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Compositional Data (compositional + data)
Selected AbstractsAssessing Ceramic Compositional Data: A Comparison of Total Reflection X-ray Fluorescence and Instrumental Neutron Activation Analysis On Late Iron Age Spanish Celtiberian CeramicsARCHAEOMETRY, Issue 3 2001M. García-Heras A solid-phase, non-chemical processing protocol was recently developed as a means of chemically characterizing archaeological ceramics by total reflection X-ray fluorescence (TXRF). Following this methodology, TXRF can provide semi-quantitative determinations for 18 elements with comparable levels of precision and accuracy for the majority of them in comparison with a clay reference material analysed by instrumental neutron activation (INAA). In order critically to assess the analytical capabilities of TXRF, a large sample set of Late Iron Age Spanish Celtiberian ceramics and modern clays was analysed both by TXRF and INAA. Semi-quantitative chemical data provided by TXRF and quantitative data provided by INAA were subjected to commonly used multivariate statistical methods as a way of evaluating the ability of the new technique to discriminate among different compositional groups. The comparison of the two data sets shows no significant discrepancies, thereby allowing support for the same archaeological interpretation. These results suggest that TXRF has potential applicability for compositional characterization of archaeological ceramics, providing data that are useful for provenance studies. [source] A latent Gaussian model for compositional data with zerosJOURNAL OF THE ROYAL STATISTICAL SOCIETY: SERIES C (APPLIED STATISTICS), Issue 5 2008Adam Butler Summary., Compositional data record the relative proportions of different components within a mixture and arise frequently in many fields. Standard statistical techniques for the analysis of such data assume the absence of proportions which are genuinely zero. However, real data can contain a substantial number of zero values. We present a latent Gaussian model for the analysis of compositional data which contain zero values, which is based on assuming that the data arise from a (deterministic) Euclidean projection of a multivariate Gaussian random variable onto the unit simplex. We propose an iterative algorithm to simulate values from this model and apply the model to data on the proportions of fat, protein and carbohydrate in different groups of food products. Finally, evaluation of the likelihood involves the calculation of difficult integrals if the number of components is more than 3, so we present a hybrid Gibbs rejection sampling scheme that can be used to draw inferences about the parameters of the model when the number of components is arbitrarily large. [source] Development and application of a fatty acid based microbial community structure similarity indexENVIRONMETRICS, Issue 4 2002Alan Werker Abstract This article presents an index of similarity that has application in monitoring relative changes of complex microbial communities for the purpose of understanding the impact of community instability in biological wastewater treatment systems. Gas chromatographic data quantifying microbial fatty acid esters extracted from biosolids samples can be used to infer the occurrence of changes in mixed culture community structure. One approach to rapidly assess the relative dissimilarity between samples is to calculate a similarity index scaled between 0 and 1. The many arbitrary scales that are associated with the available calculation methods for similarity indices limits the extent of application. Therefore, a specialized index of similarity was derived from consideration of the measurement errors associated with the chromatographic data. The resultant calculation method provides a clear mechanism for calibrating the sensitivity of the similarity index, such that inherent measurement variability is accommodated and standardization of scaling is achieved. The similarity index sensitivity was calibrated with respect to an effective gas chromatographic peak coefficient of variation, and this calibration was particularly important for facilitating comparisons made between different systems or experiments. The proposed index of similarity was tested with data acquired from a recently completed study of contaminant removal from pulp mill wastewater. The results suggest that this index can be used as a screening tool to rapidly process microbial fatty acid (MFA) compositional data, with the objective of making preliminary identification of underlying trends in (MFA) community structure, over time or between experimental conditions. Copyright © 2002 John Wiley & Sons, Ltd. [source] Synthesis of Nanohole-Structured Single-Crystalline Platinum Nanosheets Using Surfactant-Liquid-Crystals and their Electrochemical CharacterizationADVANCED FUNCTIONAL MATERIALS, Issue 4 2009Tsuyoshi Kijima Abstract Nanohole-structured single-crystalline Pt nanosheets have been synthesized by the borohydride reduction of Na2PtCl6 confined to the lyotropic liquid crystals (LLCs) of polyoxyethylene (20) sorbitan monooleate (Tween 80) with or without nonaethylene-glycol (C12EO9). The Pt nanosheets of around 4,10,nm in central thickness and up to 500,nm or above in diameter have a number of hexagonal-shaped nanoholes ,1.8,nm wide. High-resolution electron microscope images of the nanosheets showed atomic fringes with a spacing of 0.22,nm indicating that the nanosheets are crystallographically continuous through the nanoholed and non-holed areas. The inner-angle distributions for the hexagonal nanoholes indicate that the six sides of the nanoholes are walled with each two Pt (111), Pt (11) and Pt (010) planes. The formation mechanism of nanoholed Pt nanosheets is discussed on the basis of structural and compositional data for the resulting solids and their precursory LLCs, with the aid of similar nanohole growth observed for a Tween 80 free but oleic acid-incorporated system. It is also demonstrated that the nanoholed Pt nanostructures loaded on carbon exhibit fairly high electrocatalytic activity for oxygen reduction reaction and a high performance as a cathode material for polymer-electrolyte fuel cells, along with their extremely high thermostability revealed through the effect of electron-irradiation. [source] DIFFERENTIATION OF CURED COOKED HAMS BY PHYSICO-CHEMICAL PROPERTIES AND CHEMOMETRICSJOURNAL OF FOOD QUALITY, Issue 1 2009VITTORIO M. MORETTI ABSTRACT Comparison of physico-chemical and compositional traits was carried out on cooked hams. Deboned fresh pig thighs of three different origins were divided into three batches: 200 pig thighs from the Italian market, H1; 200 from The Netherlands, H2; and 200 from Denmark, H3. Boneless pig thighs were processed under commercial guidelines for production of cooked hams, using brine at 25% level of injection. After processing, 12 cooked hams from each batch were sampled randomly and analyzed for proximate and fatty acid composition. Color measurement was performed on the muscles: biceps femoris, semimembranosus, and semitendinosus. H1 hams showed a higher weight loss and a lower technological yield compared to H2 and H3 hams. Analysis of variance on compositional data showed that H1 hams had a lower moisture/protein ratio, a higher fat content, a lower percentage of, -linolenic, eicosapentaenoic and docosahexaenoic acid, and a higher percentage of myristic and palmitic acids when compared to H2 and H3 hams (P < 0.05). Analysis of color of the three muscles demonstrated that hams from the H1 group had the highest a* values. The application of linear discriminant analysis demonstrated that the use of only four variables allowed to correctly discriminate among groups of cooked hams. PRACTICAL APPLICATIONS The following are the practical applications of this research. The comparison of physico-chemical and compositional traits were carried out on cooked hams. Pig thighs of different origin were processed under commercial guidelines. The physicochemical parameters of cooked hams were defined and showed some differences characterizing the products. [source] AN UNUSUAL POLYUNSATURATED C-27 HYDROCARBON FROM THE MARINE DINOFLAGELLATE PYROCYSTIS LUNULAJOURNAL OF PHYCOLOGY, Issue 2001Article first published online: 24 SEP 200 Leblond, J. D.1 & Chapman, P. J.2 1Department of Biology, Middle Tennessee State University, Murfreesboro, TN 37132. 2US EPA (NHEERL), Gulf Ecology Division, 1 Sabine Island Dr., Gulf Breeze, FL 32561 Studies of the lipids of different algal species have revealed a diversity of fatty acids, sterols, and hydrocarbons, of which several are considered useful biomarkers, with potential for characterizing phytoplankton community composition. To extend this approach and characterize the lipids and lipid classes of laboratory-cultured marine dinoflagellates, a silicic acid fractionation system was developed to obtain compositional data for sterols and hydrocarbons of over forty species. In the course of this work, a neutral fraction obtained from a lipid extract of Pyrocystis lunula was found to contain an abundant quantity of a long-chain polyunsaturated hydrocarbon, along with previously reported keto-steranes. The hydrocarbon molecular weight (364) and retention time obtained by gas chromatography/mass spectrometry analysis suggested a C27 compound, which was confirmed by reduction (Adams catalyst) to give the straight chain alkane, n-heptacosane. The presence of eight double bonds was established by deuteration to give a product with molecular weight 396. While the positions of double bonds have not been established, the carbon number of this hydrocarbon and the number of double bonds strongly suggest formation by decarboxylation of the recently described, long-chain polyunsaturated C28 fatty acid shown to be a constituent of phospholipids. This hydrocarbon was not found in any other genus of the examined dinoflagellates, and appears to be one of the first identifications of a hydrocarbon in this class of algae. The function(s) of this compound in P. lunula is currently unclear. [source] A latent Gaussian model for compositional data with zerosJOURNAL OF THE ROYAL STATISTICAL SOCIETY: SERIES C (APPLIED STATISTICS), Issue 5 2008Adam Butler Summary., Compositional data record the relative proportions of different components within a mixture and arise frequently in many fields. Standard statistical techniques for the analysis of such data assume the absence of proportions which are genuinely zero. However, real data can contain a substantial number of zero values. We present a latent Gaussian model for the analysis of compositional data which contain zero values, which is based on assuming that the data arise from a (deterministic) Euclidean projection of a multivariate Gaussian random variable onto the unit simplex. We propose an iterative algorithm to simulate values from this model and apply the model to data on the proportions of fat, protein and carbohydrate in different groups of food products. Finally, evaluation of the likelihood involves the calculation of difficult integrals if the number of components is more than 3, so we present a hybrid Gibbs rejection sampling scheme that can be used to draw inferences about the parameters of the model when the number of components is arbitrarily large. [source] Biplots of compositional dataJOURNAL OF THE ROYAL STATISTICAL SOCIETY: SERIES C (APPLIED STATISTICS), Issue 4 2002John Aitchison Summary. The singular value decomposition and its interpretation as a linear biplot have proved to be a powerful tool for analysing many forms of multivariate data. Here we adapt biplot methodology to the specific case of compositional data consisting of positive vectors each of which is constrained to have unit sum. These relative variation biplots have properties relating to the special features of compositional data: the study of ratios, subcompositions and models of compositional relationships. The methodology is applied to a data set consisting of six-part colour compositions in 22 abstract paintings, showing how the singular value decomposition can achieve an accurate biplot of the colour ratios and how possible models interrelating the colours can be diagnosed. [source] The Epidemiologic Transition Revisited: Compositional Models for Causes of Death by Age and SexPOPULATION AND DEVELOPMENT REVIEW, Issue 2 2002Joshua A. Salomon For decades, researchers have noted systematic shifts in cause-of-death patterns as mortality levels change. The notion of the "epidemiologic transition" has influenced thinking about the evolution of health in different societies and the response of the health system to these changes. This article re-examines the epidemiologic transition in terms of empirical regularities in the cause composition of mortality by age and sex since 1950, and considers whether the theory of epidemiologic transition presents a durable framework for understanding more recent patterns. Age-sex-specific mortality rates from three broad cause groups are analyzed: Group 1 (communicable diseases, maternal and perinatal causes, and nutritional deficiencies); Group 2 (noncommunicable diseases); and Group 3 (injuries), using the most extensive international database on mortality by cause, including 1,576 country-years of observation, and new statistical models for compositional data. The analyses relate changes in cause-of-death patterns to changing levels of all-cause mortality and income per capita. The results confirm that declines in overall mortality are accompanied by systematic changes in the composition of causes in many age groups. These changes are most pronounced among children, for whom Group 1 causes decline as overall mortality falls, and in younger adults, where strikingly different patterns are found for men (shift from Group 3 to Group 2) compared to women (shift toward Group 2 then Group 3). The underlying patterns that emerge from this analysis offer insights into the epidemiologic transition from high-mortality to low-mortality settings. [source] THE HISTORY OF THE LAWRENCE BERKELEY NATIONAL LABORATORY INSTRUMENTAL NEUTRON ACTIVATION ANALYSIS PROGRAMME FOR ARCHAEOLOGICAL AND GEOLOGICAL MATERIALSARCHAEOMETRY, Issue 2 2007F. ASARO The Lawrence Berkeley National Laboratory pottery provenance group developed standards and instrumental neutron activation analysis (INAA) methods that are used at many archaeometry laboratories around the world. The background and development of ,Standard Pottery' and of methods for INAA are described. Early pottery provenance studies are described, and other research programmes, involving obsidian and magmatic mixing, the origin of the stone used for the Colossi of Memnon, and the ,Plate of Brass', are mentioned. Research work by the Laboratory included the discovery of the world-wide iridium anomaly and extensive subsequent research on what has come to be known as the ,Asteroid Impact Theory'. Characteristics of the analytical programme for pottery provenance work, including overall aims, precision and accuracy, intercalibration, and irradiation and measurement protocols, are discussed. New research areas developed in the past 15 years, to broaden the usefulness of chemical compositional data for archaeological investigation, and examples of recent work, are described. This research, which makes use of high-precision X-ray fluorescence analysis in addition to INAA measurements on sample splits, includes distinguishing the products of different workshops located at the same production site, studies on the significance of the distribution of silver in archaeological pottery and the use of high-precision chemical compositional data as an aid for making chronological distinctions. [source] Palaeo-ice streams and the subglacial landscape mosaic of the North American mid-continental prairiesBOREAS, Issue 3 2009MARTIN ROSS The analysis of the glacial landscape of southern Saskatchewan (Canada) through multiple data sets (e.g. digital elevation model, till compositional data) has revealed previously unrecognized subglacial sediment,landform assemblages. A southwest-trending corridor of mega-scale till lineations (Maskwa corridor) bounded on each side by hummocky terrain extends from the Canadian Shield to southwestern Saskatchewan. This landform assemblage is clearly cross-cut by a broad south to southeast trending corridor (Buffalo corridor) consisting of subparallel curvilinear till ridges. The carbonate content of the surface till is spatially consistent within these assemblages, suggesting a strong sediment,landform relationship. The two corridors are interpreted as the product of palaeo-ice streams. The Maskwa palaeo-ice stream flowed up the regional slope and across preglacial valleys, indicating it was thick and stable. Narrow dispersal trains extending across as well as down-glacier from the Athabasca Basin suggest that the Maskwa palaeo-ice stream extended far into the ice sheet across contrasting shield and platform terrains. In comparison, the Buffalo palaeo-ice stream was thinner and largely controlled by subglacial geology and topography. Its catchments were located at the Canadian Shield boundary and the system was oriented along-slope. It experienced lateral shifts and it was fed by a network of tributaries. The glacial dynamics shift from the Maskwa to the Buffalo system occurred at about 13.5 14C kyr BP. The Buffalo system later evolved into thin outlet lobes until final deglaciation of the area. The proposed model has implications for ice-sheet reconstruction and the assessment of till properties in the prairies and in similar terrains. [source] Cenozoic Exhumation and Thrusting in the Northern Qilian Shan, Northeastern Margin of the Tibetan Plateau: Constraints from Sedimentological and Apatite Fission-Track DataACTA GEOLOGICA SINICA (ENGLISH EDITION), Issue 3 2009Zhaojie GUO Abstract: The Qilian Shan lies along the northeastern edge of the Tibetan Plateau. To constrain its deformation history, we conducted integrated research on Mesozoic,Cenozoic stratigraphic sections in the Jiuxi Basin immediately north of the mountain range. Paleocurrent measurements, sandstone compositional data, and facies analysis of Cenozoic stratigraphic sections suggest that the Jiuxi Basin received sediments from the Altyn Tagh Range in the northwest, initially in the Oligocene (,33 Ma), depositing the Huoshaogou Formation in the northern part of the basin. Later, the source area of the Jiuxi Basin changed to the Qilian Shan in the south during Late Oligocene (,27 Ma), which led to the deposition of the Baiyanghe Formation. We suggest that uplift of the northern Qilian Shan induced by thrusting began no later than the Late Oligocene. Fission-track analysis of apatite from the Qilian Shan yields further information about the deformation history of the northern Qilain Shan and the Jiuxi Basin. It shows that a period of rapid cooling, interpreted as exhumation, initiated in the Oligocene. We suggest that this exhumation marked the initial uplift of the Qilian Shan resulting from the India,Asia collision. [source] | ||||||||||||||||