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Critical Comparison (critical + comparison)

Distribution by Scientific Domains

Chemistry	50%
Engineering	25%

Selected Abstracts

Highly Satisfactory Alkynylation of Alkenyl Halides via Pd-Catalyzed Cross-Coupling with Alkynylzincs and Its Critical Comparison with the Sonogashira Alkynylation.

CHEMINFORM, Issue 37 2003
Ei-ichi Negishi
Abstract For Abstract see ChemInform Abstract in Full Text. [source]

Hydrogen generation in a reverse-flow microreactor: 1.

AICHE JOURNAL, Issue 8 2005
Model formulation, scaling
Abstract A 1-D model for methane partial oxidation in a tubular microreactor is considered. This work is motivated by a recent report by Kikas et al. that experimentally demonstrated the possibility of autothermal generation of hydrogen by partial oxidation of methane in a tubular microreactor. The reactor consists of four cylindrical channels, each 500 microns in diameter, containing Pt/13%,Rh catalyst. Autothermal generation of hydrogen was possible in both unidirectional (UD) and reverse-flow (RF) operations of the reactor, with the RF operation providing better hydrogen yield and lower temperatures than those of the UD operation. Critical comparison of methane oxidation and reforming kinetics from the literature is performed. An analysis of the timescales of individual processes within the reactor is presented to gain fundamental insight into the reactor operation. Finally, the effect of radiation heat transfer is also considered, and it is found to play an important role for a shorter-size reactor. © 2005 American Institute of Chemical Engineers AIChE J, 2005 [source]

Heavy Metals in Matrices of Food Interest: Sequential Voltammetric Determination at Trace and Ultratrace Level of Copper, Lead, Cadmium, Zinc, Arsenic, Selenium, Manganese and Iron in Meals

ELECTROANALYSIS, Issue 18 2004
Clinio Locatelli
Abstract The voltammetric methods are very suitable and versatile techniques for the simultaneous metal determination in complex matrices. The present work, regarding the sequential determination of Cu(II), Pb(II), Cd(II), Zn(II) by square-wave anodic stripping voltammetry (SWASV), As(III), Se(IV) by square-wave cathodic stripping voltammetry (SWCSV) and Mn(II), Fe(III) by square-wave voltammetry (SWV) in matrices involved in foods and food chain as wholemeal, wheat and maize meal, are an interesting example of the possibility to sequentially determine each single element in real samples. Besides the set up of the analytical method, particular attention is aimed either at the problem of possible signal interference or to show that, using the peak area Ap as instrumental datum, it is possible to achieve lower limits of detection. The analytical procedure was verified by the analysis of the standard reference materials: Wholemeal BCR-CRM 189, Wheat Flour NIST-SRM 1567a and Rice Flour NIST-SRM 1568a. Precision, as repeatability, and accuracy, expressed as relative standard deviation and relative error, respectively, were lower than 6% in all cases. In the presence of reciprocal interference, the standard addition method considerably improved the resolution of the voltammetric technique. Once set up on the standard reference materials, the analytical procedure was transferred and applied to commercial meals sampled on market for sale. A critical comparison with spectroscopic measurements is also discussed. [source]

Numerical evaluation of two discontinuous Galerkin methods for the compressible Navier,Stokes equations

INTERNATIONAL JOURNAL FOR NUMERICAL METHODS IN FLUIDS, Issue 1-2 2002
F. Bassi
This paper presents a critical comparison between two recently proposed discontinuous Galerkin methods for the space discretization of the viscous terms of the compressible Navier,Stokes equations. The robustness and accuracy of the two methods has been numerically evaluated by considering simple but well documented classical two-dimensional test cases, including the flow around the NACA0012 airfoil, the flow along a flat plate and the flow through a turbine nozzle. Copyright © 2002 John Wiley & Sons, Ltd. [source]

Reliable multicast via satellite: a comparison survey and taxonomy

INTERNATIONAL JOURNAL OF SATELLITE COMMUNICATIONS AND NETWORKING, Issue 1 2001
Martin W. Koyabe
Abstract IP multicasting is an important service, which will be provided by the next generation Internet. A range of applications has emerged which take the advantage of multicast delivery. However, several factors currently hinder large-scale deployment of terrestrial multicast services. It is particularly difficult to support delivery to large groups of users. Satellites offer a natural way to extend the multicast service to reach this large number of users. They may offer high capacity (especially when using next generation satellite systems) and also eliminate the need for a large number of intermediate routing hops. There are important differences in the way multicast applications operate over satellite. This paper therefore reviews the key design paradigm and offers a critical comparison between different reliable multicast protocol techniques based on a taxonomy. The suitability of a set of the most common reliable multicast protocols is assessed within a satellite environment and conclusions are presented. Copyright © 2001 John Wiley & Sons, Ltd. [source]

A critical comparison between two classical and a kit-based method for mitochondria isolation

PROTEINS: STRUCTURE, FUNCTION AND BIOINFORMATICS, Issue 11 2009
Sonja Hartwig
Abstract Numerous protocols for isolation of mitochondria are available. Here, three methods for the isolation of intact mitochondria from mouse liver tissues are compared with regard to yield, purity and activity. Mitochondria were isolated by sucrose density gradient ultracentrifugation, free-flow electrophoresis or a commercially available kit-based method. Our analyses show that the sophisticated (and most expensive) free-flow electrophoresis method enables isolation of intact mitochondria with an enrichment of approximately 70%. Using the classical density centrifugation method is very laborious and time-consuming, but delivers about 57% intact mitochondria. Using standard laboratory equipment in a quick and simple procedure, the kit provides approximately 50% intact mitochondria, suitable for most standard investigations. [source]

A critical comparison of stratosphere,troposphere coupling indices

THE QUARTERLY JOURNAL OF THE ROYAL METEOROLOGICAL SOCIETY, Issue 644 2009
Mark P. Baldwin
Abstract Assessing stratosphere,troposphere coupling in observational data or model output requires a multi-level index with high time resolution. Ideally, such an index would (1) represent spatial patterns in the troposphere that are most strongly coupled with stratospheric variability and (2) be robust and computationally feasible in both observations and standard model output. Several of the indices used to diagnose extratropical stratosphere,troposphere coupling are based on the Northern and Southern Hemisphere annular modes. The annular mode indices are commonly defined as the leading empirical orthogonal functions (EOFs) of monthly-mean, hemispheric geopotential height. In the lowermost troposphere, the structure of the annular modes is defined as the leading EOF of the near-surface geopotential height field, and these patterns correspond well to the patterns of variability induced by stratospheric circulation changes. At pressure levels above the surface, the structure of the annular modes is typically found by either calculating the local EOF or regressing geopotential height data onto the leading principal component time series of near-surface geopotential height. Here we make a critical comparison of the existing methodologies used to diagnose stratosphere,troposphere coupling, including EOF-based indices as well as measures based on zonal-mean wind at a fixed latitude and geopotential height over the polar cap. We argue in favour of an alternative methodology based on EOFs of daily zonally-averaged geopotential. We find that (1) the daily evolution of stratosphere,troposphere coupling events is seen most clearly with this methodology, and (2) the methodology is robust and requires few subjective choices, making it readily applicable to climate model output available only in zonal-mean form. Copyright © 2009 Royal Meteorological Society [source]