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Conductivity Data (conductivity + data)
Selected AbstractsProton Conductivity Measurements in Yttrium Barium Cerate by Impedance SpectroscopyJOURNAL OF THE AMERICAN CERAMIC SOCIETY, Issue 11 2002W. Grover Coors Proton-conducting solid-electrolyte perovskite ceramics based on acceptor-doped barium and strontium cerates have become the focus of extensive investigations as candidate materials for fuel cells that operate at moderate temperatures. To assess the suitability of a material for this application, it is necessary that bulk electrolyte conductivity be measured at the operating temperature. However, very little reliable published conductivity data exist above 600°C. Protonic conductivity in yttrium-doped barium cerate has been observed to be less at high temperatures than would be expected, based on the activation energy and preexponential for hydrogen transport at temperatures <300°C. Conductivity data obtained from impedance spectroscopy on BaCe0.9Y0.1O3,, over the extended temperature range of 100°,900°C are presented. An Arrhenius plot of the data shows two distinct linear regions, suggesting that two different rate-limiting processes occur in series with a break-over transition at ,250°C. The decrease in conductivity is apparently not due to dehydration. An activation energy for protonic transport of 0.26 eV, about one-half of the low-temperature value, is proposed, based on curve fitting of the high-temperature data. [source] Evolution of Electrical, Chemical, and Structural Properties of Transparent and Conducting Chemically Derived Graphene Thin FilmsADVANCED FUNCTIONAL MATERIALS, Issue 16 2009Cecilia Mattevi Abstract A detailed description of the electronic properties, chemical state, and structure of uniform single and few-layered graphene oxide (GO) thin films at different stages of reduction is reported. The residual oxygen content and structure of GO are monitored and these chemical and structural characteristics are correlated to electronic properties of the thin films at various stages of reduction. It is found that the electrical characteristics of reduced GO do not approach those of intrinsic graphene obtained by mechanical cleaving because the material remains significantly oxidized. The residual oxygen forms sp3 bonds with carbon atoms in the basal plane such that the carbon sp2 bonding fraction in fully reduced GO is ,0.80. The minority sp3 bonds disrupt the transport of carriers delocalized in the sp2 network, limiting the mobility, and conductivity of reduced GO thin films. Extrapolation of electrical conductivity data as a function of oxygen content reveals that complete removal of oxygen should lead to properties that are comparable to graphene. [source] Detection of preferential infiltration pathways in sinkholes using joint inversion of self-potential and EM-34 conductivity dataGEOPHYSICAL PROSPECTING, Issue 5 2007A. Jardani ABSTRACT The percolation of water in the ground is responsible for measurable electric potentials called self-potentials. These potentials are influenced by the distribution of the electrical conductivity of the ground. Because sinkholes are associated both with self-potential and electrical conductivity anomalies, a joint inversion of EM-34 conductivity and self-potential data is proposed as a way of delineating the location of these features. Self-potential and EM conductivity data were obtained at a test site in Normandy (France) where sinkholes and crypto-sinkholes are present over a karstic area in a chalk substratum overlain by clay-with-flint and loess covers. The presence of sinkholes and crypto-sinkholes is associated with negative self-potential anomalies with respect to a reference electrode located outside the area where the sinkholes are clustered. The sinkholes also have a conductivity signature identified by the EM-34 conductivity data. We used the simulated-annealing method, which is a global optimization technique, to invert jointly EM-34 conductivity and self-potential data. Self-potential and electrical conductivity provide clear complementary information to determine the interface between the loess and clay-with-flint formations. The sinkholes and crypto-sinkholes are marked by depressions in this interface, focusing the groundwater flow towards the aquifer contained in the chalk substratum. [source] Thermodynamics and micellar properties of some surface active cobalt(III) metallosurfactants in nonaqueous mediumINTERNATIONAL JOURNAL OF CHEMICAL KINETICS, Issue 1 2007K. Santhakumar The critical micelle concentration (CMC) of four kinds of metallosurfactants of the type halogeno(dodecyl/cetylamine)-bis(ethylenediamine)cobalt(III) has been studied in n -alcohol and in formamide at different temperatures by electrical conductivity method. Specific conductivity data (at 293,313 K) served for the evaluation of temperature-dependent CMC and the thermodynamic parameters such as standard Gibbs free energy changes (,G), enthalpies (,H), and entropies (,S) of micelle formation. CMCs have also been measured as a function of percentage concentration of alcohol added. It is suggested that alcohol addition leads to increase in formamide penetration into micellar interface that depends on the alcohol chain length. The results have been discussed in terms of increased hydrophobic effect (solvophobic interaction), dielectric constant of the medium, and the chain length of the alcohols, the surfactant in the solvent mixture. © 2006 Wiley Periodicals, Inc. Int J Chem Kinet 39: 22,31, 2007 [source] Synthesis and characterization of a bis-(4-trifluoromethanesulfonyloxyphenyl)phenylamine monomer and its polymer for light-emitting applicationsJOURNAL OF POLYMER SCIENCE (IN TWO SECTIONS), Issue 10 2007Huseyin Zengin Abstract This study focuses on the preparation, polymerization, characterization, and optical properties of a new bis-(4-trifluoromethanesulfonyloxyphenyl)phenylamine monomer. This is the first nitrogen-containing monomer having nitrogen atoms as bridges between phenyl rings, and it was synthesized in three steps. The polymerization was carried out through the Ni(0)-catalyzed homocoupling reaction of the bis-(4-trifluoromethanesulfonyloxyphenyl)phenylamine compound. The resulting polymer, polybis(paraphenyl)phenylamine, emitted an intense blue color (where , = 415 nm) upon irradiation by ultraviolet light. The photoluminescence quantum yield was found to be 36% with a long excited-state lifetime of 3.3 ns. Electrical conductivity data for an HCl-doped film of the polymer were also examined. This novel polymer is of interest as an organic emitting material for electroluminescent devices. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 1860,1867, 2007 [source] Temperature-Gradient Effects in Thermal Barrier Coatings: An Investigation Through Modeling, High Heat Flux Test, and Embedded SensorJOURNAL OF THE AMERICAN CERAMIC SOCIETY, Issue 10 2010Yang Tan The harsh thermal environment in gas turbines, including elevated temperatures and high heat fluxes, induces significant thermal gradients in ceramic thermal barrier coatings (TBCs), which are used to protect metallic components. However, the thermal conductivity of plasma-sprayed TBC increases with exposure at high temperatures mainly due to sintering phenomena and possible phase transformation, resulting in coating performance degradation and potential thermal runaway issues. An analytical thermal model and experimentally obtained coating thermal conductivity data are used to determine the coating through-thickness temperature profile and effective thermal conductivity under gradient conditions at high temperatures. High heat flux tests are then performed on TBCs to evaluate coating thermal behavior under temperature gradients close to service conditions. Coating internal temperature during the tests was also measured by thermally sprayed embedded thermocouples within the top coat. This combined approach provides a sintering map with a new model and allows for the assessment of temperature-gradient effects on the thermal performance of plasma-sprayed TBCs. [source] Proton Conductivity Measurements in Yttrium Barium Cerate by Impedance SpectroscopyJOURNAL OF THE AMERICAN CERAMIC SOCIETY, Issue 11 2002W. Grover Coors Proton-conducting solid-electrolyte perovskite ceramics based on acceptor-doped barium and strontium cerates have become the focus of extensive investigations as candidate materials for fuel cells that operate at moderate temperatures. To assess the suitability of a material for this application, it is necessary that bulk electrolyte conductivity be measured at the operating temperature. However, very little reliable published conductivity data exist above 600°C. Protonic conductivity in yttrium-doped barium cerate has been observed to be less at high temperatures than would be expected, based on the activation energy and preexponential for hydrogen transport at temperatures <300°C. Conductivity data obtained from impedance spectroscopy on BaCe0.9Y0.1O3,, over the extended temperature range of 100°,900°C are presented. An Arrhenius plot of the data shows two distinct linear regions, suggesting that two different rate-limiting processes occur in series with a break-over transition at ,250°C. The decrease in conductivity is apparently not due to dehydration. An activation energy for protonic transport of 0.26 eV, about one-half of the low-temperature value, is proposed, based on curve fitting of the high-temperature data. [source] Non-adiabatic small polaron hopping conduction in sodium borate tungstate glassesPHYSICA STATUS SOLIDI (A) APPLICATIONS AND MATERIALS SCIENCE, Issue 2 2003A. Al-Shahrani Abstract The dc electrical conductivity of (100,x)Na2B4O7,xWO3 (x = 5, 15, 20 and 30 mol%) glasses is reported in the temperature range 323,473 K. The density and molar volume for these glasses are consistent with the ionic size, atomic weight and amount of different elements in the glasses. At high temperatures the Mott model of phonon-assisted small polaron hopping between nearest neighbours is consistent with conductivity data, while at intermediate temperatures the Greaves variable-range hopping model is found to be appropriate. The estimated model parameters such as number of ions per unit volume, hopping distance, polaron radius and activation energy are found to be consistent with the formation of localized states in these glasses. The electrical conduction of these glasses is confirmed to be that of non-adiabatic small polaron hopping. (© 2003 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) [source] Variation of the Fermi level in n-type microcrystalline silicon by electron bombardment and successive annealing: ESR and conductivity studiesPHYSICA STATUS SOLIDI (C) - CURRENT TOPICS IN SOLID STATE PHYSICS, Issue 3-4 2010Oleksandr Astakhov Abstract ESR and conductivity studies have been preformed on ,c-Si:H exposed to 2 MeV electron bombardment and successive annealing in order to investigate the influence of the defect density on the electronic properties of n-type ,c-Si:H. With this approach one can vary the defect density in one and the same sample and directly deduce its influence on the electronic properties. The defect density is varied by 2 orders of magnitude with strong influence on the dark conductivity and electron spin resonance (ESR) properties. The relationship of ESR and conductivity data obtained over the whole defect density range is in agreement with the data obtained on the sets of samples deposited with different doping level. The results indicate that the Fermi level position in ,c-Si:H is defined by a balance of defect and donor states densities regardless of which of these quantities is varied. (© 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) [source] Effects of cell structure and density on the properties of high performance polyimide foams,,POLYMERS FOR ADVANCED TECHNOLOGIES, Issue 2-3 2005Martha K. Williams Abstract Activity at the NASA Langley Research Center (LaRC) has focused on developing low density polyimide foam and foam structures which are made using monomeric solutions or salt solutions formed from the reaction of a dianhydride and diamine dissolved in a mixture of foaming agents and alkyl alcohol at room temperature. Monomer blends may be used to make a variety of polyimide foams with varying properties. The first foaming process developed consisted of thermal cycling the polymer precursor residuum and allowing the inflation of the particles to interact to create the foam. This process has resulted in foam structures with higher percentages of open cell content. Another innovative foaming process has been developed that begins with partially inflated microspheres, "friable balloons", with incomplete polymer molecular weight gain, which when fully cured into a foam results in more closed cell structures. In a research study performed by NASA Kennedy Space Center (KSC) and LaRC, two closely related polyimide foams, TEEK-H series and TEEK-L series, (4,4,-oxydiphthalic anhydride/3,4,-oxydianiline and 3,3,,4,4,-benzophenonetetracarboxylic acid dianhydride/4,4,-oxydianiline) were investigated for density effects and closed versus open cell effects on the thermal, mechanical, and flammability properties. Thermal conductivity data under the full range of vacuum pressures indicate that these materials are effective insulators under cryogenic conditions. Contributing factors such as cell content, density, and surface area were studied to determine the effects on thermal conductivity. Cone calorimetry data indicated decreased peak heat release rates for the closed cell system, TEEK-H friable balloons, compared to the TEEK foams with higher open cell content. Mechanical properties including tensile strength and compressive strength indicated that the materials have good structural integrity. Foams with more open cell content resulted in greater tensile and compressive strengths than the closed cell foams. The maximum closed cell content achieved in the "friable balloon" system was 78% at a foam density of 0.048 gm/cm3. Published in 2005 by John Wiley & Sons, Ltd. [source] A New Method for Simultaneous Estimation of Micellization Parameters from Conductometric DataCHEMISTRY - A EUROPEAN JOURNAL, Issue 20 2004Nenad Jal, enjak Dr. Abstract A simple method for determination of the counterion binding parameter (,) and aggregation number (N) from conductivity data is proposed. The method is based on fitting the values of the first derivative of conductivity (,) versus total surfactant concentration (ct) function according to the equation derived from the mass action model (MAM) by using different conductivity models. Sodium dodecylsulphate (SDS) and dodecyltrimethylammonium bromide (DTAB) were chosen for validation of the proposed method. It was shown that the method gives a fairly accurate values for micellisation parameters of SDS (N=51,64, ,=0.74,0.75) and DTAB (N=56,62, ,=0.77,0.79), both in good agreement with the literature data. In addition, application of the proposed method does not require the value of the critical micelle concentration (cmc). [source] | ||||||||||||||||