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Coating Film (coating + film)

Distribution by Scientific Domains

Polymers and Materials Science	42%

Selected Abstracts

Preparation and properties of polyhedral oligomeric silsesquioxane,polysiloxane copolymers

APPLIED ORGANOMETALLIC CHEMISTRY, Issue 8 2010
Takahiro Gunji
Abstract All siloxane-type siloxane,polyhedral oligomeric silsesquioxane [(HSiO3/2)8, T8H] copolymers were synthesized by the dehydrogenative condensation of T8H with diphenylsilanediol, tetraphenyldisiloxane-1,3-diol or silanol-terminated polydimethylsiloxanes in the presence of diethylhydroxylamine followed by trimethylsilylation. Coating films were prepared by spin-coating of the coating solutions prepared from the dehydrogenative condensation products. The hardness of the coating films was evaluated by a pencil hardness test and was found to increase up to 6H with increases in the curing temperature. Silica gels were prepared by concentrating the coating solution following by pyrolysis. These silica gels showed a specific surface area 449 m2/g at 650 °C corresponding to the formation of a silica network in response to combustion of the phenyl groups. Copyright © 2009 John Wiley & Sons, Ltd. [source]

Monte Carlo Study of Quantitative Electron Probe Microanalysis of Monazite with a Coating Film: Comparison of 25 nm Carbon and 10 nm Gold at E0= 15 and 25 keV

GEOSTANDARDS & GEOANALYTICAL RESEARCH, Issue 2 2007
Takenori Kato
simulation par la méthode de Monte Carlo; microanalyse par sonde électronique (EPMA); analyse quantitative; film de revêtement; monazite Carbon (25,30 nm in thickness) is the most common coating material used in the electron probe microanalysis (EPMA) of geological samples. A gold coating is also used in special cases to reduce the surface damage by electron bombardment. Monte Carlo simulations have been performed for monazite with a 25 nm carbon and a 10 nm gold coating to understand the effect of a coating film in quantitative EPMA at E0= 15 keV and 25 keV. Simulations showed that carbon-coated monazite gave the same depth distribution of the generated X-rays in the monazite as uncoated monazite, whilst gold-coated monazite gave a distorted depth distribution. A 10 nm gold coating was 1.06 (15 keV) and 1.05 (25 keV) times higher in k -ratio between monazite and pure thorium than a 25 nm carbon coating at an X-ray take-off angle of 40 degrees. Thus, a 10 nm gold coating is a possible factor contributing to inaccuracy in quantitative EPMA of monazite, while a 25 nm carbon coating does not have a significant effect. Le carbone, avec des épaisseurs de 25 à 30 nm, est le matériel de dépôt le plus fréquemment utilisé en microanalyse par sonde électronique (EPMA) d'échantillons géologiques. Un dépôt d'or est aussi utilisé dans des cas spécifiques, pour réduire les dommages causés à la surface par le bombardement d'électrons. Des simulations par la méthode de Monte Carlo ont été effectuées pour une monazite recouverte d'une couche de carbone de 25 nm et d'une couche d'or de 10 nm, dans le but de comprendre l'effet du dépôt dans les mesures quantitatives à l'EPMA, à E0= 15 keV et 25 keV. Les simulations ont montré que la monazite recouverte de carbone avait la même distribution en profondeur de rayons X générés qu'une monazite non recouverte, tandis que la monazite recouverte d'or avait une distribution en profondeur déformée. Le dépôt de 10 nm d'or avait un k -ratio qui était 1.06 (pour 15 keV) et 1.05 (pour 25 keV) fois plus important pour la monazite et du thorium pur que le dépôt de 25 nm de carbone dans le cas d'un angle de sortie des rayons X de 40 degrés. En conséquence un dépôt d'or de 10 nm est un facteur possible d'inexactitude lors de mesures quantitatives de monazites par EPMA, alors qu'un dépôt de carbone de 25 nm n'a pas d'effet significatif sur la mesure. [source]

Preparation of hybrid coating film between magneto-optical and hologram layers

PHYSICA STATUS SOLIDI (A) APPLICATIONS AND MATERIALS SCIENCE, Issue 8 2004
Tae-Youb Kim
Abstract Bi1.8Y1.2Fe5O12 nanoparticles prepared by coprecipitation and milling processes were mixed in an acrylate resin to form a magneto-optical ink. The magneto-optical ink was hybridized with a hologram to produce a magneto-optical hologram mark. The magneto-optical hologram thus obtained has the ability to distinguish true cards against counterfeit cards either with or without the magneto-optical effect of the mark. We propose that the magneto-optical hologram can applied in anti-counterfeit technology. (© 2004 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) [source]

Synthesis and photocuring of cinnamoyl trehalose esters

POLYMERS FOR ADVANCED TECHNOLOGIES, Issue 12 2007
Naozumi Teramoto
Abstract A trehalose cinnamoyl ester (TC) was synthesized from trehalose and cinnamoyl chloride in dimethylformamide (DMF) in the presence of triethylamine and 4-(N,N -dimethylamino)pyridine. The product was characterized by 1H NMR spectroscopy to reveal that the reaction proceeded. Two different types of TCs were synthesized by changing the feed ratio of cinnamoyl chloride to trehalose. When the feed ratio of cinnamoyl chloride to trehalose was 8 (TC8), the degree of substitution (DS) was 8.0, while it was 4.2 when the feed ratio was 4 (TC4). Photocuring was confirmed by observing changes in UV absorption spectrum and FT Infrared (IR) spectrum. After 5,min of UV irradiation, solubility in chloroform significantly decreased. A transparent thin coating film of TC was easily prepared by casting from a chloroform solution on a Petri dish and UV irradiation was carried out over a simple photomask. After TC within the non-irradiated region was removed by flash soaking with chloroform, the shape of the photomask appeared. A scanning electron microscope (SEM) measurement revealed that the surface of the photocured coating film was smooth and that the edge of the photocured TC had a characteristic feature. Biodegradation of the photocured TC and non-irradiated TC was examined by the biochemical oxygen demand (BOD) method using activated sludge. Copyright © 2007 John Wiley & Sons, Ltd. [source]

Chromium-Free Corrosion Resistance of Metals by Ceramic Coating

JOURNAL OF THE AMERICAN CERAMIC SOCIETY, Issue 12 2001
Satomi Ono
Metal surfaces can be improved in terms of thermal, mechanical, and chemical properties by a ceramic coating. The chromium-free corrosion resistance of stainless steel was achieved using a chemical solution method. Precursor solutions were prepared from metal alkoxides and were deposited on stainless-steel surfaces by dip coating and heat-treating at temperatures <500°C. The stainless steel was coated by silica, zirconia, and titania single-layer coating films, and/or coated by silica/zirconia and silica/titania double-layer coating films. The corrosion resistance was improved remarkably by a submicrometer silica-based coating on the stainless steel. [source]

Studies of waterborne emulsion of chemically modified epoxy resin,

POLYMERS FOR ADVANCED TECHNOLOGIES, Issue 1-2 2004
Zhaoying Zhang
Abstract The bisphenol-A type epoxy resin was modified by p -aminobenzoic acid. The modified resins were characterized using IR spectroscopy and differential scanning calorimetry (DSC). The progress of emulsification process was characterized by measuring the variations of conductivity and viscosity while dropping water into the modified resin solution. The factors influencing the emulsion particle size of the waterborne coating films of the modified resins were investigated. Copyright © 2004 John Wiley & Sons, Ltd. [source]