Cotton Fabric (cotton + fabric)

Distribution by Scientific Domains


Selected Abstracts


High affinity, high efficiency fibre-reactive dyes

COLORATION TECHNOLOGY, Issue 4 2006
Brent Smith
A straightforward two-step method for modifying commercial dichlorotriazine-based fibre-reactive dyes prior to their use in the dyeing process can greatly improve affinity and fixation efficiency on cotton, and reduce the salt requirements. The modification used in this study involved prereacting the commercial dyes with either cysteine or cysteamine followed by reaction of the resulting intermediate with cyanuric chloride. Cotton fabric dyed with the modified dyes had technical properties that were essentially equal to those obtained from the unmodified commercial dyes. [source]


Application of a fibre-reactive chitosan derivative to cotton fabric as a zero-salt dyeing auxiliary

COLORATION TECHNOLOGY, Issue 3 2004
Sang-Hoon Lim
Cotton fabric has been treated with a fibre-reactive chitosan derivative containing quaternary ammonium groups, O -acrylamidomethyl- N -[(2-hydroxy-3-trimethylammonium)propyl]chitosan chloride (NMA-HTCC). Cotton treated with NMA-HTCC has been dyed with direct and reactive dyes without the addition of salt. The colour yield was higher than that on untreated cotton, despite the addition of a large amount salt in the latter case. After dyeing, cotton treated with NMA-HTCC gave better wash fastness than the untreated cotton. The light fastness was however inferior to that on untreated cotton. The antimicrobial activity of cotton treated with NMA-HTCC against Staphylococcus aureus was considerably lower after dyeing, probably due to the antimicrobial effect of the cationic group on NMA-HTCC being blocked by its combination with the anionic dye. [source]


Water-repellent finishing of cotton fabrics by ultraviolet curing

JOURNAL OF APPLIED POLYMER SCIENCE, Issue 2 2008
F. Ferrero
Abstract Cotton fabrics were water-repellent-finished by radical ultraviolet curing of silicone and urethane acrylates with different formulations. The fabrics were impregnated with undiluted resins and with toluene solutions or water emulsions. Moreover, cationic ultraviolet-curable systems were also investigated, such as an epoxy-functional polysiloxane and mixtures of an epoxy resin with hydroxyl-containing silicone additives. The gel content and polymerization yield were considered for the ultraviolet-curing process evaluation. Water-resistance properties were determined in terms of the contact angle, wettability, moisture adsorption, and water vapor permeability measurements, whereas the morphology and surface composition of treated fabrics were examined with scanning electron microscopy and energy-dispersive X-ray analysis. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 [source]


Durable antimicrobial finish of cotton fabrics

JOURNAL OF APPLIED POLYMER SCIENCE, Issue 2 2007
Eun S. Bang
Abstract Cotton fabrics were treated with Biopag, which does not have any functional groups that are reactive toward cellulose, using crosslinking agents or a binder, for the purpose of imparting a durable antimicrobial finish. In this respect, it was found that the crosslinking agents were more effective than the binder. It was confirmed by FT-IR that the characteristic split peaks of Biopag were still seen even after repeated launderings. The crosslinking agents deteriorated the whiteness and tensile strength of the Biopag-treated cotton fabrics, while the wrinkle recovery angles (WRAs) were significantly improved. The one-step padding of Biopag and the crosslinking agent was found to be superior to the two-step padding method in which Biopag padding was followed by padding of crosslinking agent in respect of WRA, whereas the whiteness and tensile strength were vice versa. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2007 [source]


Silver-Loaded Cotton/Polyester Fabric Modified by Dielectric Barrier Discharge Treatment

PLASMA PROCESSES AND POLYMERS, Issue 1 2009
Mirjana Kosti
Abstract The preparation of antimicrobial silver-loaded cotton/polyester fabrics has been carried out by DBD surface activation followed by silver sorption from aqueous silver nitrate solution. A series of DBD fabric treatments was performed in order to determine the most suitable experimental conditions for the fabric surface activation. The capillarity, silver ion uptake, and copper number were used to assess the surface changes on the fabrics. An effective process has been developed to obtain antimicrobial silver-loaded Co/PES fabrics. The antimicrobial activity of the silver-loaded fabrics against different pathogens was evaluated in vitro. The quantity of bonded silver ions is enough to develop desirable antimicrobial activity in the Co/PES fabrics. [source]


Potential Applications of Oxidoreductases for the Re-oxidation of Leuco Vat or Sulfur Dyes in Textile Dyeing

ENGINEERING IN LIFE SCIENCES (ELECTRONIC), Issue 3 2008
F. Xu
Abstract Conventional textile dyeing by vat and sulfur dyes includes reduction and re-oxidation steps (with chemical reductants and oxidants), so that the insoluble dyes can be solubilized in the dyeing solution, adsorbed by the fabric, and fixed onto the dyed fabric. The treatments often involve hazardous chemicals, expensive catalysts, or conditions that are suboptimally effective, energy-intensive, caustic, or polluting. Improving these steps with enzyme technology could be of significant interest in terms of better dyeing, handling of hazardous chemicals, disposal of waste, or production economy. The idea of an enzymatic re-oxidation step for vat and sulfur dyeings was tested under simplified laboratory conditions. Selected vat and sulfur dyes, including Vat Blue,43, Vat Orange,7, Vat Green,3, Vat Orange,2, Vat Red,13, Vat Yellow,2, and Sulfur Black,1, were first chemically reduced. The reduced (leuco) dyes were then re-oxidized by aerated buffer solutions or H2O2, in the presence or absence of an oxidoreductase, selected from seven laccases from Myceliophthora thermophila, Scytalidium thermophilum, Coprinus cinereus, Trametes villosa, Rhizoctonia solani, Pycnoporus cinnabarinus, Botrytis cinerea, a bilirubin oxidase from Myrothecium verrucaria, and a heme peroxidase from Coprinus cineresu. It was shown that the enzymes were able to catalyze and accelerate the re-oxidation of the reduced dyes, even when they were adsorbed on cotton fabric, by dissolved air (O2) or H2O2. Small redox-active mediators could facilitate the enzymatic re-oxidation. For Sulfur Black,1, a higher conversion of the leuco dye was achieved with laccase-catalyzed re-oxidation. The further development of this potential enzyme application is discussed. [source]


Modeling multi-stage decomposition of cotton fabrics considering char oxidation in the presence of oxygen

FIRE AND MATERIALS, Issue 8 2009
F. L. Zhu
Abstract A theoretical model, describing thermal degradation behavior of cotton fabrics that exposed to a constant radiant heat flux, is proposed in the paper. The model describes thermal and oxidative degradation of cotton fabric under the oxygen-containing atmosphere and considers pseudo-bi-component separate-stage kinetic process. Both exothermic and endothermic reactions are included in the decomposition process. At present, gas phase oxidation reactions are not included. Comparison with experimental results demonstrates that the predictions of the mass loss rate and temperature profile with these cotton fabrics are in agreement with the experiment. Effects of thermal radiation and ambient oxygen concentration on decomposition have also been investigated. The gas phase temperature is also predicted by the present numerical model. Results from numerical model will help contribute to a better understanding of the ignition mechanism of flame-resistant cotton fabrics used for fire safety garments. Copyright © 2009 John Wiley & Sons, Ltd. [source]


Combination of a hydroxy-functional organophosphorus oligomer and a multifunctional carboxylic acid as a flame retardant finishing system for cotton: Part II.

FIRE AND MATERIALS, Issue 5 2003
Formation of calcium salt during laundering
Abstract Multifunctional carboxylic acids, such as 1,2,3,4-butanetetracarboxylic acid (BTCA), were used to bond a hydroxy-functional organophosphorus oligomer (FR) to cotton fabric in the presence of a catalyst, such as sodium hypophosphite (NaH2PO2). Previously, it was found that the cotton fabric treated with FR and BTCA showed a high level of phosphorus retention after one home laundering cycle. However, the flame retardant properties quickly deteriorated as the number of home laundering cycles was increased. In this research, it was found that the free carboxylic acid groups bound to the cotton fabric form an insoluble calcium salt during home laundering, thus diminishing the flame retardant properties of the treated cotton fabric. It was also found that the free carboxylic acid groups on the treated cotton fabric were esterified by triethanolamine (TEA), and that the formation of calcium salt on the fabric was suppressed by the esterification of the free carboxylic acid groups by TEA. The cotton fabric treated with BTCA and the hydroxy-functional organophosphorus oligomer significantly improved its flame retardance when a new catalyst system consisting of hypophosphorous acid (H3PO2) and TEA was used in the system. Copyright © 2003 John Wiley & Sons, Ltd. [source]


The microencapsulation of terbinafine via in situ polymerization of melamine-formaldehyde and their application to cotton fabric

JOURNAL OF APPLIED POLYMER SCIENCE, Issue 6 2010
Gökhan Erkan
Abstract In this study an antifungal pharmaceutical agent, terbinafine, was microencapsulated by using in situ polymerization. The polymerization was carried out at four mole ratio level and preparations were applied to the 100% cotton fabric. X-ray diffractometry, DSC, FTIR, BET, contact angle measurements, particle size distribution and imaging techniques were performed. Best results were obtained in the case of 8 : 1 mole ratio. Strength of microcapsule applied fabrics to washing and fungus were also determined. After 25 washing cycle, microcapsules were still in the fabric and had antifungal properties against A. niger. Antifungal strength against T. rubrum was observed up to 15 washing cycles. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2010 [source]


Possibilities of polymer-aided dyeing of cotton fabric with reactive dyes at neutral pH

JOURNAL OF APPLIED POLYMER SCIENCE, Issue 3 2010
B. J. Agarwal
Abstract Water-soluble polymers have versatile application, viz., water-soluble polyacrylates have been widely used in the reactive dyeing of cellulosic fibers and the related soaping as an important component of the leveling and washing agent. In this article, one such water-soluble polymer, polyacrylic acid has been synthesized, characterized, and applied in conjunction with various types of reactive dyes, namely triazinyl, vinyl sulfone, high exhaustion, and bifunctional reactive dyes, along with crosslinking agents, namely glycerol 1,3-dichlorohydrin and hexamethylene tetramine-hydroquinone, respectively. One of the crosslinking agents (the former one) has been synthesized in the laboratory. Crosslinking agent is necessary to adhere the dye molecule onto the cellulose macromolecule. Different process sequences have been formulated and explored for dyeing purpose. All such dyeings were carried out at neutral pH. The dyed samples were assessed through color strength in terms of K/S values and their fastness properties were assessed by standard methods. All such dyeings were compared with conventional dyed samples. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2010 [source]


Antibacterial activity of cationically modified cotton fabric with carboxymethyl chitosan

JOURNAL OF APPLIED POLYMER SCIENCE, Issue 3 2008
Amira M. El-Shafei
Abstract A water-soluble carboxymethyl chitosan was prepared with a view to develop a multifunctional finish on cotton. Carboxymethyl chitosan (CMCTS) was synthesized by chemical reaction of chitosan with monochloroacetic acid under alkaline condition. The water soluble CMCTS was applied to cationized cotton with different concentrations. The treated fabrics were characterized through monitoring the textile physical properties and for the antibacterial activity against Escherichia coli DSMZ 498 and Micrococcus luteus ATCC 9341. The results obtained show that the physical properties of the treated fabrics are improved by increasing the CMCTS concentration, as well as the antibacterial activity. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 [source]


Development of flame retardancy properties of new halogen-free phosphorous doped SiO2 thin films on fabrics

JOURNAL OF APPLIED POLYMER SCIENCE, Issue 6 2007
Aysun Cireli
Abstract In this study, flame retardancy properties of fabrics treated with phosphorous (P) doped and undoped SiO2 thin films were developed by sol,gel technique. As to this aim, P-doped and undoped SiO2 film were coated on cotton fabric from the solutions prepared from P, Si-based precursors, solvent, and chelating agent at low temperature in air using sol,gel technique. To determine solution characteristics, which affect thin film structure, turbidity, pH values, and rheological properties of the prepared solutions were measured using a turbidimeter, a pH meter, and a rheometer machines before coating process. The thermal, structural, and microstructural characterization of the coating were done using differential thermal analysis/thermograviometry, fourier transform infrared spectroscopy, X-ray diffractometry, and scanning electron microscopy. In addition, tensile strength, wash fastness, flame retandancy, and lightness properties of the coated fabrics were determined. To compensate the slight loss of tensile strength of samples, which occurred at the treated fabrics with P-doped Si-based solutions, the cotton fabrics were coated with polyurethane films during second step. In conclusion, the flame retardant cotton fabric with durability of washing as halogen-free without requiring after treatment with formaldehyde was fabricated using sol,gel processing for the first time. Moreover the cotton fabrics, which were treated with P-doped Si-based solutions and then coated with polyurethane at second step, still has got nonflammable property. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2007 [source]


A novel approach to excellent UV protecting cotton fabric with functionalized MWNT containing water vapor permeable PU coating

JOURNAL OF APPLIED POLYMER SCIENCE, Issue 5 2007
S. Mondal
Abstract This research paper presented a novel approach of developing excellent protection from ultraviolet (UV) radiation of cotton fabrics by means of water vapor permeable (WVP) coatings containing multiwall carbon nanotube (MWNT), a stable and strongly UV absorbing species. The WVP of MWNT containing UV protective coatings of the present development are formed from solution polymer of hydrophilic polyurethane (HPU). MWNTs were dispersed in HPU solution by functionalization of MWNT. The nanotube containing HPU coating shows excellent protection against UV radiation, with only 1 wt % of MWNT (calculated based on solid content of the polymer), a UV Protection Factor (UPF) of 174 and with 2.5 wt % of MWNT a UPF of 421 was obtained, which stated excellent protection (UPF ,50) according to the Australian/New Zealand standards. Scanning electron micrographs of coated fabrics surface showed a film like polymer coating, confirming the fabric surface was successfully coated by polyurethane. The coated fabrics would maintain very good water vapor permeability, hence confirmed the wearing comfort. Room temperature (20,23°C) range soft segment crystal melting of HPU enhances the permeability of coated fabrics. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 103: 3370,3376, 2007 [source]


Kinetics of lactose hydrolysis by ,-galactosidase of Kluyveromyces lactis immobilized on cotton fabric

BIOTECHNOLOGY & BIOENGINEERING, Issue 2 2003
Quinn Zhengkun Zhou
Abstract A mathematic model for describing the Michaelis-Menten-type reaction kinetics with product competitive inhibition and side-reaction is proposed. A multiresponse nonlinear simulation program was employed to determine the coefficients of a four-parameter rate expression. The rate expression was compared with the conventional Michaelis-Menten reaction rate models with and without product inhibition. Experimental data were obtained using ,-galactosidase of Kluyveromyces lactis immobilized on cotton fabric in a batch system at a temperature of 37°C and at various initial concentrations of dissolved lactose ranging from 3,12.5% (w/v). The reaction is followed by concentration changes with time in the tank. Samples were obtained after the outlet stream of the packed bed reactor is mixed in a well-stirred tank. High-performance liquid chromatography (HPLC) was applied to monitor the concentrations of all the sugars (reactants as well as products). The four-parameter rate model is featured with a term to describe the formation of trisaccharides, a side-reaction of the enzymatic hydrolysis. The proposed model simulates the process of lactose hydrolysis and the formation of glucose and galactose, giving better accuracy compared with the previous models. © 2002 Wiley Periodicals, Inc. Biotechnol Bioeng 81: 127,133, 2003. [source]


Predicting the crease recovery performance and tear strength of cotton fabric treated with modified N -methylol dihydroxyethylene urea and polyethylene softener

COLORATION TECHNOLOGY, Issue 5 2010
Tanveer Hussain
This study aimed at developing a model for predicting the crease recovery performance and tear strength of cotton fabric using modified N -methylol dihydroxyethylene urea, polyethylene softener, catalyst, curing time and curing temperature as the predictor variables. A quarter factorial design was constructed and, based on the experimental results, regression models were built to predict crease recovery angle and tear strength of the treated fabric. All experimental design and statistical analysis steps were implemented, using Minitab statistical software. [source]


Bleaching of cotton fabric with peracetic acid in the presence of different activators

COLORATION TECHNOLOGY, Issue 6 2005
Pavla Kri
Peracetic acid is an efficient oxidant and a good alternative to conventional chemicals for bleaching cotton. In order to establish optimal conditions for its use, giving a high degree of whiteness and good water absorption without damage to the fabric, the chemistry of its consumption and the efficiency of the bleaching process have been examined. The effect of temperature and initial pH was assessed, and in particular the influence of the alkali used to control the pH. The highest and most rapid consumption of peracetic acid was seen with magnesium carbonate, the slowest with sodium hydroxide. The bleaching effect was greatest with sodium carbonate and least with sodium hydroxide, although the differences were not large. In all cases damage to the fabric was minimal. The best conditions for bleaching with peracetic acid were found to be 60 °C and an initial pH 7, in the presence of either sodium carbonate or magnesium carbonate. [source]


Dyeing of cotton with a bifunctional disulphide bis(ethylsulphone-sulphatoethylsulphone) disazo reactive dye

COLORATION TECHNOLOGY, Issue 5 2005
Y A Youssef
A new bifunctional disazo reactive dye of a temporarily high molecular structure based on a disulphide bis(ethylsulphone-sulphatoethylsulphone) reactive system was synthesised and applied to cotton fabric. This dye displayed good primary exhaustion under different neutral exhaustion conditions. The results assessed for the alkaline exhaust dyeing indicate that the disulphide bis(ethylsulphone-sulphatoethylsulphone) dye showed higher exhaustion and fixation values compared to those obtained with the commercial CI Reactive Black 5. The fastness properties of the disulphide dye were similar to those of the commercial dye. Received: 24 March 2005; Accepted: 15 June 2005. [source]


Application of a fibre-reactive chitosan derivative to cotton fabric as a zero-salt dyeing auxiliary

COLORATION TECHNOLOGY, Issue 3 2004
Sang-Hoon Lim
Cotton fabric has been treated with a fibre-reactive chitosan derivative containing quaternary ammonium groups, O -acrylamidomethyl- N -[(2-hydroxy-3-trimethylammonium)propyl]chitosan chloride (NMA-HTCC). Cotton treated with NMA-HTCC has been dyed with direct and reactive dyes without the addition of salt. The colour yield was higher than that on untreated cotton, despite the addition of a large amount salt in the latter case. After dyeing, cotton treated with NMA-HTCC gave better wash fastness than the untreated cotton. The light fastness was however inferior to that on untreated cotton. The antimicrobial activity of cotton treated with NMA-HTCC against Staphylococcus aureus was considerably lower after dyeing, probably due to the antimicrobial effect of the cationic group on NMA-HTCC being blocked by its combination with the anionic dye. [source]


Co-application of hydroxyalkyl dyes and polyphosphonic acids to cotton to achieve dye,fibre covalent bonding

COLORATION TECHNOLOGY, Issue 6 2001
Estelle L Gillingham
The dyeing of cotton to a high standard of wet-fastness with hydroxyalkyl dyes and a polyphosphonatecrosslinker system has been investigated. Dyes containing hydroxyalkyl groups were prepared, by the reaction of commercial reactive dyes with ethanolamine, and applied to cotton fabric in the presence of polyphosphonic acid crosslinking agents using cyanamide as a catalyst. The application was carried out using a pad-thermosol method. The effects of cyanamide concentration, the nature of the crosslinker and the type of hydroxyalkyl dye were studied in detail. It was concluded that multifunctional polyphosphonates are capable of producing dyeings on cellulosic fibres exhibiting a high degree of covalent bonding (fixation). The efficiency of dye fixation at ca. 2% pure dye (owf), obtained from this method, was greater than 90%. [source]


Modeling multi-stage decomposition of cotton fabrics considering char oxidation in the presence of oxygen

FIRE AND MATERIALS, Issue 8 2009
F. L. Zhu
Abstract A theoretical model, describing thermal degradation behavior of cotton fabrics that exposed to a constant radiant heat flux, is proposed in the paper. The model describes thermal and oxidative degradation of cotton fabric under the oxygen-containing atmosphere and considers pseudo-bi-component separate-stage kinetic process. Both exothermic and endothermic reactions are included in the decomposition process. At present, gas phase oxidation reactions are not included. Comparison with experimental results demonstrates that the predictions of the mass loss rate and temperature profile with these cotton fabrics are in agreement with the experiment. Effects of thermal radiation and ambient oxygen concentration on decomposition have also been investigated. The gas phase temperature is also predicted by the present numerical model. Results from numerical model will help contribute to a better understanding of the ignition mechanism of flame-resistant cotton fabrics used for fire safety garments. Copyright © 2009 John Wiley & Sons, Ltd. [source]


Polyurethane/clay and polyurethane/POSS nanocomposites as flame retarded coating for polyester and cotton fabrics

FIRE AND MATERIALS, Issue 4-5 2002
Eric Devaux
Polyurethane resins (PU) are widely used as coatings for textile fabrics in order to improve some properties (for example mechanical behaviour, water repellency and air impermeability). Two kinds of additives have been added to the polyurethane in order to provide flame retardancy to the coated textile structure: montmorillonite clay and polyhedral oligomeric silsesquioxanes (POSS) have been used to process PU nanocomposites. The paper presents some results obtained with PU/clay and PU/POSS coated polyester or cotton fabrics, using cone calorimetry and thermogravimetric analysis. The efficiency of the additive chosen is clearly demonstrated and discussed. In particular, the great potential of using POSS for fire retardant applications is highlighted. Copyright © 2002 John Wiley & Sons, Ltd. [source]


Tetrakis(trimethysilyl)hypophosphate P2O2(OTMS)4: Synthesis, reactivity and application as flame retardant

HETEROATOM CHEMISTRY, Issue 7 2007
Catherine Ruflin
The preparation of tetrakis(trimethy- silyl)hypophosphate, P2O2(OTMS)4 (TMS = SiMe3), which is easily obtained from cheap starting materials, is reported. Reaction with protic substrates (H2O, alcohols) proceeds under stepwise cleavage of silylethers, ROTMS, and formation of hypophosphoric acid, P2O2(OH)4. Amines in the presence of molecular sieves lead to desilylation and formation of ammonium salts of the [P2O2(OTMS)2(O,)2] dianion. On cotton fabrics, P2O2(OTMS)4 hydrolyzes to give P2O2(OH)4 within about 1 h when exposed to air, and this compound acts as an efficient flame retardant (limiting oxygen index >26%) even at low loadings (P content <3%). © 2007 Wiley Periodicals, Inc. Heteroatom Chem 18:721,731, 2007; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/hc.20373 [source]


Experimental study of a new shock pre-drying method for cotton fabrics

INTERNATIONAL JOURNAL OF ENERGY RESEARCH, Issue 9 2007
I. Tarakç
Abstract This paper reveals a new method for drying of textiles with the combination of vacuum-extraction and convective drying methods. The new method provides an inconceivable fast drying due to the synergistic effect of heat energy and mechanical forces. During vacuum extraction, hot air or superheated steam was applied as suction in place of air at room temperature and named as shock pre-drying. Vacuum extraction and shock pre-drying of cotton woven fabrics were performed at several working speeds between 1 and 30 m min,1 and the drying effects were compared. It was observed that it was possible to obtain effective pre-drying in , s or less time with shock pre-drying method. The method's water removal efficiency mainly depends on working speed and hot air or superheated steam temperature. Copyright © 2006 John Wiley & Sons, Ltd. [source]


Water-repellent finishing of cotton fabrics by ultraviolet curing

JOURNAL OF APPLIED POLYMER SCIENCE, Issue 2 2008
F. Ferrero
Abstract Cotton fabrics were water-repellent-finished by radical ultraviolet curing of silicone and urethane acrylates with different formulations. The fabrics were impregnated with undiluted resins and with toluene solutions or water emulsions. Moreover, cationic ultraviolet-curable systems were also investigated, such as an epoxy-functional polysiloxane and mixtures of an epoxy resin with hydroxyl-containing silicone additives. The gel content and polymerization yield were considered for the ultraviolet-curing process evaluation. Water-resistance properties were determined in terms of the contact angle, wettability, moisture adsorption, and water vapor permeability measurements, whereas the morphology and surface composition of treated fabrics were examined with scanning electron microscopy and energy-dispersive X-ray analysis. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 [source]


Durable antimicrobial finish of cotton fabrics

JOURNAL OF APPLIED POLYMER SCIENCE, Issue 2 2007
Eun S. Bang
Abstract Cotton fabrics were treated with Biopag, which does not have any functional groups that are reactive toward cellulose, using crosslinking agents or a binder, for the purpose of imparting a durable antimicrobial finish. In this respect, it was found that the crosslinking agents were more effective than the binder. It was confirmed by FT-IR that the characteristic split peaks of Biopag were still seen even after repeated launderings. The crosslinking agents deteriorated the whiteness and tensile strength of the Biopag-treated cotton fabrics, while the wrinkle recovery angles (WRAs) were significantly improved. The one-step padding of Biopag and the crosslinking agent was found to be superior to the two-step padding method in which Biopag padding was followed by padding of crosslinking agent in respect of WRA, whereas the whiteness and tensile strength were vice versa. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2007 [source]


Development of flame retardancy properties of new halogen-free phosphorous doped SiO2 thin films on fabrics

JOURNAL OF APPLIED POLYMER SCIENCE, Issue 6 2007
Aysun Cireli
Abstract In this study, flame retardancy properties of fabrics treated with phosphorous (P) doped and undoped SiO2 thin films were developed by sol,gel technique. As to this aim, P-doped and undoped SiO2 film were coated on cotton fabric from the solutions prepared from P, Si-based precursors, solvent, and chelating agent at low temperature in air using sol,gel technique. To determine solution characteristics, which affect thin film structure, turbidity, pH values, and rheological properties of the prepared solutions were measured using a turbidimeter, a pH meter, and a rheometer machines before coating process. The thermal, structural, and microstructural characterization of the coating were done using differential thermal analysis/thermograviometry, fourier transform infrared spectroscopy, X-ray diffractometry, and scanning electron microscopy. In addition, tensile strength, wash fastness, flame retandancy, and lightness properties of the coated fabrics were determined. To compensate the slight loss of tensile strength of samples, which occurred at the treated fabrics with P-doped Si-based solutions, the cotton fabrics were coated with polyurethane films during second step. In conclusion, the flame retardant cotton fabric with durability of washing as halogen-free without requiring after treatment with formaldehyde was fabricated using sol,gel processing for the first time. Moreover the cotton fabrics, which were treated with P-doped Si-based solutions and then coated with polyurethane at second step, still has got nonflammable property. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2007 [source]


A novel approach to excellent UV protecting cotton fabric with functionalized MWNT containing water vapor permeable PU coating

JOURNAL OF APPLIED POLYMER SCIENCE, Issue 5 2007
S. Mondal
Abstract This research paper presented a novel approach of developing excellent protection from ultraviolet (UV) radiation of cotton fabrics by means of water vapor permeable (WVP) coatings containing multiwall carbon nanotube (MWNT), a stable and strongly UV absorbing species. The WVP of MWNT containing UV protective coatings of the present development are formed from solution polymer of hydrophilic polyurethane (HPU). MWNTs were dispersed in HPU solution by functionalization of MWNT. The nanotube containing HPU coating shows excellent protection against UV radiation, with only 1 wt % of MWNT (calculated based on solid content of the polymer), a UV Protection Factor (UPF) of 174 and with 2.5 wt % of MWNT a UPF of 421 was obtained, which stated excellent protection (UPF ,50) according to the Australian/New Zealand standards. Scanning electron micrographs of coated fabrics surface showed a film like polymer coating, confirming the fabric surface was successfully coated by polyurethane. The coated fabrics would maintain very good water vapor permeability, hence confirmed the wearing comfort. Room temperature (20,23°C) range soft segment crystal melting of HPU enhances the permeability of coated fabrics. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 103: 3370,3376, 2007 [source]


Effect of adsorption characteristics of a modified cellulase on indigo backstaining

JOURNAL OF CHEMICAL TECHNOLOGY & BIOTECHNOLOGY, Issue 6 2004
Diomi Mamma
Abstract The effect of limited proteolysis (digestion) of a commercial cellulase preparation (Ecostone® L350) on backstaining with indigo was investigated. The influence of protease (papain) concentration on limited proteolysis of cellulase preparation was studied, applying different ratios of papain/cellulase (w/w). Changes in adsorption on Avicel cellulose of the non-digested compared with the papain-digested Ecostone® L350 were examined using the Langmuir adsorption isotherm. The non-digested Ecostone® L350 exhibited stronger interaction to Avicel cellulose compared with the digested form, while the maximum efficiency of cellulase adsorption to Avicel cellulose decreased after digestion. When papain-digested Ecostone® L350 was applied on cotton fabrics during the dyeing procedure with indigo, a reduction of indigo backstaining was obtained compared with the non-digested Ecostone® L350. Copyright © 2004 Society of Chemical Industry [source]


Transfer of Triazine-iron(II) Chromic Complexes Left by Iron Items on Textile Background and Human Skin

JOURNAL OF FORENSIC SCIENCES, Issue 4 2010
Jakub Szumera M.Sc.
Abstract:, The research is focused on the detection and transfer of iron traces left by iron items on clothing and human skin. The method is based on the formation of colored complexes between ferrous ions and five synthesized, mostly new triazines. Iron traces originally were left by iron rings on slightly wetted (artificial sweat) cotton fabrics and subsequently transferred to a separate textile substrate. Prior to the use of trazines the contact spots were treated with a new inorganic reducing agent (Sn2+) to reduce Fe3+ to Fe2+. The method is sensitive to detect iron traces on wetted canvas after 10 min contact with iron items. More spectacular results were obtained for traces left on human palm even after very short contact (10 sec). The new iron-trace-transfer method eliminated the contact of triazines solutions with human skin. Transmission visible spectra of Fe(II),triazine complexes were determined. [source]


Effects of a cationic diblock copolymer derived from [2-(methacryloyloxy)-ethyl]trimethylammonium chloride in the dyeing of cotton with reactive dye

COLORATION TECHNOLOGY, Issue 4 2008
Shin Young Han
A cationic diblock copolymer (PEO45 -MeDMA) derived from [2-(methacryloyloxy)-ethyl]trimethylammonium chloride (MeDMA) gave a positive charge to a cotton surface and provided strong attraction to an anionically charged reactive dye. PEO45 -MeDMA was used as the cotton pretreatment. The dyeability of cationised cotton fabrics using CI Reactive Blue 250 was found to be dependent on the PEO45 -MeDMA concentration. The colour strength and fastness properties of the dyed fabrics using the PEO45 -MeDMA copolymer and sodium sulphate were compared. The dyeability of the cotton fabrics pretreated with PEO45 -MeDMA indicated higher dye uptake than that of sodium sulphate. This suggests that the pretreatment of cotton by PEO45 -MeDMA diblock copolymer can be considered as an alternative to the use of the exhausting agent sodium sulphate. [source]