exploring the effects of dilute doping of magnetic impurities on the physical properties of functional non-magnetic metal oxides such as TiO2 and ZnO. This effort is aimed at inducing spin functionality (magnetism, spin polarization) and thereby novel magneto-transport and magneto-optic effects in such oxides. After an early excitement and in spite of some very promising results reported in the literature, this field of diluted magnetic semiconducting oxides (DMSO) has continued to be dogged by concerns regarding uniformity of dopant incorporation, the possibilities of secondary ferromagnetic phases, and contamination issues. The rather sensitive dependence of magnetism of the DMSO systems on growth methods and conditions has led to interesting questions regarding the specific role played by defects in the attendant phenomena. Indeed, it has also led to the rapid re-emergence of the field of defect ferromagnetism. Many theoretical studies have contributed to the analysis of diverse experimental observations in this field and in some cases to the predictions of new systems and scenarios. In this review an attempt is made to capture the scope and spirit of this effort highlighting the successes, concerns, and questions. [source] Phase diagram of a thin Heisenberg antiferromagnetic filmPHYSICA STATUS SOLIDI (B) BASIC SOLID STATE PHYSICS, Issue 9 2007J. Cabral Neto Abstract We investigate the thickness dependence of the Néel temperature of a thin quantum spin-1/2 Heisenberg antiferromagnetic film as a function of the magnetic field on a simple cubic lattice. The Néel temperature TN(H, ,) is obtained by using the framework of the effective-field theory for films consisting of , = 2, 3, 5, 10 and , (bulk) interacting layers. We present the phase diagram of T versus H in the whole range of the magnetic field for several values of ,. A continuous phase-transition line separating the antiferromagnetic and ferromagnetic phases is observed. The critical temperature TN(H, ,) of the film is smaller than the corresponding bulk critical temperature (H) , TN(H, ,) of the infinite system, which has been analyzed recently by Bublitz Filho and de Sousa [Phys. Lett. A 323, 9 (2004)]; as , is increased, TN(H, ,) also increases and approaches (H) for large values of ,. We have, also, studied the quantum phase transition where three critical fields were found: Hc(,) = 6.224 for , , 3 (three-dimensional regime), Hc(, = 2) = 5.210 (intermediate regime) for , = 2 and, finally, the two-dimensional regime at , = 1 with Hc(, = 1) = 4.194. (© 2007 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) [source] | |||||||||||||