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Selected AbstractsGrayscale Photopatterning of an Amorphous Polymer Thin Film Prepared by Photopolymerization of a Bisanthracene-Functionalized Liquid-Crystalline MonomerADVANCED FUNCTIONAL MATERIALS, Issue 10 2010Hideyuki Kihara Abstract A method for grayscale photopatterning of an amorphous polymer film derived from a bisanthracene-functionalized liquid-crystalline monomer is developed. Solution photopolymerization of a monomer with two anthracene moieties, one at each end, affords an amorphous polymer. A combination of irradiation with patterned UV light and heating results in photopatterning on thin films prepared from the polymer. On non-irradiated areas of the film, the polymer reverts to the monomer owing to the thermal back-reaction of the anthracene photodimer, forming an ordered phase. On irradiated areas remaining in the amorphous phase, the thermal back-reaction is suppressed. This phenomenon results in a clear contrast and visual images on the film under polarized light. Grayscale photopatterning is also made possible for the solution-polymerized polymer by controlling the intensity of exposure. In addition, rewritable photopatterning can be achieved by melt photopolymerization of the monomer. The new photopatterning is essentially nondestructive because it needs neither image development nor anthracene-excitation light for reading. [source] Skin moisturization by hydrogenated polyisobutene,Quantitative and visual evaluationINTERNATIONAL JOURNAL OF COSMETIC SCIENCE, Issue 1 2010N. Dayan J. Cosmet. Sci., 60, 15,24 (January/February 2009) Synopsis Hydrogenated polyisobutene (HP) is used in topically applied cosmetic/personal care formulations as an emollient that leaves a pleasing skin feel when applied, and rubbed in after application. This effect, although distinguishable to the user, is difficult to define and quantify. Recognizing that some of the physical properties of HP such as film formation and wear resistance may contribute, in certain mechanisms, to skin moisturization, we designed a short-term pilot study to follow changes in skin moisturization. HP's incorporation into an o/w emulsion at 8% yielded increased viscosity and reduced emulsion droplet size as compared to the emollient ester CCT (capric/caprylic triglyceride) or a control formulation. Quantitative data indicate that application of the o/w emulsion formulation containing either HP or CCT significantly elevated skin moisture content and thus reduced transepidermal water loss (TEWL) by a maximal ,33% against the control formulation within 3 h and maintained this up to 6 h. Visual observation of skin treated with the HP-containing formulation showed fine texture and clear contrast as compared to the control or the CCT formulation, confirming this effect. As a result of increased hydration, skin conductivity, as measured in terms of corneometer values, was also elevated significantly by about tenfold as early as 20 min after HP or CCT application and was maintained throughout the test period. Throughout the test period the HP formulation was 5,10% more effective than the CCT formulation both in reduction of TEWL as well as in increased skin conductivity. Thus, compared to the emollient ester (CCT), HP showed a unique capability for long-lasting effect in retaining moisture and improving skin texture. [source] Welfare reform and future challenges in the Republic of Korea: Beyond the developmental welfare state?INTERNATIONAL SOCIAL SECURITY REVIEW, Issue 4 2002ju Kwon Since the economic crisis of 1997,98, the Republic of Korea has carried out vigorous social policy initiatives including the reform of the National Pension Programme and National Health Insurance. This paper seeks to answer whether the country's welfare state has moved beyond welfare developmentalism, by examining the cases of those two programmes. By the reform, the coverage of the National Pension Programme was extended to the whole population; and its financial sustainability and accountability were enhanced. Regarding National Health Insurance, efficiency reform was carried out on the management structure, while reform regarding financing was put on hold. These reforms were in clear contrast to the welfare developmentalism that used to place overwhelming emphasis on economic considerations. Despite these reforms, however, the Republic of Korea's welfare state faces the issues of ineffectual implementation and lack of financial sustainability of social policy. The National Pension Programme has failed to cover the majority of irregular workers, whose numbers are on the increase, and National Health Insurance needs to find a way to meet increasing health expenditure. [source] SHRIMP zircon and EPMA monazite dating of granitic rocks from the Maizuru terrane, southwest Japan: Correlation with East Asian Paleozoic terranes and geological implicationsISLAND ARC, Issue 3 2008Masahiro Fujii Abstract The Maizuru terrane, distributed in the Inner Zone of southwest Japan, is divided into three subzones (Northern, Central and Southern), each with distinct lithological associations. In clear contrast with the Southern zone consisting of the Yakuno ophiolite, the Northern zone is subdivided into the western and eastern bodies by a high-angle fault, recognized mainly by the presence of deformed granitic rocks and pelitic gneiss. This association suggests an affinity with a mature continental block; this is supported by the mode of occurrence, and petrological and isotopic data. Newly obtained sensitive high mass-resolution ion microprobe (SHRIMP) zircon U,Pb ages reveal the intrusion ages of 424 ± 16 and 405 ± 18 Ma (Siluro,Devonian) for the granites from the western body, and 249 ± 10 and 243 ± 19 Ma (Permo,Triassic) for the granodiorites from the eastern body. The granites in the western body also show inherited zircon ages of around 580 and 765 Ma. In addition, electron probe microanalysis (EPMA) monazite U,Th,total Pb dating gives around 475,460 Ma. The age of intrusion, inherited ages, mode of occurrence, and geological setting of the Siluro,Devonian granites of the Northern zone all show similarities with those of the Khanka Massif, southern Primoye, Russia, and the Hikami granitic rocks of the South Kitakami terrane, Northeast Japan. We propose that both the Siluro,Devonian and Permo,Triassic granitic rocks of the Northern zone are likely to have been juxtaposed through the Triassic,Late Jurassic dextral strike-slip movement, and to have originated from the Khanka Massif and the Hida terrane, respectively. This study strongly supports the importance of the strike-slip movement as a mechanism causing the structural rearrangement of the Paleozoic,Mesozoic terranes in the Japanese Islands, as well as in East Asia. [source] Expression patterns of hair and epithelial keratins and transcription factors HOXC13, LEF1, and ,-catenin in a malignant pilomatricoma: a histological and immunohistochemical studyJOURNAL OF CUTANEOUS PATHOLOGY, Issue 1 2006Bernard Cribier Background:, We have previously shown that benign pilomatricomas not only maintain the sequential expression of the hair matrix and precortex keratins hHa5 and hHa1 of normal hair follicles in their transitional cell compartment, but also preserve the association of hHa5 expression with that of its regulatory homeoprotein HOXC13 in the lower transitional cell compartment. In contrast, hHa1 expression in the upper transitional cell compartment is uncoupled from the nuclear co-expression of the LEF1/,-catenin complex seen in normal hair follicles (Cribier et al., J Invest Dermatol 2004; 122: 1078). Methods:, Formalin-fixed paraffin sections of the tumor were examined using a panel of mono- and polyclonal hair and epithelial keratin antibodies as well as antibodies against HOXC13, LEF1, and ,-catenin. Results:, Morphologically, the malignant pilomatricoma investigated here clearly deviated from the described major tumor type by a large number of differently sized parakeratotic squamoid whorls emerging within the mass of basaloid cells and surrounded by cells remembering transitional cells, but only rarely containing shadow cells and signs of calcification. We show that hHa5/HOXC13 co-expression was maintained in transitional cell areas, in which hHa1 expression was much stronger than in benign pilomatricomas, but again uncoupled from concomitant nuclear LEF1/,-catenin expression. Surprisingly, however, and in clear contrast to benign pilomatricomas, these transitional cells co-expressed the epithelial keratins K5, K14, and K17, with the latter being as strongly expressed as hHa1, both also staining the entire inner mass of the parakeratotic whorls. Conclusions:, Although the malignant pilomatricoma investigated here was distinctive in that it contained a multitude of parakeratinizing whorls and no signs of calcification, it shared both hHa5/HOXC13 co-expression and disrupted hHa1/,-catenin,LEF1 expression in its transitional cell compartment around the whorls with benign pilomatricomas. However, in clear contrast to the latter, transitional cells of the malignant tumor also strongly expressed the epithelial keratins K5, K14, and K17. We speculate that the observed dominance of the epithelial differentiation pathway over the competing conventional shadow cell differentiation pathway may prevent massive calcification of the tumor. [source] Improvement in Latent Fingerprint Detection on Thermal Paper Using a One-Step Ninhydrin Treatment with Polyvinylpyrrolidones (PVP)JOURNAL OF FORENSIC SCIENCES, Issue 4 2010Lothar Schwarz Dr. Phil. Abstract:, Most thermosensitive surfaces of thermal paper turn black when they come into contact with polar organic solvents such as are used in ninhydrin petroleum benzin solution. This dark staining reduces the contrast between the developed fingerprint and the background to such an extent that the identification process becomes very difficult. Integrating polyvinylpyrrolidones (PVP) into a ninhydrin solution prevents the black staining, and the developed fingerprints appear in clear contrast to the background. The new ninhydrin solution containing PVP is successful compared to the two-step ninhydrin,acetone washing method for thermal paper which is popular in Germany. [source] Optimal search for a moving target with the option to waitNAVAL RESEARCH LOGISTICS: AN INTERNATIONAL JOURNAL, Issue 6 2009János Flesch Abstract We investigate the problem in which an agent has to find an object that moves between two locations according to a discrete Markov process (Pollock, Operat Res 18 (1970) 883,903). At every period, the agent has three options: searching left, searching right, and waiting. We assume that waiting is costless whereas searching is costly. Moreover, when the agent searches the location that contains the object, he finds it with probability 1 (i.e. there is no overlooking). Waiting can be useful because it could induce a more favorable probability distribution over the two locations next period. We find an essentially unique (nearly) optimal strategy, and prove that it is characterized by two thresholds (as conjectured by Weber, J Appl Probab 23 (1986) 708,717). We show, moreover, that it can never be optimal to search the location with the lower probability of containing the object. The latter result is far from obvious and is in clear contrast with the example in Ross (1983) for the model without waiting. © 2009 Wiley Periodicals, Inc. Naval Research Logistics 2009 [source] Another Textual Frontier: Contemporary Fiction on the Northern Mexican BorderBULLETIN OF LATIN AMERICAN RESEARCH, Issue 1 2002Nú Vilanova This article approaches fiction writing from the northern Mexican frontier from the perspective of the border. It perceives the border between Mexico and the United States as a multispace that permeates fictional texts from the area. In clear contrast with most Chicano and Border Studies perspectives, the border is viewed here as a physical rather that metaphorical space whose dynamics formulates textual discourses and aesthetics. The fiction works of Luis Humberto Crosthwaite and Jesús Gardea are analysed from this perspective. 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