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Denitrification Process (denitrification + process)
Selected AbstractsLong-term stability of biological denitrification process for high strength nitrate removal from wastewater of uranium industryENVIRONMENTAL PROGRESS & SUSTAINABLE ENERGY, Issue 3 2008Prashant M. Biradar Abstract The aim of the present study was to biologically denitrify uranium nitrate raffinate (UNR) from nuclear industry, which is a principle source of high strength nitrate waste. To denitrify the high nitrate waste, a pilot-scale continuous stirred tank reactor was designed with two inbuilt settlers. Acclimatization of mixed culture with synthetic waste was carried out prior to the inoculation of the acclimatized sludge into the reactor. Initial concentration of nitrate in uranium raffinate was 77,000 mg/L NO3. It was diluted and used as a feed to the reactor. Concentration of nitrate in feed was increased gradually from 10,000 mg/L NO3 to 40,000 mg/L NO3 with hydraulic retention time (HRT) maintained at 34.4 h. Complete denitrification of 40,000 mg/L NO3 was achieved in a specified HRT. To facilitate understanding of the treatablity and long-term stability of biological denitrification of UNR, study was carried out for 211 days by periodical perturbation of the system. Furthermore, to find the volume ratio of reactor to settler required for the full-scale design of the denitrification plant, settling of acclimatized sludge was carried out. © 2008 American Institute of Chemical Engineers Environ Prog, 2008 [source] Paracoccus denitrificans for the effluent recycling during continuous denitrification of liquid foodBIOTECHNOLOGY PROGRESS, Issue 3 2010Nils Tippkötter Abstract Nitrate is an undesirable component of several foods. A typical case of contamination with high nitrate contents is whey concentrate, containing nitrate in concentrations up to 25 l. The microbiological removal of nitrate by Paracoccus denitrificans under formation of harmless nitrogen in combination with a cell retention reactor is described here. Focus lies on the resource-conserving design of a microbal denitrification process. Two methods are compared. The application of polyvinyl alcohol-immobilized cells, which can be applied several times in whey feed, is compared with the implementation of a two step denitrification system. First, the whey concentrate's nitrate is removed by ion exchange and subsequently the eluent regenerated by microorganisms under their retention by crossflow filtration. Nitrite and nitrate concentrations were determined by reflectometric color measurement with a commercially available Reflectoquant® device. Correction factors for these media had to be determined. During the pilot development, bioreactors from 4 to 250 mg·L,1 and crossflow units with membrane areas from 0.02 to 0.80 m2 were examined. Based on the results of the pilot plants, a scaling for the exemplary process of denitrifying 1,000 tons per day is discussed. © 2010 American Institute of Chemical Engineers Biotechnol. Prog. 2010 [source] Nitrate behaviour in the groundwater of a headwater wetland, Chiba, JapanHYDROLOGICAL PROCESSES, Issue 16 2004Changyuan Tang Abstract A wetland is an important part of the headwater in the discharge area of a basin. It controls not only groundwater discharge such as seepage or springs, but also the migration of chemical matter from the basin. In order to make clear how and where natural attenuation processes happen in wetlands, a typical headwater in Chiba, Japan, was chosen for an investigation of the behaviour of nitrate in groundwater. From the viewpoint of hydro-geomorphology, the wetland in the study site can be divided into three zones: the shallow water-table zone, the seepage zone, and the spring zone along the downstream direction. There were six piezometer groups; each group contained four piezometers, individually set at depths of 1, 2, 3 and 4 m. Major ions and ,15N of groundwater from piezometers, wells and springs were analysed. It was found that nitrate in groundwater mainly came from the fertilizers used in the upstream recharge area of the study site. When the groundwater moved up across the wetland, nitrate concentration in the groundwater decreased rapidly in the shallow water-table zone due to denitrification. Nitrate-free water can be found at the seepage zone. However, the behaviour of nitrate in the spring water was different from that in the seepage zone, since both dilution and denitrification processes were involved in the decrease of nitrate concentration in groundwater. In particular, the dilution process mainly controlled the decline of nitrate at the location where the nitrate-free groundwater flowing horizontally from the seepage zone mixed with the high-nitrate groundwater flowing upward before emerging as a spring. It was also found that denitrification only occurs suddenly in a narrow zone or a thin layer of the order of a few metres. Copyright © 2004 John Wiley & Sons, Ltd. [source] Stable isotope natural abundance of nitrous oxide emitted from Antarctic tundra soils: effects of sea animal excrement depositionsRAPID COMMUNICATIONS IN MASS SPECTROMETRY, Issue 22 2008Renbin Zhu Nitrous oxide (N2O), a greenhouse gas, is mainly emitted from soils during the nitrification and denitrification processes. N2O stable isotope investigations can help to characterize the N2O sources and N2O production mechanisms. N2O isotope measurements have been conducted for different types of global terrestrial ecosystems. However, no isotopic data of N2O emitted from Antarctic tundra ecosystems have been reported although the coastal ice-free tundra around Antarctic continent is the largest sea animal colony on the global scale. Here, we report for the first time stable isotope composition of N2O emitted from Antarctic sea animal colonies (including penguin, seal and skua colonies) and normal tundra soils using insitu field observations and laboratory incubations, and we have analyzed the effects of sea animal excrement depositions on stable isotope natural abundance of N2O. For all the field sites, the soil-emitted N2O was 15N- and 18O-depleted compared with N2O in local ambient air. The mean , values of the soil-emitted N2O were ,15N,=,,13.5,±,3.2, and ,18O,=,26.2,±,1.4, for the penguin colony, ,15N,=,,11.5,±,5.1, and ,18O,=,26.4,±,3.5, for the skua colony and ,15N,=,,18.9,±,0.7, and ,18O,=,28.8,±,1.3, for the seal colony. In the soil incubations, the isotopic composition of N2O was measured under N2 and under ambient air conditions. The soils incubated under the ambient air emitted very little N2O (2.93,µg,N2ON,kg,1). Under N2 conditions, much more N2O was formed (9.74,µg,N2ON,kg,1), and the mean ,15N and ,18O values of N2O were ,19.1,±,8.0, and 21.3,±,4.3,, respectively, from penguin colony soils, and ,17.0,±,4.2, and 20.6,±,3.5,, respectively, from seal colony soils. The data from in situ field observations and laboratory experiments point to denitrification as the predominant N2O source from Antarctic sea animal colonies. Copyright © 2008 John Wiley & Sons, Ltd. [source] |