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Different Periodicities (different + periodicity)

Distribution by Scientific Domains

Polymers and Materials Science	50%

Selected Abstracts

Rapid assessment of internodal myelin integrity in central nervous system tissue

JOURNAL OF NEUROSCIENCE RESEARCH, Issue 4 2010
Daniel A. Kirschner
Abstract Monitoring pathology/regeneration in experimental models of de-/remyelination requires an accurate measure not only of functional changes but also of the amount of myelin. We tested whether X-ray diffraction (XRD), which measures periodicity in unfixed myelin, can assess the structural integrity of myelin in fixed tissue. From laboratories involved in spinal cord injury research and in studying the aging primate brain, we solicited "blind" samples and used an electronic detector to record rapidly the diffraction patterns (30 min each pattern) from them. We assessed myelin integrity by measuring its periodicity and relative amount. Fixation of tissue itself introduced ±10% variation in periodicity and ±40% variation in relative amount of myelin. For samples having the most native-like periods, the relative amounts of myelin detected allowed distinctions to be made between normal and demyelinating segments, between motor and sensory tracts within the spinal cord, and between aged and young primate CNS. Different periodicities also allowed distinctions to be made between samples from spinal cord and nerve roots and between well-fixed and poorly fixed samples. Our findings suggest that, in addition to evaluating the effectiveness of different fixatives, XRD could also be used as a robust and rapid technique for quantitating the relative amount of myelin among spinal cords and other CNS tissue samples from experimental models of de- and remyelination. © 2009 Wiley-Liss, Inc. [source]

Climatic influence on the inter-annual variability of late-Holocene minerogenic sediment supply in a boreal forest catchment

EARTH SURFACE PROCESSES AND LANDFORMS, Issue 4 2010
Gunilla Petterson
Abstract Processes controlling sediment yield vary over a range of timescales, although most process-based observations are extremely short. Lake sediments, however, can be used to extend the observational timescale and are particularly useful when annually laminated (varved) sediment is present. The sediment record at Kassjön (N. Sweden) consists of ,6400 varves, each 0·5,1 mm thick. Image analysis was used to determine grey-scale variation and varve thickness from which annual minerogenic accumulation rate (MinAR) (mg cm,2 year,1) was inferred for the period 4486 BC , AD 1900. MinAR varies on annual to centennial scales and mainly reflects channel bank erosion by the inflow streams. The mineral input reflects the intensity of the spring run-off, which is dependent on the amount of snow accumulated during the winter, and hence MinAR is a long-term record of variability in past winter climate; other factors will be a variable response to catchment uplift, vegetation succession and pedogenesis. A major shift from low to high MinAR occurred ,250 BC, and peaks occurred around AD 250, 600, 1000, 1350 and 1650. Wavelet power spectrum analysis (confirmed by Fourier analyses) indicated significantly different periodicities throughout the period 4000 BC , AD 1700, including 275 years for the period 4000 BC , 2900 BC, 567 years for the period 2901 BC , 1201 BC, and 350 and 725 years for the period 1200 BC , AD 1700. The long-term, centennial scale variability (,350 years) may reflect solar forcing (cf the 385-year peak in tree-ring calibrated 14C activity) but interestingly, there is no obvious link to high frequency forcing, such as the North Atlantic Oscillation. The high resolution component of the record highlights the relevance of varved lake sediment records for understanding erosion dynamics in undisturbed forested catchments and their link to long-term climate dynamics and future climate change. Copyright © 2010 John Wiley & Sons, Ltd. [source]

Fabrication of Periodic Microstructures in Pentaerythritol Triacrylate Through Femtosecond Laser Interference Two-Photon Polymerization,

ADVANCED ENGINEERING MATERIALS, Issue 7 2009
Andrés Lasagni
Fabrication of periodic, two-dimensional microstructures in pentaerythritol triacrylate (PETIA) is demonstrated through femtosecond laser interference patterning. Planar arrayed structures of different periodicities and geometries were fabricated using three, four, and five interfering beams from an 800,nm ultrafast femtosecond laser. The periodic topography can be varied from isolated conical pillars to interconnected cellular structures by simple control of the interference pattern in combination with energy dose. [source]

Melt Structure and its Transformation by Sequential Crystallization of the Two Blocks within Poly(L -lactide)- block -Poly(, -caprolactone) Double Crystalline Diblock Copolymers

MACROMOLECULAR CHEMISTRY AND PHYSICS, Issue 11 2006
I. W. Hamley
Abstract Summary: Sequential crystallization of poly(L -lactide) (PLLA) followed by poly(, -caprolactone) (PCL) in double crystalline PLLA- b -PCL diblock copolymers is studied by differential scanning calorimetry (DSC), polarized optical microscopy (POM), wide-angle X-ray scattering (WAXS) and small-angle X-ray scattering (SAXS). Three samples with different compositions are studied. The sample with the shortest PLLA block (32 wt.-% PLLA) crystallizes from a homogeneous melt, the other two (with 44 and 60% PLLA) from microphase separated structures. The microphase structure of the melt is changed as PLLA crystallizes at 122,°C (a temperature at which the PCL block is molten) forming spherulites regardless of composition, even with 32% PLLA. SAXS indicates that a lamellar structure with a different periodicity than that obtained in the melt forms (for melt segregated samples). Where PCL is the majority block, PCL crystallization at 42,°C following PLLA crystallization leads to rearrangement of the lamellar structure, as observed by SAXS, possibly due to local melting at the interphases between domains. POM results showed that PCL crystallizes within previously formed PLLA spherulites. WAXS data indicate that the PLLA unit cell is modified by crystallization of PCL, at least for the two majority PCL samples. The PCL minority sample did not crystallize at 42,°C (well below the PCL homopolymer crystallization temperature), pointing to the influence of pre-crystallization of PLLA on PCL crystallization, although it did crystallize at lower temperature. Crystallization kinetics were examined by DSC and WAXS, with good agreement in general. The crystallization rate of PLLA decreased with increase in PCL content in the copolymers. The crystallization rate of PCL decreased with increasing PLLA content. The Avrami exponents were in general depressed for both components in the block copolymers compared to the parent homopolymers. Polarized optical micrographs during isothermal crystallization of (a) homo-PLLA, (b) homo-PCL, (c) and (d) block copolymer after 30 min at 122,°C and after 15 min at 42,°C. [source]