Expansion Ratio (expansion + ratio)

Distribution by Scientific Domains
Distribution within Chemistry


Selected Abstracts


Analysis of OTA-C filters with weakly nonlinear transconductors

INTERNATIONAL JOURNAL OF CIRCUIT THEORY AND APPLICATIONS, Issue 7 2008
Slawomir KozielArticle first published online: 11 OCT 200
Abstract An efficient approach for analysis of nonlinear distortion in OTA-C filters with weakly nonlinear transconductors is presented. The procedure is developed based on an algebraic description of a general OTA-C filter structure and, therefore, the results are valid for any filter architecture within OTA-C class. On the basis of the proposed method, explicit formulas for calculating a gain compression/expansion ratio in an arbitrary OTA-C filter are developed. The formulas are easy to implement and use in computer-aided filter design tools. For illustration purposes, several filter structures are considered. The accuracy of the method is verified by comparing the results with the exact values of gain compression/expansion ratio achieved by integrating the differential system that determines the time response of OTA-C filter. The presented approach can be generalized in order to consider other nonlinear parameters. Copyright © 2007 John Wiley & Sons, Ltd. [source]


Electrokinetic instability effects in microchannels with and without nanofilm coatings

ELECTROPHORESIS, Issue 24 2008
Lung-Ming Fu
Abstract This paper presents a parametric experimental investigation into the electrokinetic instability (EKI) phenomenon within three different types of microfluidic device, namely T-type, cross-shaped, and cross-form with an expansion configuration. The critical electric field strength at which the EKI phenomenon is induced is examined as a function of the conductivity ratio, the microchannel width, the expansion ratio, and the surface treatment of the microchannel walls. It is found that the critical electric field strength associated with the onset of EKI is strongly dependent on the conductivity ratio of the two samples within the microfluidic device and reduces as the channel width increases. The surfaces of the microchannel walls are coated with hydrophilic or hydrophobic organic-based spin-on-glass (SOG) nanofilms for glass-based microchips. The experimental results indicate that no significant difference exists in the critical electric field strengths in the hydrophilic or hydrophobic SOG-coated microchannels, respectively. However, for a given conductivity ratio and microchannel width, the critical strength of the electric field is slightly lower in the SOG-coated microchannels than in the non-coated channels. In general, the results presented in this study demonstrate the potential for designing and controlling on-chip assays requiring the manipulation of samples with high conductivity gradients, and provide a useful general reference for avoiding EKI effects in capillary electrophoresis analysis applications. [source]


Optimising microwave vacuum puffing for blue honeysuckle snacks

INTERNATIONAL JOURNAL OF FOOD SCIENCE & TECHNOLOGY, Issue 3 2010
Chenghai Liu
Abstract Fresh blue honeysuckle fruit slices were puffed in a microwave vacuum dryer up to a final moisture content about 5% (w.b.). The effect of initial moisture content (IMC) (25,45%), vacuum pressure (VP) (70,90 kPa) and microwave intensity (MI) (10,30 W g,1) on quality attributes, in terms of expansion ratio (ER), hardness (HD), crispness (CR) and colour of the products, were analysed by response surface methodology. Besides the effect of MI on chroma (CH), the high IMC and low VP had a significantly positive impact on the quality attributes of blue honeysuckle snacks. The optimum product qualities, which were ER (1.62 times), HD (5836.31 g), CR (4.48), and CH (28.7) were obtained at an IMC of 38.42%, VP of 82.02 kPa, and MI of 22.42 W g,1. The microwave vacuum method has obvious advantages when puffing the blue honeysuckle snacks. [source]


Effect of extrusion parameters on flavour retention, functional and physical properties of mixtures of starch and d -limonene encapsulated in milk protein

INTERNATIONAL JOURNAL OF FOOD SCIENCE & TECHNOLOGY, Issue 2006
Sri Yuliani
Summary The purpose of this research was to investigate the retention of flavour volatiles encapsulated in water-insoluble systems during high temperature,short time extrusion process. A protein precipitation method was used to produce water-insoluble capsules encapsulating limonene, and the capsules were added to the extruder feed material (cornstarch). A twin-screw extruder was used to evaluate the effect of capsule level of addition (0,5%), barrel temperature (125,145 °C) and screw speed (145,175 r.p.m.) on extruder parameters (torque, die pressure, specific mechanical energy, residence time distribution) and extrudate properties [flavour retention, texture, colour, density, expansion, water absorption index, water solubility index (WSI)]. Capsule level had a significant effect on extrusion conditions, flavour retention and extrudate physical properties. Flavour retention increased with the increase in capsule level from 0% to 2.5%, reached a maximum value at capsule level of 2.5% and decreased when the capsule level increased from 2.5% to 5%. The die pressure, torque, expansion ratio, hardness and WSI exhibited the opposite effect with the presence of capsules. [source]


Physical characterization of starch extrudates as a function of melting transitions and extrusion conditions

ADVANCES IN POLYMER TECHNOLOGY, Issue 4 2004
Stéphanie Blanche
Abstract The objective of this study was to investigate the relationships between starch melt transition characteristics, extrusion conditions, and final product properties. Cornstarch was extruded using a corotating twin-screw extruder at varying moisture content, medium/high screw configuration, and 300/400-rpm screw speeds. Extrudates were evaluated for bulk density, expansion ratio, cell structure, bending strength, thermal and pasting properties. Temperature change (,T) was defined as the temperature difference between the native starch melting temperature and its melt temperature just behind the die during extrusion at a given moisture content. ,T was significantly affected by starch moisture content and mechanical shearing, which controlled the melting behavior of the starch in the barrel. Amylose,lipid complex formation during extrusion increased as ,T increased and leveled off at ,T of about 20°C. Pasting peak viscosity of the starch extrudates decreased as ,T increased and leveled off at ,T of about 15°C. Within the same range of mechanical shearing intensity, extrudate bulk density and bending strength decreased linearly as ,T increased. Extrudate expansion was negatively correlated to bulk density. © 2004 Wiley Periodicals, Inc. Adv Polym Techn 23: 277,290, 2004; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/adv.20017 [source]


QUALITIES OF EXTRUDED PUFFED SNACKS FROM MAIZE/SOYBEAN MIXTURE

JOURNAL OF FOOD PROCESS ENGINEERING, Issue 2 2006
A. OBATOLU VERONICA
ABSTRACT A maize-based snack was fortified with partially defatted soybean (PDS) at 10, 20 and 30% of total weight and analyzed for physical (expansion ratio, density, color and texture [brittleness, breaking strength and hardness]), chemical and sensory characteristics. Incorporating PDS in a maize-based snack had a positive effect on chemical properties but had a negative effect on the physical and sensory characteristics. The results showed a protein range of 9.3 ± 0.90% in 100% maize-based snacks to 19.3 ± 1.03% in 30% replacements with soybean. The overall consumer acceptability test showed a score range between 4.1 ± 0.82 in 30% level of fortification and 8.2 ± 1.04 in 100% maize and 10% fortified extrudate. Panelists perceived the puffed extrudates with 20 and 30% PDS as not puffy or crispy, less acceptable and harder to crack. Up to 20% of PDS could be used in maize-based puffed extrudates. [source]


Influence of Sulfonation on the Properties of Expanded Extrudates Containing 32% Whey Protein

JOURNAL OF FOOD SCIENCE, Issue 2 2006
David P. Taylor
ABSTRACT Whey protein concentrate (WPC) was treated with sodium sulfite to achieve 4 levels of disulfide bond sulfonation (0%, 31%, 54%, and 71% mole/mole). The WPCs were blended with cornstarch to a 32% (weigh/weight) protein content and extruded into an expanded product. Extrudates were collected at 160 °C and 170 °C and analyzed for physical (air cell diameter, expansion ratio, breaking strength, and density) and chemical (water adsorption index [WAI], water solubility index, moisture content, soluble protein, and carbohydrates) properties. The control and 54% sulfonated samples had larger expansion ratios and air cell diameters and smaller densities and breaking strengths than the 31% and 71% samples. Expansion increased at 170 °C in the sulfonated samples. The WAI was influenced by both sulfonation and temperature, whereas the other chemical properties (except moisture content) were influenced only by sulfonation level. Soluble protein and carbohydrate were highest in the control and 54% samples. The anomalous behavior of the 54% sample may have been the result of significant structural and functional changes of ,-lactalbumin that are predicted to occur at approximately 50% sulfonation. Many functional properties of the WPCs were measured and were significantly correlated to the extrudate properties, particularly those related to protein unfolding and flexibility The increased ability for the proteins to become unfolded during extrusion may have promoted protein-starch interactions, which led to decreases in expansion and overall quality Disulfide bond content did influence the chemical and physical properties of an extruded-expanded whey protein products. [source]


Extrusion Cooking Process for Amaranth (Amaranthus caudatus L.)

JOURNAL OF FOOD SCIENCE, Issue 6 2000
R.N. Chávez-Jáuregui
ABSTRACT: Amaranth (Amaranthus caudatus L.) extrusion was optimized by response surface methodology (RSM). Response (dependent) variables were: expansion ratio, shearing strength, and sensory texture acceptability. Independent variables were processing temperature and feed moisture. All other process variables (screw speed, screw compression ratio, feed speed, and die diameter) were kept constant (200 rpm, 70 g.min,1, and 3 mm, respectively). The most expanded products also had the best texture and were obtained at 150 °C and 15% moisture. These conditions resulted in greater expansion, greater shearing force of extrudates, greater extrudate surface area per unit weight, and reduced shearing stress at maximum shearing force. This study showed that under conditions that induced the maximum expansion ratio, extrusion produced a highly acceptable snack product based on amaranth flour. [source]


Steeping-induced physicochemical changes of milled waxy rice and their relation to the quality of yukwa (an oil-puffed waxy rice snack)

JOURNAL OF THE SCIENCE OF FOOD AND AGRICULTURE, Issue 5 2004
Sung Bin Cho
Abstract The influence of water-steeping periods (0 to 15 days, 25 °C) on the physicochemical properties of raw waxy rice in relation to the yukwa quality was investigated. The moisture contents in waxy rice and reducing sugar in its steeping medium were increased, while contents of protein and minerals of raw waxy rice were decreased in proportion to the water-steeping duration. With longer steeping periods, swelling power, solubility and peak viscosity were increased, while grain hardness was decreased with apparent kernel structural change. Depending on the water-steeping duration of raw waxy rice, the hardness decreased from 26.0 to 1.8 g, and the expansion ratio of yukwa increased from 762 to 1539%. Correlations between the physicochemical properties and yukwa quality indicated that variables having the most positive influential on expansion ratio were reducing sugar (, = 0.961, P < 0.01) and peak viscosity (, = 0.897, P < 0.01), and those for hardness of yukwa were crude protein (, = 0.875, P < 0.01) and hardness (, = 0.887, P < 0.01) of the steeped waxy rice. It is suggested that steeping-induced physicochemical changes of raw waxy rice had a significant influence on the final quality of yukwa in terms of hardness and expansion ratio. Copyright © 2004 Society of Chemical Industry [source]


Chemical composition and physical properties of extruded snacks containing crab-processing by-product

JOURNAL OF THE SCIENCE OF FOOD AND AGRICULTURE, Issue 11 2003
Michael G Murphy
Abstract The crab-processing industries generate millions of pounds of by-product annually, which results in a loss of edible product and presents a considerable waste disposal problem. The purpose of this research was to investigate the use of crab-processing by-product (CB) in the development of a calcium-rich expanded snack. The specific objectives were to examine the effects of type of CB (wet or dry), feed composition and screw speed (150 or 250 rpm) on selected properties of extruded snacks. Product formulations consisting of 0,400 g kg,1 CB combined with corn meal and potato flakes were processed in a twin-screw extruder. The resulting extrudates were analysed for proximate and mineral (calcium, sodium) composition, pH, water activity (aw), total plate count, bulk density, expansion ratio and colour. Both CB type and level of incorporation had significant effects (P < 0.05) on the calcium content, expansion ratio, bulk density and pH of the extrudates. Increasing the CB level resulted in increased calcium content (from 5.1 to 52.4 mg g,1) and pH (from 6.1 to 8.8). Screw speed had no significant effects (P > 0.05) on expansion ratio and bulk density. A high processing temperature (157 °C) and low aw resulted in undetectable microbial growth on the extrudates. This research demonstrates that ground crab-processing by-product can be successfully incorporated into an expanded snack product. Further research will evaluate consumer response to this novel value-added product. Copyright © 2003 Society of Chemical Industry [source]


Effect of eggshell powder as nucleating agent on the structure, morphology and functional properties of normal corn starch foams,

PACKAGING TECHNOLOGY AND SCIENCE, Issue 3 2007
Yixiang Xu
Abstract Corn starch and eggshell powder (with particle sizes of 4,5µm and 8,10µm) composite foams were prepared by extrusion. Effects of eggshell on the structure, morphology, physical properties (unit density and expansion ratio), mechanical properties (spring index and compressibility) and thermal behaviour (thermal transition and stability) of the foams were investigated. Foam cell size decreased and cell population increased with addition of eggshell into starch matrix. The foam unit density, expansion ratio and compressibility decreased significantly (p < 0.05), while the spring index increased significantly (p < 0.05) as the eggshell content increased from 0 to 6wt%. Further increasing eggshell content to 10wt% increased the unit density and compressibility and decreased the expansion ratio and spring index. The thermal transition and stability increased with the addition of eggshell. The optimum eggshell content was 6wt% and the smaller-sized eggshell powder had a favourable effect on the functional properties of the foams. Copyright © 2006 John Wiley & Sons, Ltd. [source]


Response surface optimization of the feed compositions of biodegradable packaging foams

PACKAGING TECHNOLOGY AND SCIENCE, Issue 6 2005
Jinchyau Peng
Abstract Response surface methodology (RSM) was used to analyse the effects of polyvinyl alcohol (PVOH) and calcium carbonate (CaCO3) on the physical and mechanical properties (radial expansion ratio, bulk density, compressibility and spring index) of a biodegradable cushioning extrudate. A rotatable central-composite design (CCD) was used to develop models for the objective responses. The experiments were run at 125°C with a feed rate of 27.8,l/h, screw speed of 215,r.p.m. and die diameter of 3.92,mm. Responses were most affected by changes in PVOH levels and to a lesser extent by CaCO3 levels. Individual contour plots of the different responses were overlaid. An optimum radial expansion ratio of 3.39, bulk density of 0.065 (g/cm3), compressibility of 32.27(N), and spring index of 0.906 were identified at 36% PVOH and 5% CaCO3. Copyright © 2005 John Wiley & Sons, Ltd. [source]


Tailoring viscoelastic and mechanical properties of the foamed blends of EVA and various ethylene-styrene interpolymers

POLYMER COMPOSITES, Issue 3 2003
I-Chun Liu
Foamed materials (EVA/ESI) have been prepared from blends of ethylene-vinyl acetate copolymer (EVA) and ethylene-styrene interpolymers (ESI) in the presence of various amounts of dicumyl peroxide (DCP). Four ESIs of different compositions were employed in this study; their styrene contents ranged from 30 to 73 wt% and their Tg ranged from ,2 to 33°C. It has been found that microcellular morphology, degree of crosslinking and expansion ratio were strongly affected by the DCP concentration and the type of ESI employed. A minimum degree of crosslinking was required for making good foams and the same degree of crosslinking could be achieved by employing a smaller amount of DCP for an EVA/ESI blend having a higher styrene content. In contrast to other EVA blends, such as EVA/LDPE, these EVA/ESI blends exhibited no existence of any optimum DCP concentration, and the , glass transition temperatures of the foams varied with the ESI type, covering a wide span from 0°C to 37°C. Therefore, it was possible to tailor the Tg of an EVA/ESI blend by choosing an appropriate type of ESI. Furthermore, by correctly tailoring the Tg, the EVA/ESI foam could be made into a rubbery material with a custom-designed damping factor. Tensile strength and modulus of the EVA/ESI foams increased generally with an increase in the styrene content, with the exception that ESIs with very low styrene content will confer on the blend a high modulus at small strain and a large elongation at break. [source]


Foaming of PS/wood fiber composites using moisture as a blowing agent

POLYMER ENGINEERING & SCIENCE, Issue 10 2000
Ghaus Rizvi
This paper presents an experimental study on foam processing of polystyrene (PS) and high-impact polystyrene HIPS/wood-fiber composites in extrusion using moisture as a blowing agent. Wood-fiber inherently contains moisture that can potentially be used as a blowing agent. Undried wood-fiber was processed together with PS and HIPS materials in extrusion and wood-fiber composite foams were produced. The cellular morphology and volume expansion ratios of the foamed composites were characterized. Because of the high stiffness of styrenic materials, moisture condensation during cooling after expansion at high temperature did not cause much contraction of the foamed composite and a high volume expansion ratio up to 20 was successfully obtained. The experimental results showed that the expansion ratio could be controlled by varying the processing temperature and the moisture content in the wood fiber. The effects of a small amount of a chemical blowing agent and mineral oil on the cell morphologies of plastic/wood-fiber composite foams were also investigated. [source]


Polystyrene microcellular plastic generation by quick-heating process at high temperature

POLYMER ENGINEERING & SCIENCE, Issue 7 2000
Sumarno
Generation of microcellular plastic in the polystyrene-nitrogen system was studied in a batch process. In this study, a quick-heating method was applied to study the effects of saturation temperature, decompression rate and heating time on the microcellular structure for sheet samples with a thickness of 1.3 mm. The saturation pressure in each process was kept constant at 25 MPa. At saturation temperatures above 393 K, we found that, although the solubility of nitrogen increased with increasing saturation temperature, cell density decreased, and the average cell diameter and volume expansion ratio increased. The samples that were saturated at 433 K shattered after microcellular processing. The change in decompression rate affected the supersaturation degree of the dissolved gas in the polymer, and affected the cell structure. Variation of heating time for difference saturation/heating temperature could be used to obtain the optimum relation between cell density, average cell diameter, and volume expansion ratio. [source]


Experimental and computational study of the bed dynamics of semi-cylindrical gas,solid fluidized bed

THE CANADIAN JOURNAL OF CHEMICAL ENGINEERING, Issue 1 2009
A. Sahoo
Abstract With computational fluid dynamics (CFD) it is possible to get a detailed view of the flow behaviour of the fluidized beds. A profound and fundamental understanding of bed dynamics such as bed pressure drop, bed expansion ratio, bed fluctuation ratio, and minimum fluidization velocity of homogeneous binary mixtures has been made in a semi-cylindrical fluidized column for gas,solid systems, resulting in a predictive model for fluidized beds. In the present work attempt has been made to study the effect of different system parameters (viz., size and density of the bed materials and initial static bed height) on the bed dynamics. The correlations for the bed expansion and bed fluctuations have been developed on the basis of dimensional analysis using these system parameters. Computational study has also been carried out using a commercial CFD package Fluent (Fluent, Inc.). A multifluid Eulerian model incorporating the kinetic theory for solid particles was applied in order to simulate the gas,solid flow. CFD simulated bed pressure drop has been compared with the experimental bed pressure drops under different conditions for which the results show good agreements. La simulation par ordinateur de la dynamique des fluides (CFD) permet de décrire le comportement des écoulements dans les lits fluidisés. Une étude fondamentale et approfondie de la dynamique de lit, tels la perte de charge de lit, le taux d'expansion de lit, le taux de fluctuation de lit et la vitesse de fluidisation minimale de mélanges binaires homogènes, a été réalisée dans une colonne fluidisée semi-cylindrique pour des systèmes solides de gaz, permettant d'obtenir un modèle prédictif pour les lits fluidisés. Dans le présent travail, on a tenté d'étudier l'effet de différents paramètres de système (à savoir, la taille et la masse volumique des matériaux de lit et la hauteur statique initiale de lit) sur la dynamique de lit. Des corrélations ont été établies pour l'expansion de lit et les fluctuations de lit en s'appuyant sur l'analyse dimensionnelle de ces paramètres de système. Une étude par ordinateur a également été menée à l'aide du logiciel commercial de CFD Fluent (Fluent, Inc.). Un modèle eulérien multifluide faisant appel à la théorie cinétique pour les particules solides a été utilisé afin de simuler l'écoulement gaz-solides. La perte de charge de lit simulée par la CFD a été comparée à la perte de charge de lit expérimentale dans différentes conditions et les résultats montrent un bon accord. [source]


Effect of nanoclay on the microcellular structure and morphology of high internal phase emulsion (HIPE) foams

ASIA-PACIFIC JOURNAL OF CHEMICAL ENGINEERING, Issue 2 2009
M. Serry Ahmed
Abstract High internal phase emulsion (HIPE) polymerization foaming process is controlled for the production of novel foams with various microcellular structures and morphologies. In this study, two types of organoclay and one type of natural clay, sodium montmorillonite (NaMMT) were introduced at different concentrations to control the microcellular morphologies, cell sizes and open cell contents. A scanning electron microscopy was used to observe the microcellular morphologies and open cell contents; volume expansion ratio (VER) and cell sizes were evaluated. It was believed that the open cell contents increased as organoclay content increased, due to the lowering of the viscosity ratio of dispersed to continuous phases, as a result of adding nanoclay into the oil phase of emulsion. A correlation between the open cell content and VER that depended on clay content was attempted and the result was quite satisfactory. Copyright © 2008 Curtin University of Technology and John Wiley & Sons, Ltd. [source]


Influence of Sulfonation on the Properties of Expanded Extrudates Containing 32% Whey Protein

JOURNAL OF FOOD SCIENCE, Issue 2 2006
David P. Taylor
ABSTRACT Whey protein concentrate (WPC) was treated with sodium sulfite to achieve 4 levels of disulfide bond sulfonation (0%, 31%, 54%, and 71% mole/mole). The WPCs were blended with cornstarch to a 32% (weigh/weight) protein content and extruded into an expanded product. Extrudates were collected at 160 °C and 170 °C and analyzed for physical (air cell diameter, expansion ratio, breaking strength, and density) and chemical (water adsorption index [WAI], water solubility index, moisture content, soluble protein, and carbohydrates) properties. The control and 54% sulfonated samples had larger expansion ratios and air cell diameters and smaller densities and breaking strengths than the 31% and 71% samples. Expansion increased at 170 °C in the sulfonated samples. The WAI was influenced by both sulfonation and temperature, whereas the other chemical properties (except moisture content) were influenced only by sulfonation level. Soluble protein and carbohydrate were highest in the control and 54% samples. The anomalous behavior of the 54% sample may have been the result of significant structural and functional changes of ,-lactalbumin that are predicted to occur at approximately 50% sulfonation. Many functional properties of the WPCs were measured and were significantly correlated to the extrudate properties, particularly those related to protein unfolding and flexibility The increased ability for the proteins to become unfolded during extrusion may have promoted protein-starch interactions, which led to decreases in expansion and overall quality Disulfide bond content did influence the chemical and physical properties of an extruded-expanded whey protein products. [source]


Foaming of PS/wood fiber composites using moisture as a blowing agent

POLYMER ENGINEERING & SCIENCE, Issue 10 2000
Ghaus Rizvi
This paper presents an experimental study on foam processing of polystyrene (PS) and high-impact polystyrene HIPS/wood-fiber composites in extrusion using moisture as a blowing agent. Wood-fiber inherently contains moisture that can potentially be used as a blowing agent. Undried wood-fiber was processed together with PS and HIPS materials in extrusion and wood-fiber composite foams were produced. The cellular morphology and volume expansion ratios of the foamed composites were characterized. Because of the high stiffness of styrenic materials, moisture condensation during cooling after expansion at high temperature did not cause much contraction of the foamed composite and a high volume expansion ratio up to 20 was successfully obtained. The experimental results showed that the expansion ratio could be controlled by varying the processing temperature and the moisture content in the wood fiber. The effects of a small amount of a chemical blowing agent and mineral oil on the cell morphologies of plastic/wood-fiber composite foams were also investigated. [source]


Calculation of the Energy of Explosives with a Partial Reaction Model.

PROPELLANTS, EXPLOSIVES, PYROTECHNICS, Issue 1 2006
Comparison with Cylinder Test Data
Abstract The energy delivered by explosives is described by means of the useful expansion work along the isentrope of the detonation products. A thermodynamic code (W-DETCOM) is used, in which a partial reaction model has been implemented. In this model, the reacted fraction of the explosive in the detonation state is used as a fitting factor so that the calculated detonation velocity meets the experimental value. Calculations based on such a model have been carried out for a number of commercial explosives of ANFO and emulsion types. The BKW (Becker-Kistiakowsky-Wilson) equation of state is used for the detonation gases with the Sandia parameter set (BKWS). The energy delivered in the expansion (useful work) is calculated, and the values obtained are compared with the Gurney energies from cylinder test data at various expansion ratios. The expansion work values obtained are much more realistic than those from an ideal detonation calculation and, in most cases, the values predicted by the calculation are in good agreement with the experimental ones. [source]