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Corrosion Properties (corrosion + property)
Selected AbstractsGeneral Corrosion and Galvanic Corrosion Properties of Differently PVD Treated Magnesium Die Cast Alloy AZ91,ADVANCED ENGINEERING MATERIALS, Issue 12 2003H. Hoche Developing PVD coating systems with better corrosion resistance leads to a duplex process, consisting of a plasma anodisation and an Al2O3 top coating which can both be performed in a modified commercial PVD unit. The tested specimens were investigated by means of optical microscopy, SEM and EDX. Furthermore a novel immersion technique to determine the time dependent corrosion behavior of coated magnesium alloys is introduced. [source] Influence of Homogenization Annealing of AZ91 on Mechanical Properties and Corrosion Behavior,ADVANCED ENGINEERING MATERIALS, Issue 1-2 2008M.-C. Zhao A homogenization annealing (HA) heat treatment is proposed for property enhancement for AZ91; HA for 10 h at 410,°C caused an improvement in hardness, ultimate tensile strength and ductility without loss of corrosion properties. The influence on the corrosion behavior of the microstructure was studied. [source] Corrosion Behavior of PM Processed Ti,Ca,P Bioceramic Composites in Hank's Balanced Salt Solution Using Potentiodynamic StudiesINTERNATIONAL JOURNAL OF APPLIED CERAMIC TECHNOLOGY, Issue 2 2010Malobika Karanjai Ti,Ca,P bioceramic composites for load bearing implants developed by a new powder metallurgy processing technique were studied for their electrochemical corrosion properties. For determining corrosion behavior of such composites having in situ formed bioactive Ca,P phases, potentiodynamic and studies were conducted in simulated body fluid namely Hank's balanced salt solution. Potentiodynamic polarization tests showed no evidence of pitting corrosion. Corrosion potentials (,0.27 to ,0.53 V) and corrosion rates (0.17,4.46 mills per year) of Ti,Ca,P bioceramic composite samples were superior to earlier reported results for coated Ti implants due to the formation of passive layer of bone-like calcium phosphate on the sample surface. [source] Metallurgical characterization, galvanic corrosion, and ionic release of orthodontic brackets coupled with Ni-Ti archwiresJOURNAL OF BIOMEDICAL MATERIALS RESEARCH, Issue 1 2007Myrsini S. Darabara Abstract In orthodontics, a combination of metallic alloys is placed into the oral cavity during medical treatment and thus the corrosion resistance and ionic release of these appliances is of vital importance. The aim of this study is to investigate the elemental composition, microstructure, hardness, corrosion properties, and ionic release of commercially available orthodontic brackets and Copper Ni-Ti archwires. Following the assessment of the elemental composition of the orthodontic wire (Copper Ni-TiÔ) and the six different brackets (Micro Loc, Equilibrium, OptiMESHXRT, Gemini, Orthos2, and Rematitan), cyclic polarization curves were obtained for each material to estimate the susceptibility of each alloy to pitting corrosion in 1M lactic acid. Galvanic corrosion between the orthodontic wire and each bracket took place in 1M lactic acid for 28 days at 37°C and then the ionic concentration of Nickel and Chromium was studied. The orthodontic wire is made up from a Ni-Ti alloy with copper additions, while the orthodontic brackets are manufactured by different stainless steel grades or titanium alloys. All tested wires and brackets with the exception of Gemini are not susceptible to pitting corrosion. In galvanic corrosion, following exposure for 28 days, the lowest potential difference (,250 mV) appears for the orthodontic wire Copper Ni-Ti and the bracket made up from pure titanium (Rematitan) or from the stainless steel AISI 316 grade (Micro Loc). Following completion of the galvanic corrosion experiments, measurable quantities of chromium and nickel ions were found in the residual lactic acid solution. © 2006 Wiley Periodicals, Inc. J Biomed Mater Res Part B: Appl Biomater, 2006 [source] Mechanical and corrosion properties of spot-welded high-strength austenitic stainless steel EN 1.4318MATERIALS AND CORROSION/WERKSTOFFE UND KORROSION, Issue 4 2008M. T. Alenius Abstract Mechanical and corrosion properties of spot-welded high-strength austenitic stainless steels EN 1.4318 2H/C1150 and EN 1.4318 2H/C850 were studied. Microhardness measurements, lap shear and cross-tension tests, corrosion fatigue tests and corrosion tests were carried out. The corrosion environment was 3.5% sodium chloride solution at +50,°C in the corrosion fatigue tests and 3.5% sodium chloride solution at ambient temperature in the electrochemical pitting corrosion tests. Stainless steel EN 1.4318 2H/C850, t,=,1.92 mm, exhibited better fatigue endurance than EN 1.4318 2H/C1150, t,=,1.2 mm, and EN 1.4318 2H/C850, t,=,1.0 mm, stainless steels did. There were no significant differences between the stainless steels of different strength levels (2H/C850 vs. 2H/C1150) in the line load range analysis of the fatigue data. High hardness gradient was found in the heat-affected zone (HAZ) of EN 1.4318 2H/C1150 stainless steels. EN 1.4318 2H/C1150, t,=,1.2 mm, stainless steels seemed to have slightly higher lap shear strength with the same nugget diameter as EN 1.4318 2H/850, t,=,1.9 mm, stainless steel. In the case of EN 1.4318 2H/C1150 stainless steel increase in the nugget diameter bigger than required 5,t did not increase the cross-tension force significantly. The pitting corrosion susceptibility of the spot-welded samples and the base materials of the steels EN 1.4318 2H/C850 and EN 1.4318 2H/C1150, t,=,1.2 mm, was investigated by measuring the corrosion current for 1 h at +100 mV versus saturated calomel electrode (SCE) in 3.5% sodium chloride solution at ambient temperature. Pitting corrosion occurred in all spot-welded samples but not in the base materials. There was a difference between the investigated steels in the location of the pits. In stainless steels EN 1.4318 2H/C850 the pits appeared around the spot weld, but in the steel EN 1.4318 2H/C1150, t,=,1.2 mm, the pits are located mainly at the spot-weld area. [source] The influence of artificial aging on the microstructure, mechanical properties, corrosion, and environmental cracking susceptibility of a 7075 friction-stir-weldMATERIALS AND CORROSION/WERKSTOFFE UND KORROSION, Issue 10 2007C. S. Paglia The influence of overaging to the T7451 temper on the microstructure, the mechanical properties, and the corrosion susceptibility of friction-stir-welded 7075 aluminum alloy was investigated by means of transmission electron microscope (TEM), SEM investigations, constant extension rate tests (CERT), alternate immersion tests, and potentiodynamic scans. The overaging that occurs during welding within the heat-affected zones of the friction-stir-welded 7075-O tempered plates promotes a slight formation of intragranular and grain boundary precipitates and increases the mechanical as well as the corrosion resistance properties as compared to the T7451 welded plates. The "double" overaging treatment, consisting of the T7451 temper and the thermal transient experienced by the heat-affected zones of the 7075-T7451 welded plates, increases the size of the intragranular and the grain boundary precipitates as well as the precipitate-free zones. These facts decrease the mechanical and corrosion properties of the 7075-T7451 weld. The T7451 thermal treatment applied after the welding of the 7075-O plates promotes the high presence of small precipitates and reduces the size of the precipitate-free zones. This fact increases the general corrosion resistance, but decreases the mechanical properties. Therefore, the corrosion as well as the mechanical properties are greatly correlated with minute changes in the microstructure, which can arise by short-term heat exposure as for instance during welding. It was also found that the environmental susceptibility measured by means of CERTs may be influenced by "solution-strengthening" corrosion mechanisms which increase the strain. This fact is present in weld microzones particularly susceptible to corrosion. [source] Effect of thermal exposure on the microstructure, tensile properties and the corrosion behaviour of 6061 aluminium alloy sheetMATERIALS AND CORROSION/WERKSTOFFE UND KORROSION, Issue 3 2005R. Braun Abstract Sheet material of the Al-Mg-Si alloy 6061 in the tempers T4 and T6 was thermally exposed at temperatures ranging from 85 to 120°C for 1000 h. The microstructure, tensile properties and the corrosion behaviour in the different heat treatment conditions were investigated using differential scanning calorimetry and transmission electron microscopy as well as performing tensile tests and various corrosion tests. The additional heat treatments, which should simulate aging during long-term service usage, caused an increase in strength of 6061-T4 sheet, associated with changes in the naturally aged microstructure. Thermal exposure at 120°C for 1000 h resulted in tensile and corrosion properties being similar to those obtained for peak-aged sheet. Alloy 6061 in the T6 temper exhibited microstructural stability when additionally heat treated at 85 and 120°C for 1000 h. No significant alterations in the microstructure, tensile properties, and corrosion performance were observed after exposure to slightly elevated temperatures. [source] Exfoliation corrosion of aluminum alloy AA7075 examined by electrochemical impedance spectroscopyMATERIALS AND CORROSION/WERKSTOFFE UND KORROSION, Issue 1 2004F.-H. Cao Abstract A typical aluminum alloy, AA7075, was immersed in the EXCO solution, and its corrosion properties during different immersion time were measured repetitively using electrochemical impedance spectroscopy technique (EIS). The EIS data a were simulated using equivalent circuit with ZView program. The results show that once the exfoliation occurs, the low frequency inductive loop in the Nyquist plot associated with the relaxation phenomenon of reaction intermediates disappears, and the Nyquist plane is mainly composed of two capacitive arcs in the high frequency range and low frequency range respectively. The former originates from the original corroded surface, while the latter from the newly formed interface by exfoliation corrosion (EXCO). With the increased immersion time, the high frequency capacitance arc decreases gradually, while the low frequency capacitance arc increases gradually. From the beginning of immersion up to 9 hours, charge transfer resistance gradually decreases, illustrating the acceleration of the corrosion rate, whereas the proton concentration decreases steeply, indicating the cathodic process is pre-dominant. Then the corrosion rate decreases gradually corresponding to the exhausting of proton ions. The results also show that the exfoliation corrosion is developed from pitting corrosion through intergranular corrosion to general corrosion at the end. [source] Galvanisches Verzinken von MagnesiumlegierungenMATERIALWISSENSCHAFT UND WERKSTOFFTECHNIK, Issue 2 2007H. Pokhmurska magnesium alloy; zinc coating; electro plating of zinc; corrosion behaviour Abstract Magnesiumlegierungen sind sehr korrosionsanfällig, was ihre Anwendung unter korrosiven Bedingungen einschränkt. Eine Möglichkeit, um Magnesium vor aggressiven Umweltbedingungen zu schützen, ist das Beschichten. Es werden Ergebnisse über das Korrosionsverhalten der aus verschiedenen Elektrolyten galvanisch verzinkten Magnesiumknetlegierung AZ31 gezeigt. Die Bewertung der Korrosionsprozesse in chloridhaltigen Lösungen erfolgte durch elektrochemische Messungen. Durch einstündige Auslagerung der beschichteten Proben wurde festgestellt, dass dicke und dichte galvanische Zinkschichten auf AZ31 die Korrosionseigenschaften verbessern. Eine Erhöhung der Immersionszeit führt jedoch zu einer Verschlechterung der Korrosionseigenschaften. Elektrolytische Zinkschichten, die durch einen konsekutiven alkalisch / sauren Prozess erzeugt werden, stabilisieren die Schicht und verbessern somit die Korrosionsbeständigkeit des beschichteten AZ31. Zinc-Plating of Magnesium Alloys Magnesium alloys are highly susceptible to corrosion that limits their application when exposure to corrosive service conditions is needed. One of the ways to prevent corrosion is to coat the magnesium-based substrate to avoid a contact with an aggressive environment. Results concerning corrosion behaviour of wrought AZ31 magnesium alloy with electrolytic zinc coatings deposited from different electrolyte solutions are described. Evaluation of corrosion processes in chlorides containing solutions was performed by electrochemical measurements. It was found that thick and dense electrolytic zinc coatings formed on AZ31 significantly improve the corrosion behaviour of magnesium alloy after one hour immersion of zinc coated magnesium alloys in corrosive media. Further increase of immersion time leads to relatively fast decrease of corrosion properties. Electrolytic zinc coatings obtained in consecutive alkaline / acidic process demonstrate an improvement of corrosion resistance of coated AZ31. The time to coating degradation strongly increases. [source] Engineering and Design of Wear and Corrosion Resistant PVD Coatings Regarding the Exceptional Properties of Magnesium SubstratesPLASMA PROCESSES AND POLYMERS, Issue S1 2007Holger Hoche Abstract Although magnesium alloys were popular in the first half of the 20th century, the bad corrosion properties prevented their breakthrough in industrial mass production. Since the technology for the production of high purity alloys was introduced in the 1970s, magnesium alloys became more and more in the focus of industrial attention. Today magnesium alloys are state-of-the-art in construction parts in automotive industry. Despite its outstanding properties like good castability, low density and nearly unlimited availability the negative aspects like weak corrosion and wear behaviour still limit the application of magnesiums in industry, due to the need of sufficient surface protection (E. Aghion, B. Bronfin, Mater. Sci. Forum2000, 350,351, 19). Today, plasma electrolytic anodisations are state-of-the-art (H. Haferkamp, "Magnesiumkorrosion,Prozesse, Schutz von Anode und Kathode", in: Moderne Beschichtungsverfahren, F.-W. Bach, T. Duda, Eds., Wiley-VCH, Weinheim 2000, ISBN 3-527-30117-8, 242; M. Thoma, Metalloberfläche1984, 38, 393; T. W. Jelinek, Galvanotechnik2003, 94, 46; A. Kuhn, Galvanotechnik2003, 94, 1114). They provide acceptable corrosion resistance and protect the magnesium from mechanical damage due to their high hardness. On the other hand, their high porosity limits their use in combination with electrochemically noble materials, leading to galvanic corrosion (J. Senf, "Untersuchung und Beschreibung von Magnesiumdruckgusslegierungen unter tribologischer, korrosiver und mechanisch-korrosiver Beanspruchung, Berichte aus der Werkstofftechnik", Shaker Verlag, Germany 2001, ISBN 3-8265-8428-7). In addition, the high surface roughness of the plasma electrolytic anodisations restricts their use in tribological applications, particularly under sliding conditions (H. Hoche, "Grundlegende Untersuchungen zur Entwicklung von PVD-Beschichtungen auf Magnesiumlegierungen im Hinblick auf die Erhöhung der Verschleißbeständigkeit und unter Berücksichtigung des Korrosionsverhaltens", Dissertation, TU-Darmstadt D17, Shaker Verlag, Germany 2004). In order to achieve smooth surfaces with high quality, the PVD technology moves into the centre of interest. Since the 1980s PVD coatings are well established and widely used for different industrial applications, mainly for steel and tool coatings. The authors were the first who carried out serious studies on the development of PVD coatings for magnesium alloys in 1999 (J. Senf, "Untersuchung und Beschreibung von Magnesiumdruckgusslegierungen unter tribologischer, korrosiver und mechanisch-korrosiver Beanspruchung, Berichte aus der Werkstofftechnik", Shaker Verlag, Germany 2001, ISBN 3-8265-8428-7; H. Hoche, "Grundlegende Untersuchungen zur Entwicklung von PVD-Beschichtungen auf Magnesiumlegierungen im Hinblick auf die Erhöhung der Verschleißbeständigkeit und unter Berücksichtigung des Korrosionsverhaltens", Dissertation, TU-Darmstadt D17, Shaker Verlag, Germany 2004). The extensive research activities lead to the recent development of a coating system, which provides both, good wear properties as well as good corrosion behaviour. [source] Laser composite surfacing of stainless steel with SiCPHYSICA STATUS SOLIDI (A) APPLICATIONS AND MATERIALS SCIENCE, Issue 9 2006J. Dutta Majumdar Abstract In the present study, an attempt has been made to improve wear resistance of AISI 304 stainless steel by laser composite surfacing with SiC. Laser processing has been carried out by pre-deposition of Fe + SiC powders (in the ratio of 85:15 and thickness of 100 ,m) on AISI 304 stainless steel substrate and subsequently, melting it using a 2 kW continuous wave CO2 laser. Following laser processing, a detailed characterization and evaluation of mechanical/electrochemical properties of the composite layer were undertaken to study the influence of laser processing on the characteristics and properties of the composite layer. Microstructure of the composite layer consisted of uniformly dispersed SiC particles in grain refined ,-Fe dendrites. Laser composite surfacing led to a significant improvement in microhardness and wear resistance as compared to as-received substrate. However, pitting corrosion property was marginally deteriorated due to laser composite surfacing. (© 2006 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) [source] | ||||||||||