Energy Density (energy + density)

Distribution by Scientific Domains

Kinds of Energy Density

  • high energy density
  • strain energy density

  • Terms modified by Energy Density

  • energy density analysis
  • energy density material

  • Selected Abstracts


    Aqueous Lithium-ion Battery LiTi2(PO4)3/LiMn2O4 with High Power and Energy Densities as well as Superior Cycling Stability**,

    ADVANCED FUNCTIONAL MATERIALS, Issue 18 2007
    J.-Y. Luo
    Abstract Porous, highly crystalline Nasicon-type phase LiTi2(PO4)3 has been prepared by a novel poly(vinyl alcohol)-assisted sol,gel route and coated by a uniform and continuous nanometers-thick carbon thin film using chemical vapor deposition technology. The as-prepared LiTi2(PO4)3 exhibits excellent electrochemical performance both in organic and aqueous electrolytes, and especially shows good cycling stability in aqueous electrolytes. An aqueous lithium-ion battery consisting of a combination of LiMn2O4 cathode, LiTi2(PO4)3 anode, and a 1 M Li2SO4 electrolyte has been constructed. The cell delivers a capacity of 40 mA,h,g,1 and a specific energy of 60 W,h,kg,1 with an output voltage of 1.5 V based on the total weight of the active electrode materials. It also exhibits an excellent cycling stability with a capacity retention of 82,% over 200 charge/discharge cycles, which is much better than any aqueous lithium-ion battery reported. [source]


    Inactivation of Shigella boydii 18 IDPH and Listeria monocytogenes Scott A with Power Ultrasound at Different Acoustic Energy Densities and Temperatures

    JOURNAL OF FOOD SCIENCE, Issue 4 2007
    Edgar Ugarte-Romero
    ABSTRACT:, The effect of acoustic energy density (AED) on inactivation of Shigella boydii 18 IDPH and Listeria monocytogenes Scott A in a cell suspension was studied at sublethal temperatures and at AEDs of 0.49, 0.85, and 1.43 W/mL. The effect of temperature on ultrasonic inactivation of L. monocytogenes Scott A at 35, 50, and 65 °C was examined at an AED of 1.43 W/mL. Increasing AED increased the rate of inactivation for both S. boydii and L. monocytogenes. The destruction of S. boydii and L. monocytogenes followed 1st order kinetics in a 20-min treatment, except for S. boydii inactivation at 1.43 W/mL where a tailing effect was observed after 15 min. At sublethal temperatures, the D-values of S. boydii were 8.8, 4.3, and 2.5 min for AEDs of 0.49, 0.85, and 1.43 W/mL, whereas those for L. monocytogenes at the 3 AED levels were 31.5, 13.5, and 7.3 min, respectively. Ultrasonic treatment of L. monocytogenes at 35 and 50 °C enhanced inactivation. However, at 65 °C, application of ultrasound did not result in additional inactivation compared to thermal treatment alone at the same temperature. With the experimental conditions and the ultrasound system used in this study, an upper temperature limit for thermosonication was evident above which no added killing due to ultrasound was observed. [source]


    Nanocomposites of Ferroelectric Polymers with TiO2 Nanoparticles Exhibiting Significantly Enhanced Electrical Energy Density,

    ADVANCED MATERIALS, Issue 2 2009
    Junjun Li
    Novel dielectric nanocomposites composed of ferroelectric polymers and surface-functionalized TiO2 nanoparticles with comparable dielectric permittivities and homogeneous nanoparticle dispersions are prepared and characterized. Enhancements in electric displacement and energy density at high electric fields are demonstrated. [source]


    Hildebrand and Hansen solubility parameters from Molecular Dynamics with applications to electronic nose polymer sensors

    JOURNAL OF COMPUTATIONAL CHEMISTRY, Issue 15 2004
    M. Belmares
    Abstract We introduce the Cohesive Energy Density (CED) method, a multiple sampling Molecular Dynamics computer simulation procedure that may offer higher consistency in the estimation of Hildebrand and Hansen solubility parameters. The use of a multiple sampling technique, combined with a simple but consistent molecular force field and quantum mechanically determined atomic charges, allows for the precise determination of solubility parameters in a systematic way (, = 0.4 hildebrands). The CED method yields first-principles Hildebrand parameter predictions in good agreement with experiment [root-mean-square (rms) = 1.1 hildebrands]. We apply the CED method to model the Caltech electronic nose, an array of 20 polymer sensors. Sensors are built with conducting leads connected through thin-film polymers loaded with carbon black. Odorant detection relies on a change in electric resistivity of the polymer film as function of the amount of swelling caused by the odorant compound. The amount of swelling depends upon the chemical composition of the polymer and the odorant molecule. The pattern is unique, and unambiguously identifies the compound. Experimentally determined changes in relative resistivity of seven polymer sensors upon exposure to 24 solvent vapors were modeled with the CED estimated Hansen solubility components. Predictions of polymer sensor responses result in Pearson R2 coefficients between 0.82 and 0.99. © 2004 Wiley Periodicals, Inc. J Comput Chem 25: 1814,1826, 2004 [source]


    Dietary Energy Density and Body Weight: Is There a Relationship?

    NUTRITION REVIEWS, Issue 11 2004
    Adam Drewnowski PhD
    The energy density of foods and beverages is defined as the available energy per unit weight (kJ/g). Energy density of the diet is usually calculated excluding non-caloric beverages and drinking water. Because water contributes more to the weight of foods than any macronutrient, energydense foods are not necessarily those high in sugar or fat, but those that are dry. Evidence linking dietary energy density with body weight is critically evaluated in this review. Existing reports of a positive association between dietary energy density, higher energy intakes, and weight gain are based on laboratory and clinical studies. Although some cross-sectional epidemiological studies have linked dietary energy density with higher body mass index (BMI) values, the data are not consistent. At this time, there are no longitudinal cohort data linking dietary energy density with higher obesity risk. [source]


    Energy density of anchovy Engraulis encrasicolus in the Bay of Biscay

    JOURNAL OF FISH BIOLOGY, Issue 3 2009
    J. Dubreuil
    The energy density (ED) of anchovy Engraulis encrasicolus in the Bay of Biscay was determined by direct calorimetry and its evolution with size, age and season was investigated. The water content and energy density varied seasonally following opposite trends. The ED g,1 of wet mass (MW) was highest at the end of the feeding season (autumn: c. 8 kJ g,1MW) and lowest in late winter (c. 6 kJ g,1MW). In winter, the fish lost mass, which was partially replaced by water, and the energy density decreased. These variations in water content and organic matter content may have implications on the buoyancy of the fish. The water content was the major driver of the energy density variations for a MW basis. A significant linear relationship was established between ED g,1 (y) and the per cent dry mass (MD; x): y =,4·937 + 0·411x. In the light of the current literature, this relationship seemed to be not only species specific but also ecosystem specific. Calibration and validation of fish bioenergetics models require energy content measurements on fish samples collected at sea. The present study provides a first reference for the energetics of E. encrasicolus in the Bay of Biscay. [source]


    Energy density of marine pelagic fish eggs

    JOURNAL OF FISH BIOLOGY, Issue 6 2002
    J. Riis-Vestergaard
    Analysis of the literature on pelagic fish eggs enabled generalizations to be made of their energy densities, because the property of being buoyant in sea water appears to constrain the proximate composition of the eggs and thus to minimize interspecific variation. An energy density of 1.34 J ,l,1 of total egg volume is derived for most species spawning eggs without visible oil globules. The energy density of eggs with oil globules is predicted by x (J ,11) where x is the fractional volume of the oil globule. [source]


    Dietary Energy Density and Body Weight: Is There a Relationship?

    NUTRITION REVIEWS, Issue 11 2004
    Adam Drewnowski PhD
    The energy density of foods and beverages is defined as the available energy per unit weight (kJ/g). Energy density of the diet is usually calculated excluding non-caloric beverages and drinking water. Because water contributes more to the weight of foods than any macronutrient, energydense foods are not necessarily those high in sugar or fat, but those that are dry. Evidence linking dietary energy density with body weight is critically evaluated in this review. Existing reports of a positive association between dietary energy density, higher energy intakes, and weight gain are based on laboratory and clinical studies. Although some cross-sectional epidemiological studies have linked dietary energy density with higher body mass index (BMI) values, the data are not consistent. At this time, there are no longitudinal cohort data linking dietary energy density with higher obesity risk. [source]


    Improvement of Postfractional Laser Erythema with Light-Emitting Diode Photomodulation

    DERMATOLOGIC SURGERY, Issue 5 2009
    TINA S. ALSTER MD
    BACKGROUND The most common side effects of fractional laser skin treatment are erythema and edema. Low-level light therapy and light-emitting diode (LED) devices have been used to stimulate fibroblast activity and hasten wound healing. OBJECTIVE To determine whether LED treatment immediately after fractional laser skin resurfacing affects the severity and duration of postoperative eythema. MATERIALS AND METHODS Twenty patients received treatment with a 590-nm wavelength LED array to randomly selected facial halves immediately after undergoing full-face fractional laser skin resurfacing with a 1,550-nm erbium-doped fiber laser. Differences in erythema between LED-treated and untreated facial halves were recorded at 24, 48, and 96 hours post-treatment. RESULTS The LED-treated facial halves were less erythematous in all 20 patients 24 hours postoperatively. The six patients who received the highest mean energy densities during fractional laser treatment continued to exhibit decreased erythema in the LED-treated areas at 48 hours. At 96 hours post-treatment, no discernible differences between facial halves were observed in any patient. CONCLUSIONS Photomodulation with a 590-nm-wavelength LED array can decrease the intensity and duration of postfractional laser treatment erythema. [source]


    Quantitative Phase Field Modeling of Precipitation Processes,

    ADVANCED ENGINEERING MATERIALS, Issue 12 2006
    Q. Bronchard
    Phase Field modelling of microstructural evolution in alloys has already a long and successful history. One of the basics of the theory is the introduction of continuous fields (concentration, long-range order parameters) that describe the local state of the alloy. These fields have a meaning only at a mesoscopic scale. One consequence is that we can treat much larger systems than with microscopic methods such as Monte Carlo or molecular dynamics simulations. The aim of this work is to precisely analyse the status of the mesoscopic free energy densities that are used in Phase Field theories and, simultaneously, to clarify the form that the Phase Field equations should adopt. [source]


    Design and Synthesis of Hierarchical Nanowire Composites for Electrochemical Energy Storage

    ADVANCED FUNCTIONAL MATERIALS, Issue 21 2009
    Zheng Chen
    Abstract Nanocomposites of interpenetrating carbon nanotubes and vanadium pentoxide (V2O5) nanowires networks are synthesized via a simple in situ hydrothermal process. These fibrous nanocomposites are hierarchically porous with high surface area and good electric conductivity, which makes them excellent material candidates for supercapacitors with high energy density and power density. Nanocomposites with a capacitance up to 440 and 200,F g,1 are achieved at current densities of 0.25 and 10 A g,1, respectively. Asymmetric devices based on these nanocomposites and aqueous electrolyte exhibit an excellent charge/discharge capability, and high energy densities of 16,W h kg,1 at a power density of 75,W kg,1 and 5.5,W h kg,1 at a high power density of 3,750,W kg,1. This performance is a significant improvement over current electrochemical capacitors and is highly competetive with Ni,MH batteries. This work provides a new platform for high-density electrical-energy storage for electric vehicles and other applications. [source]


    Hydrologic responses to earthquakes and a general metric

    GEOFLUIDS (ELECTRONIC), Issue 1-2 2010
    CHI-YUEN WANG
    Geofluids (2010) 10, 206,216 Abstract Hydrologic responses to earthquakes, including liquefaction, changes in stream and spring discharge, changes in the properties of groundwater such as geochemistry, temperature and turbidity, changes in the water level in wells, and the eruption of mud volcanoes, have been documented for thousands of years. Except for some water-level changes in the near field which can be explained by poroelastic responses to static stress changes, most hydrologic responses, both within and beyond the near field, can only be explained by the dynamic responses associated with seismic waves. For these responses, the seismic energy density e may be used as a general metric to relate and compare the various hydrologic responses. We show that liquefaction, eruption of mud volcanoes and increases in streamflow are bounded by e , 10,1 J m,3; temperature changes in hot springs are bounded by e , 10,2 J m,3; most sustained groundwater changes are bounded by e , 10,3 J m,3; geysers and triggered seismicity may respond to seismic energy density as small as 10,3 and 10,4 J m,3, respectively. Comparing the threshold energy densities with published laboratory measurements, we show that undrained consolidation induced by dynamic stresses can explain liquefaction only in the near field, but not beyond the near field. We propose that in the intermediate field and far field, most responses are triggered by changes in permeability that in turn are a response to the cyclic deformation and oscillatory fluid flow. Published laboratory measurements confirm that changes in flow and time-varying stresses can change permeability, inducing both increases and decreases. Field measurements in wells also indicate that permeability can be changed by earthquakes in the intermediate field and far field. Further work, in particular field monitoring and measurements, are needed to assess the generality of permeability changes in explaining far-field hydrologic responses to earthquakes. [source]


    Ultrahigh-Energy-Density Microbatteries Enabled by New Electrode Architecture and Micropackaging Design

    ADVANCED MATERIALS, Issue 20 2010
    Wei Lai
    Monolithic cathodes of optimized porosity prepared by sintering LiCoO2 powders provide high volume utilization and surprising stability under electrochemical cycling. Combined with a novel packaging approach, ultrahigh energy densities in small volumes are enabled. The microbatteries have volumes <6 mm3 and provide sustained ,2.5,h discharges with energy densities of 400,650,W,h,L,1. [source]


    Hot-electron numerical modelling of short gate length pHEMTs applied to novel field plate structures

    INTERNATIONAL JOURNAL OF NUMERICAL MODELLING: ELECTRONIC NETWORKS, DEVICES AND FIELDS, Issue 1 2003
    Shahzad Hussain
    Abstract Hot-electron numerical simulations were carried out in order to simulate the DC parameters of pseudomorphic high electron mobility transistors (pHEMTs). The hot-electron effects were studied by simulating several HEMT device structures. Hot-carrier injection in the substrate and the formation of the peak of electric field in the channel were studied in detail. The inclusion of a field-plate contact in a multiple recessed pHEMT structure lowered the peak value of the electric field by 24% compared with the conventional pHEMT. These devices were modelled by solving the two-dimensional Poisson, current continuity and energy transport equations consistently with the time-independent Schrödinger wave equation. Appropriate Ohmic boundaries are discussed here and implemented in the simulations of pHEMT structures. A new integral approximation is used to calculate electron densities and electron energy densities for degenerate approximations. Copyright © 2002 John Wiley & Sons, Ltd. [source]


    Ozone cracking and flex cracking of crosslinked polymer blend compounds

    JOURNAL OF APPLIED POLYMER SCIENCE, Issue 4 2007
    M. F. Tse
    Abstract Ozone cracking and flex cracking of crosslinked elastomer blends of brominated isobutylene/para -methylstyrene copolymer (BIMSM) and unsaturated elastomers, such as polybutadiene rubber (BR) and natural rubber (NR), are studied. This saturated BIMSM elastomer, which is a terpolymer of isobutylene, para -bromomethylstyrene, and para -methylstyrene, functions as the ozone-inert phase of the blend. Ozone cracking is measured by the failure time of a tapered specimen under a fixed load in a high severity ozone oven, whereas flex cracking is ranked by the De Mattia cut growth. The ozone resistance of BIMSM/BR/NR blends is compared to that of a BR/NR blend (with or without antiozonant) at constant strain energy densities. The effects of the BIMSM content in the blend, the structural variations of BIMSM, and the network chain length between crosslinks on these two failure properties, which are important in crosslinked compounds for applications in tire sidewalls, are discussed. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 103: 2183,2196, 2007 [source]


    Use of intense pulsed light in the treatment of scars

    JOURNAL OF COSMETIC DERMATOLOGY, Issue 1 2005
    H Cartier
    Summary Background, Reducing erythema and infiltration of inflamed, hypertrophic, and colloidal scars have been a challenge for healthcare providers. Peer-reviewed scientific data for intense pulsed light systems are lacking. Objective, A chronicle of three patients who have participated in the treatment of inflamed, hypertrophic, and colloidal scars, using intense pulsed light. Methods, Intense pulsed light with a selection of wavelengths, pulse durations, and energy densities was used on patients with inflamed, hypertrophic, and colloidal scars. Results, A definite improvement in scar tissue was observed and achieved in all the cases. Conclusion, Intense pulsed light source with the correct outputs is an effective tool for the treatment and improvement of inflamed, hypertrophic, and colloidal scars. [source]


    Energy density of marine pelagic fish eggs

    JOURNAL OF FISH BIOLOGY, Issue 6 2002
    J. Riis-Vestergaard
    Analysis of the literature on pelagic fish eggs enabled generalizations to be made of their energy densities, because the property of being buoyant in sea water appears to constrain the proximate composition of the eggs and thus to minimize interspecific variation. An energy density of 1.34 J ,l,1 of total egg volume is derived for most species spawning eggs without visible oil globules. The energy density of eggs with oil globules is predicted by x (J ,11) where x is the fractional volume of the oil globule. [source]


    Thermal machines based on surface energy of wetting: Thermodynamic analysis

    AICHE JOURNAL, Issue 3 2003
    A. Laouir
    This work proposes an original thermodynamic-energetic analysis of the feasibility and ideal performance of thermal machines based on the wetting phenomenon proposed by V. A. Eroshenko. The extension or contraction of a liquid film is taken as a "tutorial" example to introduce the basic thermodynamic relations of this 2-D transformation. It implies both mechanical and thermal effects, and this coupling allows conversion of heat to work (thermal engine) or conversely to pump heat (refrigeration/heat pump effect). A similar approach is then developed for the interface between a liquid and a highly microporous solid, having a large internal surface area. The thermodynamic behavior of this interface involves as state variables the surface tension of the liquid, the contact angle, and their dependence on temperature. Depending on the relative magnitude and sign of these quantities, and, therefore, on the working couple and the temperature range, a variety of machine cycles are feasible, or excluded, and a method is proposed for a comprehensive inventory. Order-of-magnitude calculations of the energy densities are presented based on the existing experimental data for several systems involving water as the fluid. The tentative conclusions are that the energy densities are very small on a mass basis compared to conventional systems based on vaporization, but the contrary is true on a volume basis because the phase transformation (extension of the surface) occurs in a condensed state. There may, therefore, be some niches for thermal machines of this type, but they remain to be identified and validated. [source]


    Low-level laser irradiation (LLLI) promotes proliferation of mesenchymal and cardiac stem cells in culture

    LASERS IN SURGERY AND MEDICINE, Issue 4 2007
    Hana Tuby MSc
    Abstract Background and Objectives Low-level laser irradiation (LLLI) was found to promote the proliferation of various types of cells in vitro. Stem cells in general are of significance for implantation in regenerative medicine. The aim of the present study was to investigate the effect of LLLI on the proliferation of mesenchymal stem cells (MSCs) and cardiac stem cells (CSCs). Study Design/Materials and Methods Isolation of MSCs and CSCs was performed. The cells were cultured and laser irradiation was applied at energy densities of 1 and 3 J/cm2. Results The number of MSCs and CSCs up to 2 and 4 weeks respectively, post-LLLI demonstrated a significant increase in the laser-treated cultures as compared to the control. Conclusion The present study clearly demonstrates the ability of LLLI to promote proliferation of MSCs and CSCs in vitro. These results may have an important impact on regenerative medicine. Lasers Surg. Med. 39: 373,378, 2007. © 2007 Wiley-Liss, Inc. [source]


    Mathematical modeling of 980-nm and 1320-nm endovenous laser treatment

    LASERS IN SURGERY AND MEDICINE, Issue 3 2007
    Serge R. Mordon PhD
    Abstract Background and Objectives Endovenous laser treatment (ELT) has been proposed as an alternative in the treatment of reflux of the great saphenous vein (GSV) and small saphenous vein (SSV). Numerous studies have since demonstrated that this technique is both safe and efficacious. ELT was presented initially using diode lasers of 810 nm, 940 nm, and 980 nm. Recently, a 1,320-nm Nd:YAG laser was introduced for ELT. This study aims to provide mathematical modeling of ELT in order to compare 980 nm and 1,320 nm laser-induced damage of saphenous veins. Study Design/Materials and Methods The model is based on calculations describing light distribution using the diffusion approximation of the transport theory, the temperature rise using the bioheat equation, and the laser-induced injury using the Arrhenius damage model. The geometry to simulate ELT was based on a 2D model consisting of a cylindrically symmetric blood vessel including a vessel wall and surrounded by an infinite homogenous tissue. The mathematical model was implemented using the Macsyma-Pdease2D software (Macsyma, Inc., Arlington, MA). Calculations were performed so as to determine the damage induced in the intima tunica, the externa tunica and inside the peri-venous tissue for 3 mm and 5 mm vessels (considered after tumescent anesthesia) and different linear endovenous energy densities (LEED) usually reported in the literature. Results Calculations were performed for two different vein diameters: 3 mm and 5 mm and with LEED typically reported in the literature. For 980 nm, LEED: 50 to 160 J/cm (CW mode, 2 mm/second pullback speed, power: 10 W to 32 W) and for 1,320 nm, LEED: 50 to 80 J/cm (pulsed mode, pulse duration 1.2 milliseconds, peak power: 135 W, repetition rate 30 Hz to 50 Hz). Discussion and Conclusion Numerical simulations are in agreement with LEED reported in clinical studies. Mathematical modeling shows clearly that 1,320 nm, with a better absorption by the vessel wall, requires less energy to achieve wall damage. In the 810,1,320-nm range, blood plays only a minor role. Consequently, the classification of these lasers into hemoglobin-specific laser wavelengths (810, 940, 980 nm) and water-specific laser wavelengths (1,320 nm) is inappropriate. In terms of closure rate, 980 nm and 1,320 nm can lead to similar results and, as reported by the literature, to similar side effects. This model should serve as a useful tool to simulate and better understand the mechanism of action of the ELT. Lasers Surg. Med. 39:256,265, 2007. © 2007 Wiley-Liss, Inc. [source]


    Attenuation of infarct size in rats and dogs after myocardial infarction by low-energy laser irradiation

    LASERS IN SURGERY AND MEDICINE, Issue 3 2001
    Uri Oron PhD
    Abstract Background and Objective The aim of the present study was to investigate the possibility that low-energy laser irradiation attenuates infarct size formation after induction of chronic myocardial infarction (MI) in small and large experimental animals. Study Design/Materials and Methods Laser irradiation was applied to the infarcted area of rats and dogs at various power densities (2.5 to 20 mW/cm2) after occlusion of the coronary artery. Results In infarcted laser-irradiated rats that received laser irradiation immediately and 3 days after MI at energy densities of 2.5, 6, and 20 mW/cm2, there was a 14%, 62% (significant; P,<,0.05), and 2.8% reduction of infarct size (14 days after MI) relative to non,laser-irradiated rats, respectively. In dogs, a 49% (significant; P,<,0.01) reduction of infarct size was achieved. Conclusion The results of the present study indicate that delivery of low-energy laser irradiation to infarcted myocardium in rats and dogs has a profound effect on the infarct size after MI. Lasers Surg. Med. 28:204,211, 2001. © 2001 Wiley-Liss, Inc. [source]


    Variability in the nutritional value of the major copepods in Cape Cod Bay (Massachusetts, USA) with implications for right whales

    MARINE ECOLOGY, Issue 2 2006
    Amy DeLorenzo Costa
    Abstract The North Atlantic right whale, a seriously endangered species, is found in Cape Cod Bay (Massachusetts, USA) during the winter and early spring. During their residency in these waters, these whales are frequently observed feeding. This study evaluated spatial and temporal changes in the chemical composition (carbon weight and C/N ratio) of the food resource targeted by the right whales in Cape Cod Bay. The three taxa measured (Centropages typicus, Pseudocalanus spp., and Calanus finmarchicus) had highly variable chemical compositions resulting from the different life strategies and from fluctuations in their surrounding environment. The impact of seasonal variability in the energy densities of the food resource of right whales was calculated and compared to the energetic requirements of these whales. Calculations indicated that differences in the nutritional content of the zooplankton prey in Cape Cod Bay could have a considerable effect on the nutrition available to the right whales. Therefore, it is likely that using more precise estimates of the energetic densities of the prey of right whales would lead to a re-evaluation of the adequacy of the food resource available to these whales in the North Atlantic. [source]


    Advanced models for erosion corrosion and its mitigation,

    MATERIALS AND CORROSION/WERKSTOFFE UND KORROSION, Issue 2 2008
    G. Schmitt
    Erosion corrosion, i.e., flow-induced localized corrosion (FILC) is initiated when flow dynamic forces surpass the fracture energy of protective layers or scales on metals. With a new model the maximum interaction energies between flowing media and solid walls can be quantified in terms of "freak" energy densities created during singular events (freak events) of perpendicular impacts by near-wall microturbulence elements. The freak energy densities are in the megaPascal range and match well in the order of magnitude with fracture energies of protective layers and can be estimated from Wavelet diagnostics of electrochemical current noise measured at microelectrodes under mass transport controlled conditions. This solves the problem that wall shear stresses, generally used to quantify critical flow intensities for FILC initiation, range several orders of magnitude (Pa range) below the fracture energies of protective layers. The new advanced model allows for the first time to quantify the maximum fluid dynamic forces exerted on solid walls under different turbulent and disturbed flow conditions (one-phase liquid flow on jet impinged surfaces and on coupons in rotated cages, surfaces impacted by slug flow and gas-pulsed impinging jets). Drag reducing additives were shown to reduce freak energy densities to values significantly below fracture energies of protective layers and hence inhibit initiation of FILC. The onset of FILC can be monitored online with the newly developed CoulCount method, an easy-to-use, non-invasive diagnostic tool which evaluates electrochemical current noise between jet impinged electrode pairs made from the metals to be tested. [source]


    Electromagnetic energy in absorptive and dispersive medium based on the assembly of atomic oscillators

    MICROWAVE AND OPTICAL TECHNOLOGY LETTERS, Issue 11 2006
    Haibo Cao
    Abstract On the basis of the idealized structure of an atomic medium described by an assembly of independent oscillators, expressions for the stored electric and magnetic energy densities in absorptive and dispersive medium are derived. Such formulas are also valid for a left-handed medium (LHM), where the permittivity and permeability are simultaneously less than zero within a frequency band. These formulas are completely equivalent to those derived from a general definition of electromagnetic energy density using the classical electromagnetics. It has been shown that the stored energy densities, no matter in a right-handed medium or in a left-handed medium, are always positive. © 2006 Wiley Periodicals, Inc. Microwave Opt Technol Lett 48: 2288,2291, 2006; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/mop.21899 [source]


    Fast foods, energy density and obesity: a possible mechanistic link

    OBESITY REVIEWS, Issue 4 2003
    A. M. Prentice
    Summary Fast foods are frequently linked to the epidemic of obesity, but there has been very little scientific appraisal of a possible causal role. Here we review a series of studies demonstrating that the energy density of foods is a key determinant of energy intake. These studies show that humans have a weak innate ability to recognise foods with a high energy density and to appropriately down-regulate the bulk of food eaten in order to maintain energy balance. This induces so called ,passive over-consumption'. Composition data from leading fast food company websites are then used to illustrate that most fast foods have an extremely high energy density. At some typical outlets the average energy density of the entire menus is ,1100 kJ 100 g,1. This is 65% higher than the average British diet (,670 kJ 100 g,1) and more than twice the energy density of recommended healthy diets (,525 kJ 100 g,1). It is 145% higher than traditional African diets (,450 kJ 100 g,1) that probably represent the levels against which human weight regulatory mechanisms have evolved. We conclude that the high energy densities of many fast foods challenge human appetite control systems with conditions for which they were never designed. Among regular consumers they are likely to result in the accidental consumption of excess energy and hence to promote weight gain and obesity. [source]


    Domains in helicoidal magnetic structure

    PHYSICA STATUS SOLIDI (B) BASIC SOLID STATE PHYSICS, Issue 4 2010
    E. V. Rosenfeld
    Abstract Theoretical investigation of the magnetic spiral behavior in a layered magnet with strong hexagonal magnetic anisotropy has been performed. It is shown that if the exchange integrals between the first and second neighboring layers meet the requirement |J1|,=,,J2, the energy densities for spirals with three and four (at J1,<,0) or four and six (at J1,>,0) layers in the period coincide. Moreover, near the surface of contact of the above phases the energy density is equal to or even lower than inside each of them, which should result in the appearance of a domain magnetic structure. [source]


    IR and UV laser-induced morphological changes in silicon surface under oxygen atmosphere

    PHYSICA STATUS SOLIDI (C) - CURRENT TOPICS IN SOLID STATE PHYSICS, Issue 10 2005
    J. Jiménez-Jarquín
    Abstract We irradiated silicon (100) wafers with IR (1064 nm) and UV (355 nm) nanosecond laser pulses with energy densities within the ablation regime and used scanning electron microscopy to analyze the morphological changes induced on the Si surface. The changes in the wafer morphology depend both on the incident radiation wavelength and the environmental atmosphere. We have patterned Si surfaces with a single focused laser spot and, in doing the experiments with IR or UV this reveals significant differences in the initial surface cracking and pattern formation, however if the experiment is carried out in O2 the final result is an array of microcones. We also employed a random scanning technique to irradiate the silicon wafer over large areas, in this case the microstructure patterns consist of a "semi-ordered" array of micron-sized cones. (© 2005 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) [source]


    Dissolution of waste plastics in biodiesel

    POLYMER ENGINEERING & SCIENCE, Issue 5 2010
    Ying Zhang
    The dissolution behavior of polystyrene (PS) and low-density polyethylene (LDPE) in biodiesel was investigated with an eye towards developing methods to dispose waste plastics by burning them with fuel. To complement and guide the experimental investigations, molecular dynamics simulations were performed to calculate solubility parameters, cohesive energy densities, Flory-Huggins , parameters and phase diagrams of the target systems. Dissolution kinetics of PS and LDPE in methyl esters was monitored by gravimetry, from which parameters such as dissolution rates, activation energies, and scaling indices were estimated. The shear viscosity of the polymer solutions was measured to ascertain their suitability as fuel mixtures. The dissolution of PS in biodiesel appears to be controlled by the diffusion of polymer chains through a boundary layer adjacent to the polymer/solvent interface. Taken together, the experimental and modeling studies provide a predictive toolbox to design biodiesels of different compositions that will dissolve commodity polymers such as PS and LDPE to be used as fuels in engines. POLYM. ENG. SCI., 2010. © 2009 Society of Plastics Engineers [source]


    Combustion of Environmentally Altered Molybdenum Trioxide Nanocomposites

    PROPELLANTS, EXPLOSIVES, PYROTECHNICS, Issue 3 2006
    Kevin Moore
    Abstract Nanocomposite thermite mixtures are currently under development for many primer applications due to their high energy densities, high ignition sensitivity, and low release of toxins into the environment. However, variability and inconsistencies in combustion performance have not been sufficiently investigated. Environmental interactions with the reactants are thought to be a contributing factor to these variabilities. Combustion velocity experiments were conducted on aluminum (Al) and molybdenum trioxide (MoO3) mixtures to investigate the role of environmental interactions such as light exposure and humidity. While the Al particles were maintained in an ambient, constant environment, the MoO3 particles were exposed to UV or fluorescent light, and highly humid environments. Results show that UV and fluorescent lighting over a period of days does not significantly contribute to performance deterioration. However, a humid environment severely decreases combustion performance if the oxidizer particles are not heat-treated. Heat treatment of the MoO3 greatly increases the material's ability to resist water absorption, yielding more repeatable combustion performance. This work further quantifies the role of the environment in the decrease of combustion performance of nanocomposites over time. [source]


    Topological properties of hydrogen bonds and covalent bonds from charge densities obtained by the maximum entropy method (MEM)

    ACTA CRYSTALLOGRAPHICA SECTION B, Issue 5 2009
    Jeanette Netzel
    Charge densities have been determined by the Maximum Entropy Method (MEM) from the high-resolution, low-temperature (T, 20,K) X-ray diffraction data of six different crystals of amino acids and peptides. A comparison of dynamic deformation densities of the MEM with static and dynamic deformation densities of multipole models shows that the MEM may lead to a better description of the electron density in hydrogen bonds in cases where the multipole model has been restricted to isotropic displacement parameters and low-order multipoles (lmax = 1) for the H atoms. Topological properties at bond critical points (BCPs) are found to depend systematically on the bond length, but with different functions for covalent C,C, C,N and C,O bonds, and for hydrogen bonds together with covalent C,H and N,H bonds. Similar dependencies are known for AIM properties derived from static multipole densities. The ratio of potential and kinetic energy densities |V(BCP)|/G(BCP) is successfully used for a classification of hydrogen bonds according to their distance d(H...O) between the H atom and the acceptor atom. The classification based on MEM densities coincides with the usual classification of hydrogen bonds as strong, intermediate and weak [Jeffrey (1997). An Introduction to Hydrogen Bonding. Oxford University Press]. MEM and procrystal densities lead to similar values of the densities at the BCPs of hydrogen bonds, but differences are shown to prevail, such that it is found that only the true charge density, represented by MEM densities, the multipole model or some other method can lead to the correct characterization of chemical bonding. Our results do not confirm suggestions in the literature that the promolecule density might be sufficient for a characterization of hydrogen bonds. [source]