COD Concentration (cod + concentration)

Distribution by Scientific Domains


Selected Abstracts


Feedback control design for an anaerobic digestion process

JOURNAL OF CHEMICAL TECHNOLOGY & BIOTECHNOLOGY, Issue 6 2002
Jose Alvarez-Ramirez
Abstract An approach for the design of linear feedback controllers for anaerobic digestion systems is presented. The effluent chemical oxigen demand (COD) concentration and the dilution rate are taken respectively as the regulated and the manipulated variables. The control design is based on simple step-response models of the process endowed with an input delay to account for dead-times induced by measurement devices. The resulting feedback controller has a traditional proportional-integral (PI) control structure, so it can be easily implemented with conventional control technologies. Since the concentration of volatile fatty acids can be easily and quickly measured as compared with COD concentration, it is used as a secondary measurement that is incorporated into the feedback loop scheme to enhance the robustness of the control scheme with respect of influent disturbances. The performance of the proposed control scheme is illustrated via numerical simulations and experimental work. © 2002 Society of Chemical Industry [source]


In situ hypochlorous acid generation for the treatment of brackish shrimp aquaculture wastewater

AQUACULTURE RESEARCH, Issue 5 2008
Krishnan Vijayaraghavan
Abstract This study presents an unconventional framework for treating shrimp aquaculture wastewater based on in situ hypochlorous acid (HOCl) oxidation. The in situ oxidation process makes use of the salinity present in aquaculture wastewater to generate HOCl. The undivided electrolytic cell consisted of two sets of graphite as the anode and stainless sheets as the cathode. The electrochemical oxidation of shrimp aquaculture wastewater was carried out for an influent COD concentration of 1730 mg L,1 at current densities of 37.2 and 74.5 mA cm,2. The results showed that in order to achieve a residual COD concentration of 50±5 mg L,1 at current densities of 37.2 and 74.5 mA cm,2, electrolysis periods of 60 and 30 min are required respectively. Hence, for the above-mentioned current densities, the corresponding energy requirements were found to be 19.4 and 13.3 W h L,1. The cost incurred in treating 1 m3 of shrimp aquaculture wastewater was found to be RM 4 and 3 when the electrolytic reactor was operated at a current density of 37.2 and 74.5 mA cm,2 with a salinity of 23,. The foregoing study highlights the potential of in situ HOCl oxidation in treating brackish shrimp aquaculture wastewater. [source]


Screening co-digestion of food waste water with manure for biogas production

BIOFUELS, BIOPRODUCTS AND BIOREFINING, Issue 1 2009
Yan Liu
Abstract Anaerobic digestion, an environmental protection technology for treating organic compounds in waste water, produces biogas, resulting in a renewable energy source. A protocol including waste analysis, waste blending, energy potential and energy balance calculations was developed to determine the energy production from blending food and animal wastes. Fruit and vegetable waste water produced from crop commodity processing was characterized in terms of quantity and 5-day biochemical oxygen demand (BOD). Often these wastes have high levels of degradable carbon but lack buffering capacity and adequate nitrogen and other nutrients to meet the minimal C/N ratio needed for optimal digestion. Blending food-processing waste water with high nutrient manure can enhance the biogas production by optimizing nutrient levels and providing buffering capacity. The protocol shows the procedure to determine the optimal blend and theoretical biogas production from the anaerobic digestion of that blend. An energy balance technique that determines the lowest COD concentration required to close the energy balance in the digester during different seasons is illustrated. A case study was conducted to determine the potential energy production from anaerobically digesting blended waste water from the top 14 fruit and vegetable commodities in Michigan. The resulting biogas production supports a substantial amount of the energy consumption needed for the treatment process. This case study in Michigan can be extended to national level since the calculations were based on the mean value of their typical range. © 2008 Society of Chemical Industry and John Wiley & Sons, Ltd [source]


Electricity generation from the treatment of wastewater with a hybrid up-flow microbial fuel cell

BIOTECHNOLOGY & BIOENGINEERING, Issue 1 2010
Krishna P. Katuri
Abstract The performance of a prototype up-flow single-chambered microbial fuel cell (MFC) for electrical power generation using brewery wastewater as fuel is reported. The designed reactor consisted of three zones, namely a lower anaerobic digestion zone, a central MFC zone, and an upper effluent clarifier zone. Tests were conducted in batch mode using a beer wastewater as the fuel/electron donor (COD concentration: 430,mg/L) and mixed consortia (both sewage microflora and anaerobic sludge) as a source of electrogenic bacteria. A stable current density of ,2,270,mA/m2 was generated under continuous polarization with a constant external resistance (0.01,k,) and cell polarization gave a peak power density of 330,mW/m2 at a current density of 1,680,mA/m2. Electrochemical impedance analysis showed that the overall internal resistance of the reactor was quite low, that is, 8.0,,. Cyclic voltammetric analysis of the anodic biofilm at low scan rate revealed quite complex processes at the anode, with three redox peaks, at potentials of 116, 214, and 319,mV (vs. NHE). Biotechnol. Bioeng. 2010;107: 52,58. © 2010 Wiley Periodicals, Inc. [source]


Novel application of oxygen-transferring membranes to improve anaerobic wastewater treatment

BIOTECHNOLOGY & BIOENGINEERING, Issue 4 2005
Anthony S. Kappell
Abstract Anaerobic biological wastewater treatment has numerous advantages over conventional aerobic processes; anaerobic biotechnologies, however, still have a reputation for low-quality effluents and operational instabilities. In this study, anaerobic bioreactors were augmented with an oxygen-transferring membrane to improve treatment performance. Two anaerobic bioreactors were fed a synthetic high-strength wastewater (chemical oxygen demand, or COD, of 11,000 mg l,1) and concurrently operated until biomass concentrations and effluent quality stabilized. Membrane aeration was then initiated in one of these bioreactors, leading to substantially improved COD removal efficiency (>95%) compared to the unaerated control bioreactor (,65%). The membrane-augmented anaerobic bioreactor required substantially less base addition to maintain circumneutral pH and exhibited 75% lower volatile fatty acid concentrations compared to the unaerated control bioreactor. The membrane-aerated bioreactor, however, failed to improve nitrogenous removal efficiency and produced 80% less biogas than the control bioreactor. A third membrane-augmented anaerobic bioreactor was operated to investigate the impact of start-up procedure on nitrogenous pollutant removal. In this bioreactor, excellent COD (>90%) and nitrogenous (>95%) pollutant removal efficiencies were observed at an intermediate COD concentration (5,500 mg l,1). Once the organic content of the influent wastewater was increased to full strength (COD = 11,000 mg l,1), however, nitrogenous pollutant removal stopped. This research demonstrates that partial aeration of anaerobic bioreactors using oxygen-transferring membranes is a novel approach to improve treatment performance. Additional research, however, is needed to optimize membrane surface area versus the organic loading rate to achieve the desired effluent quality. © 2005 Wiley Periodicals, Inc. [source]