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Eutectic Temperature (eutectic + temperature)
Selected AbstractsRe-determination of the pseudobinary system Li2O , MoO3CRYSTAL RESEARCH AND TECHNOLOGY, Issue 4 2008M. Moser Abstract The quasi-binary phase diagram lithium oxide , molybdenum(VI) oxide was investigated by differential scanning calorimetry and X-ray diffraction. The four intermediate phases Li4MoO5, Li2MoO4, Li4Mo5O17, and Li2Mo4O13 show incongruent melting. The system has one eutectic point at 50.5 mol% MoO3 and 49.5 mol% LiO0.5 with a eutectic temperature of 524.6°C. At this point the melt is in equilibrium with Li2MoO4 and Li4Mo5O17. (© 2008 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) [source] Room-Temperature Freeze Casting for Ceramics with Nonaqueous Sublimable Vehicles in the Naphthalene,Camphor Eutectic SystemJOURNAL OF THE AMERICAN CERAMIC SOCIETY, Issue 11 2004Kiyoshi Araki Freeze casting for Al2O3 was accomplished at room temperature with nonaqueous sublimable vehicles in the naphthalene,camphor eutectic system with a eutectic temperature of 31°C. A fully dense sintered body (>99.5% of theoretical density (T.D.)) was obtained with a eutectic composition vehicle, whereas at most 90% T.D. was obtained with an off-eutectic (i.e., hypo- or hypereutectic) composition vehicle due to formation of large uniquely shaped voids. Microstructural observation suggested that growing pro-eutectic crystals rejected the suspended Al2O3 particles to form large voids during the solidification process. At the eutectic composition, formation of fine lamellar microstructure in a solidified vehicle is considered to inhibit particle rejection resulting in large voids. [source] Templated Grain Growth of Barium Titanate Single CrystalsJOURNAL OF THE AMERICAN CERAMIC SOCIETY, Issue 11 2000Paul W. Rehrig BaTiO3 single crystals were grown via templated grain growth (TGG), which is a process in which a single-crystal "template" is placed in contact with a sintered polycrystalline matrix and then heated to migrate the single-crystal boundary into the matrix. Millimeter-sized, stoichiometric single crystals of BaTiO3 were produced by heating polycrystalline matrix with a relative density of 97% and a Ba/Ti ratio of <1.00, which was bonded to a BaTiO3 single crystal, at temperatures above the eutectic temperature. Growth rates of 590,790, 180,350, and 42,59 ,m/h were observed for {111}-, {100}-, and {110}-oriented single-crystal templates, respectively. Lower-surface-energy facets were formed for {111}- and {100}-oriented templates, whereas {110} crystals maintained a {110} growth front, which indicated that this plane orientation was the lowest-energy surface in this system. SrTiO3 also was shown to be a suitable substrate for TGG of BaTiO3. [source] Origin of kamacite, schreibersite, and perryite in metal-sulfide nodules of the enstatite chondrite Sahara 97072 (EH3)METEORITICS & PLANETARY SCIENCE, Issue 2 2010Stephen W. LEHNER We have measured concentrations of Ni, Cu, Ga, Au, Ir, Ru, and Pd in these minerals with laser ablation, inductively coupled plasma mass spectrometry (ICP-MS). We also measured their Fe, Ni, P, Si, and Co concentrations with electron microprobe. In kamacite, ratios of Ru/Ir, Pd/Ir, and Pd/Ru cluster around their respective CI values and all elements analyzed plot near the intersection of the equilibrium condensation trajectory versus Ni and the respective CI ratios. In schreibersite, the Pd/Ru ratio is near the CI value and perryite contains significant Cu, Ga, and Pd. We propose that schreibersite and perryite formed separately near the condensation temperatures of P and Si in a reduced gas and were incorporated into Fe-Ni alloy. Upon further cooling, sulfidation of Fe in kamacite resulted in the formation of additional perryite at the sulfide interface. Still later, transient heating re-melted this perryite near the Fe-FeS eutectic temperature during partial melting of the metal-sulfide nodules. The metal-sulfide nodules are pre-accretionary objects that retain CI ratios of most siderophile elements, although they have experienced transient heating events. [source] | ||||||||||