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Excitation Mechanism (excitation + mechanism)

Distribution by Scientific Domains

Physics and Astronomy	75%

Selected Abstracts

Minocycline-Based Europium(III) Chelate Complexes: Synthesis, Luminescent Properties, and Labeling to Streptavidin

HELVETICA CHIMICA ACTA, Issue 11 2009
Takuya Nishioka
Abstract Two chelate ligands for europium(III) having minocycline (=(4S,4aS,5aR,12aS)-4,7-bis(dimethylamino)-1,4,4a,5,5a,6,11,12a-octahydro-3,10,12,12a-tetrahydroxy-1,11-dioxonaphthacene-2-carboxamide; 5) as a VIS-light-absorbing group were synthesized as possible VIS-light-excitable stable Eu3+ complexes for protein labeling. The 9-amino derivative 7 of minocycline was treated with H6TTHA (=triethylenetetraminehexaacetic acid=3,6,9,12-tetrakis(carboxymethyl)-3,6,9,12-tetraazatetradecanedioic acid) or H5DTPA (=diethylenetriaminepentaacetic acid=N,N -bis{2-[bis(carboxymethyl)amino]ethyl}glycine) to link the polycarboxylic acids to minocycline. One of the Eu3+ chelates, [Eu3+(minocycline-TTHA)] (13), is moderately luminescent in H2O by excitation at 395,nm, whereas [Eu3+(minocycline-DTPA)] (9) was not luminescent by excitation at the same wavelength. The luminescence and the excitation spectra of [Eu3+(minocycline-TTHA)] (13) showed that, different from other luminescent EuIII chelate complexes, the emission at 615,nm is caused via direct excitation of the Eu3+ ion, and the chelate ligand is not involved in the excitation of Eu3+. However, the ligand seems to act for the prevention of quenching of the Eu3+ emission by H2O. The fact that the excitation spectrum of [Eu3+(minocycline-TTHA)] is almost identical with the absorption spectrum of Eu3+ aqua ion supports such an excitation mechanism. The high stability of the complexes of [Eu3+(minocycline-DTPA)] (9) and [Eu3+(minocycline-TTHA)] (13) was confirmed by UV-absorption semi-quantitative titrations of H4(minocycline-DTPA) (8) and H5(minocycline-TTHA) (12) with Eu3+. The titrations suggested also that an 1,:,1 ligand Eu3+ complex is formed from 12, whereas an 1,:,2 complex was formed from 8 minocycline-DTPA. The H5(minocycline-TTHA) (12) was successfully conjugated to streptavidin (SA) (Scheme,5), and thus the applicability of the corresponding Eu3+ complex to label a protein was established. [source]

Discovery of 17 new sharp-lined Ap stars with magnetically resolved lines,

MONTHLY NOTICES OF THE ROYAL ASTRONOMICAL SOCIETY, Issue 1 2008
L. M. Freyhammer
ABSTRACT Chemically peculiar A stars (Ap) are extreme examples of the interaction of atomic element diffusion processes with magnetic fields in stellar atmospheres. The rapidly oscillating Ap stars provide a means for studying these processes in three dimensions and are at the same time important for studying the pulsation excitation mechanism in A stars. As part of the first comprehensive, uniform, high-resolution spectroscopic survey of Ap stars, which we are conducting in the Southern hemisphere with the Michigan Spectral Catalogues as the basis of target selection, we report here the discovery of 17 new magnetic Ap stars having spectroscopically resolved Zeeman components from which we derive magnetic field moduli in the range 3,30 kG. Among these are (1) the current second strongest known magnetic A star, (2) a double-lined Ap binary with a magnetic component and (3) an A star with particularly peculiar and variable abundances. Polarimetry of these stars is needed to constrain their field geometries and to determine their rotation periods. We have also obtained an additional measurement of the magnetic field of the Ap star HD 92499. [source]

Infrared [Fe ii] emission in the circumstellar nebulae of luminous blue variables

MONTHLY NOTICES OF THE ROYAL ASTRONOMICAL SOCIETY, Issue 2 2002
Nathan Smith
Abstract After a serendipitous discovery of bright [Fe ii],16435 emission in nebulae around , Carinae and P Cygni, infrared spectra of other luminous blue variables (LBV) and LBV candidates were obtained. Bright infrared [Fe ii] emission appears to be a common property among LBVs with prominent nebulae; this is an interesting discovery because strong [Fe ii],16435 is typically seen in shock-excited objects like supernova remnants and outflows from newly formed massive stars, as well as in active galactic nuclei (AGN), where the excitation mechanism is uncertain. This paper presents spectra in the H-band (1.5 to 1.75 ,m) for the central stars and nebulae of , Car, AG Car, P Cyg, Wra 751, HR Car, HD 168625, HD 160529, R 127 and S Doradus. Seven of nine targets show bright [Fe ii],16435 in their nebulae, while it is absent in all central stars except the LBV candidate Wra 751. The two objects (S Dor and HD 160529) without prominent [Fe ii],16435 are not yet known to have nebulae detected in optical images, and both lack bright thermal infrared emission from dust. The possible excitation mechanisms for this line and the implications of its discovery in LBV nebulae are discussed; there are good reasons to expect shock excitation in some objects, but other mechanisms cannot be ruled out. [source]

Full-color nanostructured thin-film electroluminescent device utilizing ZnS nanocrystals doped with activator-ions

PHYSICA STATUS SOLIDI (A) APPLICATIONS AND MATERIALS SCIENCE, Issue 1 2008
T. Toyama
Abstract We have studied nanostructured (NS-) thin-film electroluminescent (TFEL) devices utilizing the ZnS nanocrystals (NCs) with the mean crystal sizes of ca. 2,4 nm doped with activator-ions. As compared to the conventional TFEL device, we have achieved a remarkable reduction in the operation voltages by >100 V0,p. Moreover, toward full-color emissions, EL emissions of three primary colors, i.e., red, green, and blue have been derived from Mn2+, Tb3+, and Tm3+ ions, respectively. In this article, we review the studies on the fundamental properties of ZnS NCs as well as the device performance of the NS-TFEL devices. We also discuss the excitation mechanisms of the activator-ions in the ZnS NCs. (© 2008 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) [source]