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Chemical Variations (chemical + variation)

Distribution by Scientific Domains

Polymers and Materials Science	28%

Selected Abstracts

Chemical variation in the essential oils of Hyptis crenata Pohl ex Benth.

FLAVOUR AND FRAGRANCE JOURNAL, Issue 1 2002
Maria das Graças B. Zoghbi
Abstract Essential oils from Hyptis crenata growing wild in the Amazon Region were submitted to hydrodistillation and analysed by GC,MS. The main compounds identified in the oil of specimen A, collected at Porto Nacional, State of Tocantins, were terpinolene (37.8%) and ,-caryophyllene (9.9%). The major components found in the oils of specimens B, collected at São Sebastião da Boa Vista, State of Par a, were 1,8-cineole (23.9%), borneol (21.8%) and ,-caryophyllene (18.8%). The oils of specimens C and D, collected at Melgaço, Marajó Island, State of Pará, were dominated by ,-pinene (51.1%; 14.5%), 1,8-cineole (16.5%; 36.7%), limonene (15.0%; ,) and ,-pinene (10.3%; 7.9%), respectively. Copyright © 2001 John Wiley & Sons, Ltd. [source]

Chemical variation within fragments of Australasian tektites

METEORITICS & PLANETARY SCIENCE, Issue 6 2005
Trinh Hai SON
No data for intra-sample trace element variations existed. Thus, we sectioned a Muong Nong-type tektite fragment from Vietnam and a splash-form tektite fragment from the Philippines into eleven and six pieces, respectively, and analyzed the individual fragments for major and trace element contents. The compositions obtained agree well with those found in previous studies, supporting argument that tektites have been derived from terrestrial upper crustal sediments. Chemical variations within the tektite fragments are present, but do not show any systematic trends, probably reflecting incomplete mixing of parent rocks. The intra-sample heterogeneity of the Muong Nong-type tektite is more pronounced than that in the philippinite. For the Muong Nong-type tektite, the intra-sample variation in the trace element contents is higher than that for the major elements, again reflecting target rock properties. For the philippinite the intra-sample variations mostly do not exceed the limits imposed by the precision of the analytical data, confirming that the splash form tektites are indeed well homogenized. [source]

Petrography, mineralogy, and trace element geochemistry of lunar meteorite Dhofar 1180

METEORITICS & PLANETARY SCIENCE, Issue 9 2009
Aicheng Zhang
Dhofar 1180 is predominantly composed of fine-grained matrix with abundant mineral fragments and a few lithic and glassy clasts. Lithic clasts show a variety of textures including cataclastic, gabbroic, granulitic, ophitic/subophitic, and microporphyritic. Both feldspathic and mafic lithic clasts are present. Most feldspathic lithic clasts have a strong affinity to ferroan anorthositic suite rocks and one to magnesian suite rocks. Mafic lithic clasts are moderately to extremely Fe-rich. The Ti/[Ti+Cr]-Fe/[Fe+Mg] compositional trend of pyroxenes in mafic lithic clasts is consistent with that of low-Ti mare basalts. Glasses display a wide chemical variation from mafic to feldspathic. Some glasses are very similar to those from Apollo 16 soils. KREEP components are essentially absent in Dhofar 1180. One glassy clast is rich in K, REE and P, but its Mg/[Mg+Fe] is very low (0.25). It is probably a last-stage differentiation product of mare basalt. Molar Fe/Mn ratios of both olivine and pyroxene are essentially consistent with a lunar origin. Dhofar 1180 has a LREE-enriched (La 18 × CI, Sm 14 × CI) pattern with a small positive Eu anomaly (Eu 15 × CI). Th concentration is 0.7 ppm in Dhofar 1180. Petrography, mineralogy, and trace element geochemistry of Dhofar 1180 are different from those of other lunar meteorites, indicating that Dhofar 1180 represents a unique mingled lunar breccia derived from an area on the lunar nearside but far away from the center of the Imbrium Basin. [source]

Bio-mimetic scaling of mechanical behavior of thin films, coatings, and surfaces by Laser Interference Metallurgy

ADVANCED ENGINEERING MATERIALS, Issue 9 2005
C. Daniel
Biological solutions to enhance strength and stability often use hierarchical composite structures. The effect is not based on large chemical variations, but instead is realized by structural composites with long-range order. Laser Interference Metallurgy is a newly developed technique that utilizes this biological approach to optimize the mechanical properties of surfaces and thin films. The possibility of scaling mechanical properties is quantitatively analyzed and compared with the biological approach. [source]

Mechanical Gradient Cues for Guided Cell Motility and Control of Cell Behavior on Uniform Substrates

ADVANCED FUNCTIONAL MATERIALS, Issue 18 2009
Barbara Cortese
Abstract A novel method for the fabrication and the use of simple uniform poly(dimethylsiloxane) PDMS substrates for controlling cell motility by a mechanical gradient is reported. The substrate is fabricated in PDMS using soft lithography and consists of a soft membrane suspended on top of a patterned PDMS substrate. The difference in the gradient stiffness is related to the underlying pattern. It is shown experimentally that these uniform substrates can modulate the response of cell motility, thus enabling patterning on the surfaces with precise cell motility. Because of the uniformity of the substrate, cells can spread equally and a directional movement to stiffer regions is clearly observed. Varying the geometry underlying the membrane, cell patterning and movement can be quantitatively characterized. This procedure is capable of controlling cell motility with high fidelity over large substrate areas. The most significant advance embodied in this method is that it offers the use of mechanical features to control cell adhesion and not topographical or chemical variations, which has not been reported so far. This modulation of the response of cell motility will be useful for the design and fabrication of advanced planar and 3D biological assemblies suitable for applications in the field of biotechnology and for tissue-engineering purposes. [source]

A counter-clockwise P,T path for the Voltri Massif eclogites (Ligurian Alps, Italy)

JOURNAL OF METAMORPHIC GEOLOGY, Issue 7 2005
G. VIGNAROLI
Abstract Integrated petrological and structural investigations of eclogites from the eclogite zone of the Voltri Massif (Ligurian Alps) have been used to reconstruct a complete Alpine P,T deformation path from burial by subduction to subsequent exhumation. The early metamorphic evolution of the eclogites has been unravelled by correlating garnet zonation trends with the chemical variations in inclusions found in the different garnet domains. Garnet in massive eclogites displays typical growth zoning, whereas garnet in foliated eclogites shows rim-ward resorption, likely related to re-equilibration during retrogressive evolution. Garnet inclusions are distinctly different from core to rim, consisting primarily of Ca-, Na/Ca-amphibole, epidote, paragonite and talc in garnet cores and of clinopyroxene ± talc in the outer garnet domains. Quantitative thermobarometry on the inclusion assemblages in the garnet cores defines an initial greenschist-to-amphibolite facies metamorphic stage (M1 stage) at c. 450,500 °C and 5,8 kbar. Coexistence of omphacite + talc + katophorite inclusion assemblage in the outer garnet domains indicate c. 550 °C and 20 kbar, conditions which were considered as minimum P,T estimates for the M2 eclogitic stage. The early phase of retrograde reactions is polyphase and equilibrated under epidote,blueschist facies (M3 stage), characterized by the development of composite reaction textures (garnet necklaces and fluid-assisted Na-amphibole-bearing symplectites) produced at the expense of the primary M2 garnet-clinopyroxene assemblage. The blueschist retrogression is contemporaneous with the development of a penetrative deformation (D3) that resulted in a non-coaxial fabric, with dominant top-to-the-N sense of shear during rock exhumation. All of that is overprinted by a texturally late amphibolite/greenschist facies assemblages (M4 & M5 stages), which are not associated with a penetrative structural fabric. The combined P,T deformation data are consistent with an overall counter-clockwise path, from the greenschist/amphibolite, through the eclogite, the blueschist to the greenschist facies. These new results provide insights into the dynamic evolution of the Tertiary oceanic subduction processes leading to the building up of the Alpine orogen and the mechanisms involved in the exhumation of its high-pressure roots. [source]